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A viable anode of atomic Sb with a super-coordinated O2Sb1N4 structure anchored on N-doped micropore carbon nanosheets (O–Sb–N SA@NC) is developed, demonstrating significantly enhanced performance in both half and full potassium-ion batteries.

Purpose The purpose of this paper is to develop high-performance Au-coated Ag alloy wires (ACAA wires) and demonstrate the effect of Au coating layers on the bonding performance and oxidation resistance for stable and reliable electronic packaging applications. Design/methodology/approach ACAA wire with a diameter of approximately 25 µm and Au layer thickness of approximately 100 nm were prepared by the continuous casting, plating and wire drawing method. The bonding performance of the ACAA wires were studied through bonding on 3,535 chips. The oxidation resistance of ACAA wires and Ag alloy wires (AA wires) were comparatively studied by means of chemical oxidation tests, accelerated life tests and electrochemical tests systematically. Findings ACAA wires could form axi-symmetrical spherical free air balls with controllable diameter of 1.5∼2.5 times of the wire diameter after electric flame-off process. The ball shear strength of ACAA wire was higher than that of AA wires. Most importantly, because of the surface Au coating layer, the oxidation resistance of ACAA wires was much enhanced. Research limitations/implications ACAA wires with different lengths of heat affected zone were not developed in this study, which limited their application with different loop height requirements. Practical implications With higher bonding strength and oxidation resistance, ACAA wires would be a better choice than previous reported AA wire in chip packaging which require high stability and reliability. Originality/value This paper provides a kind of novel ACAA wire, which possess the merits of high bonding strength and reliability, and show great potential in electronic packaging applications.

Constructing 3D skeletons modified with lithiophilic seeds has proven effective in achieving dendrite-free lithium metal anodes. However, these lithiophilic seeds are mostly alloy- or conversion-type materials, and they tend to aggregate and redistribute during cycling, resulting in the failure of regulating Li deposition. Herein, we address this crucial but long-neglected issue by using intercalation-type lithiophilic seeds, which enable antiaggregation owing to their negligible volume expansion and high electrochemical stability against Li. To exemplify this, a 3D carbon-based host is built, in which ultrafine TiO

Carbonaceous materials featuring both ordered graphitic structure and disordered defects hold great promise for high-performance K-ion batteries (KIBs) due to the concurrent advantages of high electronic conductivity, fast and reversible K

Underwater acoustic sensor networks (UASNs) have gradually received attention due to their widespread applications, such as in disaster prevention, environmental monitoring and military activities, and they simultaneously face security challenges. In recent years, trust management mechanisms have become important tools for responding to internal attackers. However, most of the existing trust management mechanisms do not consider the adverse influence of complex underwater environment on node evaluation, and do not deal with the case that normal nodes are misjudged as malicious nodes. To achieve accurate trust evaluation of nodes and reduce the possibility of misjudgment of normal nodes, a redeemable Support Vector Machine-Dempster-Shafer (SVM-DS) fusion-based trust management mechanism (SDFTM) is proposed for UASNs in this paper. First, according to the characteristics of attacks, three kinds of trust evidence are selected: packet-based evidence, data-based evidence and energy-based evidence. Then the support vector machine (SVM) is applied to classify the trust of node from the aspect of each kind of trust evidence, while Dempster-Shafer (DS) evidence theory is used to fuse the different trust classification results of nodes. Second, to deal with cases where a normal node may be misclassified as a malicious node, trust redemption process is carried out based on the historical performance and environmental influence (unreliable acoustic channel, weak link connectivity). Finally, the trust value is calculated and updated. The simulation results prove that the proposed scheme yields satisfactory performance in malicious detection and reduce the possibility of misjudgment of normal nodes.

Owing to the dramatically enhanced charge-mass transport and abundant electrochemically active sites, transition metal compound electrodes are increasingly attractive for achieving high-performance supercapacitors (SCs). Here, we report the fabrication of nickel foam supported three-dimensional (3D) branched nickel–cobalt phosphides@tri-metal cobalt–nickel-molybdenum phosphides core/shell nanowire heterostructures (denoted as NiCo-P@CoNiMo-P) as high-performance electrode materials for hybrid supercapacitors. The presence of multiple valences of the cations in such NiCo-P@CoNiMo-P enables rich redox reactions and promoted synergy effects. Benefiting from their collective effects, the resulting electrode demonstrates high specific capacity of 1366 C g−1 at 2 A g−1 (2.03 C cm−2 at 2 mA cm−2) and 922 C g−1 at 10 A g−1, as well as good cycling stability (retaining ~ 94% of the initial capacity after 6000 cycles at 15 A g−1). A hybrid SC using the NiCo-P@CoNiMo-P as the positive electrode and N-doped rGOs as the negative electrode exhibits a high energy density of 81.4 Wh kg−1 at a power density of 1213 W kg−1 and a capacity retention of 132% even after 6000 cycles at 10 A g−1. Our findings can facilitate the material design for boosting the performance of transition metal compounds based materials for fast energy storage.

Topography and soil factors are known to play crucial roles in the species composition of plant communities in subtropical evergreen-deciduous broadleaved mixed forests. In this study, we used a systematic quantitative approach to classify plant community types in the subtropical forests of Hubei Province (central China), and then quantified the relative contribution of drivers responsible for variation in species composition and diversity. We classified the subtropical forests in the study area into 12 community types. Of these, species diversity indices of three communities were significantly higher than those of others. In each community type, species richness, abundance, basal area and importance values of evergreen and deciduous species were different. In most community types, deciduous species richness was higher than that of evergreen species. Linear regression analysis showed that the dominant factors that affect species composition in each community type are elevation, slope, aspect, soil nitrogen content, and soil phosphorus content. Furthermore, structural equation modeling analysis showed that the majority of variance in species composition of plant communities can be explained by elevation, aspect, soil water content, litterfall, total nitrogen, and total phosphorus. Thus, the major factors that affect evergreen and deciduous species distribution across the 12 community types in subtropical evergreen-deciduous broadleaved mixed forests include elevation, slope and aspect, soil total nitrogen content, soil total phosphorus content, soil available nitrogen content and soil available phosphorus content., Highlights • Plant community structure and species composition were studied in evergreen-deciduous broadleaved mixed forests in northwestern Hubei Province (central China). • We identified environmental factors, including topography and soil content, that drive plant community structure and species composition. • The major factors that affect species distribution in subtropical forests include elevation and soil available phosphorus content.

One environmentally friendly method used to manage Bactrocera dorsalis (Hendel), a key agricultural pest of substantial economic importance, is the sterile insect technique (SIT). Nevertheless, several deficiencies related to this strategy impair the success of the SIT, including the inferior performance of released sterile males compared with wild males, which could be partly solved by the utilization of gut symbionts as probiotic dietary components. In this study, a culture-dependent method was used to isolate and characterize gut-associated bacterial species in adult B. dorsalis genetic sexing strain (GSS) males. In addition, three bacterial isolates from the Enterobacteriaceae family, namely, Enterobacter sp., Morganella morganii, and Moellerella wisconsensis, were used as supplements in larval and adult diets to assess their effects on the life-history traits of irradiated males. Consistent with many previous studies, Enterobacter spp. was shown to be beneficial, with some quality control indices, such as adult size, pupal weight, survival rate under stress and nutritionally rich conditions, and mating competitiveness, being significantly increased, while slight nonsignificant increases in emergence rate and flight ability were observed. Conversely, the M. morganii and M. wisconsensis strains both had negative effects on irradiated male fitness and mating competitiveness. Our results, in combination with those of earlier studies, can contribute to improving the effectiveness of SIT application by enhancing the different aspects of augmentative rearing and biological traits of pests under laboratory rearing conditions.

Low silver Sn-0.3Ag-0.7Cu (SAC0307) composite solder reinforced with graphene nanosheets (GNs) was prepared by powder metallurgy techniques, and the effects of GN content on the melting characteristics, wettability, microhardness and shear strength of the composite solder were investigated. The wettability and microhardness of the composite solder increased significantly, and the initial melting temperature decreased slightly with increasing doping content of GNs, the wettability and microhardness of the composite solder increased significantly, but the initial melting temperature decreased slightly. When the GN content reaches 0.01 wt.%, the wettability angle of the composite solder decreases by ∼ 29%. When the content of GNs reaches 0.09 wt.%, composite solder of microhardness is up to 15.3 HV, approximately 1.12 times larger than that of the un-doped SAC0307 solder. At the same time, it is also found that the shear strength of the composite solder increases with the increase of GN content. When reaching 0.05 wt.%, the shear strength is the highest (24.70 MPa) and then presents a downward trend. In addition, the fracture morphology of microscale solder joints exhibits a typical ductile fracture character to the brittle one with increasing GN content.

Cysteine (Cys) is well-known to be an important biothiol and related to many diseases. However, the in situ trapping of endogenous Cys is still handicapped by a lack of straightforward methods combined with long-wavelength emission and high-performance response. In this work, we described the rational design strategy of cyanine-based near-infrared (NIR) probes for the rapid detection of mitochondrial Cys in living cells and mice. We focus on how to improve the response rate via regulating the electron density of the recognition units in probes. The obtained three probes all displayed remarkable fluorescence enhancement at 780 nm. From screening the obtained probes, it was found that the probe Cy-S-diOMe with electron-donating recognition unit displayed the fastest response rate, the lowest detection limit, and the highest signal-to-noise ratio. More importantly, Cy-S-diOMe was successfully applied to monitor Cys in tumor-bearing mice (within merely 5 min). This paradigm by modulation of the response rate in the cyanine dyes provides a promising methodology for the design of high-performance cyanine-based NIR probes.

The tensile creep properties of line-type Cu/Sn–0.3Ag–0.7Cu(SAC0307)–xNi (x = 0, 0.02, 0.05 and 0.10 wt%)/Cu solder micro-joints were comparatively investigated via dynamic mechanical analysis. The effect of Ni content on the creep behaviour of the solder micro-joints was analysed and discussed. The creep behaviour of the joints at various temperatures and applied stresses was described by a power law. The results showed that the creep lifetime, creep activation energy and creep stress exponent of the Ni-containing solder micro-joints were greater than those of the Ni-free joint. Hence, adding Ni to the SAC0307 solder can enhance the creep resistance of the solder joints. The creep activation energy and the creep stress exponent of the solder micro-joints at 353–398 K and under a tensile stress of 8–15 MPa were 82.44–93.36 kJ/mol and 4.35–4.75, respectively. As the Ni content increased, the creep activation energy and the creep stress exponent first increased and then decreased. The Cu/SAC0307–0.05Ni/Cu solder micro-joint exhibited the strongest creep resistance among the tested joints. The creep deformation mechanisms of all solder micro-joints were mainly controlled by dislocation climbing, and the main creep failure mode was mixed brittle/ductile fracture.

Glucose oxidase (GOD)-based synergistic cancer therapy has aroused great research interest in the context of cancer treatment due to the inherent biocompatibility and biodegradability. However, this emerging therapeutic system still lacks a strategy to predict and regulate the in vivo biocatalytic behavior of GOD in real time to minimize the side effects on normal tissues. Herein, we developed a tumor-specific cascade nanotheranostic system (BNG) that combines GOD-catalyzed oxidative stress and dual-channel fluorescent sensing, significantly improving the synergistic therapeutic efficacy with real-time feedback information. The nanotheranostic system remains completely silent in the blood circulatory system and selectively releases GOD enzymes in the tumor site, with enhanced near-infrared (NIR) fluorescence at 825 nm. Subsequently, GOD catalyzes H2O2 production, triggering cascade reactions with NIR fluorescence at 650 nm as an optical output, along with GSH depletion, enabling synergistic cancer treatment. The designed nanotheranostic system, integrated with tumor-activated cascade reactions and triggering a dual-channel output at each step, represents an insightful paradigm for precise cooperative cancer therapy., Herein, we described the strategy of cascade nanotheranostics for in real-time tracking of GOD release and thus provide the feedback information of biocatalysis cascade process with significantly enhanced in vivo therapeutic efficiency.

Hard carbon materials have been recognized as a promising family of anode materials for potassium ion batteries (PIBs), but their practical application is severely hindered due to the inferior initial coulombic efficiency (ICE) and low capacity. Herein, we report our findings in simultaneously improved potassium storage capacity and ICE through the design of nano-size and porous structure and the appropriate selection of electrolytes. Benefiting from the high specific surface area, stable electrode|electrolyte interface, and fast potassium ion and electron transfer, the optimized electrode exhibits a high ICE of up to 68.2% and an outstanding reversible capacity of 232.6 mA h g-1 at 200 mA g-1. In particular, superior cycling stability of 165.2 mA h g-1 at 1000 mA g-1 and 129.7 mA h g-1 at 2000 mA g-1 can be retained after 1500 cycles, respectively. Quantitative analysis reveals that this optimized structure leads to an enhanced surface-controlled contribution, resulting in fast potassiation kinetics and electronic|ionic conductivities, which are regarded as essential features for potassium storage. Our findings in this work provide an efficient strategy to significantly improve potassium storage capacity while maintaining a high ICE for hard carbon electrodes.

The oxygen evolution reaction (OER) is a vital proton donor for various clean energy technologies. Here, we synthesized IrOx-decorated ultrathin NiFe-LDH nanosheets (thickness 1–2 nm) by a one-step co-precipitation method. The IrOx was uniformly dispersed on the surface of ultrathin NiFe-LDH nanosheets, greatly increasing the active sites and the electric conductivity for NiFe-LDH. As a result, the IrOx/U-NiFe-LDH exhibited excellent OER performance with a low overpotential (236 mV) and a Tafel slope (74.3 mA dec−1).

Metallic-phase selenide molybdenum (1T-MoSe

Lithium-ion batteries based on single-crystal LiNi

Developing suitable electrode materials capable of tolerating severe structural deformation and overcoming sluggish reaction kinetics resulting from the large radius of potassium ion (K