9 results on '"Gexcon AS"'
Search Results
2. Assessing the influence of real releases on explosions : selected results from large-scale experiments
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Jérôme Hebrard, Melodia Lucas, Lorenzo Mauri, Antoine Dutertre, Lorraine Jenney, Kees van Wingerden, Thibault Marteau, Trygve Skjold, Emmanuel Leprette, Michael Johnson, Pierre Quillatre, Gordon Atanga, Helene Hisken, Andrzej Pekalski, Christophe Proust, Dan Allason, Didier Jamois, Institut National de l'Environnement Industriel et des Risques (INERIS), Gexcon AS, University of Bergen (UiB), GRTgaz, TotalFinaElf, Shell Global Solutions, DNV GL, and Civs, Gestionnaire
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Release point ,General Chemical Engineering ,Nuclear engineering ,Flow (psychology) ,Energy Engineering and Power Technology ,02 engineering and technology ,Management Science and Operations Research ,7. Clean energy ,Industrial and Manufacturing Engineering ,law.invention ,chemistry.chemical_compound ,020401 chemical engineering ,law ,Natural gas ,0502 economics and business ,LARGE-SCALE EXPERIMENTS ,GAS EXPLOSIONS ,050207 economics ,0204 chemical engineering ,Safety, Risk, Reliability and Quality ,Flammable liquid ,Jet (fluid) ,Turbulence ,business.industry ,[SDE.IE]Environmental Sciences/Environmental Engineering ,Scale (chemistry) ,05 social sciences ,Initial turbulence ,Ignition system ,chemistry ,13. Climate action ,Control and Systems Engineering ,Environmental science ,REALISTIC RELEASES ,[SDE.IE] Environmental Sciences/Environmental Engineering ,business ,Food Science - Abstract
International audience; The research activities in the project Assessing the Influence of Real Releases on Explosions (AIRRE) included a unique series of large-scale explosion experiments with high-momentum jet releases directed into congested geometries with subsequent ignition. The primary objective for the AIRRE project was to gain improved understanding of the effect that realistic releases and turbulent flow conditions have on the consequences of accidental gas explosions in the petroleum industry. A secondary objective was to develop a methodology that can facilitate safe and optimal design of process facilities. This paper presents selected results from experiments involving ignition of a highly turbulent gas cloud, generated by a large-scale, pressurised release of natural gas. The paper gives an overview of the effect on maximum explosion overpressures of varying the ignition position relative to the release point of the jet and a congested region placed inside the flammable cloud, with either a high or a medium level of congestion. For two of the tests, involving a jet release and the medium congestion rig, the maximum overpressures significantly exceeded those obtained in a quiescent reference test. The paper presents detailed results for selected tests and discusses the effect of the initial flow field generated by realistic releases - including turbulence, net flow and concentration gradients - on relevant explosion phenomena.
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- 2020
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3. Integration of experimental facilities : a joint effort for establishing a common knowledge base in experimental work on hydrogen safety
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A. Grafwallner, Andrzej Teodorczyk, David W. Hedley, I. Tkatschenko, Ernst-Arndt Reinecke, Peter C.J. De Bruijn, B. Gavrikov, Mike Kuznetsov, Beatriz Acosta-Iborra, M. Wilkins, Christophe Proust, Inaki Azkarate, A. Marangon, Armin Kessler, Thomas Huebert, Institute for Energy Research IEF-6, BAM, Commissariat à l'Energie Atomique, Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Fraunhofer Institute for Chemical Technology (Fraunhofer ICT), Fraunhofer (Fraunhofer-Gesellschaft), Forschungszentrum Karlsruh, Forschungszentrum Karlsruhe, Gexcon AS, Périnatalité et Risques Toxiques - UMR INERIS_I 1 (PERITOX), Université de Picardie Jules Verne (UPJV)-CHU Amiens-Picardie-Institut National de l'Environnement Industriel et des Risques, Energy Unit, Tecnalia Materials and Components Dept, Institut National de l'Environnement Industriel et des Risques (INERIS), Institute for Energy [Petten], European Commission - Joint Research Centre [Petten], Kurchatov Institute, The Netherlands Organisation for Applied Scientific Research (TNO), DIMNP, University of Pisa - Università di Pisa, Warsaw University of Technology [Warsaw], Energie Technologie, Institut National de l'Environnement Industriel et des Risques (INERIS)-Université de Picardie Jules Verne (UPJV)-CHU Amiens-Picardie, and Civs, Gestionnaire
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Computer science ,[SPI] Engineering Sciences [physics] ,Best practice ,media_common.quotation_subject ,Energy Engineering and Power Technology ,INFRASTRUCTURE EXPERIMENTALE ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Hydrogen safety ,[SPI]Engineering Sciences [physics] ,Documentation ,Common knowledge ,Quality (business) ,Instrumentation (computer programming) ,EBP - Explosions, Ballistics & Protection ,SECURITE ,ComputingMilieux_MISCELLANEOUS ,media_common ,Facilities ,TS - Technical Sciences ,HySafe ,Renewable Energy, Sustainability and the Environment ,Experimental data ,Mechatronics, Mechanics & Materials ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,0104 chemical sciences ,Engineering management ,Fuel Technology ,HYDROGENE ,Joint (building) ,METROLOGIE ,Safety ,0210 nano-technology ,Experiments - Abstract
In the area of hydrogen safety, research facilities are essential for the experimental investigation of relevant phenomena, for testing devices and safety concepts, as well as for the generation of validation data for the various numerical codes and models. Within the framework of the European HySafe Network of Excellence (NoE), the 'Integration of Experimental Facilities (IEF)' activity has provided basic support for joint experimental work. Even beyond the funding period of the HySafe NoE in the 6th Framework Program, IEF represents a long-lasting effort for the sustainable integration of experimental research capacities and expertise of the partners from different research fields. In order to achieve a high standard in the quality of experimental data provided by the partners, emphasis was put on the know-how transfer between the partners. On the one hand, documentation on the experimental capacities was prepared and analyzed. On the other hand, a wiki-based communication platform was established, supported by biannual workshops covering topics ranging from measurement technologies to safety issues. Based on the partners' contributions, a working document was created on best practice including the joint experimental knowledge of all partners with regard to experimental set-ups and instrumentation. The paper gives an overview of the IEF partners and the network activities over the last five years. © 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
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- 2009
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4. On the use of hydrogen in confined spaces : results from the internal project InsHyde
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Olav R. Hansen, A. Gavrikov, Ernst-Arndt Reinecke, Inaki Azkarate, A.G. Venetsanos, Andrzej Teodorczyk, Stuart J. Hawksworth, P. Adams, D. Tigreat, Thomas Jordan, Ulrich Schmidtchen, L. Brett, Angunn Engebø, Sandra Nilsen, Eduardo Gallego, Alain Bengaouer, Armin Kessler, M. Stöcklin, Marco Nicola Mario Carcassi, Suresh Kumar, Vladimir Molkov, N.H.A. Versloot, Environmental Research Laboratory, National Centre for Scientific Research Demokritos, Volvo Technology Corporation, VOLVO, Energy Unit, Tecnalia Materials and Components Dept, Commissariat à l'Energie Atomique, Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Institute for Energy [Petten], European Commission - Joint Research Centre [Petten], DIMNP, University of Pisa - Università di Pisa, AS Energy Solutions, Det Norske Veritas, Escue a Técnica Superior de Ingenieros Industria es, Universidad Politécnica de Madrid (UPM), Kurchatov Institute, Gexcon AS, Health and Safety Laboratory, Forschungszentrum Karlsruh, Forschungszentrum Karlsruhe, Fraunhofer Institute for Chemical Technology (Fraunhofer ICT), Fraunhofer (Fraunhofer-Gesellschaft), Fire division, Building Research Establishment Limited, HySAFER Centre, University of Ulster, StatoilHydro, Forschungszentrum Jülich GmbH | Centre de recherche de Juliers, Helmholtz-Gemeinschaft = Helmholtz Association, Forschung and Technik GmbH, BMW, Federal Institut for Material Research and Testing, Warsaw University of Technology [Warsaw], Institut National de l'Environnement Industriel et des Risques (INERIS), The Netherlands Organisation for Applied Scientific Research (TNO), Civs, Gestionnaire, Research and Innovation, Statoil A.S.A. [Norway], Federal Institute for Materials Research and Testing - Bundesanstalt für Materialforschung und -prüfung (BAM), and TNO Defence, Security and Safety (TNO)
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Computer science ,[SPI] Engineering Sciences [physics] ,Nuclear engineering ,Automotive industry ,Combustion ,Energy Engineering and Power Technology ,02 engineering and technology ,Guidelines ,Computational fluid dynamics ,GUIDELINES ,7. Clean energy ,Hydrogen safety ,law.invention ,Hydrogen storage ,COMBUSTION ,[SPI]Engineering Sciences [physics] ,DISPERSION ,PERMEATION ,law ,0502 economics and business ,DETECTORS ,050207 economics ,TS - Technical Sciences ,Energy ,Scope (project management) ,Renewable Energy, Sustainability and the Environment ,business.industry ,Fluid Mechanics Chemistry & Energetics ,05 social sciences ,Detectors ,Dispersion ,Permeation ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Ignition system ,Fuel Technology ,Work (electrical) ,EM - Energetic Materials ,HYDROGEN SAFETY ,0210 nano-technology ,business - Abstract
The paper presents an overview of the main achievements of the internal project InsHyde of the HySafe NoE. The scope of InsHyde was to investigate realistic small-medium indoor hydrogen leaks and provide recommendations for the safe use/storage of indoor hydrogen systems. Additionally, InsHyde served to integrate proposals from HySafe work packages and existing external research projects towards a common effort. Following a state of the art review, InsHyde activities expanded into experimental and simulation work. Dispersion experiments were performed using hydrogen and helium at the INERIS gallery facility to evaluate short and long term dispersion patterns in garage like settings. A new facility (GARAGE) was built at CEA and dispersion experiments were performed there using helium to evaluate hydrogen dispersion under highly controlled conditions. In parallel, combustion experiments were performed by FZK to evaluate the maximum amount of hydrogen that could be safely ignited indoors. The combustion experiments were extended later on by KI at their test site, by considering the ignition of larger amounts of hydrogen in obstructed environments outdoors. An evaluation of the performance of commercial hydrogen detectors as well as inter-lab calibration work was jointly performed by JRC, INERIS and BAM. Simulation work was as intensive as the experimental work with participation from most of the partners. It included pre-test simulations, validation of the available CFD codes against previously performed experiments with significant CFD code inter-comparisons, as well as CFD application to investigate specific realistic scenarios. Additionally an evaluation of permeation issues was performed by VOLVO, CEA, NCSRD and UU, by combining theoretical, computational and experimental approaches with the results being presented to key automotive regulations and standards groups. Finally, the InsHyde project concluded with a public document providing initial guidance on the use of hydrogen in confined spaces. © 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
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- 2009
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5. An inter-comparison exercise on the capabilities of CFD models to predict the short and long term distribution and mixing of hydrogen in a garage
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Thomas Jordan, M.M. Van Der Voort, Asmund Huser, Olav R. Hansen, M. Heitsch, W. Jahn, M. Delichatsios, Alexander Venetsanos, Andrei V. Tchouvelev, Jean-Marc Lacome, Prankul Middha, Javier García, F. Verbecke, Andrzej Teodorczyk, Etienne Studer, E. Papanikolaou, Dmitriy Makarov, H.S. Ledin, Environmental Research Laboratory, National Centre for Scientific Research Demokritos, FireSERT Institute, University of Ulster, Escue a Técnica Superior de Ingenieros Industria es, Universidad Politécnica de Madrid (UPM), Gexcon AS, Research Management Division, Gesellschaft für Anlagen-und Reaktorsicherheit mbH, AS Energy Solutions, Det Norske Veritas, Forschungszentrum Jülich GmbH | Centre de recherche de Juliers, Helmholtz-Gemeinschaft = Helmholtz Association, Forschungszentrum Karlsruhe, Institut National de l'Environnement Industriel et des Risques (INERIS), Health and Safety Laboratory, HySAFER Centre, Commissariat à l'Energie Atomique, Commissariat à l'énergie atomique et aux énergies alternatives (CEA), A.V. Tchouvelev & Associates Inc., Warsaw University of Technology [Warsaw], The Netherlands Organisation for Applied Scientific Research (TNO), AZKARATE, I., EZPONDA, E., CARCASSI, M.N., MARANGON, A., ROSSI, and TNO Defensie en Veiligheid
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Diffusion (acoustics) ,Discretization ,020209 energy ,Energy Engineering and Power Technology ,GARAGE ,02 engineering and technology ,Computational fluid dynamics ,[SPI]Engineering Sciences [physics] ,DISPERSION ,Benchmark (surveying) ,0202 electrical engineering, electronic engineering, information engineering ,Traffic ,Dispersion (water waves) ,Confined space ,Renewable Energy, Sustainability and the Environment ,Turbulence ,business.industry ,Mechanics ,BENCHMARK ,HYDROGEN ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Fuel Technology ,SAFETY ,Environmental science ,0210 nano-technology ,business ,CFD ,Body orifice - Abstract
International audience; The paper presents the results of the CFD inter-comparison exercise SBEP-V3, performed within the activity InsHyde, internal project of the HYSAFE network of excellence, in the framework of evaluating the capability of various CFD tools and modeling approaches in predicting the physical phenomena associated to the short and long term mixing and distribution of hydrogen releases in confined spaces. The experiment simulated was INERIS-TEST-6C, performed within the InsHyde project by INERIS, consisting of a 1 g/s vertical hydrogen release for 240 s from an orifice of 20 mm diameter into a rectangu ar room (garage) of dimensions 3.78x7.2x2.88 m in width, length and height respectively. Two small openings at the front and bottom side of the room assured constant pressure conditions. During the test hydrogen concentration time histories were measured at 12 positions in the room, for a period up to 5160 s after the end of release, covering both the release and the subsequent diffusion phases. The benchmark was organized in two phases. The first phase consisted of blind simulations performed prior to the execution of the tests. The second phase consisted of post-calculations performed after the tests were concluded and the experimental results made available. The participation in the benchmark was high: 12 different organizations (2 non-HYSAFE partners) 10 different CFD codes and 8 different turbulence models. Large variation in predicted results was found in the first phase of the benchmark, between the various modeling approaches. This was attributed mainly to differences in turbulence models and numerical accuracy options (time/space resolution and discretization schemes). During the second phase of the benchmark the variation between predicted results was reduced.
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- 2009
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6. Determination of hazardous zones for a generic hydrogen station. A case study
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Nielsen, S., Marangon, A., Middha, P., Engeboe, A., Frank Markert, Ezponda, E., Chaineaux, J., Civs, Gestionnaire, AZKARATE, I., EZPONDA, E., CARCASSI, M.N., MARANGON, A., ROSSI, E., Oil and Energy Research Centre, Norsk Hydro ASA, DIMNP, University of Pisa - Università di Pisa, Gexcon AS, Research and Innovation / Energy and Resources, Det Norske Veritas, Risø National Laboratory, Danish Ministry of Science, Technology and Innovation, Energy Unit, Tecnalia Materials and Components Dept, Institut National de l'Environnement Industriel et des Risques (INERIS), AZKARATE, I., EZPONDA, E., CARCASSI, M.N., MARANGON, A., and ROSSI
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[SPI]Engineering Sciences [physics] ,[SPI] Engineering Sciences [physics] - Abstract
International audience; A method for determination of hazardous zones for hydrogen installations has been studied. This work has been carried out within the NoE HySafe. The method is based on the Italian Method outlined in Guide 31-30(2004), Guide 31-35(2001), Guide 31-35/A(2001), and Guide 31-35/A; V1(2003). Hazardous zones for a "generic hydrogen refuelling station"(HRS) are assessed, based on this method. The method is consistent with the EU directive 1999/92/EC "Safety and Health Protection of Workers potentially at risk from explosive atmospheres" which is the basis for determination of hazardous zones in Europe. This regulation is focused on protection of workers, and is relevant for hydrogen installations, such as hydrogen refuelling stations, repair shops and other stationary installations where some type of work operations will be involved. The method is also based on the IEC standard and European norm IEC/EN60079-10 "Electrical apparatus for explosive gas atmospheres. Part 10 Classification of hazardous areas". This is a widely acknowledged international standard/norm and it is accepted/approved by Fire and Safety Authorities in Europe and also internationally. Results from the HySafe work and other studies relevant for hydrogen and hydrogen installations have been included in the case study. Sensitivity studies have been carried out to examine the effect of varying equipment failure frequencies and leak sizes, as well as environmental condition (ventilation, obstacles, etc.). The discharge and gas dispersion calculations in the Italian Method are based on simple mathematical formulas. However, in this work also CFD (Computational Fluid Dynamics) and other simpler numerical tools have been used to quantitatively estimate the effect of ventilation and of different release locations on the size of the flammable gas cloud. Concentration limits for hydrogen to be used as basis for the extent of the hazardous zones in different situations are discussed.
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- 2007
7. Blind-prediction: Estimating the consequences of vented hydrogen deflagrations for homogeneous mixtures in 20-foot ISO containers
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T. Skjold, H. Hisken, S. Lakshmipathy, G. Atanga, M. Carcassi, M. Schiavetti, J.R. Stewart, A. Newton, J.R. Hoyes, I.C. Tolias, A.G. Venetsanos, O.R. Hansen, J. Geng, A. Huser, S. Helland, R. Jambut, K. Ren, A. Kotchourko, T. Jordan, J. Daubech, G. Lecocq, A.G. Hanssen, C. Kumar, L. Krumenacker, S. Jallais, D. Miller, C.R. Bauwens, Civs, Gestionnaire, CARCASSI, Marco, JORDAN, Thomas, Gexcon AS, University of Pisa - Università di Pisa, Health and Safety Executive, National Centre for Scientific Research Demokritos, Det Norske Veritas, DNV GL, Karlsruhe Institute of Technology (KIT), Institut National de l'Environnement Industriel et des Risques (INERIS), Fluidyn, parent, Air Liquide [Siège Social], and FM Global Research, Research Division, Norwood, MA, United States
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Vented hydrogen deflagrations ,STRUCTURAL RESPONSE ,[SDE.IE]Environmental Sciences/Environmental Engineering ,Renewable Energy, Sustainability and the Environment ,05 social sciences ,Energy Engineering and Power Technology ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,VENTED DEFLAGRATIONS ,7. Clean energy ,Containers ,Fuel Technology ,BLIND-PREDICTION ,13. Climate action ,20-foot containers ,Blind-prediction ,Consequence modelling ,Hydrogen safety ,Structural response ,Vented deflagrations ,20-FOOT CONTAINERS ,0502 economics and business ,Homogeneous mixtures ,CONSEQUENCE MODELLING ,HYDROGEN SAFETY ,[SDE.IE] Environmental Sciences/Environmental Engineering ,050207 economics ,0210 nano-technology - Abstract
This paper was presented at the Seventh International Conference of Hydrogen Safety (ICHS 2017) in Hamburg on 11-13 September 2017. The paper summarises the results from a blind-prediction study for models developed for estimating the consequences of vented hydrogen deflagrations. The work is part of the project Improving hydrogen safety for energy applications through pre-normative research on vented deflagrations (HySEA). The scenarios selected for the blind-prediction entailed vented explosions with homogeneous hydrogen-air mixtures in a 20-foot ISO container. The test program included two configurations and six experiments, i.e. three repeated tests for each scenario. The comparison between experimental results and model predictions reveals reasonable agreement for some of the models, and significant discrepancies for others. It is foreseen that the first blind-prediction study in the HySEA project will motivate developers to improve their models, and to update guidelines for users of the models. The paper is a deliverable from the project “Improving hydrogen safety for energy applications through pre-normative research on vented deflagrations”, or HySEA (www.hysea.eu), which receives funding from the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) under grant agreement no. 671461. This Joint Undertaking receives support from the European Union’s Horizon 2020 research and innovation programme and United Kingdom, Italy, Belgium and Norway.
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8. Achievements of the EC network of excellence HySafe
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Jordan Thomas, Adams Paul, Azkarate Inaki, Baraldi Daniele, Barthelemy Herve, Bauwens Luc, Bengaouer Alain, Brennan Sile, Carcassi Marco, Dahoe Arief, Eisenreich Norbert, Engebo Angunn, Funnemark Espen, Gallego Eduardo, Gavrikov Andrey, Haland Erling, Hansen Anne Marit, Haugom Gerd Petra, Hawksworth Stuart, Jedicke Olaf, Kessler Armin, Kotchourko Alexei, Kumar Suresh, Langer Gesa, Ledin Stefan, Lelyakin Alexander, Makarov Dmitriy, Marangon Alessia, Markert Frank, Middha Prankul, Molkov Vladimir, Nilsen Sandra, Papanikolaou Efthymia, Perrette Lionel, Reinecke Ernst-Arendt, Schmidtchen Ulrich, Serre-Combe Pierre, Stöcklin Michael, Sully Aurelie, Teodorczyk Andrzej, Tigreat Delphine, Venetsanos Alexander, Verfondern Karl, Versloot Nico, Vetere Ana, Wilms Manfred, Zaretskiy Nikolay, Forschungszentrum Karlsruh, Forschungszentrum Karlsruhe, Volvo Technology Corporation, VOLVO, Energy Unit, Tecnalia Materials and Components Dept, Institute for Energy [Petten], European Commission - Joint Research Centre [Petten], Air Liquide [Siège Social], University of Calgary, Commissariat à l'Energie Atomique, Commissariat à l'énergie atomique et aux énergies alternatives (CEA), HySAFER Centre, University of Ulster, DIMNP, University of Pisa - Università di Pisa, Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie (KIT), AS Energy Solutions, Det Norske Veritas, Escue a Técnica Superior de Ingenieros Industria es, Universidad Politécnica de Madrid (UPM), Kurchatov Institute, StatoilHydro, Health and Safety Laboratory, Fraunhofer Institute for Chemical Technology (Fraunhofer ICT), Fraunhofer (Fraunhofer-Gesellschaft), Fire division, Building Research Establishment Limited, Institute for Nuclear and Energy Technologies [Eggenstein-Leopoldshafen] (IKET), Karlsruhe Institute of Technology (KIT), Gexcon AS, Environmental Research Laboratory, National Centre for Scientific Research Demokritos, Institut National de l'Environnement Industriel et des Risques (INERIS), Forschungszentrum Jülich GmbH | Centre de recherche de Juliers, Helmholtz-Gemeinschaft = Helmholtz Association, Federal Institut for Material Research and Testing, Forschung and Technik GmbH, BMW, Warsaw University of Technology [Warsaw], The Netherlands Organisation for Applied Scientific Research (TNO), Risø National Laboratory, Danish Ministry of Science, Technology and Innovation, Civs, Gestionnaire, and TNO Industrie en Techniek
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[SPI] Engineering Sciences [physics] ,Process (engineering) ,Hydrogen Safety ,Energy Engineering and Power Technology ,02 engineering and technology ,010402 general chemistry ,7. Clean energy ,01 natural sciences ,[SPI]Engineering Sciences [physics] ,Hydrogen safety ,NoE hysafe ,Benchmark (surveying) ,NETWORKING ,COORDINATION ,PRE-NORMATIVE RESEARCH ,Renewable Energy, Sustainability and the Environment ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Hydrogen vehicle ,Hazard ,0104 chemical sciences ,Chemistry ,Identification (information) ,Fuel Technology ,Work (electrical) ,Risk analysis (engineering) ,Ranking ,STATE-OF-THE-ART ,HYDROGEN SAFETY ,0210 nano-technology ,INTEGRATION - Abstract
International audience; In many areas European research has been largely fragmented. To support the required integration and to focus and coordinate related research efforts the European Commission created a new instrument, the Networks of Excellences (NoEs). The goal of the NoE HySafe has been to provide the basis to facilitate the safe introduction of hydrogen as an energy carrier by removing the safety related obstacles. The prioritisation of the HySafe internal project activities was based on a phenomena identification and ranking exercise (PIRT) and expert interviews. The identified research headlines were "Releases in (partially) confined areas", "Mitigation" and "Quantitative Risk Assessment". Along these headlines existing or planned research work was re-orientated and slightly modified, to build up three large internal research projects "InsHyde", "HyTunnel", and "HyQRA". In InsHyde realistic indoor hydrogen leaks and associated hazards have been investigated to provide recommendations for the safe use of indoor hydrogen systems including mitigation and detection means. The appropriateness of available regulations, codes and standards (RCS) has been assessed. Experimental and numerical work was conducted to benchmark simulation tools and to evaluate the related recommendations. HyTunnel contributed to the understanding of the nature of the hazards posed by hydrogen vehicles inside tunnels and its relative severity compared to other fuels. In HyQRA quantitative risk assessment strategies were applied to relevant scenarios in a hydrogen refuelling station and the performance was compared to derive also recommendations. The integration process was supported by common activities like a series of workshops and benchmarks related to experimental and numerical work. The networks research tools were categorised and published in online catalogues. Important integration success was provided by commonly setting up the International Conference on Hydrogen Safety, the first academic education related to hydrogen safety and the Hydrogen Safety Handbook. Finally, the network founded the International Association for Hydrogen Safety, which opens the future networking to all interested parties on an international level.
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9. Flame Inhibition by Potassium-Containing Compounds.
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Babushok VI, Linteris GT, Hoorelbeke P, Roosendans D, and van Wingerden K
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A kinetic model of inhibition by the potassium-containing compound potassium bicarbonate is suggested. The model is based on the previous work concerning kinetic studies of suppression of secondary flashes, inhibition by alkali metals and the emission of sulfates and chlorides during biomass combustion. The kinetic model includes reactions with the following gas-phase potassium-containing species: K, KO, KO
2 , KO3 , KH, KOH, K2 O, K2 O2 , (KOH)2 , K2 CO3 , KHCO3 and KCO3 . Flame equilibrium calculations demonstrate that the main potassiumcontaining species in the combustion products are K and KOH. The main inhibition reactions, which comprise the radical termination inhibition cycle are KOH+H=K+H2 O and K+OH+M=KOH+M with the overall termination effect: H+OH=H2 O. Numerically predicted burning velocities for stoichiometric methane/air flames with added KHCO3 demonstrate reasonable agreement with available experimental data. A strong saturation effect is observed for potassium compounds: approximately 0.1% volume fraction of KHCO3 is required to decrease burning velocity by a factor of 2, however an additional 0.6% volume fraction is required to reach a burning velocity of 5 cm/s. Analysis of the calculation results indicates that addition of the potassium compound quickly reduces the radical super-equilibrium down to equilibrium levels, so that further addition of the potassium compound has little effect on the flame radicals.- Published
- 2017
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