92 results on '"Genki Saito"'
Search Results
2. Effects of Normalizing Temperature on the Precipitation of Fine Particles and Austenite Grain Growth during Carburization of Al- and Nb-Microalloyed Case-Hardening Steel
- Author
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Genki Saito, Norihito Sakaguchi, Kiyotaka Matsuura, Taichi Sano, and Takuya Yamaoka
- Subjects
Mechanics of Materials ,Mechanical Engineering ,Materials Chemistry ,Metals and Alloys - Published
- 2023
3. (1,6)Pyrenophanes containing crown ether moieties as fluorescence sensors for metal and ammonium ions. Formation of sandwich, dumbbell, and pseudorotaxane complexes
- Author
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Hajime Maeda, Genki Saito, Taniyuki Furuyama, and Masahito Segi
- Subjects
Materials Chemistry ,General Chemistry ,Catalysis - Abstract
(1,6)Pyrenophanes 1 and 2 in which 1,6-positions of pyrene are bridged with respective tri- and tetra-ethylene glycol chains were synthesized.
- Published
- 2023
4. Precipitation Behavior of Combined Precipitates in Carbon Steels
- Author
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Genki Saito
- Subjects
Materials science ,chemistry ,Precipitation (chemistry) ,Metallurgy ,chemistry.chemical_element ,Carbon - Published
- 2021
5. Sr-Doped Ca2AlMnO5 + δ for Energy-Saving Oxygen Separation Process
- Author
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Norihito Sakaguchi, Hidekazu Naya, Keita Tanahashi, Yusei Omura, Yuji Kunisada, Genki Saito, Takahiro Nomura, and Kaho Miyazaki
- Subjects
Materials science ,chemistry ,Renewable Energy, Sustainability and the Environment ,General Chemical Engineering ,Doping ,Analytical chemistry ,Environmental Chemistry ,chemistry.chemical_element ,General Chemistry ,Oxygen ,Energy (signal processing) ,Separation process - Published
- 2021
6. Effects of Cooling Rate after Hot Forging on Precipitation of Fine Particles during Subsequent Normalizing and Austenite Grain Growth during Carburization of Al- and Nb-microalloyed Case-hardening Steel
- Author
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Kiyotaka Matsuura, Koki Minoguchi, Taichi Sano, Masayoshi Takeuchi, Norihito Sakaguchi, Takuya Yamaoka, Munekazu Ohno, and Genki Saito
- Subjects
Materials science ,Cooling rate ,Mechanics of Materials ,Precipitation (chemistry) ,Mechanical Engineering ,Metallurgy ,Materials Chemistry ,Metals and Alloys ,Abnormal grain growth ,Austenite grain ,Case hardening ,Forging - Published
- 2021
7. Faster Generation of Nanoporous Hematite Ore through Dehydration of Goethite under Vacuum Conditions
- Author
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Tomohiro Akiyama, Ade Kurniawan, Takahiro Nomura, and Genki Saito
- Subjects
Goethite ,Materials science ,Nanoporous ,Mechanical Engineering ,Metals and Alloys ,porous ore ,Hematite ,low-grade iron ore ,medicine.disease ,vacuum-dehydration ,Chemical engineering ,Mechanics of Materials ,visual_art ,pore morphology ,Materials Chemistry ,visual_art.visual_art_medium ,medicine ,goethite ,Dehydration - Abstract
Goethite (FeOOH)-based ore has become attractive to be utilized in ironmaking. As mildly dehydrated to remove its high combined water (CW), it changes to a nanoporous hematite ore. The nanopore contributes a significant increase in ore reduction reactivity due to the nanocontact between iron oxide and reducing agents such as C, CO, or H-2. However, the long dehydration time of goethite ore is still one problem. This study revealed the effect of vacuum condition on the mild-dehydration of goethite-based ore significantly reduces the ore dehydration time. The dehydration is finished within one hour at 300 degrees C under high-vacuum condition (P=1.7 Pa), producing nanoporous hematite ore that is similar to under atmospheric one for 24 h. However, no significant decrease in the dehydration temperature under the high-vacuum condition. In contrast, in-situ heating TEM observation reveals that nanopore generation can occur at low temperatures under ultra-high vacuum conditions (P = 5.6 x 10(-6) Pa). Slit pore generates at low temperatures that then eventually disappear by merging to bigger pores at the higher temperatures.
- Published
- 2021
8. Synthesis of Ba0.79(Al, Zn)10.9O17.14−δ:Eu2+ Phosphor with a Single Phase and the Effect of Zn Doping on Photoluminescence Properties
- Author
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Hiromi Nakano and Genki Saito
- Subjects
Fluid Flow and Transfer Processes ,Photoluminescence ,Materials science ,Process Chemistry and Technology ,Analytical chemistry ,Filtration and Separation ,Phosphor ,Single phase ,Zn doping ,Catalysis - Published
- 2021
9. Effects of Concentrations of Micro-alloying Elements and Hot-forging Temperature on Austenite Grain Structure Formed during Carburization of Case-hardening Steel
- Author
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Kiyotaka Matsuura, Takuya Yamaoka, Koki Minoguchi, Norihito Sakaguchi, Genki Saito, Munekazu Ohno, Masayoshi Takeuchi, and Taichi Sano
- Subjects
Materials science ,Mechanics of Materials ,Mechanical Engineering ,Metallurgy ,Materials Chemistry ,Metals and Alloys ,Abnormal grain growth ,Austenite grain ,Case hardening ,Forging - Published
- 2020
10. Glassy Porphyrin/C60 Composites: Morphological Engineering of C60 Fullerene with Liquefied Porphyrins
- Author
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Tomokazu Umeyama, Sono Sasaki, Mitsuhiko Morisue, Genki Saito, Shinichi Sakurai, Hiroyasu Masunaga, Koji Mitamura, Hiroshi Imahori, Daiki Sasada, and Taiki Hoshino
- Subjects
Materials science ,Supramolecular chemistry ,Solvation ,Cooperativity ,Surfaces and Interfaces ,Condensed Matter Physics ,Porphyrin ,Toluene ,Solvent ,chemistry.chemical_compound ,Molecular recognition ,chemistry ,Electrochemistry ,General Materials Science ,Composite material ,Spectroscopy ,Stoichiometry - Abstract
Morphological control of C60 fullerene using liquefied porphyrins (1 and 2) as the host matrices was explored. Slow evaporation of the solvent of the equimolar mixture of porphyrin and C60 in toluene afforded the porphyrin/C60 composite with a 3:1 molar ratio. The stoichiometric binding behaviors suggest that specific porphyrin-C60 interactions operate the formation of the porphyrin/C60 composites, as corroborated by spectroscopic and thermal properties, and glazing-incidence wide-angle X-ray diffraction. Under the bulk conditions, the conventional thermodynamic advantage of multiple binding cooperativity for molecular recognition is unlikely to explain the stoichiometric binding behaviors. Instead, we propose a size-matching effect on the porphyrin-C60 interaction in the bulk porphyrin matrices, i.e., "supramolecular solvation". The glassy nature of the porphyrin matrices was transmitted to C60 through the specific interaction, and the porphyrin/C60 composites adopted glassy states at room temperature.
- Published
- 2020
11. Trimethylsilanolate-Promoted Activation of Alkynyl Trimethylsilanes: Hiyama-Type Sonogashira Cross-Coupling for the Synthesis of Arylene-Ethynylene-Linked Porphyrin Arrays
- Author
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Mitsuhiko Morisue, Nanase Ohno, Genki Saito, and Miho Kawanishi
- Subjects
Porphyrins ,Alkynes ,Organic Chemistry ,Solvents ,Copper - Abstract
To synthesize
- Published
- 2022
12. Synthesis of AlN particles via direct nitridation in a drop tube furnace
- Author
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Takahiro Nomura, Genki Saito, Tomohiro Akiyama, Keisuke Abe, and Tatsuya Senda
- Subjects
Materials science ,Metallurgy ,Materials Chemistry ,Ceramics and Composites ,General Chemistry ,Tube furnace ,Condensed Matter Physics - Published
- 2019
13. Master of Puppets: Analyzing And Attacking A Botnet For Fun And Profit.
- Author
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Genki Saito and Gianluca Stringhini
- Published
- 2015
14. Effect of additives in electrode paste of p-type crystalline Si solar cells on potential-induced degradation
- Author
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Kyotaro Nakamura, Genki Saito, Sachiko Jonai, Atsushi Masuda, Aki Tanaka, Yoshio Ohshita, Kazuo Muramatsu, and Atsushi Ogura
- Subjects
Fabrication ,Materials science ,Renewable Energy, Sustainability and the Environment ,020209 energy ,Sodium ,digestive, oral, and skin physiology ,Photovoltaic system ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Potential induced degradation ,chemistry ,Chemical engineering ,Electrode ,0202 electrical engineering, electronic engineering, information engineering ,Degradation (geology) ,General Materials Science ,Lithium ,Crystalline silicon ,0210 nano-technology - Abstract
Sodium (Na) and lithium (Li) in the silver (Ag) paste cause the potential-induced degradation (PID), while the PID of p-type crystalline silicon (Si) photovoltaic modules is caused by Na in the front cover glass. Some Ag pastes contain these elements to control the firing properties in solar cells fabrication. In order to eliminate the effect of Na and other elements in the front cover glass on PID, PID tests for crystalline Si photovoltaic modules without front cover glass and using cells with various electrode pastes of controlled additive contents were performed. When the Ag paste with Na is used, the shunt resistance decreases and the PID occurs. This phenomenon is similar to that induced by Na in the front cover glass, but, it requires the shorter time duration as compared with the case of Na in the front cover glass. In addition, it is found that Li in the paste also causes the PID equivalent to that by Na in the paste.
- Published
- 2019
15. Solution Combustion Synthesis of Functional Powders
- Author
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Tomohiro Akiyama, Genki Saito, and Chunyu Zhu
- Subjects
Fluid Flow and Transfer Processes ,Materials science ,Chemical engineering ,Process Chemistry and Technology ,Filtration and Separation ,Solution combustion ,Catalysis - Published
- 2019
16. Crystalline Evaluation of Size-Controlled Silicon and Silicon Oxide Nanoparticles Produced by Solution Plasma Discharge
- Author
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Ryo Ota, Genki Saito, Norihito Sakaguchi, Heishichiro Takahashi, and Hitoshi Sasaki
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Materials science ,Silicon ,chemistry ,Chemical engineering ,Mechanics of Materials ,Mechanical Engineering ,chemistry.chemical_element ,Nanoparticle ,General Materials Science ,Plasma ,Condensed Matter Physics ,Silicon oxide - Published
- 2019
17. Microencapsulation of eutectic and hyper-eutectic Al-Si alloy as phase change materials for high-temperature thermal energy storage
- Author
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Yuta Hasegawa, Takahiro Nomura, Hiroki Sakai, Nan Sheng, Tomohiro Akiyama, Julalak Yoolerd, Genki Saito, and Miki Haga
- Subjects
Boehmite ,Materials science ,Renewable Energy, Sustainability and the Environment ,business.industry ,020209 energy ,Alloy ,02 engineering and technology ,engineering.material ,Thermal energy storage ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Chemical engineering ,Boiling ,0202 electrical engineering, electronic engineering, information engineering ,engineering ,Melting point ,Supercooling ,business ,Thermal energy ,Eutectic system - Abstract
Thermal energy storage using phase change materials (PCMs) has been world-widely accepted as an effective technology for energy saving. In this study, Micro-Encapsulated PCMs (MEPCMs) were developed from Al-Si alloys, in which four kinds of Al-Si microspheres with different Al-Si compositions: Al-12%Si, Al-17%Si, Al-20%Si, and Al-30%Si (mass%) were encapsulated by two facile steps for controlling heat storage property. First, boehmite film was formed over the Al-Si microspheres as a precursor shell during boiling in distilled water. Subsequently, the boehmite-coated particles were oxidized by pure oxygen at the high temperatures to ensure the formation of a stable Al2O3 shell. Three different temperatures, 1100 °C, 1150 °C, and 1200 °C, were chosen to study the effect of temperature on the product; the shell morphology, structure, and latent heat storage capacity. Interestingly, the results revealed an increase in MEPCM thermal storage capacity with decreasing Si content and lowering the temperature. The MEPCM melting point was almost identical to its eutectic temperature at ~577 °C, in contrast the larger supercooling was observed for samples with the higher Si content. The cyclic durability of MEPCM was also evaluated through repeated heating and cooling processes in air. The obtained results showed no significant change in both MEPCM structure and thermal storage capacity. It indicated a good repetition durability of MEPCMs oxidized at high temperatures. In conclusion, the Al-Si microencapsulated PCMs appealed great potential as MEPCMs for use in high-temperature thermal energy applications.
- Published
- 2018
18. Glassy Porphyrin/C
- Author
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Mitsuhiko, Morisue, Genki, Saito, Daiki, Sasada, Tomokazu, Umeyama, Hiroshi, Imahori, Koji, Mitamura, Hiroyasu, Masunaga, Taiki, Hoshino, Shinichi, Sakurai, and Sono, Sasaki
- Abstract
Morphological control of C
- Published
- 2020
19. Sr substitution effects on atomic and local electronic structure of Ca2 AlMnO5+δ
- Author
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Genki Saito, Norihito Sakaguchi, Takahiro Nomura, Kazuki Hayami, and Yuji Kunisada
- Subjects
Materials science ,Jahn–Teller effect ,Substitution (logic) ,02 engineering and technology ,Surfaces and Interfaces ,General Chemistry ,Electronic structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,Crystallography ,Materials Chemistry ,Density functional theory ,0210 nano-technology - Published
- 2018
20. Combustion synthesis of AlN doped with carbon and oxygen
- Author
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Genki Saito, Xuemei Yi, Takumi Watanabe, Takahiro Nomura, Tomohiro Akiyama, Norihito Sakaguchi, and Yuji Kunisada
- Subjects
010302 applied physics ,Materials science ,Doping ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Combustion ,01 natural sciences ,Oxygen ,chemistry ,Chemical engineering ,0103 physical sciences ,Materials Chemistry ,Ceramics and Composites ,0210 nano-technology ,Carbon - Published
- 2018
21. Formation of Different Si3N4 Nanostructures by Salt-Assisted Nitridation
- Author
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Qingda Li, Ran Guo, Takahiro Nomura, Xiongzhang Liu, Sengjing Zhang, Xuemei Yi, and Genki Saito
- Subjects
010302 applied physics ,Materials science ,Nanostructure ,Evaporation ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Decomposition ,Amorphous solid ,chemistry.chemical_compound ,Silicon nitride ,chemistry ,Chemical engineering ,Transmission electron microscopy ,visual_art ,0103 physical sciences ,visual_art.visual_art_medium ,General Materials Science ,Ceramic ,0210 nano-technology ,Nitriding - Abstract
Silicon nitride (Si3N4) products with different nanostructure morphologies and different phases for Si3N4 ceramic with high thermal conductivity were synthesized by a direct nitriding method. NaCl and NH4Cl were added to raw Si powders, and the reaction was carried out under a nitrogen gas flow of 100 mL/min. The phase composition and morphologies of the products were systemically characterized by X-ray diffraction, field emission scanning electron microscopy, and high-resolution transmission electron microscopy. At 1450 °C, the NaCl content was 30 wt %, the NH4Cl content was 3 wt %, and the maximum α-Si3N4 content was 96 wt %. The process of Si nitridation can be divided into three stages by analyzing the reaction schemes: in the first stage (25–900 °C), NH4Cl decomposition and the generation of stacked amorphous Si3N4 occurs; in the second stage (900–1450 °C), NaCl melts and Si3N4 generates; and in the third stage (>1450 °C), α-Si3N4 → β-Si3N4 phase change and the evaporation of NaCl occurs. The product...
- Published
- 2018
22. Combustion synthesis of YAG:Ce phosphors via the thermite reaction of aluminum
- Author
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Junpei Ohyama, Takahiro Nomura, Chunyu Zhu, Genki Saito, Norihito Sakaguchi, Miki Haga, and Tomohiro Akiyama
- Subjects
Exothermic reaction ,Materials science ,chemistry.chemical_element ,Mineralogy ,Yttrium aluminum garnet ,Phosphor ,02 engineering and technology ,Raw material ,010402 general chemistry ,Combustion ,01 natural sciences ,Geochemistry and Petrology ,Aluminium ,Rare earths ,Flux ,Coprecipitated material ,Thermite ,General Chemistry ,Yttrium ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Combustion synthesis ,chemistry ,Chemical engineering ,0210 nano-technology ,Luminescence - Abstract
Cerium-doped yttrium aluminum garnet (YAG:Ce) as a yellow phosphor for white light-emitting diodes (LEDs) was synthesized via a facile combustion method using Y2O3, CeO2, Al2O3, Al, and NaClO4 as raw materials. The combustion synthesis approach utilizes the strong exothermic oxidation of aluminum to realize a self-sustaining reaction. In this study, we investigated the effects of the ratios of Al2O3 to Al, fluxes, and coprecipitated materials as raw materials on the luminescence properties of the synthesized YAG:Ce phosphors. When the amount of Al2O3 x is varied, the combustion reaction proceeds at x
- Published
- 2018
23. Development of a microencapsulated Al–Si phase change material with high-temperature thermal stability and durability over 3000 cycles
- Author
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Genki Saito, Nan Sheng, Tomohiro Akiyama, Miki Haka, Yuta Hasegawa, Takahiro Nomura, Chunyu Zhu, Hiroki Sakai, and Takehito Hiraki
- Subjects
Boehmite ,Materials science ,Renewable Energy, Sustainability and the Environment ,Precipitation (chemistry) ,020209 energy ,Shell (structure) ,02 engineering and technology ,General Chemistry ,Thermal energy storage ,Phase-change material ,Durability ,0202 electrical engineering, electronic engineering, information engineering ,Melting point ,General Materials Science ,Thermal stability ,Composite material - Abstract
Development of highly durable phase change materials (PCMs) above 500 °C is essential in future high-temperature thermal energy storage systems. In this study, we report the fabrication of microencapsulated PCM (MEPCM) microspheres with high-temperature stability and cycling durability over 3000 cycles. The MEPCM consists of an Al–Si alloy core (Al–25 wt% Si; melting point of 577 °C) and a self-repairing Al2O3 shell. The uniform and highly durable Al2O3 shell is processed in three indispensable steps. Firstly, a boehmite treatment in an Al(OH)3 turbid solution under an optimal pH value of 8 is used for the formation of AlOOH and Al(OH)3 shell precursors. Secondly, additional Al(OH)3 is further precipitated on the surface to enhance the formation of a thicker shell. Finally, a stable and self-repairing two-phase (α-Al2O3 and θ-Al2O3) Al2O3 shell is formed by heat-oxidation in an O2 atmosphere. The surface morphology, crystal structure of the shell, thermal durability, cycling stability and the shell formation mechanism are carefully investigated. The newly introduced boehmite and precipitation pre-treatments under optimal conditions can reinforce the formation of a thick and highly compact shell with small α-Al2O3 and θ-Al2O3 grains, which are beneficial to disperse the thermal stress during high-temperature cycling and restrain crack propagation. The excellent achievement of durability over 3000 cycles can promote the practical applications of the MEPCM for high-temperature thermal storage, for example, it can be applied to the thermal storage system of a concentrated solar power plant for more than 6 years based on the reported durability.
- Published
- 2018
24. Combustion synthesis of Ca-α-SiAlON:Eu2+ phosphors with different Ca concentrations and diluent ratios
- Author
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Yuji Kunisada, Tomohiro Akiyama, Takahiro Nomura, Norihito Sakaguchi, and Genki Saito
- Subjects
Sialon ,Materials science ,Process Chemistry and Technology ,Analytical chemistry ,Mineralogy ,Phosphor ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Combustion ,01 natural sciences ,Diluent ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Lattice constant ,Scanning transmission electron microscopy ,Materials Chemistry ,Ceramics and Composites ,Grain boundary ,0210 nano-technology ,Luminescence - Abstract
Yellow Ca-α-SiAlON:Eu 2+ phosphors for white light-emitting diodes (LEDs) were synthesized by a facile combustion synthesis method using CaO, Eu 2 O 3 , α-Si 3 N 4 , Si, and Al as raw materials. Ca concentrations and diluent ratios were optimized to improve their luminescence properties. The lattice constant and luminescence properties improved as x increased from 0.4 to 1.2 in Ca x Si 12 − (m+n) Al m+n O n N 16−n :Eu 0.06 . The optimum value was x = 1.2. Scanning transmission electron microscopy combined with energy dispersive X-ray analysis detected segregation of Ca and Eu at grain boundaries, which decreased luminescence behavior in the x = 1.4 sample. The influence of Si and Si 3 N 4 diluents was investigated by varying the diluent ratio φ = (CaO + Eu 2 O 3 + α-Si 3 N 4 )/(CaO + Eu 2 O 3 + α-Si 3 N 4 + Al + Si). Changes in temperature and flame propagation speed were measured during combustion synthesis using two thermocouples. When φ was less than 0.5, the combustion temperature exceeded 1600 °C and the synthesized material contained an amount of the high-temperature β-SiAlON phase. At φ > 0.7, the reaction temperature fell below 1200 °C, and unreacted raw materials remained. The optimum value of φ was 0.6. The internal quantum efficiency of the product synthesized at x = 1.2 and φ = 0.6 was approximately 35% under 450-nm excitation. According to electron probe X-ray microanalysis, composition varied within individual synthesized particles, which may explain the decrease in emission behavior relative to a commercial product.
- Published
- 2017
25. Effects of Al particle size and nitrogen pressure on AlN combustion synthesis
- Author
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Jing Niu, Ayako Hiranaka, Xuemei Yi, Tomohiro Akiyama, and Genki Saito
- Subjects
010302 applied physics ,Diffraction ,Nitrogen pressure ,Materials science ,Morphology (linguistics) ,Scanning electron microscope ,Process Chemistry and Technology ,Nanotechnology ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Combustion ,01 natural sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Chemical engineering ,Nanofiber ,0103 physical sciences ,Materials Chemistry ,Ceramics and Composites ,Particle size ,0210 nano-technology ,Phase purity - Abstract
This study investigates the combustion synthesis of AlN fibers using an NH4Cl additive and reports the effects of Al particle size (3, 30, and 180 µm) and N2 pressure (0.10, 0.25, and 0.50 MPa) on the purity and morphology of AlN fibers. The combustion temperature was directly measured during the synthesis to elucidate the formation mechanism of the AlN fibers. The phase purity and morphology of the products were studied using X-ray diffraction and scanning electron microscopy, respectively. When the particle size of Al was reduced from 180 to 3 µm, the purity of the AlN product increased significantly owing to the large reaction area, which increased the combustion temperature. Furthermore, lower N2 pressures enhanced the formation of AlN nanofibers due to the accelerated gasification of Al. The optimum values of the particle size of Al and the N2 pressure for the formation of high-purity AlN nanofibers were found to be 3 µm and 0.10 MPa, respectively.
- Published
- 2017
26. Three-dimensional analysis of Eu dopant atoms in Ca-α-SiAlON via through-focus HAADF-STEM imaging
- Author
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Tomohiro Akiyama, Fuuta Yamaki, Yuji Kunisada, Norihito Sakaguchi, and Genki Saito
- Subjects
010302 applied physics ,Sialon ,Materials science ,Dopant ,Resolution (electron density) ,Analytical chemistry ,Context (language use) ,Phosphor ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Radial distribution function ,01 natural sciences ,Molecular physics ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,0103 physical sciences ,Atom ,Cathode ray ,0210 nano-technology ,Instrumentation - Abstract
Three-dimensional (3D) distributional analysis of individual dopant atoms in materials is important to development of optical, electronic, and magnetic materials. In this study, we adopted through-focus high-angle annular dark-field (HAADF) imaging for 3D distributional analysis of Eu dopant atoms in Ca-α-SiAlON phosphors. In this context, the effects of convergence semi-angle and Eu z-position on the HAADF image contrast were investigated. Multi-slice image simulation revealed that the contrast of the dopant site was sensitive to change of the defocus level. When the defocus level matched the depth position of a Eu atom, the contrast intensity was significantly increased. The large convergence semi-angle greatly increased the depth resolution because the electron beam tends spread instead of channeling along the atomic columns. Through-focus HAADF-STEM imaging was used to analyze the Eu atom distribution surrounding 10nm cubes with defocus steps of 0.68nm each. The contrast depth profile recorded with a narrow step width clearly analyzed the possible depth positions of Eu atoms. The radial distribution function obtained for the Eu dopants was analyzed using an atomic distribution model that was based on the assumption of random distribution. The result suggested that the Ca concentration did not affect the Eu distribution. The decreased fraction of neighboring Eu atoms along z-direction might be caused by the enhanced short-range Coulomb-like repulsive forces along the z-direction.
- Published
- 2017
27. Microencapsulated phase change materials with high heat capacity and high cyclic durability for high-temperature thermal energy storage and transportation
- Author
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Takehito Hiraki, Chunyu Zhu, Genki Saito, Nan Sheng, Tomohiro Akiyama, Daiki Hanzaki, and Takahiro Nomura
- Subjects
Phase transition ,Materials science ,Chemical substance ,020209 energy ,Mechanical Engineering ,Mechanical engineering ,02 engineering and technology ,Building and Construction ,Management, Monitoring, Policy and Law ,Sensible heat ,Thermal energy storage ,Phase-change material ,Heat capacity ,Durability ,General Energy ,0202 electrical engineering, electronic engineering, information engineering ,Composite material ,Science, technology and society - Abstract
Latent heat storage (LHS) technology employing phase change materials (PCMs) has received great attention as an alternative to conventional solid sensible heat storage (SHS) for future high-temperature energy utilisation systems. In this study, we report the synthesis of a core-shell type microencapsulated PCM (MEPCM) consisting of Al-25 wt% Si microspheres (mean diameter of 36.3 μm and melting temperature of 577 °C) as the core (PCM) and Al2O3 as the shell. The MEPCM was prepared in two steps involving (1) the formation of an AlOOH precursor shell on the PCM microspheres by a hydroxide precipitation process in hot water and (2) heat-oxidation treatment in an O2 atmosphere to form a stable Al2O3 shell. In particular, the effects of heat-oxidation temperature on the shell morphology, shell crystal structure, mechanical strength, heat capacity, and cyclic durability of the prepared MEPCMs were examined. The resultant MEPCM is composed of a stable α-Al2O3 shell and Al-25 wt% Si core with an effective void inside the core to allow for volume expansion of the PCMs during solid-liquid phase transitions. The heat capacity measured for this material is five times higher than that of conventional solid SHS materials. Additionally, the MEPCM exhibits excellent durability up to 300 heating and cooling cycles under oxygen atmosphere. Consequently, it can potentially be used in the next-generation LHS-based high-temperature thermal energy storage and transportation systems.
- Published
- 2017
28. Enhanced cycling performance of surface-doped LiMn2O4 modified by a Li2CuO2-Li2NiO2 solid solution for rechargeable lithium-ion batteries
- Author
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Chunyu Zhu, Cheng-Gong Han, Nan Sheng, Tomohiro Akiyama, Takahiro Nomura, and Genki Saito
- Subjects
cathode ,Materials science ,Scanning electron microscope ,General Chemical Engineering ,Analytical chemistry ,chemistry.chemical_element ,02 engineering and technology ,Manganese ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,chemistry ,Transmission electron microscopy ,Phase (matter) ,LiMn2O4 ,Lithium ,0210 nano-technology ,surface modification ,Dissolution ,Solid solution - Abstract
A series of surface-doped LiMn2O4 samples modified by a Li2CuO2-Li2NiO2 solid solution were synthesized using a simple and facile sol-gel method to achieve the enhanced cycling performance, especially at elevated temperatures. The corresponding phase structure and morphology were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The modified layer on the surface of LiMn2O4 particles, featuring a LiNi delta Mn2-delta O4-like phase, together with a Li2CuO2-Li2NiO2 solid solution, as confirmed by XRD and transmission electron microscopy (TEM), plays a key role in alleviating the dissolution of manganese, thus enhancing the cycling performance and rate capability relative to bare LiMn2O4. The 0.5 wt.%-modified LiMn2O4 sample delivers a discharge capacity of 113 mAh g(-1), and a capacity retention of 93.2% following 300 cycles at 1C and 25 degrees C, which is higher than the values of 96 mAh g(-1) and 81.2% for bare LiMn2O4. In addition, at 55 degrees C, a capacity retention of 81.2% at 1C is obtained for the 0.5 wt.%-modified LiMn2O4 sample after 200 cycles, compared to 70.0% for bare LiMn2O4. Modifying the surface of the latter by a LiNi delta Mn2-delta O4-like phase mixed with a Li2CuO2Li2NiO2 solid solution, is an effective strategy for improving electrochemical properties.
- Published
- 2017
29. Estimating the Spatial Distribution of Ca Dopants in α-SiAlON by Statistical Analysis of HAADF-STEM Image
- Author
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Norihito Sakaguchi, Yuji Kunisada, Fuuta Yamaki, and Genki Saito
- Subjects
010302 applied physics ,Sialon ,Materials science ,Dopant ,Mechanical Engineering ,Mineralogy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Spatial distribution ,01 natural sciences ,Mechanics of Materials ,0103 physical sciences ,General Materials Science ,Statistical analysis ,0210 nano-technology - Published
- 2017
30. INFLUENCE OF NUMBER OF WIND-FORCE SAMPLES ON RESPONSE OF HIGH-RISE BASE-ISOLATED BUILDING USING ELASTOPLASTIC MODEL
- Author
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Takeshi Ohkuma, Junji Katagiri, Keisuke Yoshie, Daiki Sato, Genki Saito, and Haruyuki Kitamura
- Subjects
business.industry ,Ensemble average ,0211 other engineering and technologies ,020101 civil engineering ,02 engineering and technology ,Building and Construction ,Structural engineering ,Multi degree of freedom ,0201 civil engineering ,Wind force ,021105 building & construction ,Architecture ,Base (exponentiation) ,business ,Geology ,High rise - Published
- 2017
31. Atomic and Local Electronic Structures of Ca2AlMnO5+δ as an Oxygen Storage Material
- Author
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Genki Saito, Yuji Kunisada, Takahiro Nomura, Norihito Sakaguchi, and Kazuki Hayami
- Subjects
Oxygen storage ,Chemistry ,General Chemical Engineering ,Analytical chemistry ,Solid oxygen ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,Electronic structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Oxygen ,0104 chemical sciences ,Chemical bond ,Covalent bond ,Oxidation state ,Scanning transmission electron microscopy ,Materials Chemistry ,0210 nano-technology - Abstract
We investigated the atomic and local electronic structures of Ca2AlMnO5+δ to assess its potential as an oxygen storage material. High-angle annular dark-field scanning transmission electron microscopy was used to investigate structural changes in the material during oxygen storage. We found that the AlO4 tetrahedra convert to AlO6 octahedra during such a process. According to the Mn L-edge electron energy-loss near-edge structure (ELNES) measurements, the Mn oxidation state increased from +3 to +4 on oxygen storage. The observed site-resolved oxygen K-ELNES and first-principles electronic structure calculations showed that each nonequivalent oxygen site has different characteristics, corresponding to local chemical bonding and oxygen intake and release. For Ca2AlMnO5, the prepeak intensity was higher at MnO6 octahedral sites, indicating covalent bonding between the oxygen and Mn atoms. After oxygen storage, the ELNES spectra revealed that the Jahn–Teller distortion of the Mn sites was suppressed by the in...
- Published
- 2016
32. Facile synthesis of MnO/carbon composites by a single-step nitrate-cellulose combustion synthesis for Li ion battery anode
- Author
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Chunyu Zhu, Cheng-Gong Han, Genki Saito, and Tomohiro Akiyama
- Subjects
Battery (electricity) ,Thermogravimetric analysis ,Materials science ,Inorganic chemistry ,chemistry.chemical_element ,Composite ,02 engineering and technology ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,Lithium-ion battery ,symbols.namesake ,X-ray photoelectron spectroscopy ,Materials Chemistry ,Cellulose ,MnO ,Mechanical Engineering ,Metals and Alloys ,Li ion battery ,021001 nanoscience & nanotechnology ,Anode ,0104 chemical sciences ,Combustion synthesis ,chemistry ,Mechanics of Materials ,symbols ,0210 nano-technology ,Raman spectroscopy ,Carbon - Abstract
In this paper, a novel method is proposed to produce MnO/carbon composites, in which the MnO nanoparticles were embedded into a porous carbon matrix, by a single-step nitrate-cellulose combustion synthesis. The composition, structure and morphology of the composites were characterized by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and scanning/transmission electron microscopy. The composites were used as lithium ion battery anodes to evaluate their electrochemical properties. The MnO/carbon composite with a proper carbon content showed enhanced cycling performance and capacity retention, which delivered a reversible capacity of 561 mAh g −1 after 90 cycles at 0.2 A g −1 . The easy production and good electrochemical properties enables the composite to be a possible candidate as an anode alternative for high-performance lithium ion battery.
- Published
- 2016
33. Twin formation in hematite during dehydration of goethite
- Author
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Norihito Sakaguchi, Tomohiro Akiyama, Yuji Kunisada, Takahiro Nomura, and Genki Saito
- Subjects
Diffraction ,Goethite ,Twinning ,Hematite ,Crystal growth ,02 engineering and technology ,01 natural sciences ,Transformation ,Geochemistry and Petrology ,0103 physical sciences ,General Materials Science ,010306 general physics ,Thermal decomposition ,Dehydration ,Chemistry ,021001 nanoscience & nanotechnology ,Surface energy ,Crystallography ,Electron diffraction ,Transmission electron microscopy ,visual_art ,visual_art.visual_art_medium ,0210 nano-technology ,Crystal twinning ,Twin boundary - Abstract
Twin formation in hematite during dehydration was investigated using X-ray diffraction, electron diffraction, and high-resolution transmission electron microscopy (TEM). When synthetic goethite was heated at different temperatures between 100 and 800 °C, a phase transformation occurred at temperatures above 250 °C. The electron diffraction patterns showed that the single-crystalline goethite with a growth direction of [001]G was transformed into hematite with a growth direction of [100]H. Two non-equivalent structures emerged in hematite after dehydration, with twin boundaries at the interface between the two variants. As the temperature was increased, crystal growth occurred. At 800 °C, the majority of the twin boundaries disappeared; however, some hematite particles remained in the twinned variant. The electron diffraction patterns and high-resolution TEM observations indicated that the twin boundaries consisted of crystallographically equivalent prismatic (100) (010), and (1 $$\bar{1}$$ 0) planes. According to the total energy calculations based on spin-polarized density functional theory, the twin boundary of prismatic (100) screw had small interfacial energy (0.24 J/m2). Owing to this low interfacial energy, the prismatic (100) screw interface remained after higher-temperature treatment at 800 °C.
- Published
- 2016
34. Salt-assisted combustion synthesis of Ca-α-SiAlON:Eu2+ phosphors
- Author
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Genki Saito, Tomohiro Akiyama, Norihito Sakaguchi, Jing Niu, Xuemei Yi, and Yuji Kunisada
- Subjects
Sialon ,Materials science ,Photoluminescence ,Mechanical Engineering ,Metals and Alloys ,Mineralogy ,Phosphor ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Combustion ,01 natural sciences ,Diluent ,0104 chemical sciences ,law.invention ,Lattice constant ,Chemical engineering ,Mechanics of Materials ,law ,Materials Chemistry ,Thermal stability ,0210 nano-technology ,Light-emitting diode - Abstract
In this study, Ca-α-SiAlON:Eu2+ yellow phosphors for white light-emitting diodes (LEDs) were synthesized via a facile combustion synthesis method by using CaO, Eu2O3, Si, and Al as raw materials, while NaCl and Si3N4 were utilized as diluents to contain the combustion temperature. The concentration of Eu was varied, and the resulting changes in phase purity, photoluminescence properties, and thermal quenching were investigated. We observed that the increase in lattice constant depended on the amount of Al, while the Ca sites were partially substituted by Eu ions. The synthesized Ca-α-SiAlON:Eu2+ powders exhibited emission wavelength at 556–560 nm and high thermal stability, revealing high potential for application in white LEDs.
- Published
- 2016
35. Influence of Module Structure on Reliability of Silicon Solar Cells
- Author
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Katsuhiko Shirasawa, Genki Saito, Hidetaka Takato, Shuichi Asao, and Taeko Semba
- Subjects
010302 applied physics ,Materials science ,Moisture ,Silicon ,business.industry ,05 social sciences ,chemistry.chemical_element ,Electroluminescence ,Modular design ,01 natural sciences ,law.invention ,Reliability (semiconductor) ,chemistry ,law ,0103 physical sciences ,Solar cell ,Optoelectronics ,Degradation (geology) ,0501 psychology and cognitive sciences ,business ,050104 developmental & child psychology ,High humidity - Abstract
In order to investigate the influence of the difference in module structure on the degradation of the solar cell, two kinds of different solar modules were fabricated, and a high temperature and high humidity test was carried out and the degradation mode was compared by electrical characteristics and electroluminescence inspection. Although degradation of output occurred in both modules, different degradation modes were confirmed by electroluminescence images. It is assumed that the difference in degradation mode between these modular structures is due to the difference in concentration distribution inside the module of moisture intruded into the module and acetic acid generated from the encapsulant inside the module.
- Published
- 2019
36. In-situ observation of abnormal grain growth in a low-alloyed carbon steel using SEM-EBSD
- Author
-
Masayoshi Takeuchi, Tianglong Zhang, Koki Minoguchi, Munekazu Ohno, Norihito Sakaguchi, Takuya Yamaoka, Taichi Sano, Kiyotaka Matsuura, and Genki Saito
- Subjects
010302 applied physics ,Austenite ,Materials science ,Carbon steel ,Misorientation ,Metallurgy ,02 engineering and technology ,engineering.material ,Abnormal grain growth ,021001 nanoscience & nanotechnology ,01 natural sciences ,Grain growth ,0103 physical sciences ,engineering ,General Materials Science ,Grain boundary ,0210 nano-technology ,Pinning force ,Electron backscatter diffraction - Abstract
Because abnormal grain growth (AGG) degrades mechanical properties of industrial polycrystalline materials such as steel, understanding and controlling AGG are important. In this study, AGG of Al-Nb-microalloyed low-carbon steel was investigated at 1100°C using in-situ scanning electron microscopy-electron backscatter diffraction (SEM-EBSD). Owing to the pinning particles of AlN and Nb(C,N), fine austenite grains formed initially, and AGG appeared owing to the dissolution of the pinning particles at high temperatures. Relatively large grains invaded the surrounding smaller grains with a size ratio of approximately 0.3, resulting in AGG. We developed the in-situ observation method to investigate the AGG of the carburization process using a diffusion couple of high- and low-carbon steels. The carbon diffusion into the low-carbon steel from the high-carbon steel enhanced the grain growth of the low-carbon steel. Although the detailed mechanism is still unclear, we clearly showed that carburization can reduce the pinning force. When focusing on the misorientation of the grain boundary, grain boundaries with misorientation angles of 50–59° remained during AGG, which is explained by their lower mobility owing to their lower grain boundary energy. These results suggest that the difference in grain-boundary mobility can induce duplex grain growth with a bimodal distribution, resulting in AGG.
- Published
- 2021
37. Rapid oxygen storage and release with Brownmillerite-structured Ca2AlMnO5
- Author
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Tomohiro Akiyama, Yuji Kunisada, Keisuke Abe, Takahiro Nomura, Genki Saito, Ayumu Sato, and Norihito Sakaguchi
- Subjects
Materials science ,Oxygen storage ,Mechanical Engineering ,Diffusion ,Metals and Alloys ,Oxygen evolution ,Nanoparticle ,02 engineering and technology ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Durability ,0104 chemical sciences ,Catalysis ,Chemical engineering ,Mechanics of Materials ,Materials Chemistry ,engineering ,Brownmillerite ,Particle size ,0210 nano-technology - Abstract
Brownmillerite-structured Ca2AlMnO5 is inexpensive and capable of rapid oxygen storage and release. This study focused on improving the oxygen storage/release rate of Ca2AlMnO5, which is essential for its application in practical oxygen production systems. Two approaches were investigated for improving the oxygen-trapping ability of Ca2AlMnO5: heat treatment for 2 h and 24 h after solution combustion synthesis (SCS) and the addition of Pt nanoparticles as a catalyst. Noticeably, crystalline Ca2AlMnO5 was formed after heat treatment at 1250 °C for at least 2 h. For the 2-h heat treatment, the average particle size of Ca2AlMnO5 was 11.4 μm, while that for the 24-h treatment was 18.9 μm. This reduction in the particle size increases the oxygen storage/release rate because of the relatively short diffusion distance within the particles. The oxygen storage rate increased with the addition of Pt nanoparticles because the nanoparticles were distributed across the surface and acted as catalyst. This catalyst accelerated the oxygen-evolution reaction by activating the surface reactions between oxygen ions and the Ca2AlMnO5 particles. The short 2-h heat treatment prevented the Pt nanoparticles from aggregating. When the Pt nanoparticle addition was implemented in combination with the 2-h heat treatment, the storage and release rates were drastically improved, i.e., by 2.5 and 6.1 times, respectively, compared with the sample after 24-h heat treatment without Pt nanoparticles. The oxygen storage/release rate remained constant even after repeated use at 550 °C, for over 25 cycles. Furthermore, Ca2AlMnO5 suffered no surface damage, and none of the Pt nanoparticles re-agglomerated after this test, further indicating the durability of the treated material.
- Published
- 2021
38. Optimization of the Dehydration Temperature of Goethite to Control Pore Morphology
- Author
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Tomohiro Akiyama, Takahiro Nomura, Genki Saito, and Norihito Sakaguchi
- Subjects
Materials science ,Goethite ,Morphology (linguistics) ,Mechanical Engineering ,Metals and Alloys ,02 engineering and technology ,021001 nanoscience & nanotechnology ,medicine.disease ,020501 mining & metallurgy ,0205 materials engineering ,Chemical engineering ,Mechanics of Materials ,visual_art ,Materials Chemistry ,visual_art.visual_art_medium ,medicine ,pore morphology ,goethite ,Dehydration ,dehydration temperature ,0210 nano-technology - Abstract
This study optimizes the dehydration temperature of goethite to control pore morphology. The pore morphology was characterized by using transmission electron microscopy and the nitrogen adsorption method. When the goethite was dehydrated at 200–250°C, slit-like pores with a width lesser than 2 nm were formed along the [010] direction. These slit-like pores changed to spherical micropores (300–500°C), and eventually disappeared (600–800°C). Compared to the synthetic goethite, natural goethite has a lower crystallinity and smaller primary particle size of under 100 nm. The natural goethite before dehydration contained 4 nm pores as cracks that remained even after heating to 800°C. In the case of natural goethite, the optimum dehydration temperature for higher surface area and pore volume was 350°C, which was higher than that of 250°C for the synthetic goethite.
- Published
- 2016
39. Limonitic Laterite Ore as a Catalyst for the Dry Reforming of Methane
- Author
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Takahiro Nomura, Genki Saito, Keisuke Abe, and Tomohiro Akiyama
- Subjects
Carbon dioxide reforming ,General Chemical Engineering ,Metallurgy ,Energy Engineering and Power Technology ,chemistry.chemical_element ,02 engineering and technology ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Methane ,0104 chemical sciences ,Catalysis ,chemistry.chemical_compound ,Nickel ,Fuel Technology ,chemistry ,Transmission electron microscopy ,Laterite ,engineering ,Particle ,0210 nano-technology ,Dispersion (chemistry) - Abstract
We investigated four catalysts for the dry reforming of methane: three Ni-containing natural iron ores (LN, SN, and NN ores) and one Ni-supported ore (Ni-supported NN ore) to solve the problems about unused high-temperature waste heat and CO2 emission in the steel industry. The CO2 conversion ratio was highest for the LN ore (1.18 wt % Ni), followed by Ni-supported NN (1.0 wt % Ni), SN (0.30 wt % Ni), and NN (0 wt % Ni) ores. The CO2 conversion ratio of the LN ore was much higher than that of the Ni-supported NN ore, despite the fact that they contained almost the same amount of Ni. This is because the LN ore had a higher surface area and a higher nickel dispersion. Transmission electron microscopy with energy-dispersive X-ray spectroscopy revealed that Ni existed quite finely in the LN ore but existed as a larger particle (20 nm) in the Ni-supported NN ore. Smaller Ni particles have a higher surface area, resulting in the higher catalytic performance of the LN ore. More CO2 and CH4 reacted and higher amo...
- Published
- 2016
40. Improved electrochemical performance of LiMn2O4 surface-modified by a Mn4+-rich phase for rechargeable lithium-ion batteries
- Author
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Chunyu Zhu, Cheng-Gong Han, Genki Saito, and Tomohiro Akiyama
- Subjects
Materials science ,Scanning electron microscope ,General Chemical Engineering ,Metallurgy ,Spinel ,chemistry.chemical_element ,02 engineering and technology ,Electrolyte ,Manganese ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,chemistry ,Chemical engineering ,Phase (matter) ,Chemical Engineering(all) ,Electrochemistry ,engineering ,Surface modification ,Lithium ,0210 nano-technology ,Dissolution - Abstract
The surface of spinel LiMn2O4 is modified with different quantities of a Mn4+-rich phase prepared by a facile sol-gel method to improve electrochemical properties at elevated temperatures. Impurity-free and uniform morphologies for the LiMn2O4 particles are demonstrated from the X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The Mn4+-rich phase modified on the surface of the LiMn2O4 alleviates the dissolution of manganese in the electrolyte, thus improving the cycling performance and rate capability relative to the bare LiMn2O4. 1 wt.%-modified LiMn2O4 delivers a capacity retention of 92.7% and a discharge capacity of 113.5 mAh g−1 after 200 cycles at 1C and 25 °C, compared with that of 83.1%, and 100.8 mAh g−1 for the bare LiMn2O4. In addition, after 100 cycles, a capacity retention of 88.6% at 1C is achieved for 1 wt.%-modified LiMn2O4 at 55 °C, which is higher than the 76.0% for the bare LiMn2O4. Furthermore, this sample shows the best rate capability among all samples. The Mn4+-rich phase is an appropriate candidate for modifying surfaces to suppress dissolution of manganese, thereby improving the electrochemical properties of LiMn2O4.
- Published
- 2016
41. Solution combustion synthesis of porous Sn–C composite as anode material for lithium ion batteries
- Author
-
Tomohiro Akiyama, Norihito Sakaguchi, Genki Saito, Cheng-Gong Han, and Chunyu Zhu
- Subjects
Materials science ,General Chemical Engineering ,Inorganic chemistry ,Composite number ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,Combustion ,01 natural sciences ,0104 chemical sciences ,law.invention ,Anode ,chemistry ,Chemical engineering ,Mechanics of Materials ,law ,Phase (matter) ,Calcination ,Lithium ,0210 nano-technology ,Carbon - Abstract
In this study, a Sn–C composite material as anode material for lithium ion batteries was fabricated via MgO template-assisted solution combustion synthesis, in which the starting material was a gel containing Sn(NO 3 ) 2 , glycine (C 2 H 5 O 2 N) as the carbon source, and Mg(NO 3 ) 2 ·6H 2 O for the template. After the combustion reaction, the generated MgO was removed from the carbon, and the Sn nanoparticles were dispersed into a porous carbon structure during the carbon reduction of SnO 2 under calcination in N 2 . The effects of ratios of glycine ( n ) and MgO ( m ) on the material phase, morphology, carbon content, and electrochemical properties were mainly investigated. At glycine ( n ) ratios of 2 and 3, the SnO 2 phase was not fully reduced to Sn. With n > 3, a composite material of metallic Sn nanoparticles and carbon was synthesized, in which the ratio of carbon increased with increasing n . With increasing m , the porosity of the particles increased, resulting in enhanced cyclic stability owing to the buffer space provided by the porous structure of carbon. The composite material obtained at n = 4 and m = 4 exhibited the highest reversible capacity of 588 mA h/g after 100 discharge/charge cycles at a current rate of 0.5 A/g as compared to the 269 mA h/g observed for n = 4 and m = 2.
- Published
- 2016
42. MnO nanocrystals incorporated in a N-containing carbon matrix for Li ion battery anodes
- Author
-
Tomohiro Akiyama, Cheng-Gong Han, Chunyu Zhu, and Genki Saito
- Subjects
Thermogravimetric analysis ,Materials science ,General Chemical Engineering ,Inorganic chemistry ,chemistry.chemical_element ,02 engineering and technology ,Manganese ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,Lithium-ion battery ,symbols.namesake ,anode material ,X-ray photoelectron spectroscopy ,composite ,manganese oxide ,carbon ,General Chemistry ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Anode ,chemistry ,Chemical engineering ,symbols ,lithium ion battery ,0210 nano-technology ,Raman spectroscopy ,Carbon - Abstract
In this study, MnO nanocrystals incorporated in a N-containing carbon matrix were fabricated by the facile thermal decomposition of manganese nitrate-glycine gels. MnO/C composites with different carbon contents were prepared by controlling the initial ratio of manganese to glycine. The composition, phase structure and morphology of the composites were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, scanning and transmission electron microscopy, and thermogravimetric analysis. The results indicated that MnO nanocrystals were uniformly embedded in the N-doped carbon matrix. The carbon matrix could effectively enhance the electrical conductivity of MnO and alleviate the strain arising from the discharge/charge cycling. The composite materials exhibited high discharge/charge capacities, superior cycling performance, and excellent rate capability. A high reversible capacity of 556 mA h g(-1) was obtained after 110 cycles of discharging and charging at a current rate of 0.5 A g(-1). Even at a high current rate of 3 A g(-1), the sample still delivered a capacity of around 286 mA h g(-1). The easy production and superior electrochemical properties enables the composites to be a promising candidate as an anode alternative for high-performance lithium-ion batteries.
- Published
- 2016
43. Generation of solution plasma over a large electrode surface area.
- Author
-
Genki Saito, Yuki Nakasugi, and Tomohiro Akiyama
- Subjects
- *
NANOSTRUCTURED materials , *ELECTRODES , *ELECTROLYSIS , *TEMPERATURE , *GASES , *POWER density - Abstract
Solution plasma has been used in a variety of fields such as nanomaterials synthesis, the degradation of harmful substances, and solution analysis. However, as existing methods are ineffective in generating plasma over a large surface area, this study investigated the contact glow discharge electrolysis, in which the plasma was generated on the electrode surface. To clarify the condition of plasma generation, the effect of electrolyte concentration and temperature on plasma formation was studied. The electrical energy needed for plasma generation is higher than that needed to sustain a plasma, and when the electrolyte temperature was increased from 32 to 90 °C at 0.01 M NaOH solution, the electric power density for vapor formation decreased from 2005 to 774 W/cm2. From these results, we determined that pre-warming of the electrolyte is quite effective in generating plasma at lower power density. In addition, lower electrolyte concentrations required higher power density for vapor formation owing to lower solution conductivity. On the basis these results, a method for large-area and flat-plate plasma generation is proposed in which an initial small area of plasma generation is extended. When used with a plate electrode, a concentration of current to the edge of the plate meant that plasma could be formed by covering the edge of the electrode plate. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
44. Glycine–nitrate-based solution-combustion synthesis of SrTiO3
- Author
-
Yuki Nakasugi, Genki Saito, Norihito Sakaguchi, Chunyu Zhu, and Tomohiro Akiyama
- Subjects
Materials science ,Mechanical Engineering ,Metals and Alloys ,Nanoparticle ,Nanotechnology ,Combustion ,Dispersant ,law.invention ,Chemical engineering ,Mechanics of Materials ,law ,Materials Chemistry ,Photocatalysis ,Calcination ,Particle size ,Photodegradation ,Porosity - Abstract
In this paper, we describe the glycine–nitrate-based solution combustion synthesis of SrTiO3 nanoparticles. The effects of the fuel ratio, φ, and washing treatment by HNO3 on the size, morphology, and crystalline structure of the synthesized particles were investigated. The photocatalytic activity of the final samples was also evaluated by measuring the photodegradation of methylene blue. The samples, which were calcined at 1000 °C for 10 h after combustion synthesis, were mainly SrTiO3. When φ was increased, the number of pores in the sample was increased because of the increase in volume of ejected gas. Additionally, the initial particle size decreased with increasing φ because glycine functioned not only as a fuel but also as a dispersant and stabilizer. After washing in a HNO3 solution, the porous structure decomposed to particles with high crystalline structure. The photocatalytic activity of SrTiO3 was significantly improved by HNO3 washing owing to the elimination of impurities, the increase in surface area, and the uncovering of the surface that consisted of (100) planes.
- Published
- 2015
45. Urchin-like hollow-structured cobalt oxides with excellent anode performance for lithium-ion batteries
- Author
-
Chunyu Zhu, Genki Saito, and Tomohiro Akiyama
- Subjects
Materials science ,Mechanical Engineering ,Thermal decomposition ,Inorganic chemistry ,Metals and Alloys ,chemistry.chemical_element ,Electrochemistry ,Lithium-ion battery ,Anode ,chemistry.chemical_compound ,chemistry ,Mechanics of Materials ,Materials Chemistry ,Hydroxide ,Lithium ,Cobalt ,Faraday efficiency - Abstract
Urchin-like CoO and Co 3 O 4 hollow structures with potential use as anodes in lithium ion batteries were synthesized via the facile thermal decomposition of precipitated amorphous cobalt carbonate hydroxide under either Ar or air. The morphology and, consequently, electrochemical properties of the samples were highly dependent on the precipitation temperature. The cobalt oxides, as derived from precursors that were obtained at room temperature, exhibited superior activity to those obtained at 50 °C and 80 °C because of their unique nanosized architecture. Meanwhile, CoO samples demonstrated much better cyclability and rate capability than Co 3 O 4 samples, as they exhibited much higher coulombic efficiency and lower hysteresis for lithium insertion/extration. The curved, short, and closely entangled nanowires of CoO sample, which was derived from room temperature precursor, yielded excellent electrochemical performance. The sample displayed a high reversible capacity of about 850 mAh g −1 at a current density of 500 mA g −1 , a good stability through 50 cycles with a high coulombic efficiency of about 98%, and a high rate capability of 610 mAh g −1 even at a rate of 3000 mA g −1 .
- Published
- 2015
46. An Influence of the Module Structure on Reliability of Crystalline Silicon Solar Cells
- Author
-
Hidetaka Takato, Taeko Semba, Shuichi Asao, Katsuhiko Shirasawa, and Genki Saito
- Subjects
Silver paste ,Reliability (semiconductor) ,Materials science ,chemistry ,Aluminium ,chemistry.chemical_element ,Crystalline silicon ,Composite material ,Corrosion - Published
- 2020
47. Formation of Different Si
- Author
-
Xiongzhang, Liu, Ran, Guo, Sengjing, Zhang, Qingda, Li, Genki, Saito, Xuemei, Yi, and Takahiro, Nomura
- Abstract
Silicon nitride (Si
- Published
- 2018
48. A facile solution combustion synthesis of nanosized amorphous iron oxide incorporated in a carbon matrix for use as a high-performance lithium ion battery anode material
- Author
-
Tomohiro Akiyama, Chunyu Zhu, and Genki Saito
- Subjects
Materials science ,Mechanical Engineering ,Inorganic chemistry ,Composite number ,Metals and Alloys ,Iron oxide ,chemistry.chemical_element ,Composite ,Anode material ,Electrochemistry ,Iron oxides ,Lithium-ion battery ,Anode ,Amorphous solid ,Lithium ion battery ,chemistry.chemical_compound ,Nanoparticle ,chemistry ,Mechanics of Materials ,Materials Chemistry ,Lithium ,Faraday efficiency - Abstract
An amorphous iron oxide–carbon composite has been fabricated through an effective, inexpensive, and scalable method employing solution combustion synthesis. Amorphous iron oxide nanoparticles with diameters of about 5 nm were synthesized and uniformly embedded in a dense carbon matrix. The synthesized composite exhibits enhanced cyclability and rate capability, showing a high reversible capacity of 687 mA h g − 1 after 200 discharge/charge cycles at a current rate of 0.5 A g − 1 , compared to the 400 mA h g − 1 observed for Fe 2 O 3 nanoparticles. This enhanced performance was retained despite more demanding conditions, delivering a high capacity of about 525 mA h g − 1 and a nearly perfect coulombic efficiency even after 400 cycles at 1 A g − 1 . The easy production and superior electrochemical properties of this composite suggest that it is a promising material for use as an anode material in high performance lithium ion batteries.
- Published
- 2015
49. Solution plasma synthesis of Au nanoparticles for coating titanium dioxide to enhance its photocatalytic activity
- Author
-
Yuki Nakasugi, Genki Saito, Norihito Sakaguchi, Tomohiro Akiyama, and Toru Yamashita
- Subjects
Materials science ,Catalyst support ,Metals and Alloys ,Nanoparticle ,Nanotechnology ,Surfaces and Interfaces ,Electrolyte ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Titanium dioxide ,Materials Chemistry ,Photocatalysis ,Rhodamine B ,Light emission ,Particle size - Abstract
A convenient method for coating titanium dioxide (TiO 2 ) by Au nanoparticles (AuNPs) is demonstrated in solution plasma to improve the photocatalytic activity of TiO 2 . AuNPs from a metallic Au electrode were bonded to the surface of a commercial TiO 2 powder, which acted as a catalyst support, with the reaction taking place in an electrolyte solution. The effect of diverse plasma conditions on the size and productivity of the AuNPs was investigated initially to provide a reference in the absence of TiO 2 . At 290 V, “ partial plasma ” was attained, with only a weak light emission surrounding the Au electrode. Conditions then evolved to “ full plasma ”, with a strong orange emission at 330 V. Partial or full status was maintained for 1 h at 300 and 400 V, respectively. At the transition to full, the AuNP particle size increased from 3.72 to 6.09 nm and the productivity increased dramatically from 0.025 to 0.87 mg h − 1 mm − 2 . Stronger plasma very efficiently synthesized AuNPs, and therefore, it was adopted for further study. AuNP–TiO 2 combinations were formed by applying 400 V to a TiO 2 -dispersed solution. In these experiments, TiO 2 coated with AuNPs was synthesized; these combinations of AuNP–TiO 2 had 0.44 mol% of Au. The photocatalytic activity of AuNP–TiO 2 was investigated by measuring the degradation of Rhodamine B (RhB). Under UV irradiation, the AuNP–TiO 2 particles removed up to 95% of the dye in 70 min. Commercial TiO 2 achieves values closer to 85%. The results thus raise the possibility that solution plasma methods can be generalized as a means for achieving catalysis-enhancing coatings.
- Published
- 2015
50. Glycine/sucrose-based solution combustion synthesis of high-purity LiMn2O4 with improved yield as cathode materials for lithium-ion batteries
- Author
-
Chunyu Zhu, Tomohiro Akiyama, Genki Saito, and Cheng-Gong Han
- Subjects
Materials science ,Scanning electron microscope ,General Chemical Engineering ,Inorganic chemistry ,chemistry.chemical_element ,Nanoparticle ,Electrochemistry ,Cathode ,law.invention ,chemistry ,Mechanics of Materials ,law ,Phase (matter) ,Yield (chemistry) ,Lithium ,Calcination ,Nuclear chemistry - Abstract
Single-phase, high-purity nanosized LiMn 2 O 4 powders, which are employed as cathode materials for lithium-ion batteries, were produced by solution combustion synthesis using glycine, sucrose, and nitrate, followed by calcination. Phase structure and morphology of the powders were characterized by X-ray diffraction and scanning electron microscopy. The electrochemical performance was measured by galvanostatic charge–discharge cycling in a voltage range of 3.2–4.4 V. The analysis of yield, morphology, and electrochemical performance mainly focused on the influence of different glycine/sucrose ratios. Compared to the sample obtained using 100% glycine, the yields of powders obtained by adding sucrose to the fuel were remarkably improved, from around 50% to over 90%. The highest discharge capacity at 1 C was obtained for the sample with 2% added sucrose, which retained a capacity of 116.6 mAh/g after 80 cycles.
- Published
- 2015
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