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A facile solution combustion synthesis of nanosized amorphous iron oxide incorporated in a carbon matrix for use as a high-performance lithium ion battery anode material
- Source :
- Journal of Alloys and Compounds. 633:424-429
- Publication Year :
- 2015
- Publisher :
- ELSEVIER, 2015.
-
Abstract
- An amorphous iron oxide–carbon composite has been fabricated through an effective, inexpensive, and scalable method employing solution combustion synthesis. Amorphous iron oxide nanoparticles with diameters of about 5 nm were synthesized and uniformly embedded in a dense carbon matrix. The synthesized composite exhibits enhanced cyclability and rate capability, showing a high reversible capacity of 687 mA h g − 1 after 200 discharge/charge cycles at a current rate of 0.5 A g − 1 , compared to the 400 mA h g − 1 observed for Fe 2 O 3 nanoparticles. This enhanced performance was retained despite more demanding conditions, delivering a high capacity of about 525 mA h g − 1 and a nearly perfect coulombic efficiency even after 400 cycles at 1 A g − 1 . The easy production and superior electrochemical properties of this composite suggest that it is a promising material for use as an anode material in high performance lithium ion batteries.
- Subjects :
- Materials science
Mechanical Engineering
Inorganic chemistry
Composite number
Metals and Alloys
Iron oxide
chemistry.chemical_element
Composite
Anode material
Electrochemistry
Iron oxides
Lithium-ion battery
Anode
Amorphous solid
Lithium ion battery
chemistry.chemical_compound
Nanoparticle
chemistry
Mechanics of Materials
Materials Chemistry
Lithium
Faraday efficiency
Subjects
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 633
- Database :
- OpenAIRE
- Journal :
- Journal of Alloys and Compounds
- Accession number :
- edsair.doi.dedup.....e60cdfde7fcdb740d733e201c0d15842