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A facile solution combustion synthesis of nanosized amorphous iron oxide incorporated in a carbon matrix for use as a high-performance lithium ion battery anode material

Authors :
Tomohiro Akiyama
Chunyu Zhu
Genki Saito
Source :
Journal of Alloys and Compounds. 633:424-429
Publication Year :
2015
Publisher :
ELSEVIER, 2015.

Abstract

An amorphous iron oxide–carbon composite has been fabricated through an effective, inexpensive, and scalable method employing solution combustion synthesis. Amorphous iron oxide nanoparticles with diameters of about 5 nm were synthesized and uniformly embedded in a dense carbon matrix. The synthesized composite exhibits enhanced cyclability and rate capability, showing a high reversible capacity of 687 mA h g − 1 after 200 discharge/charge cycles at a current rate of 0.5 A g − 1 , compared to the 400 mA h g − 1 observed for Fe 2 O 3 nanoparticles. This enhanced performance was retained despite more demanding conditions, delivering a high capacity of about 525 mA h g − 1 and a nearly perfect coulombic efficiency even after 400 cycles at 1 A g − 1 . The easy production and superior electrochemical properties of this composite suggest that it is a promising material for use as an anode material in high performance lithium ion batteries.

Details

Language :
English
ISSN :
09258388
Volume :
633
Database :
OpenAIRE
Journal :
Journal of Alloys and Compounds
Accession number :
edsair.doi.dedup.....e60cdfde7fcdb740d733e201c0d15842