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2. Exceptional Activity for Methane Combustion over Modular Pd@CeO2 Subunits on Functionalized AI2O3.

Author

Cargnello, M., Jaén, J. J. Delgado, Garrido, J. C. Hernández, Bakhmutsky, K., Montini, T., Gámez, J. J. Calvino, Gorte, R. J., and Fornasiero, P.

Subjects
*SUPRAMOLECULAR chemistry, *METHANE, *OXIDATION, *CATALYST synthesis, *PALLADIUM catalysts, *ELECTRON microscopy, *STRUCTURAL analysis (Science), *GREENHOUSE gas mitigation, *CATALYST testing
Abstract

The article discusses research describing a supramolecular approach for improved methane (CH4)-oxidation catalysts in which single units composed of a palladium (Pd) core and a ceria (CeO2) shell are deposited onto a functionalized hydrophobic alumina (Al2O3). Topics include the environmental impact of CH4, which is a potent greenhouse gas (GHG), the need for improved CH4-oxidation catalysts to reduce CH4 emissions and improve the performance of gas turbines, and a structural analysis using electron microscopy and other methods to examine the activity for methane combustion under various temperature conditions.

Published
2012
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