Search

Here we show a novel approach to characterize the gas transfer behavior of silicon-oxide (SiO x) coatings and explain the underlying dynamics. For this, we investigate the coating on a nm-scale both by measurement and simulation. Positron annihilation spectroscopy (PAS) and quantum mechanical electronic structure-based molecular dynamics simulations are combined to characterize the porous landscape of SiO x coatings. This approach analyses the influence of micropores smaller than 2 nm in diameter on gas permeation which are difficult to study with conventional methods. We lay out the main pore diameter ranges and their associated porosity estimates. An influence of layer growth on pore size and porosity was found, with an increased energy input during layer deposition leading to smaller pore sizes and a reduced porosity. The molecular dynamics simulations quantify the self-diffusion of oxygen and water vapor through those PAS deducted micropore ranges for hydrophilic and hydrophobic systems. The theoretical pore size ranges are fitting to our PAS results and complete them by giving diffusion coefficients. This approach enables detailed analysis of pore morphology on mass transport through thin film coatings and characterization of their barrier or membrane performance. This is a crucial prerequisite for the development of an exhaustive model of pore dominated mass transports in PECVD coatings. [ABSTRACT FROM AUTHOR]

To engage in socio-emotional interactions, children with autism spectrum conditions (ASC) need support to understand and convey emotions. In our approach, a humanoid robot (Pepper, Softbanks Robotics) acts as a tutor for the child within autism care. The robot, equipped with multimodal sensor technology to acquire the emotional feedback of the child, stimulates the child to perform tasks, adapted to its current arousal state. By in-, or decreasing the difficulties of implemented training modules, the child can be given the appropriate task according to its emotional state. The child’s arousal is measured with different techniques implemented in and on the robot: emotion detection based on audio recordings of the speech signal and camera detected facial expressions, or heart rate. To this end, the remote Photoplethysmography (rPPG) signal from camera recordings of the subjects’ face is acquired. While its unintrusive measurement is an advantage, a major drawback for rPPG is its proneness to motion and light artefacts requiring de-noising steps. A wavelet transform based on log-Gabor wavelets and a filter bank with 32 filters was implemented. The signal was filtered with a prior filter and afterwards with a Markov chain in order to extract the underlying pulse rate. Within an initial study, five children were observed watching videos with different co-notated emotions. As reference for the heart rate (HR), a wristband (empatica E4) was used. The captured emotions of all subjects were annotated to identify low and high arousal parts and positive and negative emotions. Extracted HR from rPPG-data indicated a correlation with the annotated emotions.

We present a method to model the gas permeation through silicon-oxide thin film coatings that are afflicted with nanoscale defects. With it, we are able to give an estimation of the diffusion coefficient in bulk by subtracting the influence of the defects. The model is based on data obtained from positron annihilation spectroscopy, which is processed to yield possible defect allocation patterns of the coatings. For a systematic evaluation of these patterns, a path through the coating is calculated and then subjected to in-depth analysis to evaluate the used approach as well as to interpret the results for insights on the permeation mechanisms. The model appears to function as intended and no unexpected behaviour is observed. The defect volume share is overestimated, which can be retraced to the underlying algorithm, and a correction method is applied to the resulting bulk diffusion coefficient. The model gives reasonable results both for oxygen and water vapor permeation. These results can be used in following works that build on the presented model. [ABSTRACT FROM AUTHOR]