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2. A covalent succinylcysteine-like intermediate in the enzyme-catalyzed transformation of maleate to fumarate by maleate isomerase

Author

Fisch, Florian, Fleites, Carlos Martinez, Delenne, Marie, Hauer, Bernhard, Baudendistel, Nina, Turkenburg, Johan P., Hart, Sam, Bruce, Neil C., and Grogan, Gideon

Subjects
Catalysis -- Analysis, Cysteine -- Chemical properties, Gene mutations -- Analysis, Isomerization -- Analysis, Nocardia -- Genetic aspects, Chemistry
Abstract

Several mutation studies are conducted to analyze the significance of maleate isomerase (MI) in the catalysis of the cis-trans isomerization of the double bond present in the maleate. The formation of the covalent succinylcysteine-like intermediate during the isomerization process is also discussed.

Published
2010

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