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Frustration in nematic-ordered media (endowed with a director field) is treated in a purely geometric fashion in a flat, two-dimensional space. We recall the definition of quasi-uniform distortions and envision these as viable ways to relieve director fields prescribed on either a straight line or the unit circle. We prove that using a planar spiral is the only way to fill the whole plane with a quasi-uniform distortion. Apart from that, all relieving quasi-uniform distortions can at most be defined in a half-plane; however, in a generic sense, they are all asymptotically spirals.

Chromonic liquid crystals are lyotropic materials which are attracting growing interest for their adaptability to living systems. To describe their elastic properties, the classical Oseen-Frank theory requires anomalously small twist constants and (comparatively) large saddle-splay constants, so large as to violate one of Ericksen’s inequalities, which guarantee that the Oseen-Frank stored-energy density is bounded below. While such a violation does not prevent the existence and stability of equilibrium distortions in problems with fixed geometric confinement, the study of free-boundary problems for droplets has revealed a number of paradoxical consequences. Minimizing sequences driving the total energy to negative infinity have been constructed by employing ever growing needle-shaped tactoids incorporating a diverging twist (Paparini and Virga in Phys. Rev. E 106: 044703, 2022). To overcome these difficulties, we propose here a novel elastic theory that extends for chromonics the classical Oseen-Frank stored energy by adding a quartic twist term. We show that the total energy of droplets is bounded below in the quartic twist theory, so that the known paradoxes are ruled out. The quartic term introduces a phenomenological length "Equation missing" in the theory; this affects the equilibrium of chromonics confined within capillary tubes. Use of published experimental data allows us to estimate "Equation missing".

Chromonic liquid crystals constitute a novel lyotropic phase, whose elastic properties have so far been modeled within the classical Oseen-Frank theory, provided that the twist constant is assumed to be considerably smaller than the saddle-splay constant, in violation of one Ericksen inequality. This paper shows that paradoxical consequences follow from such a violation for droplets of these materials surrounded by an isotropic fluid. For example, tactoids with a degenerate planar anchoring simply disintegrate indefinitely in myriads of smaller ones.

Walter Noll (1925–2017) was an American mathematician of German birth who made lasting contributions to the foundations of continuum physics and the classical non-linear field theory. This essay is an attempt to put in a broader perspective Noll’s methods and achievements in the hope that young generations of researchers may find their inspiration in the talent and depth of the old. By no means should this be considered as a historical account on the development of continuum mechanics through the second half of the twentieth century. We are content to illuminate Noll’s precious legacy.

An extensive experimental study of the shapes of two-dimensional bipolar droplets of the chromonic N nematic phase of disodium cromoglycate (DSCG) sandwiched between glass plates, by Y.-K. Kim et al. was published in [Y.-K. Kim et al., J. Phys.: Condens. Matter 25, 404202 (2013)]. The paper includes a mathematical model of this system. We have extended this study by further theoretical modelling. Our results are in good, quantitative agreement with the experimental data. The model has produced what promises to be a more accurate estimate for the isotropic surface ten- sion at the nematic/isotropic solution interface—and predicts a regime of shape bistability (which has not yet been observed) for larger droplets, where tactoids (pointed, zeppelin-shaped droplets) and smooth-edged discoids can coexist in equilibrium. The general method presented in this paper is also applied to the tactoids formed by F-actin filaments in solution, for which an estimate is given for the value of the isotropic surface tension at the nematic/isotropic interface.

We study packings of hard spheres on lattices. The partition function, and therefore the pressure, may be written solely in terms of the accessible free volume, i.e. the volume of space that a sphere can explore without touching another sphere. We compute these free volumes using a leaky cell model, in which the accessible space accounts for the possibility that spheres may escape from the local cage of lattice neighbors. We describe how elementary geometry may be used to calculate the free volume exactly for this leaky cell model in two- and three-dimensional lattice packings and compare the results to the well-known Carnahan-Starling and Percus-Yevick liquid models. We provide formulas for the free volumes of various lattices and use the common tangent construction to identify several phase transitions between them in the leaky cell regime, indicating the possibility of coexistence in crystalline materials., Comment: 18 pages, 10 figures

Tactoids are pointed, spindlelike droplets of nematic liquid crystal in an isotropic fluid. They have long been observed in inorganic and organic nematics, in thermotropic phases as well as lyotropic colloidal aggregates. The variational problem of determining the optimal shape of a nematic droplet is formidable and has only been attacked in selected classes of shapes and director fields. Here, by considering a special class of admissible solutions for a bipolar droplet, we study the prevalence in the population of all equilibrium shapes of each of the three that may be optimal (tactoids primarily among them). We show how the prevalence of a shape is affected by a dimensionless measure $\ensuremath{\alpha}$ of the drop's volume and the ratios ${k}_{24}$ and ${k}_{3}$ of the saddle-splay constant ${K}_{24}$ and the bending constant ${K}_{33}$ of the material to the splay constant ${K}_{11}$. Tactoids, in particular, prevail for $\ensuremath{\alpha}⪅16.2+0.3{k}_{3}\ensuremath{-}(14.9\ensuremath{-}0.1{k}_{3}){k}_{24}$. Our class of shapes (and director fields) is sufficiently different from those employed so far to unveil a rather different role of ${K}_{24}$.

Within this work, we derive and analyse an expression for the free energy of a single-species system in the thermodynamic limit in terms of a generalised cavity volume, that is exact in general, and in principle applicable to systems across their entire range of density, as well as to particles within a general coordinate space. This provides a universal equation of state, and can thus relate the cavity volume to classical results, such as Mayer’s cluster expansions. Through this, we are able to provide some insight into the connections between cavity volume and free energy density, as well as their consequences. We use examples which permit explicit computations to further probe these results, reclaiming the exact results for a classical Tonks gas and providing a novel derivation of Onsager’s free energy for a single species, isotropic system. Given the complexity of the problem, we also provide a local lattice ansatz, exact in one dimension, with which we may approximate the cavity volume for hard sphere systems to provide an accurate equation of state in the cases of hard disks and spheres in both dilute regimes as well as beyond the freezing transition.

Abstract Minimizing the elastic free energy of a thin sheet of nematic polymer network among smooth isometric immersions is the strategy purported by the mainstream theory. In this paper, we broaden the class of admissible spontaneous deformations: we consider ridged isometric immersions, which can cause a sharp ridge in the immersed surfaces. We propose a model to compute the extra energy distributed along such ridges. This energy comes from bending; it is shown under what circumstances it scales quadratically with the sheet’s thickness, falling just in between stretching and bending energies. We put our theory to the test by studying the spontaneous deformation of a disk on which a radial hedgehog was imprinted at the time of crosslinking. We predict the number of folds that develop in terms of the degree of order induced in the material by external agents (such as heat and illumination). Graphic Abstract

Nematic polymeric networks are (heat and light) activable materials, which combine the features of rubber and nematic liquid crystals. When only the stretching energy of a thin sheet of nematic polymeric network is minimized, the intrinsic (Guassian) curvature of the shape it takes upon (thermal or optical) actuation is determined. This, unfortunately, produces a multitude of possible shapes, for which we need a selection criterion, which may only be provided by a correcting bending energy depending on the extrinsic curvatures of the deformed shape. The literature has so far offered approximate corrections depending on the mean curvature. In this paper, we derive the appropriate bending energy of a sheet of polymeric nematic network from the celebrated neo-classical energy of nematic elastomers in three space dimensions. This task is performed via a dimension reduction based on a modified Kirchhoff-Love hypothesis, which withstands to the criticism of more sophisticated analytical tools. The result is a surface elastic free-energy density where stretching and bending are blended together; they may or may not be length-separated, and should be minimized together. The extrinsic curvatures of the deformed shape not only feature in the bending energy through the mean curvature, but also through the relative orientation of the nematic director in the frame of the directions of principal curvature.

Paradoxes in the impact dynamics of rigid bodies are known to arise in the presence of friction. We show here that, on specific occasions, in the absence of friction, the conservation laws of classical mechanics are also incompatible with the collisions of smooth, strictly convex rigid bodies. Under the assumption that the impact impulse is along the normal direction to the surface at the contact point, two convex rigid bodies that are well separated can come into contact, and then interpenetrate each other. This paradox can be demonstrated in both 2D and 3D when the collisions are tangential, in which case no momentum or energy transfer between the two bodies is possible. The postcollisional interpenetration can be realized through the contact points or through neighboring points only. The penetration distance is shown to be [Formula: see text]. The conclusion is that rigid-body dynamics is not compatible with the conservation laws of classical mechanics.

The classical theory of liquid crystal elasticity as formulated by Oseen and Frank describes the (orientable) optic axis of these soft materials by a director $\mathbf{n}$. The ground state is attained when $\mathbf{n}$ is uniform in space; all other states, which have a non-vanishing gradient $\nabla\mathbf{n}$, are distorted. This paper proposes an algebraic (and geometric) way to describe the local distortion of a liquid crystal by constructing from $\mathbf{n}$ and $\nabla\mathbf{n}$ a third-rank, symmetric and traceless tensor $\mathbf{A}$ (the octupolar tensor). The (nonlinear) eigenvectors of $\mathbf{A}$ associated with the local maxima of its cubic form $\Phi$ on the unit sphere (its octupolar potential) designate the directions of distortion concentration. The octupolar potential is illustrated geometrically and its symmetries are charted in the space of distortion characteristics, so as to educate the eye to capture the dominating elastic modes. Special distortions are studied, which have everywhere either the same octupolar potential or one with the same shape, but differently inflated.

Ordinary nematic liquid crystals are characterized by having a uniform director field as ground state. In such a state, the director is the same everywhere and no distortion is to be seen at all. We give a definition of uniform distortion which makes precise the intuitive notion of seeing everywhere the same director landscape. We characterize all such distortions and prove that they fall into two families, each described by two scalar parameters. Uniform distortions exhaust R. Meyer's heliconical structures, which, as it has recently been recognized, include the ground state of twist-bend nematics. The generalized elasticity of these new phases is treated with a simple free-energy density, which can be minimized by both uniform and non-uniform distortions, the latter injecting a germ of elastic frustration.

Toroidal nematics are droplets of nematic liquid crystals in the form of a circular torus. When the nematic director is subject to planar degenerate boundary conditions, the bend-only director field with vector lines along the parallels of all nested torodial shells is an equilibrium solution for all values of the elastic constants. Local stability analyses have shown that an instability is expected to occur for sufficiently small values of the twist elastic constant. It is natural to wonder whether in this regime the global equilibrium would be characterized by a monotonic twist, or not. In the former case, the twist distribution over the torus' circular cross-section would be represented pictorially by a fennel-like surface emanating from the centre. We prove that instead the stable twist distribution is represented by a lily-like surface. Thus, generically the twist distribution is not monotonic and its maximum may fall well within the torus, far away from the boundary. To cope with the peculiar complexity of the elastic free-energy functional in the fully non-linear setting, we developed an ad hoc deep-learning optimization method, which here is also further validated and documented for it promises to be applicable to other similar problems, equally intractable analytically.

Octupolar tensors are third order, completely symmetric and traceless tensors. Whereas in 2D an octupolar tensor has the same symmetries as an equilateral triangle and can ultimately be identified with a vector in the plane, the symmetries that it enjoys in 3D are quite different, and only exceptionally reduce to those of a regular tetrahedron. By use of the octupolar potential, that is, the cubic form associated on the unit sphere with an octupolar tensor, we shall classify all inequivalent octupolar symmetries. This is a mathematical study which also reviews and incorporates some previous, less systematic attempts.

Nematic polymer networks (NPNs) are nematic elastomers within which the nematic director is enslaved to the elastic deformation. The elastic free energy of a NPN sheet of thickness $h$ has both stretching and bending components (the former scaling like h, the latter scaling like $h^3$). NPN sheets bear a director field $\mathbf{m}$ imprinted in them (usually, uniformly throughout their thickness); they can be activated by changing the nematic order (e.g. by illumination or heating). This paper illustrates an attempt to compute the bending energy of a NPN sheet and to show which role it can play in determining the activated shape. Our approach is approximate: the activated surface consists of flat sectors connected by ridges, where the unit normal jumps and the bending energy is concentrated. By increasing the number of ridges, we should get closer to the real situation, where the activated surface is smooth and the bending energy is distributed on it. The method is applied to a disk with imprinted a spiraling hedgehog. It is shown that upon activation the disk, like a tiny hand, is able to grab a rigid lamina.

By use of a standard theoretical method, we arrive at a coarse-grained elastic energy density for twist-bend nematic (Ntb) phases which features two fields, a director t designating the outer macroscopic optic axis and a variable cone angle reflecting the inner heliconical microscopic structure. The theory describes the Ntb phase through a nematic-like energy with an extra scalar order parameter. The coupling with an external field is similarly described at the same coarse-grained level and a field-induced transition to the ordinary nematic phase is also predicted to take place in a confined Frederiks cell, in the simplified setting where natural boundary conditions are prescribed on the cell’s plates.

In this experimental and theoretical study, we examine the equilibrium shapes of quasi-two-dimensional twist-bend nematic (Ntb) drops formed within a planarly aligned nematic layer of the liquid crystal CB7CB. Initially, at the setting point of the Ntb phase, the drops assume a nonequilibrium cusped elliptical geometry with the major axis orthogonal to the director of the surrounding nematic fluid; this growth is governed principally by anisotropic heat diffusion. The drops attain equilibrium through thermally driven dynamical evolution close to their melting temperature. They are associated with a characteristic twin-striped morphology that transforms into the familiar focal conic texture as the temperature is lowered. At equilibrium, large millimetric drops are tactoidlike, elongated along the director of the surrounding nematic fluid. This geometry is explained using a mathematical model that features two dimensionless parameters, of which one is the structural cone angle of the Ntb phase and the other is the relative strength of mismatch elastic energy at the drop's interface. Both parameters are extracted from the observations by measuring the aspect ratio of the equilibrium shapes and the inner corner angle of the cusps.

When a material surface is functionalized so as to acquire some type of order, functionalization of which soft condensed matter systems have recently provided many interesting examples, the modeller faces an alternative. Either the order is described on the curved, physical surface where it belongs, or it is described on a flat surface that is unrolled as pre-image of the physical surface under a suitable height function. This paper applies a general method that pursues the latter avenue by lifting whatever order tensor is deemed appropriate from a flat to a curved surface. We specialize this method to nematic shells, for which it also provides a simple, but perhaps convincing interpretation of the outcomes of some molecular-dynamics experiments on ellipsoidal shells.

Toroidal nematics are nematic liquid crystals confined within a circular torus and subject to planar degenerate anchoring on the boundary of the torus. They may be droplets floating in an isotropic environment or cavities carved out of a solid substrate. A universal solution of Frank's elastic free energy is an equilibrium configuration for the nematic director field, irrespective of the values of the elastic constants, whose vector lines are the coaxial parallels of the torus. We explore the local stability of this configuration and identify a range of parameters where the main drive towards instability does not come from the surface-like elastic constant $K_{24}$ being large, but from the the ratio $K_2/K_3$ of the twist to bend elastic constants being small, which also makes our study relevant to chromonic liquid crystals.

"A version of Ericksen's order parameter theory of liquid crystals is studied in the case of a cylindrical container with anchoring on the curved surface only. The solutions are determined rather explicitly and the equilibrium orientation field is shown to vary between that of the Frank solution (possessing an axial disclination) and that of the disclination-free Cladis-Kleman solution as a scalar parameter in the free energy varies from 0 to [infinity]."

Both repulsive and attractive molecular interactions can be used to explain the onset of nematic order. The object of this paper is to combine these two nematogenic molecular interactions in a unified theory. This attempt is not unprecedented; what is perhaps new is the focus on the understanding of nematics in the high density limit. There, the orientational probability distribution is shown to exhibit a unique feature: it has compact support on configuration space. As attractive interactions are turned on, the behavior changes, and at a critical attractive interaction strength, thermotropic behavior of the Maier-Saupe type is attained., Comment: 14 pages, 4 figures

We study nematic liquid crystal textures exhibiting topological defects (TDs) on a two-dimensional (2D) toroidal shell. For the toroidal topology the total topological charge of TDs is equal to zero. We use a mesoscopic Landau-de Gennes approach which features a 2D nematic order tensor Q. We show that fat tori unbind TDs. If no extrinsic free energy couples Q with the Weingarten tensor of the torus, then defects and antidefects are assembled along the innermost and the outermost circles of the torus, respectively. In this case, we estimate the critical condition for the onset of TDs using an electrostatic analogy. If, on the other hand, an extrinsic free energy is present, then defects are repelled from these regions.

The celebrated work of Onsager on hard particle systems, based on the truncated second order virial expansion, is valid at relatively low volume fractions for large aspect ratio particles. While it predicts the isotropic-nematic phase transition, it does not provide a realistic equation of state in that the pressure remains finite for arbitrarily high densities. In this work, we derive a mean field density functional form of the Helmholtz free energy for nematics with hard core repulsion. In addition to predicting the isotropic-nematic transition, the model provides a more realistic equation of state. The energy landscape is much richer, and the orientational probability distribution function in the nematic phase possesses a unique feature---it vanishes on a nonzero measure set in orientation space.

A third-order three-dimensional symmetric traceless tensor, called the \emph{octupolar} tensor, has been introduced to study tetrahedratic nematic phases in liquid crystals. The octupolar \emph{potential}, a scalar-valued function generated on the unit sphere by that tensor, should ideally have four maxima capturing the most probable molecular orientations (on the vertices of a tetrahedron), but it was recently found to possess an equally generic variant with \emph{three} maxima instead of four. It was also shown that the irreducible admissible region for the octupolar tensor in a three-dimensional parameter space is bounded by a dome-shaped surface, beneath which is a \emph{separatrix} surface connecting the two generic octupolar states. The latter surface, which was obtained through numerical continuation, may be physically interpreted as marking a possible \emph{intra-octupolar} transition. In this paper, by using the resultant theory of algebraic geometry and the E-characteristic polynomial of spectral theory of tensors, we give a closed-form, algebraic expression for both the dome-shaped surface and the separatrix surface. This turns the envisaged intra-octupolar transition into a quantitative, possibly observable prediction. Some other properties of octupolar tensors are also studied.

Nematic shells are colloidal particles coated with nematic liquid crystal molecules which may freely glide and rotate on the colloid's surface while keeping their long axis on the local tangent plane. We describe the nematic order on a shell by a unit director field on an orientable surface. Equilibrium fields can then be found by minimising the elastic energy, which in general is a function of the surface gradient of the director field. We learn how to extract systematically out of this energy a fossil component, related only to the surface and its curvatures, which expresses a curvature potential for the molecular torque. At hyperbolic points on the colloid's surface, and only there, the alignment preferred by the curvature potential may fail to be a direction of principal curvature. There the fossil energy becomes bistable.

Onsager's paper on phase transition and phase coexistence in anisotropic colloidal systems is a landmark in the theory of lyotropic liquid crystals. However, an uncompromising scrutiny of Onsager's original derivation reveals that it would be rigorously valid only for ludicrous values of the system's number density (of the order of the reciprocal of the number of particles). Based on Penrose's tree identity and an appropriate variant of the mean-field approach for purely repulsive, hard-core interactions, our theory shows that Onsager's theory is indeed valid for a reasonable range of densities.

We present a unified classical treatment of partially constrained elastic rods. Partial constraints often entail singularities in both shapes and reactions. Our approach encompasses both sleeve and adhesion problems, and provides simple and unambiguous derivations of counterintuitive results in the literature. Relationships between reaction forces and moments, geometry, and adhesion energies follow from the balance of energy during quasistatic motion. We also relate our approach to the balance of material momentum and the concept of a driving traction. The theory is generalizable and can be applied to a wide array of contact, adhesion, gripping, and locomotion problems., Comment: edited text

Octupolar order in three space dimensions is described by a real-valued, fully symmetric and traceless, third-rank tensor A. The real generalized eigenvalues of A are also the critical values of a real-valued potential $\Phi$ defined on the unit sphere $\mathbb{S}^{2}$ by A. Generalized eigenvalues of A and critical points of $\Phi$ are equivalent means to describe octupolar order in a molecular assembly according to Buckingham's formula for the probability density distribution. Intuition suggests that $\Phi$ would generically have four maxima, corresponding to the most probable molecular orientations, so that a (possibly distorted) tetrahedron would effectively describe A. This paper shows that another generic octupolar state flanks the expected one, featuring three maxima of $\Phi$ . The two generic states are divided by a separatrix manifold, which may physically represent an intra-octupolar transition.

Nematic shells are thin films of nematic liquid crystal deposited on the boundary of colloidal particles, where liquid crystal molecules may freely glide, while remaining tangent to the surface substrate. The surface nematic order is described here by an appropriate tensor field Q, which vanishes wherever a defect occurs in the molecular order. We show how the classical concept of parallel transport on a manifold introduced by Levi-Civita can be adapted to this setting to define the topological charge m of a defect. We arrive at a simple formula to compute m from a generic representation of Q. In a number of separate appendices, we revisit in a unified language several, apparently disparate applications of Levi-Civita’s parallel transport.

Basic methods from bifurcation theory are applied to derive a criterion that predicts when a symmetric tricritical point may occur in a transition between condensed ordered phases described by any finite number of scalar order parameters. At such a point, a change of order takes place in the phase transition, which passes from first to second order, or vice versa.

Within a two-dimensional Landau–de Gennes tensorial formalism we study the equilibrium configurations of nematic shells, thin films of nematic liquid crystal deposited on the boundary of colloidal particles of arbitrary shape enforcing a degenerate tangential anchoring on the nematic molecules. In this formalism, defects appear wherever a scalar order parameter vanishes. Their total number is the colloidal valence, as this is the number of molecular bridges that can bind every colloid to its peers. We show how the defect organization on a colloidal particle is affected by the Gaussian curvature of the colloidal boundary, to the point of changing its valence.

To appreciate the universal qualitative features of defect annihilation in nematic liquid crystals, we study how the viscous force of reorientational dynamics behaves under a transformation that reverses the sign of the defect's topological charge. As an illustration of our general results, we consider a class of point defects that were first studied by A. Saupe. The reorientational viscous forces acting on them differ dramatically from those acting on line defects.

We propose a simple phenomenological model for hydrodynamic defect dynamics in nematic liquid crystals, inspired by the Ericksen–Leslie theory. We identify the main forces that govern both fluid and defect motion and we comment on their symmetry. As shown for two annihilating disclinations, our model is predictive for arbitrary length scales and topological charges.

The extension of Bogoliubov Jr.’s minimax principle to biaxial nematic liquid crystals has recently made it possible to derive the universal mean-field phase diagram for all quadrupolar interactions between nematogenic biaxial molecules, including those rendering the mean-field free energy $${\fancyscript{F}_0}$$ indefinite. To justify this extension, so far largely based on heuristic arguments, we prove here a minimum principle that also applies when $${\fancyscript{F}_0}$$ is indefinite. Bogoliubov Jr.’s minimax principle then emerges as a characterization of this minimum principle. The theory presented here is more general than its application to biaxial nematic liquid crystals could reveal. It essentially builds upon a concavity property of $${\fancyscript{F}_0}$$ in the order tensor associated with the repulsive component of the molecular interaction.

We present a phenomenological theory for the homogeneous phases of nematic liquid crystals constituted by biaxial molecules. We propose a general polynomial potential in two macroscopic order parameter tensors that reproduces the mean-field phase diagram confirmed by Monte Carlo simulations [De Matteis et al. in Phys Rev E 72:041706 (2005)] and recently recognized to be universal [Bisi et al. in Phys Rev E 73:051709 (2006)] for dispersion force molecular pair-potentials enjoying the D 2h symmetry. The requirement that the phenomenological theory comply uniquely with this phase diagram reduces considerably the admissible phenomenological coefficients, both in their number and in the ranges where they can vary.

We propose a model to explore the competition between two mechanisms possibly at work in a nematic liquid crystal confined within a flat cell with strong uniaxial planar conditions on the bounding plates and subject to an external field. To obtain an electric field perpendicular to the plates, a voltage is imposed across the cell; no further assumption is made on the electric potential within the cell, which is therefore calculated together with the nematic texture. The Landau-de Gennes theory of liquid crystals is used to derive the equilibrium nematic order tensor Q. When the voltage applied is low enough, the equilibrium texture is nearly homogeneous. Above a critical voltage, there exist two different possibilities for adjusting the order tensor to the applied field within the cell: plain director reorientation, i.e., the classical Freedericksz transition, and order reconstruction. The former mechanism entails the rotation of the eigenvectors of Q and can be described essentially by the orientation of the ordinary uniaxial nematic director, whilst the latter mechanism implies a significant variation of the eigenvalues of Q within the cell, virtually without any rotation of its eigenvectors, but with the intervention of a wealth of biaxial states. Either mechanism can actually occur, which yields different nematic textures, depending on material parameters, temperature, cell thickness and the applied potential. The equilibrium phase diagram illustrating the prevailing mechanism is constructed for a significant set of parameters.

We study the invariance properties of the molecular Hamiltonian interaction put forward by Straley to describe biaxial nematic phases. We show that the reduction to two out of four scalar order parameters, which was accidently remarked upon in the literature, is indeed a rigorous consequence of the Hamiltonian invariance for specific values of the interaction parameters. The stability analysis of the mean-field free energy in the reduction classes for the order parameters reveals a sequence of Landau triple points.

We propose three integral criteria that must be satisfied by all closed surfaces with constant mean curvature immersed in the three-dimensional Euclidean space. These criteria are integral identities that follow from requiring the second variation of the area functional to be invariant under rigid displacements. We obtain from them a new proof of the old result by Delaunay, to the effect that the sphere is the only closed axis-symmetric surface.

We represent explicitly the excluded volume V(e){B(1),B(2)} of two generic cylindrically symmetric, convex rigid bodies, B(1) and B(2), in terms of a family of shape functionals evaluated separately on B(1) and B(2). We show that V(e){B(1),B(2)} fails systematically to feature a dipolar component, thus making illusory the assignment of any shape dipole to a tapered body in this class. The method proposed here is applied to cones and validated by a shape-reconstruction algorithm. It is further applied to spheroids (ellipsoids of revolution), for which it shows how some analytic estimates already regarded as classics should indeed be emended.

Octupolar order is described in two space dimensions in terms of the maxima (and conjugated minima) of the probability density associated with a third-rank, fully symmetric and traceless tensor. Such a representation is shown to be equivalent to diagonalizing the relevant third-rank tensor, an equivalence which however is only valid in the two-dimensional case.