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Interfacial and morphological features of a twist-bend nematic drop
- Source :
- Soft Matter. 12:4967-4978
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- In this experimental and theoretical study, we examine the equilibrium shapes of quasi-two-dimensional twist-bend nematic (Ntb) drops formed within a planarly aligned nematic layer of the liquid crystal CB7CB. Initially, at the setting point of the Ntb phase, the drops assume a nonequilibrium cusped elliptical geometry with the major axis orthogonal to the director of the surrounding nematic fluid; this growth is governed principally by anisotropic heat diffusion. The drops attain equilibrium through thermally driven dynamical evolution close to their melting temperature. They are associated with a characteristic twin-striped morphology that transforms into the familiar focal conic texture as the temperature is lowered. At equilibrium, large millimetric drops are tactoidlike, elongated along the director of the surrounding nematic fluid. This geometry is explained using a mathematical model that features two dimensionless parameters, of which one is the structural cone angle of the Ntb phase and the other is the relative strength of mismatch elastic energy at the drop's interface. Both parameters are extracted from the observations by measuring the aspect ratio of the equilibrium shapes and the inner corner angle of the cusps.
- Subjects :
- Elliptic geometry
Materials science
Biaxial nematic
Condensed matter physics
business.industry
Drop (liquid)
Elastic energy
FOS: Physical sciences
Non-equilibrium thermodynamics
02 engineering and technology
General Chemistry
Condensed Matter - Soft Condensed Matter
021001 nanoscience & nanotechnology
Condensed Matter Physics
01 natural sciences
Condensed Matter::Soft Condensed Matter
Optics
Liquid crystal
0103 physical sciences
Soft Condensed Matter (cond-mat.soft)
Ligand cone angle
010306 general physics
0210 nano-technology
Anisotropy
business
Subjects
Details
- ISSN :
- 17446848 and 1744683X
- Volume :
- 12
- Database :
- OpenAIRE
- Journal :
- Soft Matter
- Accession number :
- edsair.doi.dedup.....f2037662e1133cb8637f3f3ce95633c7