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The contamination on the surface of objects caused by: fungi, microbes, bacteria and viruses (and also coronavirus) can be solved using UV rays and/or ozone gas. For this reason, a UV-Ozone reactor apparatus with low cost was mounted to test two different types of HID (high intensity discharge) lamps: high pressure mercury vapor lamp (HPMVL) and metal halide lamp (MHL), both with nominal power of 400 watts and E-40 (base, screw) were studied as possible method of disinfection. Each lamp used the respective electromagnetic ballasts and both were manufactured by Osram Company. These lamps have two bulb types: the outer bulb which was removed and it is responsible for filtering the ultraviolet wavelengths and the internal bulb (where there is mercury, argon or metal halide confined at high pressure) that is the main source of ultraviolet rays. The complete apparatus was assembled using: aluminum reflector (used as a chamber), two microcomputer fans and a wooden base covered by an aluminum foil. A rubber strip was placed at the edge of the reflector for better adhesion on the aluminum foil (for better confinement ozone gas). The ozone concentration inside the reactor was measured with a monitor, the temperatures were measured near lamps with a thermocouple and a spectroradiometer with optical fiber was used to obtain the wavelengths. The results revealed to the elapsed time of 2 minutes a maximum peak of ozone concentration of 23 ppm for LVMAP, while the MHL presented 4.5 ppm only. The temperature obtained by HPMVL was lower with 31.5 ºC, while the MHL presented 48.0 ºC. The HPMVL presented higher amount of wavelengths at the ranges: UV-A, UV-B and UV-C, while the MHL presented only UV-A. For these reasons, it is suggested to be most promissory the use of HPMVL to combat the coronavirus and other pathogenic microorganisms.

This exploratory study was carried out with the objective to know the optical behavior of light-emitting diode (LED) lamps used and the temperature reached by electronic components that compose the driver (electronic circuit situated inside the body LED lamp) responsible to convert electrical alternating current from power line to direct current to operate the LED devices. Then, two different experiments were carried out with LED lamps. In the first experiment, 131 LED lamps used were chosen randomly and bought from household appliances store (bargain market product) presenting different nominal powers, 8, 10, 12 and 15 watts. All LED lamps were polarized at the power line at 127 V and revealed different optical behaviors, such as: not turn-on; flashing light (as strobe effect); flashing light (as strobe effect) with high intensity (more intense than normal); flashing light (as strobe effect) with low intensity (less intense than normal); fast turnon and turn-off only; and turn-on with low intensity of light (less intense than normal). The hypothesis for these behaviors can be attributed by three different behaviors: in lamps not turn-on, this failure can be attributed for dark spots that are created on the surface of LED device. In these lamps, all LED devices are electrically connected in serial. When a LED is inoperative, the electrical current is interrupted for all LED devices; damage to the electronic components caused by internal high temperature confined inside the lamp body during the operation causing electrical oscillations, as observed from different behaviors from flashing light, flashing light with high intensity, flashing light with low intensity and fast turn-on and turn-off only; swelling of the electrolytic capacitors causing low energy storage and varying the electrical current flow, the electrical current for other electronic components altered the normal optical behavior of the LED lamps. In the second experiment, the temperatures of electronic components located in driver were obtained out of body lamp revealing: from 33 (lowest temperature attributed to inductor) to 52.5ºC (highest temperature attributed to electrolytic capacitor). These temperature values represent the ideal or normal condition of operation for electronic components, but, when they are operating inside the lamp body, the found temperature values increased considerably. This characteristic can be better evidenced by strong color change (caused by accumulative temperature during the elapsed days used) on the printed circuit board used in the driver.

In this work, circular economy was investigated for commercial indium tin oxide (ITO) thin films deposited on glass substrates obtained from degraded organic light-emitting diodes (OLED). These devices were assembled and polarized at laboratory in a previous work. For each substrate, with geometry 2.5 × 2.5 cm, four OLEDs with active area of 3 × 3 mm were set up. These OLED devices were assembled with ITO as the electrode anode and successive depositions of other materials (layer-by-layer), to form the complete structure. To obtain the recovered ITO, all layers were removed from the samples containing the OLEDs previously mounted, remaining only the ITO thin films, that were cleaned with commercial product together with the received ITO/glass samples. Both samples were compared using some techniques, such as: colorimetry, electrical resistance, and Raman spectroscopy. A methodology with light-emitting diode (LED) device polarized emitting light crossing the ITO thin films was used, and the luminance with chromaticity coordinates was obtained, revealing the good transparency of the thin films. Electrical resistance of recovered ITO revealed five higher orders of magnitude in comparison to the one of received ITO. This fact can be tributed to a poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate) (PEDOT:PSS) layer, causing corrosion of the ITO thin films during the assembly of OLEDs or loss of the field lines created during the electrical measurements by probes of four-point probe. Raman spectroscopy did not show satisfactory results in the chemical composition analyses of the samples, but it indicated good cleaning process of the samples before the analyses.

In this study, optical and lifetime analyses of commercial light-emitting diode (LED) lamps were carried out with the objective to better understand these characteristics. Lamps of different manufacturers and powers were used: Ourolux of 9 watts, Kian of 9 watts, Black+Decker of 9 watts, FLC of 8 watts, Galaxy of 7 watts and Brilia of 7 watts. These LED lamps remained on by 24 hours/day for 4,291.16 hours. Illuminance measurements were analyzed once a week by each lamp inside the integrating sphere with a sensor of lux meter coupled. Results showed decrease of illuminance by elapsed time, due to the degradation. Results of the illuminance obtained between the initial moment of the experiment and the final one were calculated, revealing degradation of 19% to Ourolux, 20% to FLC, 26% to Black+Decker, 28% to Kian, 29% to Galaxy and 33% to Brilia. This study suggests that the diffusers can have different transmittance values interfering on the illuminance, since the FLC LED lamp presented illuminance with highest values than the other LED lamps tested with similar electrical and optical characteristics. This experiment showed that the nominal power of the LED lamp has no direct relation to the illuminance and, comparing the lifetime, the LED lamp manufactured by Black+Decker was the only one to reach 5,521 hours, that is a lifetime much shorter than the one described at the packages (25,000 hours) for all LED lamps tested

Os trabalhadores de enfermagem enfrentam inúmeros sofrimento psicológico, estando expostos a uma variedade de elementos geradores de desgaste. Para se manterem saudáveis os profissionais desenvolvem estratégias e fatores protetivos como a resiliência. Este estudo teve por objetivo avaliar a resiliência entre profissionais de enfermagem de setores de emergência no município de São José do Rio Preto (SP) e comparar com o número de vínculos empregatícios. Trata se de um estudo quantitativo, descritivo, correlacional e transversal, que utilizou os instrumentos de coleta de dados Questionário de Variáveis Sociodemográficas e Profissionais e a Escala de Resiliência de Wagnild & Young. Participaram do estudo 144 profissionais entre auxiliares, técnicos e enfermeiros. Nos resultados, dos 144 participantes, 18 (12,5%) trabalham mais do que 44 horas semanais, 29 (20,1%) trabalhando em mais de um turno e 33 (22,9%) acumulam, sendo 30 (20,8%) com 2 e 3 (2,1%) com 3 vínculos; dos que acumulam 21 (14,6%) colocam a necessidade financeira como motivação e 12 (8%) a busca por melhor remuneração. Altos índices de resiliência (média de 136,4) entre os participantes, sem diferença significativa com o número de horas trabalhadas (p = 0,438), turno de trabalho (p = 0,959) ou número de vínculos empregatícios (p = 0,390). Pode se concluir que os profissionais de enfermagem deste estudo exibem elevados níveis de resiliência, mesmo com a desgastante rotina, demonstrando amor, orgulho e comprometimento profissional, independente de jornada de trabalho, turnos de trabalho e número de vínculos empregatícios, entre outros.

Transparent conductive oxides (TCOs) known as indium tin oxide (ITO) and fluorine tin oxide (FTO) deposited on glass were compared by different techniques and also as anodes in organic light-emitting diode (OLED) devices with same structure. ITO produced at laboratory was compared with the commercial one manufactured by different companies: Diamond Coatings, Displaytech and Sigma-Aldrich, and FTO produced at laboratory was compared with the commercial one manufactured by Flexitec Company. FTO thin films produced at laboratory presented the lowest performance measured by Hall effect technique and also by I-V curve of OLED device with low electrical current and high threshold voltage. ITO thin films produced at laboratory presented elevated sheet resistance in comparison with commercial ITOs (approximately one order of magnitude greater), that can be related by a high number of defects as discontinuity of the chemical lattice or low crystalline structure. In the assembly of OLED devices with ITO and FTO produced at laboratory, neither presented luminances. ITO manufactured by Sigma-Aldrich company presented better electrical and optical characteristics, as low electrical resistivity, good wettability, favorable transmittance, perfect physicalchemical stability and lowest threshold voltage (from 3 to 4.5 V) for OLED devices.

In this work, organic light-emitting diode (OLED) devices were mounted using the structure: glass (as substrate)/indium tin oxide (ITO) (as anode)/poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate) (PEDOT:PSS) (as hole transport layer)/poly[9,9-dioctifluorene-alt-bis-tienilene(benzotiadiazole)] (PFTB) (as luminescent material)/aluminum-doped zinc oxide (AZO) (as electron transport layer)/aluminum (as cathode). The PFTB was synthetized at laboratory and diluted in different organic solvents as chloroform and trichlorobenzene. The I-V curves of OLED devices showed that the trichlorobenzene used to dillute the PFTB improved the performance for OLED devices promoting the highest electrical current of ≈50 mA and the lowest range of thresold voltage from ≈2.5 to 5 volts, while the device OLEDs mounted with PFTB dilutted in chloroform presented maximum electrical current of ≈23 mA and range of thresold voltage from ≈5 to 8 volts. A hypothesis that explain these results can be attributed to the boiling point of the organic solvent of trichlorobenzene (≈214.4ºC) to be higher than the one of the chloroform (≈61.1ºC), favoring better rearrangement of the polymer chains of PFTB and interfaces between thin films PFTB/PEDOT:PSS and PFTB/AZO improving the injection of charges (holes and electrons) inside the OLEDs devices.

A simple method with low cost of encapsulation for organic light emitting diode (OLED) devices mounted at laboratory was proposed to obtain considerable increase of the lifetime. In this study, it was used a capsule formed by: glass slide as substrate, a layer of polyvinyl acetate glue diluted in methyl alcohol, a layer of calcium oxide as secant and epoxy placed at the edges of capsule. The performance of this capsule was analyzed using a thin film of polymer semiconductor called as PEDOT:PSS, that is sensitive to moisture and oxygen from atmospheric air. The PEDOT:PSS thin layer was deposited between anode and cathode electrodes using commercial indium tin oxide (ITO) thin film deposited on glass substrate. The capsule was placed covering completely the PEDOT:PSS thin film, and the electrical resistance was measured by elapsed days. This result revealed lowest electrical resistance compared with other methods, showing also good performance as encapsulation process.

In this work, a spinner apparatus was mounted with some characteristics, as: low cost, easy operation, compact size, easy adaptation into the little glove box systems, no vacuum pump and low maintenance. Firstly, three different fans wereanalyzed to be used in thespinner apparatus. Then, the Arduino electronic circuit was analyzed and programmed to control the rotation speed using a pulse width modulation (PWM) and steps of acceleration with the signal distortion (caused by pulse width modulation) of thefan intern tachometer. After, the interface between the user and spinner apparatus was performed with information about: navigation through the menus; input of process parameters as rotation speed; rotation time and calibration menu. Successive depositions of organic thin films to assembly of OLED deviceswere used with the spinner apparatus. The experiment compared ITO (indium tin oxide) thin filmanodes with sheet resistances of 8 and 12 ?/? supplied by different manufacturersin the structure of the OLEDs.I-V curves of OLED devices showed that the ITO/glass of 12 ?/? presented better results with low variabilityand highest current values. All OLED devices presented some luminance showing the efficiency of spinner apparatus.

A glass flask obtained of pickled food was developed as bulb with intern vacuum to tests of encapsulation method for electroluminescent devices. At the lid of glass flask were adapted: two (02) metallic valves to vacuum or insert inert gas, one (01) pressure gauge (with high or low pressures) and one (01) printed circuit board with copper stripes for electrical connections, all these components were sealed with epoxy. In the first investigation was carried out intern vacuum at 76 cm.Hg observing the possible variation of intern pressure by elapsed time (for seven days). In the second investigation were used four (04) incandescent lamps (of 12 V and 10 W) without outer bulb to obtain the tungsten filaments that were polarized under vacuum atmosphere at different situations. After seven (07) days, only an insignificant increase of intern pressure was observed. The bulb with intern pressure at 76 cm.Hg promoted to the tungsten filament at least forty (40) polarizations, while outside the bulb (at room pressure) were obtained only two (02) polarizations with significant degradation. A layer of WO2 (tungsten oxide) with greenish yellow color formed on the surface of tungsten filament and it was obtained by microscopies and confirmed by EDXS measurement.

Records from experiments performed with Solid State Lighting technology are presented and discussed. They were done to expand the local knowledge about light output depreciation from Inorganic Light Emitting Diodes technology. Data were collected at the Campus of the University of Sao Paulo for road lighting and for interior lighting at the Institute of Energy and Environment. An integrating photometer was developed locally, it was put into service to sample light sources with Edison base type and preliminary results from a longterm lifespan experiment on the depreciation of light output are presented. The integrating photometer assembled use the configuration called 2π. It reduces the thermal and light output stabilization period, have the advantages at transportation to the test site and can avoid light distribution uniformity error.

Dispositivos OLEDS (diodos orgânicos emissores de luz) foram montados com copolimeros PFTB (emissao vermelha) e PFPF (emissao azul). Esses copolimeros foram sintetizados em laboratorio por reacao de acoplamento de Suzuki. Para avaliar o desempenho de cada copolimero, dispositivos OLEDs com arquitetura: vidro/ITO/PEDOT:PSS/COPOLIMERO (de emissao vermelha ou azul)/AZO/Al foram testados fora e dentro de um bulbo em atmosfera de nitrogenio. Esse bulbo foi montado a partir de um frasco e na tampa foram encaixadas e coladas uma placa de circuito impresso com contatos eletricos e duas valvulas para entrada e saida de gas nitrogenio (utilizado para purgar do ar atmosferico). Os resultados revelaram que o bulbo utilizado como encapsulamento apresentou diferenca no comportamento dos dispositivos OLEDs levando a aumento significativo nos desempenhos, como maior tempo de vida e menor nivel de degradacao.

This work studies the influence of the film deposition process on light emission performance and on threshold voltage of OLEDs, with architecture glass/ITO/PEDOT:PSS/PVK/Alq3/Al. The commercial PVK was dissolved in different solvents such as: chloroform, tetrahydrofuran, 1,2,4-trichlorobenzene and trimethylpentane. OLEDs were characterized by current-voltage and revealed a significant influence of the solvents, although all devices emitted green electroluminescence. A difference in threshold voltage up to 10 V was observed among OLEDs prepared from different solvents. The 1,2,4-trichlorobenzene showed best performance, presenting lowest treshold voltage (≈ 6 V), followed by tetrahydrofuran (≈ 8 V), trimethylpentane (≈ 14 V) and chloroform (≈ 16 V).

Dispositivos OLEDs (diodos orgânicos emissores de luz) foram montados com copolimero PFTB (ou poli[9,9-dioctifluoreno-altbis-tienileno (benzotiadiazol)]) como camada emissora de luz. Este copolimero foi sintetizado em laboratorio por reacao de acoplamento de Suzuki e apresentou rendimento de 80% com pico de fluorescencia maxima em ± 710 nm. Nas arquiteturas dos dispositivos OLEDs foram utilizadas camadas de AZO comercial:1-ITO/PEDOT:PSS/PFTB/Al; 2 ITO/PEDOT: PSS/AZO/PFTB/ Al; e 3 - ITO/PEDOT: PSS/PFTB/AZO/Al, todos os dispositivos nao foram encapsulados. A arquitetura 3 apresentou menor tensao de limiar com 4,5 V e espectros de emissao do OLED polarizado em diferentes tensoes, mostrando que a camada de AZO sobre o copolimero emissor, alem de atuar como camada injetora de eletrons, tambem protege o dispositivo contra a degradacao, aumentando o desempenho.

In a homemade UV-Ozone generator, different ignition tubes extracted from HID mercury vapor lamps were investigated, namely: 80, 125, 250 and 400 watts. The performance of the generator in function of the type of the ignition lamp was monitored by the measurements of the ozone concentration and the temperature increment. The results have shown that the 400 W set up presented the highest ozone production, which was used in the treatment of indium tin oxide (ITO) films. Polymer light emitting diodes were assembled using ITO films, treated for 10, 20 and 30 min, as an anode. The overall results indicate improvement of the threshold voltage (reduction) and electroluminescence of these devices.

This work aims the development of a compact spinner to be used inside the glove-box chamber to deposition of polymeric thin films used in the build of OLED devices. Initially, ten fans extracted of microcomputers were tested with commercial multi-voltage power supply. Four fans were selected based on the standard deviation of speed. A variable power supply was also built in order to get a more detailed response in terms of electrical current and speed in function of applied voltage. The fan that showed less variation of speed with applied voltage was selected for deposition tests using polymeric photoresist solution on the ITO (indium tin oxide) coated glass. This polymer was deposited by spin-coating at different speeds: 1000, 2000, 3000 and 4000 rpm and dried for the thicknesses measurement revealing good uniformity. Finally, three OLED devices were assembled with 2000 and 3000 rpm and the layers were dried under the same conditions. In the structure of the devices were used the materials deposited layer-by-layer:glass/ITO/PEDOT:PSS/ Polyfluorene (PFpf)/Al. The OLED devices revealed blue light electroluminescence. The I-V curves showed better performance for OLED devices mounted at 2000 rpm with higher current density and similar appearance to the diode curve.

An UV-Ozone reactor was developed with an ignition tube extracted into HID mercury lamp used to irradiation on zinc oxide (ZnO) and fluorinated tin oxide (FTO) films for PLEDs devices. Different exposures times were used. In contact angle measurements revealed better results for ZnO and FTO by 15 and 5 min, respectively. In Diffuse Reflectance Infra-red Fourier Transformed (DRIFT) spectroscopy allowed the observation of water, hydrocarbon and carbon dioxide adsorbed on the untreated TCO surfaces. After the UV-Ozone treatment the contaminants were significantly reduced or eliminated and the PLEDs devices decreased threshold voltages in comparison with respectively untreated TCOs.

In this work were carried out treatments with oxygen plasma and aquaregia on fluorinated tin oxide (FTO) films varying the treatment times. After treatments, the samples were analyzed by techniques measurements: sheet resistance, thickness, Hall effect, transmittance and superficial roughness. Devices using FTO/PEDOT:PSS/OC1C10-PPV/Al were assembled. In this experiment some variations were observed by sheet resistance and thickness and Hall effect measurements indicated most elevated carriers concentration and resistivity for aquaregia than that oxygen plasma. The roughness was elevated for the first minutes with treatment by aquaregia too. In the I-V curves the aquaregia devices presented the lowest threshold voltage for 30 minutes and devices treated by oxygen plasma presented a behavior most resistivity different of typical curves for PLEDs devices.

For electroluminescent devices new copolymers were synthesized using a Suzuki cross-coupling reaction based on monomers (fluorine-alt-phenylene) in conjugation with quinoline-alt-phenylene units. They were characterized by 1H NMR, 13C NMR and FTIR. TGA measurements indicated that the copolymers have good thermal properties and no weight loss was observed up to 250 °C. The UV-Vis spectra were characterized by absorptions from the fluorene-alt-phenylene and quinoline-alt-phenylene segments in the backbone, while their photoluminescence (PL) spectra dominated by emissions from the fluorene excimer. For devices assembly ITO films were treated using a High Intensity Discharge Lamp (HPMVL) without outer bulb presenting high ozone concentration than that conventional germicidal lamp. The device with ITO treated revealed significant decrease of threshold voltage (or turn-on voltage) compared by untreated with I-V curves. This decrease can be related by water and carbon dioxide extracted on surface after UV-Ozone treatment revealed by DRIFT measurements.

Neste trabalho foram realizados e estudados tratamentos superficiais sobre óxidos transparentes condutivos (TCOs) depositados sobre vidro, cuja aplicação ou finalidade é a montagem de dispositivos poliméricos eletroluminescentes. A principal intenção da utilização destes processos é diminuir a tensão de limiar e também aumentar a luminância desses dispositivos, sem interferir na transmitância original dos filmes. Três diferentes técnicas de tratamentos superficiais foram utilizadas: (a) Plasma de oxigênio; (b) Água-régia e (c) UV-Ozônio. Neste último processo, um reator foi montado utilizando uma lâmpada de vapor de mercúrio a alta pressão (tipo alta intensidade de descarga), sem o bulbo externo para fornecer a disponibilidade de radiação UV para a obtenção de ozônio a partir do ar atmosférico. Este reator com baixo custo e fácil manuseio foi montado para realizar um processo alternativo comparado aos dois processos anteriormente citados (Plasma de oxigênio e Água-Régia) e constitui o principal foco, comparando a partir de resultados experimentais obtidos por dispositivos montados, utilizando diferentes TCOs. Foi possível confirmar que o procedimento a partir do UV-Ozônio é reprodutível, pois pode substituir com vantagens as outras duas técnicas que apresentam custo mais elevado ou que exige manuseio especial. Pela utilização de diferentes períodos de tratamento como a única variável, nas condições estabelecidas durante os experimentos, foi mantida uma amostra sem tratamento para comparação em cada resultado obtido. Em comparação aos outros tratamentos, a técnica de UV-ozônio apresentou reprodutibilidade. Neste caso, verificamos que houve eliminação de contaminantes indesejáveis como carbono e hidrocarbonetos detectadas pela técnica de DRIFT (Diffuse Reflectance Infra-Red Fourier Transformed) e melhor espalhamento de polímero (PEDOT:PSS) sobre a superfície através da técnica de ângulo de contato foi observado. Para os filmes de ITO e FTO o período ótimo foi observado durante 5 minutos e para o ZnO, durante 15 minutos. Os resultados das medições de resistência de folha, espessura e efeito Hall, não revelaram significantes modificações. Revelando que as superfícies foram influenciadas apenas atomicamente ou molecularmente. In this work superficial treatment on transparent conductive oxides (TCOs) were carried out and studied by application or finality for the assembly of electroluminescent polymeric devices. The mean intention by use of these processes is to decrease the threshold voltage and also increase the luminance of the devices, without interfering in the original TCOs transmittances. Three different treatment techniques were used: (a) oxygen plasma; (b) aqua regia and (c) UV-ozozne. In the he last one, a reactor was assembled using a high-pressure mercury vapor lamp (high intensity discharge lamp type) without outer bulb to provide the available UV radiation to obtain ozone from atmospheric air. This reactor with low cost and easy handle was mounted to accomplish an alternative process compared by other (oxygen plasma and aqua regia) and it has the main focus of this work compared from experimental results obtained by mounted devices using different TCOs. It was possible to confirm that the procedure from the UV-Ozone is reproducible, because it can replaced with advantages the other techniques that have expansive costs or special handling. The use of different treatment times as only variable on the imposed condition in the experiments, a sample was reserved without treatment for comparison during each obtained result. In comparison with other treatments the UV-Ozônio presented reproducibility. In this case was verified the undesirable contaminants eliminated as carbon and hydrocarbon and detected by DRIFT (Diffuse Reflectance Infra-Red Fourier Transformed) technique and better scattering of polymer (PEDOT:PSS) on surface by contact angle was observed. For ITO and FTO films the optimum period was observed during 5 minutes and ZnO during 15 minutes. The measurements results of sheet resistance, thickness and Hall effect revealed no significant changes confirming that the surfaces were influenced only atomically or molecularly only.

PPV random derivates were synthesized and characterized. Polymer light emitting diodes (PLEDs) were assembled using the random copolymers as emissive layer and showed EL in the blue-green region in function of the method of preparation. The increase in the average conjugation degree in the polymer chain led to the reduction of the turn-on voltage of the device. The addition of Alq3 as ETL increased tenfold the luminescence efficiency.

Low cost UV-Ozone reactor using a high pressure mercury vapor lamp of 80 watts without outer bulb showed good results for treatment of ITO films used as anode electrode in the assembly of P-OLED (polymer-organic light emitting diode) devices. This study revealed 20 minutes as effective treatment time and it was verified also that the effect of UV-Ozone treatment loses its efficiency as the elapsed time increases. It was analyzed with measurements of contact angle using a droplet of PEDOT:PSS polymer. P-OLEDs devices were mounted with architecture: ITO/PEDOT:PSS/PVK/Alq3/Al. The PVK polymer was diluted in organic solvent of 1,2,4-trichlorobenzene with concentrations of: 5, 10, 20 and 30 mg/mL. Results revealed better performance of P-OLED devices for concentration of 5 mg/mL resulting in lower threshold voltage, elevation of electrical current and similar diode curve.

Neste trabalho foram estudados diferentes vidros de telureto dopados com íons de terras raras (TR) e nanopartículas (NPs) metálicas visando aplicação sobre a superfície de dispositivos fotovoltaicos. O objetivo foi utilizar os processos luminescentes de tais íons para otimizar a eficiência de conversão de energia de células solares. Os vidros de telureto foram escolhidos por apresentarem boas características ópticas, físicas e luminescência na presença de íons de terra rara e de NPs. Diferentes composições de telureto foram estudadas (TeO2-ZnO, TeO2-ZnO-Na2CO3) para observar a influência de diferentes janelas de transmissão sobre o desempenho de células solares, conciliando a máxima luminescência com a máxima transmitância do vidro. As amostras vítreas foram produzidas mediante o processo tradicional conhecido por \"melting quenching\" seguido por tratamento térmico. Os dopantes utilizados foram os íons de Tb3+, Yb3+, Eu3+ e nanopartículas de prata (NPs de Ag). Através dos mecanismos de conversão descendente apresentados por tais íons é possível converter comprimentos de onda que o dispositivo fotovoltaico não absorveria, para comprimentos compreendidos no seu \"band gap\" de forma a aumentar a eficiência da célula solar. Foram feitas caracterizações espectroscópicas de luminescência, absorbância e transmitância para caracterizar as propriedades ópticas dos vidros e microscopias para observar a forma e tamanho das NPs. Também foram feitas caracterizações elétricas de dispositivos fotovoltaicos com as amostras vítreas colocadas sobre suas superfícies, a fim de verificar influencias em suas eficiências. Observou-se que o tipo de célula solar e o tipo de sistema vítreo influenciam os resultados de eficiência para cada combinação de íons de terras raras. Ressaltam-se que foram obtidos aumentos na eficiência relativa de dispositivos fotovoltaicos comerciais fabricados em Si e GaP em 14% e 34,5%, respectivamente, com a utilização de vidros TeO2-ZnO dopados com Eu3+ e NPs de Ag. Foi utilizado óleo para acoplamento entre o vidro e a célula solar para aumentar o contato óptico, que possibilitou fazer a comparação da eficiência da célula coberta em relação à célula descoberta. Usando a célula solar de Si monocristalino foi observado aumento de 12,8% de eficiência relativa, quando coberta com vidros TeO2-ZnO dopados com Eu3+ e NPs de Ag. Os resultados apresentados neste trabalho demonstram que a utilização de processos de conversão descendente de íons de TR em vidros de telureto são promissores para incrementar a eficiência de células solares, assim como, o uso de NPs metálicas. In this work, different tellurite glasses doped with rare earth ions and metallic nanoparticles (NPs) were studied for applications on solar cells surface. The goal was to use the luminescent processes of the rare earth ions to optimize the solar cells energy conversion efficiency. Tellurite glasses were chosen because of the good optical and physical characteristics and luminescence in the presence of rare earth ions and metallic NPs. Different tellurite compositions were studied (TeO2-ZnO, TeO2-ZnO-Na2CO3) to observe the influence of different transmission windows on the solar cell performance, conciliating maximum luminescence with the maximum transmittance of the glasses. The vitreous samples were produced using the traditional \"melting quenching\" procedure followed by heat treatment. The dopants used were Tb3+, Yb3+, Eu3+ ions and silver NPs. The purpose was to use the downconversion processes of rare earth ions to convert the wavelengths that the photovoltaic device cannot absorb into wavelengths situated in its the band gap and enhance the energy conversion efficiency. Luminescence, absorption and transmittance spectroscopic characterizations were made to determine the optical properties of the glasses and microscopic measurements were used to observe the NPs size and shape. Electrical characterizations of the photovoltaic devices were also done with the glasses placed on their surfaces to verify the influence on their energy conversion efficiencies. It was observed that the type of solar cell and the glass host influenced the results, for each rare-earth ions combination. The results obtained with TeO2-ZnO glasses doped with Eu3+ and silver NPs can be highlighted, which show efficiency increase in 14% and 34,5%, when covering Si and GaP commercial solar cells, respectively. The oil matching was used between the solar cell and the glasses in order to enhance the optical contact and to allow the comparison between the results of the covered solar cell with the uncovered solar cell. It was observed for the energy conversion efficiency enhancement of 12% when the Si solar cell was covered with the TeO2-ZnO glasses doped with Eu3+ and with silver NPs. The results presented in this work demonstrate that the use of the rare earth ions downconversion processes are promising for improving the solar cells energy conversion efficiency as well as the use of metallic NPs.

As células solares poliméricas (PSCs) e diodos emissores de luz poliméricos (PLEDs) destacam-se dos seus análogos inorgânicos pela possibilidade de reduzir custo de fabricação, obtenção de dispositivos mais leves e flexíveis, maior liberdade no design e menor tempo de produção de dispositivos, devido à sua maior facilidade de processamento. Neste trabalho foram investigadas as mudanças nas propriedades fotofísicas, eletroquímicas e elétricas do poli[2,7-(9,9-dioctilfluoreno)-alt-4,7-bis(2,5-tiofeno)-2,1,3-benzotiadiazol] (PDBT) e seus derivados contendo grupos substituintes hexila no anel tiofeno. Este polímero conjugado é conhecido por seu potencial para aplicações em PSCs. Para tanto, três copolímeros, contendo diferentes concentrações de mero tiofeno substituído, foram sintetizados via reação de acoplamento de Suzuki. Usando técnicas adequadas, foram verificadas correlações entre o comportamento fotofísico, térmico e elétrico dos copolímeros e o teor de tiofeno substituído. Os materiais poliméricos sintetizados foram aplicados como camada ativa em PLEDs e PSCs. Em relação aos PLEDs, foi verificada baixa luminância e emissão de luz na faixa da cor laranja e cor verde. Além disso, diferentes efeitos, relacionados com a concentração de tiofeno substituído e as propriedades fotovoltaicas, foram identificados nas PSCs montadas. Polymer Solar cells (PSCs) and polymer light-emitting diodes (PLEDs) draw attention from their inorganic analogues for the possibility of manufacturing cost reduction, more light and flexible devices, as well as the greater design freedom and shorter production time devices due to its easier processing. In this work, we investigated the changes in the photophysical, electrochemical and electrical properties from poly[2,7-(9,9-dioctylfluorene)-alt-4,7-bis(2,5-thiophene)-2,1,3-benzothiadiazole] (PDBT) that was caused by hexyl substituents introduction on the copolymer thiophene rings. This conjugated polymer system is known for its PSCs applications potential. Therefore, three copolymers, with different concentrations of substituted thiophene mere, were synthesized by Suzuki polycondensation. Using appropriate techniques, direct relationships were verified between the photophysical, thermal and electrical behavior from copolymers and substituted thiophene content. The synthesized polymeric materials were applied as active layer in PLEDs and PSCs. Regarding PLEDs, it was verified a low luminance and light emission in the range of orange and green colors. Furthermore, different effects, related to the substituted thiophene concentration and photovoltaic properties, were identified from mounted PSCs.

Este trabalho tem como principais objetivos: desenvolver procedimentos sintéticos e novos materiais poliméricos que apresentem boa condutividade elétrica, estudar o comportamento eletro-óptico dos polímeros obtidos, desenvolver procedimentos para a construção de dispositivos eletroluminescentes, caracterizá-los e correlacionar as características eletro-ópticas observadas com a constituição da camada ativa polimérica. Foram realizadas diversas sínteses objetivando a preparação de polifluorenos com diferentes estruturas químicas a partir de monômeros difuncionais aromáticos boronados e bromados, utilizando uma mesma rota de acoplamento de Suzuki. Assim, foram preparados três polímeros, poli[2,7-(9,9-dioctilfluoreno)] (PF, polifluoreno), poli[1,4-fenileno-alt-2,7- (9,9-dioctilfluoreno)] [PFP, poli(fluoreno-fenileno)] e poli[(1,4-fenileno-2-flúor)-alt-2,7-(9,9- dioctilfluoreno)] [PFPF, poli(fluoreno-fenileno)fluorado]. Para obtenção destes polifluorenos com bom rendimento e com pureza adequada para a preparação de dispositivos poliméricos eletroluminescentes, foi necessário testar diversas condições de reação, até a otimização de um procedimento sintético robusto. Os polifluorenos preparados foram exaustivamente purificados por extração e solubilização-precipitação. Todos os polifluorenos tiveram a sua estrutura e composição químicas caracterizadas e confirmadas pelas técnicas de espectroscopia no infravermelho (FTIR), espectroscopia de ressonância magnética nuclear de hidrogênio (¹HNMR) e espectroscopia de energia dispersiva de raios-X (EDX). As massas molares médias e a polidispersão foram determinadas por cromatografia de permeação em gel (GPC). Soluções em clorofórmio dos polifluorenos foram analisadas por espectroscopias de absorção e emissão no UV-Vis. Estes resultados nos forneceram informações importantes quanto às propriedades de fotoluminescência dos polifluorenos obtidos. Até o momento, sabe-se que todos os três polímeros emitem cor azul e dentre as três estruturas estudadas, o PFPF apresentou maior intensidade de fluorescência. Para a fabricação dos P-OLEDs (Diodos Orgânico-Polimérico Emissor de Luz) foram feitas soluções de clorofórmio em concentrações de 1% dos três tipos de polímeros. Também foi estudada a influência dos compostos ETL (electron transport layer) (Alq3 ou butyl-PBD) com concentrações de 0,5%. Quando aplicada uma tensão no dispositivo, o PFPF apresentou menor tensão de operação entre os polímeros estudados. A partir das curvas de tensão vs. corrente, verificou-se que a adição do butyl-PBD nos três tipos de polímeros diminui a tensão de limiar em comparação com os dispositivos sem composto ETL. Os comprimentos de onda de eletroluminescência dos dispositivos polarizados permaneceram constante mesmo com a adição dos dois compostos ETL (Alq3 ou butyl-PBD). This work has as main objectives: develop synthetic procedures and new electroluminescent polymeric materials that have good electrical conductivity, study the behavior of polymer systems thus obtained, and develop procedures for the construction of electroluminescent devices, characterize them and correlate the photo- electrical behavior with the features of the constitutive active polymeric layer Several syntheses were performed aiming at preparing polyfluorenes with different structures from boronated and brominated difunctional aromatic monomers using a Suzuki coupling route. So far, three polymers were prepared, poly[2,7-(9,9-dioctylfluorene)] (PF, polyfluorene), poly[1,4-phenylene-alt-2,7-(9,9-dioctylfluorene)] [PFP, poly(fluorenephenylene)] and poly[1,4-phenylene-2-fluoro)-alt-2,7-(9,9-dioctylfluorene)] [PFPF, fluorinated poly(fluorene-phenylene)]. To obtain these polyfluorenos with good yield and purity suitable for preparing polymeric electroluminescent devices, it was necessary to test various reaction conditions and to optimize a robust synthetic procedure. The polyfluorenes prepared were thoroughly purified by extraction and solubilization-precipitation. All polyfluorenes have had their structures and chemical composition characterized and confirmed by infrared spectroscopy (FTIR), and hydrogen and carbon-13 nuclear magnetic resonance spectroscopy (¹HNMR and 13CNMR). The average molar masses and polydispersity were determined by gel permeation chromatography (GPC). Polyfluorenes in chloroform solutions were analyzed by the UV-Vis absorption and emission spectroscopy. These results provided us with important information regarding the photoluminescence properties of polyfluorenes thus obtained. Until now, it is known that all three polymers emit in the blue region and among the three structures, the PFPF has the highest fluorescence intensity. The construction of PLEDs was carried out from the chloroform solutions at concentrations of 1% for each of the all three types of polymers. The influence of an ETL (electron transport layer) compound (Alq3, PBD) was also studied, and its concentration was kept constant at 5% in the polymer solution. Tests of the devices under applied voltage have shown a higher stability for PFPF among all. From the voltage vs. current curves, it was possible to observe that the addition of PBD decreased the threshold voltage for the devices prepared from the three types of polymers. The wavelength of electroluminescence remained constant despite the addition of the ETL compound (Alq3 or butyl-PBD).