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The urea oxidation reaction (UOR) is an excellent alternative to the sluggish oxygen evolution reaction (OER) as an anode reaction for hydrogen generation via electrochemical water splitting. Here, a porphyrin-based conjugated porous polymer (CPP) has been developed through the polycondensation reaction of 2,6-diformyl-4-methylphenol and pyrrole (DMP-POR). The nickel(II) complex of this conjugated polymer Ni-DMP-POR shows efficient UOR in an alkaline medium. The as-synthesized materials were characterized by solid-state

Urea electro-oxidation in alkaline medium catalysed by nickel trithiocarbonate complex and g-C3N4 composite.

Ordered mesoporous carbon-supported gold nanoparticles (Au/OMC) have been fabricated in one step through a hard template method using gold nanoparticle-intercalated mesoporous silica (GMS) to explore two different catalytic properties, for example, electrocatalytic oxidation of methanol and colorimetric determination of glutathione (GSH). The catalytically inert but conducting nature of mesoporous carbon (OMC) and promising catalytic activity of gold nanoparticles (AuNPs) has inspired us to synthesize Au/OMC. The as-prepared Au/OMC catalyst was characterized by powder X-ray diffraction, N2 adsorption–desorption, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray analysis-elemental mapping, and X-ray photoelectron spectroscopy. The characterization results indicate that AuNPs are uniformly distributed on the surface of OMC. The conducting-OMC framework with a high surface area of Au/OMC provides superior transport of electrons through the porous surface of carbon matrix and resulted in its high efficiency and stability as an electrocatalyst for the oxidation of methanol in comparison to CMK-3, SBA-15, and GMS in alkaline medium. The efficiency of Au/OMC toward methanol oxidation in alkaline medium is much higher in comparison to that in acidic medium. The lower value of If/Ib in the acidic medium in comparison to that in the alkaline medium clearly indicates that the oxidation process with Au/OMC as a catalyst is much more superior in alkaline medium with better tolerance toward the accumulation of intermediate CO species on the active surface area. Furthermore, the Au/OMC catalyst is successfully utilized for the detection and quantification of GSH spectrophotometrically with a limit of detection value of 0.604 nM.

With 6.93M confirmed cases of COVID-19 worldwide, making individuals aware of their sanitary health and ongoing pandemic remains the only way to prevent the spread of this virus. Wearing masks is an important step in this prevention. Hence, there is a need for monitoring if people are wearing masks or not. Closed circuit television (CCTV) cameras endowed with computer vision function by embedded systems, have become popular in a wide range of applications, and can be used in this case for real time monitoring of people wearing masks or not. In this paper, we propose to model this task of monitoring as a special case of object detection. However, real-time scene parsing through object detection running on edge devices is very challenging, due to limited memory and computing power of embedded devices. To deal with these challenges, we used a few popular object detection algorithms such as YOLOv3, YOLOv3Tiny, SSD and Faster R-CNN and evaluated them on Moxa3K benchmark dataset. The results obtained from these evaluations help us to determine methods that are more efficient, faster, and thus are more suitable for real-time object detection specialized for this task.

Cadmium sulphide nanoparticles suffer an intrinsic disadvantage of photocorrosion as photocatalyst. The nanocomposites of mesoporous carbon and CdS nanoparticles improve photostability and minimise photocorrosion of CdS. The recombination of the photogenerated electron and hole which leading to photocorrosion in CdS is thereby prevented by the introduction of mesoporous carbon. The carbon percentage was gradually increased from 10 % to 40 % in the nanocomposites. The introduction of carbon enhances the stability and photocurrent response of the materials. The highly active porous carbon allows the cascading flow of the excitons from CdS restraining the recombination process and also boost up the electron flow which is evident from the increased photosensitivity and photostability. Moreover, the rate of photocatalytic H2 production from water in the presence of methanol as hole scavenger for nanocomposite was found to be much higher (37,641 μmol g−1 h−1) in comparison to pure CdS and carbon.