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Ni(II)-Incorporated Porphyrin-Based Conjugated Porous Polymer Derived from 2,6-Diformyl-4-methylphenol as a Catalyst for the Urea Oxidation Reaction
- Source :
- Inorganic Chemistry. 61:18390-18399
- Publication Year :
- 2022
- Publisher :
- American Chemical Society (ACS), 2022.
-
Abstract
- The urea oxidation reaction (UOR) is an excellent alternative to the sluggish oxygen evolution reaction (OER) as an anode reaction for hydrogen generation via electrochemical water splitting. Here, a porphyrin-based conjugated porous polymer (CPP) has been developed through the polycondensation reaction of 2,6-diformyl-4-methylphenol and pyrrole (DMP-POR). The nickel(II) complex of this conjugated polymer Ni-DMP-POR shows efficient UOR in an alkaline medium. The as-synthesized materials were characterized by solid-state
Details
- ISSN :
- 1520510X and 00201669
- Volume :
- 61
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry
- Accession number :
- edsair.doi.dedup.....9ac7aee7ae8b38d5f9b1d6f93d155a45