Search

Many advanced materials are designed for separation of immiscible oils/organic solvents and aqueous solutions, including poly(vinylidene fluoride) (PVDF)‐based materials with superwettability. However, due to the limited solubility of PVDF, techniques (e.g., phase inversion and electrospinning) often involve the use of toxic organic solvents. Here a facile organic solvent‐free method is described to prepare a porous PVDF–MWCNT (multiwalled carbon nanotube) foam using table salt as a sacrificial template. The porous PVDF–MWCNT foam is characterized as superhydrophobic–superoleophilic with good elasticity due to its 3D porosity and low surface energy. The foam exhibits high adsorption capacity to a variety of oils/organic solvents and can be easily reused by squeezing, heating, or releasing in other solvents. Moreover, the foam is highly resistant toward UV exposure, corrosive aqueous solutions such as acidic, alkaline, salty solutions, and turbulent environments, and shows effective oils/organic solvents removal in these complex environments. The continuous separation of immiscible oils/organic solvents and corrosive aqueous solutions with vacuum assistance is also presented. The organic solvent‐free and reusable PVDF–MWCNT foam is a promising candidate for large‐scale industrial separation of oils/organic solvents and water in corrosive and turbulent conditions.

Artificial self-healing superhydrophobic surfaces have become a new research hotspot because of their recoverable non-wetting performance and practical perspective. In this paper, a superhydrophobic surface was fabricated by aerosol-assisted layer-by-layer chemical vapor deposition (AA-LbL-CVD) of epoxy resins and PDMS polymer films. The obtained samples still showed superhydrophobicity even after long-term exposure to different pH solutions and UV light irradiation as well as great mechanical stability against sandpaper abrasion and double-sided tape peeling. Importantly, due to the shape memory effect of the polymer films, the as-prepared samples could recover the previously crushed micro–nano structures upon heat treatment to make the surface superhydrophobic, showing thermo-triggered healing of superhydrophobicity.