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BACKGROUND: Bioactive glass is a multifunctional synthetic composite material that releases active ions slowly and exhibits certain biological activities after affinity with tissues. Their versatility stems from the versatility of their preparation processes and components, allowing them to be applied in different clinical scenarios. OBJECTIVE: To review the main application forms, application fields of bioactive glass, as well as the influence of doping different elements on its function. METHODS: A literature search was conducted across WanFang Medical Database, CNKI Database, PubMed Database, and Web of Science Database, using the search terms “bioactive glass, slow-release ions, bone tissue engineering, composite scaffold, tissue regeneration and repair, biomedical engineering” in Chinese and English. The timeframe was limited from 2000 to 2023. Finally, 88 articles were included for review. RESULTS AND CONCLUSION: (1) In terms of application forms, bioactive glass can be fabricated as coatings, particles, bone cements, and scaffolds according to needs. Coatings have the potential to enhance the biological activity of implants, yet they are susceptible to instability as a result of degradation. Particles offer a viable solution for the repair of irregular bone defects; however, particles produced through traditional methods often possess limited functionality. Bone cement provides the benefits of minimal invasiveness and injectability, yet its application is restricted to smaller bone defects. Scaffolds exhibit excellent mechanical properties and are commonly used for larger-sized bone defects, yet they have limited toughness. (2) In terms of applications, bioactive glass can be used in a variety of tissue regeneration and repair and disease treatment fields, including dentistry, orthopedics, soft tissue engineering, and cancer. (3) In terms of element doping, the addition of specific elements to bioactive glass not only improves its mechanical properties but also endows it with special biological functions such as bioactivity, degradability, and antibacterial properties. (4) Biologically active glass is a versatile material that can be used in different forms and functions by adjusting the preparation process and element doping to meet various clinical needs in bone tissue engineering and is widely used in the field of biomedical engineering. [ABSTRACT FROM AUTHOR]

Despite significant advances in prenatal medicine, spontaneous miscarriage remains one of the most common and serious pregnancy complications, affecting an increasing number of women. Since many aspects of the pathogenesis of spontaneous miscarriage remain unexplained, the aim of this study has been to assess the involvement of the NLRP3 inflammasome as a potential causative factor. The concentrations of NLRP3, IL-1β, IL-18, and cytochrome C in the serum of patients after miscarriage were measured by means of the immunoenzymatic method. In the placental tissue, the expression of NLRP3, IL-1β, IL-18, and Caspase-1 as well as that of the classical apoptosis biomarkers Fas, FasL, Bcl-2, and Ca was evaluated by means of immunohistochemistry techniques. Additionally, in whole blood, the concentrations of elements crucial for pregnancy progression, such as Ca, K, Mg, and Na, were examined by means of the ICP-OES method. Significantly higher concentrations of NLRP3 and IL-18 were demonstrated in the serum of patients with miscarriage as compared to the control group. In the placental tissue samples, a higher expression of IL-1β, IL-18, and Caspase-1 proteins was noted in women who had experienced miscarriage as compared to the control group. At the same time, a significantly lower expression of FasL and Bcl-2 proteins as well as Ca deposits was observed in women after miscarriage as compared to those with a normal pregnancy outcome. Significantly lower concentrations of Ca and K were recorded in the blood of patients with spontaneous miscarriage as compared to pregnant women. The analysis of the results x indicated a greater involvement of the inflammasome in women with spontaneous miscarriage associated with oxidative–antioxidative imbalance than in the case of miscarriage related to NET formation. Our research has provided evidence for the involvement of the inflammasome in the process of spontaneous miscarriage and identifies a new direction for diagnostics that includes NLRP3 as a preventive element in prenatal care, particularly in light of the steadily declining number of pregnancies and the increasing number of reproductive failures. [ABSTRACT FROM AUTHOR]

Solanum microdontum (mcd) is a tuber-bearing relative of commercial potato. Although wild, it has many attractive traits for breeding. Previous research has shown it has exceptional ability to sequester calcium in its tubers, a trait associated with tuber disease resistance and tuber quality. We used a set of mcd from 50 populations in the US Potato Genebank (USPG) shown to encompass most of the genetic diversity in the species, two individuals from each population. Tubers were produced in pots in the USPG greenhouse in two years, and freeze dried samples tested for calcium content. Some exceptionally high Ca accumulators were identified (especially clone mcd40B1 from PI 473166). Because other minerals were measured in the same tests, the highest accumulators for K, Mg, Zn in mcd were also identified. All the stocks tested are available in vitro from USPG for additional research and breeding. [ABSTRACT FROM AUTHOR]

Copyright of Ordnance Industry Automation is the property of Editorial Board for Ordnance Industry Automation and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The gardenia flower not only has extremely high ornamental value but also is an important source of natural food and spices, with a wide range of uses. To support the development of gardenia flower products, this study used headspace gas chromatography–ion mobility spectrometry (HS-GC–IMS) technology to compare and analyze the volatile organic compounds (VOCs) of fresh gardenia flower and those after using four different drying methods (vacuum freeze-drying (VFD), microwave drying (MD), hot-air drying (HAD), and vacuum drying (VD)). The results show that, in terms of shape, the VFD sample is almost identical to fresh gardenia flower, while the HAD, MD, and VD samples show significant changes in appearance with clear wrinkling; a total of 59 volatile organic compounds were detected in the gardenia flower, including 13 terpenes, 18 aldehydes, 4 esters, 8 ketones, 15 alcohols, and 1 sulfide. Principal component analysis (PCA), cluster analysis (CA), and partial least-squares regression analysis (PLS-DA) were performed on the obtained data, and the research found that different drying methods impact the VOCs of the gardenia flower. VFD or MD may be the most effective alternative to traditional sun-drying methods. Considering its drying efficiency and production cost, MD has the widest market prospects. [ABSTRACT FROM AUTHOR]

The present work aims to investigate the effect of heating temperature (400, 600 and 800 °C) and inoculating elements (Ca, Ca-Ba, Ca-RE) on oxidation behavior of ductile irons containing 5.25% Si and 4.8% Si-2.3% Mo in dry air and combustion gas containing water vapour (natural gas burning). The oxidation is influenced by the gas atmosphere type, the iron alloying system, and the inoculating elements depending on the heating temperature. The weight gain increases from 0.001%-0.1% (400 °C) to 0.05%-0.70% (600 °C) and up to 0.10%-2.15% (800 °C). No particular effects of the considered influencing factors are found when heating at 400 °C, while at 600 °C, mainly the oxidation gas atmosphere type shows a visible influence. At the highest heating temperature of 800 °C, a limited increase of the weight gain is found for dry air atmosphere (up to 0.25%), but it drastically increases for combustion atmospheres (0.65%-2.15%). The water vapour presence in the combustion atmosphere is an important oxidising factor at 600-800 °C. The alloying system appears to influence the oxidation behavior mainly at a heating temperature of 800 °C in the combustion atmosphere, as evidenced by the lower weight gain in 5.25% silicon cast iron. Positive effects of inoculating elements increase with the heating temperature, with Ca and Ba-FeSi inoculation generally showing better performance. Irons inoculated with CaRE-FeSi exhibit a higher degree of oxidation. These results are in good relationship with the previous reported data: Ca-Ba-inoculation system appears to be better than simple Ca for improving the graphite parameters, while RE-bearing inoculant negatively affects the compactness degree of graphite particles in high-Si ductile irons. As the lower compactness degree is typical for graphite nodules in high-Si ductile irons, which negatively affects the oxidation resistance, it is necessary to employ specific metallurgical treatments to improve nodule quality. Inoculation, in particular, is a potential method to achieve this improvement. [ABSTRACT FROM AUTHOR]

Wildfires are serious hazards for the environment, and WFSD (Wildfire Smoke Detection) is a challenge for ensuring optimal response and mitigation efforts. Hence, this study suggests an attention-based YOLOv5 (You Only Look Once) network for detecting smoke instances within video frames, particularly ECA (Efficient Channel Attention), GAM (Global Attention Module) and CA (Coordinate Attention). Here, an open-source wildfire smoke dataset divided into train, validation and test set is used for experimentation. The comprehensive research and evaluations show that the incorporation of attention mechanisms successfully enhances the accuracy and robustness of the YOLOv5 model for WFSD. In the training among the attention modules, GAM appears as the most effective, attaining an improved 95% F1 score on the dataset. This research provides the impact of attention mechanisms on object detection in the context of wildfire smoke. The findings of the research paper contribute to improving the capabilities of deep learning models for emergency response and environmental monitoring. The proposed methodology not only outperforms regular YOLOv5 but also sets up a benchmark for future research of WFSD. [ABSTRACT FROM AUTHOR]

Aim: to determine clinical, anamnestic and molecular-genetic parallels in emergence of clinical chorioamnionitis (CA) and severe forms of intrauterine infections (IUI) in high-risk pregnant women.Materials and Methods. A single-center prospective cohort comparative case-control study was conducted by examining 58 pregnant female patients aged 18 to 42 years with a verified CA diagnosis during pregnancy and childbirth at different gestation stages (main group), and 35 age-matched pregnant women with uncomplicated pregnancy and no significant extragenital pathology, aggravated factors of obstetric and gynecological history and risk factors for developing CA (control group), observed and performed a delivery in Yudin City Clinical Hospital. All women underwent clinical, anamnestic, laboratory, instrumental and molecular-genetic examitation. We studied the polymorphism of genes FCGR2A (Fc fragment of immunoglobulin G receptor IIa), IFN-γ (interferon gamma), IL-10 (interleukin-10), IL-6 (interleukin-6) and MBL2 (mannose binding lectin 2) to determine their role in assessing a risk of maternal and neonatal infection.Results. Among the patients with developed clinical CA vs. control subjects, more of them had a history of abortion and miscarriages (17.24 %), comorbid with chronic arterial hypertension (13.79 %), previous surgical interventions (27.59 %), as well as chronic inflammatory diseases (chronic tonsillitis, bronchitis, pyelonephritis, sinusitis; 27.59 % vs. 17.14 %). In addition to risk factors directly related to the infectious and inflammatory unfavorable background, they also had a significantly higher rate of obstetric complications: moderate preeclampsia - 6 (10.34 %) cases, threat of miscarriage or premature birth - 14 (24.14 %) cases vs. 1 (2.86 %) case in control group (p = 0.007), polyhydramnions - 4 (6.9 %) cases, placental insufficiency - 6 (10.34 %) cases. The frequency of premature rupture of membranes was 31.03 % in women with CA. Questionable cardiotocography (CTG) type was found in 24 (41.38 %) women with CA vs. 4 (11.4 3%) women without CA (p = 0.003), the pathological CTG type was observed only in women with CA. In the group with clinical CA and neonatal IUI, the combination of genotypes AG rs1801274 FCGR2A, TT rs2430561 (IFN-γ)+874, GC rs1800795 (IL-6)-174 occurs in 80.65 % (25/31), whereas in women without severe neonatal IUI - in 37.04 % (10/27) (odds ratio (OR) = 7.08; 95 % confidence interval (CI) = 2.166-23.166). In addition, the combination of alleles TT rs2430561 (IFN-γ)+874, GC+CC rs1800795 (IL-6)-174, AA rs1800450 MBL2 codon 54 was detected in 90.32 % (28/31) vs. 44.44 % (12/27) in main and control group (OR = 11.667; 95 % CI = 2.842-47.886), respectively.Conclusion. The study data evidence about importance of identifying genes for developing CA and neonatal septic complications to optimize and personalize management of high-risk patients (premature birth, infections during pregnancy, premature rupture of membranes).

Waste water reuse is an effective method for reducing the quantity of wastewater that enters the environment. As a result, the appropriateness was assessed in accordance with its composition and the global criteria for drinking water quality. This study aims to evaluate the quality of surface water of Brahmani River, Odisha, by adapting multivariate statistical approaches, namely Cluster Analysis (CA) and multi-criteria decision-making (MCDM) methods such as Simple Additive Weighting (SAW). Again, Geographical Information System (GIS) is employed to assess the drinking water's quality in relation to its application. Around 15 physicochemical parameters, gathered from seven distinct sites, following a period of 2022 till 2024. The results showed high values of EC, SO42−, NO3−, PO43−, F− and Ca2+, in three stations, while other studied parameters are within the permissible limits defined by WHO standards. The CA three distinct classifications of sites namely, low, medium, and high, based on how comparable the various physicochemical traits and pollutant levels were throughout the sampling locations. Sites H-(4–6) were included in cluster 1, site H-(3) and (7) classified under Cluster 2 and finally, H-(1–2) indicated as Cluster 3. Thus, as stated by CA, 42.86 % of tested water samples were fall into the group of good quality and about 57.14 % of examined locations resides in the poor category of water. The findings indicate which characteristics, as determined by the CA technique, were accountable for the alteration in the water quality and raise the potential of runoff from cities, farms, and industries. Subsequently, MCDM techniques has been implemented to facilitate rapid comprehension of surface water behavior and address problems with water resource management. The obtained SAW index ranges from 0.5 to 0.94. Here, H-(1), (2), and (7) grouped as highly polluted zone, and they seemed to be connected to runoff from farms and untreated industrial and municipal trash as well as local pollution sources. From this innovative study, it is found that even though the water is fit for drinking at 3 places, it is medium to highly suitable for human consumption. Therefore, there needs to be treated in some way before being used in addition to being protected against contamination. Most often, the findings indicate that appropriate management actions are important to restore the water quality of this catchment in order to support a robust and promising aquatic ecosystem. Additionally, the significance of this restoration for objective ecological policy and decision-making processes is underscored.

In recent years, heavy metal pollution has become a global environmental problem and poses a great threat to the health of people and ecosystems. Therefore, strategies for the effective remediation of Cd from contaminated soil are urgently needed. In this study, ryegrass was utilized as a remediation plant, and its remediation potential was enhanced through the application of Citric Acid (CA) in conjunction with Bacillus megaterium (B. megaterium). The P3 treatment (CA + Bacillus megaterium) exhibited a significantly higher efficiency in promoting cadmium extraction by ryegrass, resulting in a 1.79-fold increase in shoot cadmium accumulation compared to the control group (CK) with no Bacillus megaterium or CA. Moreover, the P3 treatment led to an increased abundance of Actinobacteriota, Acidobacteriota, and Patescibacteria in the rhizosphere. The concentration of amino derivatives (such as betaine, sulfolithocholylglycine, N-alpha-acetyl-lysine, glycocholic acid, arginyl-threonine) showed significant upregulation following the P3 treatment. In summary, this study proposes a viable approach for phytoremediation of soil contaminated with cadmium by harnessing the mobilizing abilities of soil bacteria. NOVELTY STATEMENT: Our aim was to gain a comprehensive understanding of the mechanisms involved in phytoremediation. These findings contribute to the existing knowledge by providing insights into the mechanism of phytoremediation in Cd-contaminated soil. They are expected to serve as a theoretical foundation for further elucidation of the phytoremediation mechanisms employed in Cd-contaminated soil. HIGHLIGHTS: CA + Bacillus megaterium increased Cd accumulation in ryegrass by 1.79 times compared to CK. CA + Bacillus megaterium also significantly improved the activity of soil enzymes. CA + Bacillus megaterium significantly improved soil bacterial communities. CA + Bacillus megaterium significantly increased metabolites in the soil. [ABSTRACT FROM AUTHOR]

Abstract Different chemical solutions can significantly change the contact angle (CA) of soil, but few studies have studied the change rule and action mechanism of the CA from the mineral composition of soil essence. In unsaturated soil mechanics, the CA is an important parameter to calculate the wet suction between soil particles in unsaturated soil. When the chemical composition of the soil pore liquid changes, the CA will also change, which will affect the wet suction and other parameters, thus changing the macroscopic mechanical properties of the soil. In this study, the CA of air-solution-mineral phases with different solution components (pH, type and concentration of salt solution) of different minerals (quartz, orthoclase and plagioclase) were measured. The results show that the CAs of quartz, orthoclase and plagioclase all rise first and then drop with the rise of pH. The peak CAs are pH = 5, pH = 4 and pH = 3, respectively. Quartz, orthoclase and plagioclase all have valley values in different concentrations of NaCl and KCl solutions. In CaCl2 solution, only quartz has valley value, while orthoclase and plagioclase increase monotonously. Quartz in soil plays a main role in the influence of soil CA, followed by orthoclase and plagioclase. The CA of different minerals in different chemical solutions is mainly controlled by electric double layer interaction and functional groups interaction. In different salt solution environment, in addition to the above two effects, the mineral CA is also affected by the surface tension.

Abstract Background The quality of maize kernels is significantly enhanced by amino acids, which are the fundamental building blocks of proteins. Meanwhile, calcium (Ca) and magnesium (Mg), as important nutrients for maize growth, are vital in regulating the metabolic pathways and enzyme activities of amino acid synthesis. Therefore, our study analyzed the response process and changes of amino acid content, endogenous hormone content, and antioxidant enzyme activity in kernels to the coupling addition of sugar alcohol-chelated Ca and Mg fertilizers with spraying on maize. Result (1) The coupled addition of Ca and Mg fertilizers increased the Ca and Mg content, endogenous hormone components (indole-3-acetic acid, IAA; gibberellin, GA; zeatin riboside, ZR) content, antioxidant enzyme activity, and amino acid content of maize kernels. The content of Ca and Mg in kernels increased with the increasing levels of Ca and Mg fertilizers within a certain range from the filling to the wax ripening stage, and significantly positively correlated with antioxidant enzyme activities. (2) The contents of IAA, GA, and ZR continued to rise, and the activities of superoxide dismutase (SOD) and catalase (CAT) were elevated, which effectively enhanced the ability of cells to resist oxidative damage, promoted cell elongation and division, and facilitated the growth and development of maize. However, the malondialdehyde (MDA) content increased consistently, which would attack the defense system of the cell membrane plasma to some extent. (3) Leucine (LEU) exhibited the highest percentage of essential amino acid components and a gradual decline from the filling to the wax ripening stage, with the most substantial beneficial effect on essential amino acids. (4) CAT and SOD favorably governed essential amino acids, while IAA and MDA negatively regulated them. The dominant physiological driving pathway for the synthesis of essential amino acids was “IAA-CAT-LEU”, in which IAA first negatively drove CAT activity, and CAT then advantageously controlled LEU synthesis. Conclusion These findings provide a potential approach to the physiological and biochemical metabolism of amino acid synthesis, and the nutritional quality enhancement of maize kernel.

This paper investigates the issue of translating genderisms from Uzbek into English. It investigates and compares the approaches taken by both native and foreign translators to address this issue through a case study based on Uzbek author Abdulhamid Sulaymon o’g’li Cho’lpon’s unfinished dilogy, Night and Day. Originally written between 1933 and 1934 and translated into English by native translators Muminov and Khamidov in 2014 and foreign translator Fort in 2019, Cho’lpon’s work was specifically chosen, because it depicts women's repression in the male hegemonic cultures of Central Asian countries during the nineteenth century, particularly in the Uzbek context during the colonial period. Based on both the content analysis (CA) and critical discourse analysis (CDA), the researchers extracted the genderisms in the source text (ST) and compared them to their representation in the target text (TT). The CDA results revealed that genderisms in the ST manifest themselves in women's reliance on men, the limitations on their independence, their low status and powerlessness, and their abusive treatment and threats by men. Analysis of the translations showed that native translators mostly omitted genderisms in translation, attempting to protect their culture by avoiding the introduction of negative views of their nation. On the other hand, the foreign translator kept the genderisms in the TT, trying to realize the author's original goal of using genderism to encourage independence and selfconfidence in women. The results of this study serve to reduce the problems of expressing gender representation in translations from many Turkic languages into English. [ABSTRACT FROM AUTHOR]

The object detection model in UAV aerial image scenes faces challenges such as significant scale changes of certain objects and the presence of complex backgrounds. This paper aims to address the detection of small objects in aerial images using NATCA (neighborhood attention Transformer coordinate attention) YOLO. Specifically, the feature extraction network incorporates a neighborhood attention transformer (NAT) into the last layer to capture global context information and extract diverse features. Additionally, the feature fusion network (Neck) incorporates a coordinate attention (CA) module to capture channel information and longer-range positional information. Furthermore, the activation function in the original convolutional block is replaced with Meta-ACON. The NAT serves as the prediction layer in the new network, which is evaluated using the VisDrone2019-DET object detection dataset as a benchmark, and tested on the VisDrone2019-DET-test-dev dataset. To assess the performance of the NATCA YOLO model in detecting small objects in aerial images, other detection networks, such as Faster R-CNN, RetinaNet, and SSD, are employed for comparison on the test set. The results demonstrate that the NATCA YOLO detection achieves an average accuracy of 42%, which is a 2.9% improvement compared to the state-of-the-art detection network TPH-YOLOv5. [ABSTRACT FROM AUTHOR]

Surface defects of steel plates unavoidably exist during the industrial production proceeding due to the complex productive technologies and always exhibit some typical characteristics, such as irregular shape, random position, and various size. Therefore, detecting these surface defects with high performance is crucial for producing high-quality products in practice. In this paper, an improved network with high performance based on You Only Look Once version 5 (YOLOv5) is proposed for detecting surface defects of steel plates. Firstly, the Space to Depth Convolution (SPD-Conv) is utilized to make the feature information transforming from space to depth, helpful for preserving the entirety of discriminative feature information to the greatest extent under the proceeding of down-sampling. Subsequently, the coordinate attention mechanism is introduced and embedded into the bottleneck of C3 modules to effectively enhance the weights of some important feature channels, in favor of capturing more important feature information from different channels after SPD-Conv operations. Finally, the Spatial Pyramid Pooling Faster module is replaced by the Spatial Pyramid Pooling Fully Connected Spatial Pyramid Convolution module to further enhance the feature expression capability and efficiently realize the multi-scale feature fusion. The experimental results on NEU-DET dataset show that, compared with YOLOv5, the mAP and mAP50 dramatically increase from 51.7, 87.0 to 61.4, 92.6%, respectively. Meanwhile, the frame rate of 250 FPS implies that it still preserves a well real-time performance. Undoubtedly, the improved algorithm proposed in this paper exhibits outstanding performance, which may be also used to recognize the surface defects of aluminum plates, as well as plastic plates, armor plates and so on in the future. [ABSTRACT FROM AUTHOR]

Copyright of Environmental & Social Management Journal / Revista de Gestão Social e Ambiental is the property of Environmental & Social Management Journal and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Reducing the influence of significant noise signal components on the obtained raw ECG signal is essential for precise identification of cardiac arrhythmias (CA), which frequently present as irregularities in heart rate or rhythm. Preprocessing is used to remove noise signals and baseline drift from the ECG wave that is recorded using the internet of things (IoT). After that, the denoised signal is subjected to dimensionality reduction and feature extraction. In order to determine whether classification method is more effective in detecting cardiac arrhythmias, this study compares two methods: an adaptive neuro-fuzzy inference system and artificial feed-forward neural networks trained with the back-propagation learning algorithm. An Adaptive Neuro Fuzzy Inference System analyses ICA features obtained by non-parametric power spectral estimates, and an Artificial Neural Network (ANN) classifier uses the ECG signal's morphological and statistical aspects to identify patterns. The creation of artificial feed-forward neural networks provides a rich framework for studying the Back Propagation Algorithm. Sensitivity, specificity, accuracy, and positive predictiveivity are some of the performance characteristics that are thoroughly examined. An overall accuracy of 97.79%, sensitivity of 99.82%, specificity of 99.68%, and positive predictivity of 98.58% were seen in the results of the Artificial Neural Feed Forward Network (ANFFN). The Adaptive Neuro Fuzzy Inference System (ANFIS) outperforms these metrics with an astounding overall accuracy of 99.62%, specificity of 98.63%, and positive predictivity of 99.46%. With a classification accuracy of 99.82%, ANFIS demonstrates to be the most effective classifier for identifying cardiac arrhythmias. [ABSTRACT FROM AUTHOR]

Cardiovascular diseases (CVD) stand as the leading cause of global mortality, claiming millions of lives annually. An electrocardiogram (ECG) records the heart's electrical activity based on the Internet of Things (IoT), crucial in detecting cardiac arrhythmias (CA), characterized by irregular heart rates and rhythms. Signals from the MIT-BIH Arrhythmia Physio net database are analyzed. This chapter aims to propose a hybrid approach merging Genetic Algorithm-Support Vector Machine (GSVM) and Particle Swarm Optimization-Support Vector Machine (PSVM) for CA classification. The study introduces an algorithm for categorizing ECG beats into six groups using Independent Component Analysis (ICA)-derived features. Optimal SVM settings are determined using Genetic Algorithm (GA) and Particle Swarm Optimization (PSO) on ICA features computed via non-parametric power spectral estimation. The research delves into the origins and methodologies of GA and PSO. Simulation results comparing GSVM and PSVM are presented, emphasizing PSVM's superior performance in accuracy, sensitivity, specificity, and positive predictivity. Detailed performance metrics, including Sensitivity, Specificity, Positive Predictivity, and Accuracy percentages, are scrutinized and compared against the top classifier. The findings endorse PSVM's superiority over GSVM, indicating enhanced performance across multiple evaluation criteria. [ABSTRACT FROM AUTHOR]

Background: The quality of maize kernels is significantly enhanced by amino acids, which are the fundamental building blocks of proteins. Meanwhile, calcium (Ca) and magnesium (Mg), as important nutrients for maize growth, are vital in regulating the metabolic pathways and enzyme activities of amino acid synthesis. Therefore, our study analyzed the response process and changes of amino acid content, endogenous hormone content, and antioxidant enzyme activity in kernels to the coupling addition of sugar alcohol-chelated Ca and Mg fertilizers with spraying on maize. Result: (1) The coupled addition of Ca and Mg fertilizers increased the Ca and Mg content, endogenous hormone components (indole-3-acetic acid, IAA; gibberellin, GA; zeatin riboside, ZR) content, antioxidant enzyme activity, and amino acid content of maize kernels. The content of Ca and Mg in kernels increased with the increasing levels of Ca and Mg fertilizers within a certain range from the filling to the wax ripening stage, and significantly positively correlated with antioxidant enzyme activities. (2) The contents of IAA, GA, and ZR continued to rise, and the activities of superoxide dismutase (SOD) and catalase (CAT) were elevated, which effectively enhanced the ability of cells to resist oxidative damage, promoted cell elongation and division, and facilitated the growth and development of maize. However, the malondialdehyde (MDA) content increased consistently, which would attack the defense system of the cell membrane plasma to some extent. (3) Leucine (LEU) exhibited the highest percentage of essential amino acid components and a gradual decline from the filling to the wax ripening stage, with the most substantial beneficial effect on essential amino acids. (4) CAT and SOD favorably governed essential amino acids, while IAA and MDA negatively regulated them. The dominant physiological driving pathway for the synthesis of essential amino acids was "IAA-CAT-LEU", in which IAA first negatively drove CAT activity, and CAT then advantageously controlled LEU synthesis. Conclusion: These findings provide a potential approach to the physiological and biochemical metabolism of amino acid synthesis, and the nutritional quality enhancement of maize kernel. [ABSTRACT FROM AUTHOR]

Introduction: Trials evaluating the role of intravascular imaging in percutaneous coronary intervention (PCI) for complex coronary artery disease have yielded mixed results. This study aimed to compare the outcomes of intravascular imaging specifically intravascular ultrasound (IVUS) with those from conventional coronary angiography in complex PCI. Methods: Comprehensive electronic search of MEDLINE, EMBASE, and Cochrane databases was performed until March 2023 for randomized clinical trials (RCTs) comparing intravascular imaging with coronary angiography in patients undergoing complex PCI. Complex PCI was defined per each study, and included PCI for American College of Cardiology/American Heart Association (ACC/AHA) type B2/C lesions, unprotected left main coronary artery disease, or multivessel stenting. The primary study outcome was major adverse clinical events (MACE). Results: The meta-analysis included 10 RCTs with a total of 6615 patients (3576 in the intravascular imaging group and 3039 in the coronary angiography group). The weighted mean-follow up was 28.9 months. Compared with coronary angiography, intravascular imaging reduced MACE (8% vs. 13.3%; relative risk [RR] 0.63; 95% confidence interval [CI] 0.54–0.73), cardiac death (RR 0.47; 95% CI 0.31–0.73), definite/probable stent thrombosis (RR 0.48; 95% CI 0.24–0.97), target vessel revascularization (RR 0.62; 95% CI 0.46–0.83), and target lesion revascularization (RR 0.61; 95% CI 0.47–0.79). There was no difference between both groups in all-cause death (RR 0.79; 95% CI 0.53–1.18) and myocardial infarction (RR 0.80; 95% CI 0.61–1.04). Conclusion: In patients undergoing complex PCI, intravascular imaging—specifically IVUS—reduced MACE by decreasing the incidence of cardiac death, stent thrombosis, and target vessel and target lesion revascularization. [ABSTRACT FROM AUTHOR]

Aiming at the problems of incomplete dehazing, color distortion, and loss of detail and edge information encountered by existing algorithms when processing images of underground coal mines, an image dehazing algorithm for underground coal mines, named CAB CA DSConv Fusion gUNet (CCDF-gUNet), is proposed. First, Dynamic Snake Convolution (DSConv) is introduced to replace traditional convolutions, enhancing the feature extraction capability. Second, residual attention convolution blocks are constructed to simultaneously focus on both local and global information in images. Additionally, the Coordinate Attention (CA) module is utilized to learn the coordinate information of features so that the model can better capture the key information in images. Furthermore, to simultaneously focus on the detail and structural consistency of images, a fusion loss function is introduced. Finally, based on the test verification of the public dataset Haze-4K, the Peak Signal-to-Noise Ratio (PSNR), Structural Similarity (SSIM), and Mean Squared Error (MSE) are 30.72 dB, 0.976, and 55.04, respectively, and on a self-made underground coal mine dataset, they are 31.18 dB, 0.971, and 49.66, respectively. The experimental results show that the algorithm performs well in dehazing, effectively avoids color distortion, and retains image details and edge information, providing some theoretical references for image processing in coal mine surveillance videos. [ABSTRACT FROM AUTHOR]

In order to investigate the distribution and accumulation characteristics of metabolites and mineral elements in different parts of Peganum harmala L. (P. harmala), and the synergistic or antagonistic effects between them. In this study, nuclear magnetic resonance (NMR), high performance liquid chromatography (HPLC) and inductively coupled plasma optical emission spectrometer (ICP-OES) were used to determine the contents of metabolites (proline, phosphorylcholine, choline, lysine, 4-hydroxyisoleucine, asparagine, acetic acid, sucrose, harmaline and vasicine) and mineral elements (Ca, Mg, K, P, Na, Cr, Cu, Fe, Zn, Mn, Ni, C, N) in five parts of P. harmala, including root, seed, testa, stem and leaf, and to analyze the relationship among the contents of metabolites and mineral elements. The results showed that the contents of acetic acid, proline, lysine, sucrose and Fe in the root were higher than those in other parts, and the contents of harmaline, phosphorylcholine, P, C, N and Zn in the seeds were the highest. The leaves were rich in vasicine, Na, K, Ca, Mg and Mn. The principal component analysis (PCA) showed that the cumulative variance contribution of the first two principal components was 69.00 %, and the loading values of K, Cu and sucrose were higher, which was consistent with the results of biplot and cluster analysis(HCA). Correlation analysis (CA) results showed that there was a strong overall correlation between the different components of seeds and leaves, and the correlation was greater than that of other parts. The results of this study are helpful to understand the correlation of functional traits among different parts of plants, and determine the internal mechanism of controlling functional traits and the proportional relationship between traits, so as to provide a reference for the resource utilization of plants.

Accurate identification of Mycobacterium tuberculosis (M. tuberculosis) is a critical step in the diagnosis of tuberculosis. Existing object detection methods struggle with the challenges posed by the varied morphology and size of M. tuberculosis in sputum smear images, which makes precise targeting difficult. To solve these problems, an improved YOLOv8s model is proposed. Specifically, an additional detection head is added to focus on small target information. Second, a multi-scale feature fusion module is introduced to adapt the model to different sizes of M. tuberculosis. In addition, a convolutional layer is added to the Coordinate Attention (CA) module to extract more advanced semantic features. Finally, a self-attention mechanism is added after the CA module to enhance the model's ability to accurately understand and localize the varied morphology of M. tuberculosis. Our model performed well with an average precision of 85.7 % when tested on a publicly available dataset. This clearly demonstrates the effectiveness of our proposed model in M. tuberculosis detection.

Abstract Introduction Trials evaluating the role of intravascular imaging in percutaneous coronary intervention (PCI) for complex coronary artery disease have yielded mixed results. This study aimed to compare the outcomes of intravascular imaging specifically intravascular ultrasound (IVUS) with those from conventional coronary angiography in complex PCI. Methods Comprehensive electronic search of MEDLINE, EMBASE, and Cochrane databases was performed until March 2023 for randomized clinical trials (RCTs) comparing intravascular imaging with coronary angiography in patients undergoing complex PCI. Complex PCI was defined per each study, and included PCI for American College of Cardiology/American Heart Association (ACC/AHA) type B2/C lesions, unprotected left main coronary artery disease, or multivessel stenting. The primary study outcome was major adverse clinical events (MACE). Results The meta-analysis included 10 RCTs with a total of 6615 patients (3576 in the intravascular imaging group and 3039 in the coronary angiography group). The weighted mean-follow up was 28.9 months. Compared with coronary angiography, intravascular imaging reduced MACE (8% vs. 13.3%; relative risk [RR] 0.63; 95% confidence interval [CI] 0.54–0.73), cardiac death (RR 0.47; 95% CI 0.31–0.73), definite/probable stent thrombosis (RR 0.48; 95% CI 0.24–0.97), target vessel revascularization (RR 0.62; 95% CI 0.46–0.83), and target lesion revascularization (RR 0.61; 95% CI 0.47–0.79). There was no difference between both groups in all-cause death (RR 0.79; 95% CI 0.53–1.18) and myocardial infarction (RR 0.80; 95% CI 0.61–1.04). Conclusion In patients undergoing complex PCI, intravascular imaging—specifically IVUS—reduced MACE by decreasing the incidence of cardiac death, stent thrombosis, and target vessel and target lesion revascularization.

AimsThe safety and feasibility of combining percutaneous catheter ablation (CA) for atrial fibrillation with left atrial appendage occlusion (LAAO) as a single procedure in the USA have not been investigated. We analyzed the US National Readmission Database (NRD) to investigate the incidence of combined LAAO + CA and compare major adverse cardiovascular events (MACEs) with matched LAAO-only and CA-only patients.Methods and resultsIn this retrospective study from NRD data, we identified patients undergoing combined LAAO and CA procedures on the same day in the USA from 2016 to 2019. A 1:1 propensity score match was performed to identify patients undergoing LAAO-only and CA-only procedures. The number of LAAO + CA procedures increased from 28 (2016) to 119 (2019). LAAO + CA patients (n = 375, mean age 74 ± 9.2 years, 53.4% were males) had non-significant higher MACE (8.1%) when compared with LAAO-only (n = 407, 5.3%) or CA-only patients (n = 406, 7.4%), which was primarily driven by higher rate of pericardial effusion (4.3%). All-cause 30-day readmission rates among LAAO + CA patients (10.7%) were similar when compared with LAAO-only (12.7%) or CA-only (17.5%) patients. The most frequent primary reason for readmissions among LAAO + CA and LAAO-only cohorts was heart failure (24.6 and 31.5%, respectively), while among the CA-only cohort, it was paroxysmal atrial fibrillation (25.7%).ConclusionWe report an 63% annual growth (from 28 procedures) in combined LAAO and CA procedures in the USA. There were no significant difference in MACE and all-cause 30-day readmission rates among LAAO + CA patients compared with matched LAAO-only or CA-only patients.

The diffused bit generator (DBG) is an entropy generator that generates a stream of random bits. DBG is realized using a linear feedback shift register (LFSR) and cellular automata (CA). LFSR and CA are realized using flip-flops and XOR gates. The flip-flops required are designed using true single-phase clock (TSPC)-based logic to minimize the area and power of the LFSR and CA circuits. The XOR gates used in the circuits are realized either using a 12-transistor (12T) or a 6-transistor (6T). To further reduce power dissipation in the DBG circuit, low-power techniques are incorporated. In the proposed 8-bit DBGs, the adaptive voltage level at source (AVLS) is incorporated to reduce power consumption. The circuits are realized using Cadence Virtuoso in CMOS 180 nm technology, and Specter is used for simulation and power analysis. The DBG functionality is assessed for frequencies ranging up to 1 GHz with a supply voltage of 1.8 V. From the results, it was inferred that at 1 GHz the proposed-1 DBG (using a 12T XOR gate) is 94.05% power efficient; while, the proposed-2 DBG (using a 6T XOR gate) is 90.27% power efficient when compared to the reference circuits. Implementation of the proposed-1 DBG was also carried out in CMOS 45 nm technology, the functionality was verified and the power was analyzed. A similar trend of power reduction was observed. [ABSTRACT FROM AUTHOR]

Cinnamon is one of the most popular spices worldwide, and volatile organic compounds (VOCs) are its main metabolic products. The misuse or mixing of cinnamon on the market is quite serious. This study used gas chromatography-ion migration spectroscopy (GC-IMS) technology to analyze the VOCs of cinnamon samples. The measurement results showed that 66 VOCs were detected in cinnamon, with terpenes being the main component accounting for 45.45%, followed by aldehydes accounting for 21.21%. The content of esters and aldehydes was higher in RG-01, RG-02, and RG-04; the content of alcohols was higher in RG-01; and the content of ketones was higher in RG-02. Principal component analysis, cluster analysis, and partial least squares regression analysis can be performed on the obtained data to clearly distinguish cinnamon. According to the VIP results of PLS-DA, 1-Hexanol, 2-heptanone, ethanol, and other substances are the main volatile substances that distinguish cinnamon. This study combined GC-IMS technology with chemometrics to accurately identify cinnamon samples, providing scientific guidance for the efficient utilization of cinnamon. At the same time, this study is of great significance for improving the relevant quality standards of spices and guiding the safe use of spices. [ABSTRACT FROM AUTHOR]

To investigate the effect of calcium (Ca) application on post-harvest fruit quality in Nanfeng tangerines, this study sprayed three calcium fertilizers (Calbit, Larry 8 Calcium, and Suspended Calcium) before harvesting. The fruit quality was assessed over a storage period of 0–60 d at a controlled room temperature of 20 ± 5 °C. The evaluation methods included principal component analysis (PCA) and linearly weighted summation. Pre-harvest calcium treatments increased the fruit calcium content and maintained higher firmness and shear. Compared to the control group, fruits treated with Calbit exhibited decreased levels of decay, weight loss, and respiration rates. Additionally, they demonstrated higher values of L*, b*, C*, and H° and lower values of a* and CCI. Moreover, the Larry 8 Calcium and Calbit treatments increased the levels of soluble solids, total soluble sugars, titratable acids, and VC content in the fruit. They accelerated the decomposition of tartaric, oxalic, and citric acids in the pulp, promoting the accumulation of sucrose and glucose. PCA and comprehensive evaluation scores indicated that the comprehensive scores assessing the storage quality of Nanfeng tangerine fruits treated with pre-harvest Larry 8 Calcium and Calbit were higher than those of the control group. The highest composite quality scores for Calbit-treated fruits were observed at 40 and 60 d, and the highest scores for Larry 8 Calcium were recorded at other intervals. These findings suggest that pre-harvest calcium application improved the post-harvest fruit quality of Nanfeng tangerines, with Larry 8 Calcium and Calbit emerging as favorable options. [ABSTRACT FROM AUTHOR]

This study aimed to investigate the changes in Paraoxonase (PON), Carbonic Anhydrase (CA), and β-glucosidase levels of different aged rats and scopolamine-induced memory impairment rats. This study used young, adult, and middle-aged male Wistar Albino rats. Scopolamine was administered as a single dose/multiple doses and a Morris water maze (MWM) was used for spatial learning testing in rats. Enzyme-linked immunosorbent assays (ELISAs) were used to determine serum and liver PON and β-glucosidase levels. The CA enzyme activity was assayed following the hydration of CO2. As a result of the comparison of age-related and scopolamine-related changes in PON and β-glucosidase levels in liver and serum samples, no significant age-related and scopolamine-effective changes were observed in serum, while liver PON and liver β-glucosidase levels were found to change significantly. CA activity studies, on the other hand, showed that adults have the lowest CA activity compared to young and middle-aged groups and scopolamine inhibited CA activity in vivo. We found that adult rats modeled with memory impairment had statistically lower levels of liver PON and liver β-glucosidase. CA activity was also found to be significantly reduced. β-glucosidase and CA should be further investigated in terms of neurodegenerative disease risk factors, just like PON, whose importance has been determined by numerous studies in the literature. [ABSTRACT FROM AUTHOR]

Polydimethylsiloxane (PDMS) is recognized as an excellent stretchable substrate in wearable electronics, due to its desirable properties such as tensile properties, transparency, thermal stability, non-toxicity, and good biocompatibility. However, its limited fracture toughness and susceptibility to cracking significantly reduce the material's overall durability. In this study, the solution casting method was applied to prepare the nanofibers composites combined stretchable PDMS and aligned electrospun cellulose acetate (CA) to improve its mechanical properties and keep its transparency. The results showed that composites containing 3 wt% loadings of electrospun CA nanofibers exhibited a light transmittance exceeding 85% within the visible light range. Specifically, the PDMS/CA-400 composites exhibited maximum improvements in comparison to pure PDMS. Notably, the tensile strength increased significantly from 2.1 to 3.0 MPa, while the toughness increased from 0.93 to 2.49 MJ/m³. In addition, the tensile strength of PDMS/CA-400 composites with pre-cut cracks increased from 0.2 to 1.4 MPa, and the fracture toughness increased from 14.78 to 174.42 kJ/m³, which were respectively 7 and 12 times compared to pure PDMS. Scanning electron microscope images showed that PDMS formed good interfacial interaction with CA nanofibers. This study introduces a novel method utilizing electrospun nanofibers to create transparent and fracture-resistant stretchable composites, offering promising enhancements for the durability of wearable electronic devices. Highlights • Explore the impact of the speed of receiving rollers on the degree of fiber arrangement. • PDMS/CA-400 composite material shows good light transmittance and high fracture resistance. • The tight interface between the fiber and the matrix improves the optical transmission and mechanical properties of the composite materials. [ABSTRACT FROM AUTHOR]

Due to the issues of remote sensing object detection algorithms based on deep learning, such as a high number of network parameters, large model size, and high computational requirements, it is challenging to deploy them on small mobile devices. This paper proposes an extremely lightweight remote sensing aircraft object detection network based on the improved YOLOv5n. This network combines Shufflenet v2 and YOLOv5n, significantly reducing the network size while ensuring high detection accuracy. It substitutes the original CIoU and convolution with EIoU and deformable convolution, optimizing for the small-scale characteristics of aircraft objects and further accelerating convergence and improving regression accuracy. Additionally, a coordinate attention (CA) mechanism is introduced at the end of the backbone to focus on orientation perception and positional information. We conducted a series of experiments, comparing our method with networks like GhostNet, PP-LCNet, MobileNetV3, and MobileNetV3s, and performed detailed ablation studies. The experimental results on the Mar20 public dataset indicate that, compared to the original YOLOv5n network, our lightweight network has only about one-fifth of its parameter count, with only a slight decrease of 2.7% in mAP@0.5. At the same time, compared with other lightweight networks of the same magnitude, our network achieves an effective balance between detection accuracy and resource consumption such as memory and computing power, providing a novel solution for the implementation and hardware deployment of lightweight remote sensing object detection networks. [ABSTRACT FROM AUTHOR]

The main objective of this study is to assess the monitoring system of surface water quality in Can Tho using principal component analysis (PCA) and cluster analysis (CA). Water samples were monthly collected in 2020 at 35 sampling sites and then analyzed for 18 parameters including temperature, pH, turbidity, dissolved oxygen (DO), biological oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), ammonium (NH4 + -N), nitrate (NO3ˉ-N), nitrite (NO2ˉ-N), orthophosphate (PO4 3 ˉ-P), chromium (Cr), fluoride (F- ), arsenic (As), lead (Pb), mercury (Hg) and coliform. These values were compared with the national technical regulation on surface water quality and calculated water quality index (WQI). The findings indicated that surface water quality in Can Tho was contaminated by organic matters, suspended solids, and microorganisms. TSS, BOD and COD were high in the dry season, while high level of coliform was found in the wet season. The results of computed WQI showed that the surface water quality was from good to excellent. The PCA results show that 77.2% of water quality fluctuations in the study area were potentially affected by domestic, agricultural, industrial activities and hydrological factors (rainwater runoff, riverbank erosion). Moreover, the results of PCA revealed that water quality parameters could be diminished from 18 to 14 parameters without the loss of important for evaluating surface water quality. CA suggested that total sampling sites and frequencies in the current monitoring program are likely to reduce from 35 to 27 sites and 12 to 6-7 times/year, respectively. It is suggested that these findings can provide essential scientific information for local environmental managers in adjusting the surface water quality monitoring network in Can Tho city, Vietnam. [ABSTRACT FROM AUTHOR]

Background: Condyloma acuminatum (CA), which is a highly contagious sexually transmitted illness generated by human papillomavirus (HPV) infection, is characterized by abnormal proliferation of keratinocytes resulting in verrucous lesions. Although solute carrier family 30 member 1 (ZNT1) is highly expressed in CA tissues, the function of ZNT1 in CA remains unclear. Methods: HPV transfection was performed in HaCaT to simulate the CA pathological environment. The mRNA and protein levels were monitored using RT-qPCR and immunoblotting. Cell viability was found using the MTT test. Cell invasion and migration were probed using the transwell and wound healing. Results: ZNT1 expression was up-regulated in CA tissues, and HPV transfection increased the expression of ZNT1. Overexpression of ZNT1 promoted the proliferation, migration and invasion of Human immortalized keratinocyte (HaCaT) transfected with HPV. Meanwhile, ZNT1 knockdown repressed the proliferation, migration and invasion of HaCaT that HPV transfected. Further research displayed that ZNT1 promoted the proliferation, migration and invasion of HaCaT transfected with HPV through the PI3K/Akt pathway. Conclusion: Our research confirmed that ZNT1 regulated the proliferation, migration and invasion of HaCaT transfected with HPV through the PI3K/Akt pathway, providing a new target for the effective remedy of CA. [ABSTRACT FROM AUTHOR]

Chromosome analysis (CA) and chromosomal microarray analysis (CMA) have been successfully used to diagnose genetic disorders. However, many conditions remain undiagnosed due to limitations in resolution (CA) and detection of only unbalanced events (CMA). Optical genome mapping (OGM) has the potential to address these limitations by capturing both structural variants (SVs) resulting in copy number changes and balanced rearrangements with high resolution. In this study, we investigated OGM's concordance using 87 SVs previously identified by CA, CMA, or Southern blot. Overall, OGM was 98% concordant with only three discordant cases: (1) uncalled translocation with one breakpoint in a centromere; (2) uncalled duplication with breakpoints in the pseudoautosomal region 1; and (3) uncalled mosaic triplication originating from a marker chromosome. OGM provided diagnosis for three previously unsolved cases: (1) disruption of the SON gene due to a balanced reciprocal translocation; (2) disruption of the NBEA gene due to an inverted insertion; (3) disruption of the TSC2 gene due to a mosaic deletion. We show that OGM is a valid method for the detection of many types of SVs in a single assay and is highly concordant with legacy cytogenomic methods; however, it has limited SV detection capabilities in centromeric and pseudoautosomal regions. [ABSTRACT FROM AUTHOR]

The gardenia flower not only has extremely high ornamental value but also is an important source of natural food and spices, with a wide range of uses. To support the development of gardenia flower products, this study used headspace gas chromatography–ion mobility spectrometry (HS-GC–IMS) technology to compare and analyze the volatile organic compounds (VOCs) of fresh gardenia flower and those after using four different drying methods (vacuum freeze-drying (VFD), microwave drying (MD), hot-air drying (HAD), and vacuum drying (VD)). The results show that, in terms of shape, the VFD sample is almost identical to fresh gardenia flower, while the HAD, MD, and VD samples show significant changes in appearance with clear wrinkling; a total of 59 volatile organic compounds were detected in the gardenia flower, including 13 terpenes, 18 aldehydes, 4 esters, 8 ketones, 15 alcohols, and 1 sulfide. Principal component analysis (PCA), cluster analysis (CA), and partial least-squares regression analysis (PLS-DA) were performed on the obtained data, and the research found that different drying methods impact the VOCs of the gardenia flower. VFD or MD may be the most effective alternative to traditional sun-drying methods. Considering its drying efficiency and production cost, MD has the widest market prospects.

Land surface temperature (LST) is a crucial parameter influencing the thermal environment of urban and natural areas. Land use/land cover (LULC) patterns significantly impact LST, highlighting the need for a comprehensive understanding of their relationship. This study delves into the intricate interplay between LULC and LST in Pune city, India, employing a spatiotemporal analysis approach. The study utilizes satellite imagery from 2000, 2010, and 2022 to map LULC changes with Maximum likelihood, support vector machine and Random tree classification and their evaluation with accuracy and Kappa coefficient. Additionally, projected LULC for 2030 is prepared to assess future LST scenarios. Winter and summer LST data are analyzed to capture the seasonal dynamics of LST-LULC interactions. Pune has undergone significant LULC transformations, with the proportion of built-up areas increasing from 7% in 2000 to 47% in 2022, while barren land has decreased from 41% to 37%. Built-up areas exhibit consistently lower LST values during winter, while barren land tends to have the highest LST. In contrast, during summer, built-up and barren areas experience higher LST values, while water bodies and vegetation display relatively lower LST values due to their cooling effects. Mean LST in Pune has increased from 34.59°C in 2000 to 39.38℃ in 2022, reflecting the changing thermal dynamics associated with LULC alterations. The expansion of built-up areas has contributed to temperature increases of up to 5.5℃ in specific locations, highlighting the urban heat island effect. The study's findings emphasize the need for sustainable land use planning and development strategies to mitigate the adverse impacts of urbanization on LST. Policymakers, urban planners, and environmentalists can utilize these insights to develop informed land use policies, zoning regulations, and climate-smart urban development strategies. [ABSTRACT FROM AUTHOR]

Bearing fault diagnosis plays an important part in preventing rotating equipment faults, especially in the field of ultra-low-speed bearing fault diagnosis. Due to their low fault frequency and insignificant fault characteristics, it is difficult to realise the fault diagnosis of ultra-low-speed bearings using traditional methods; therefore, based on acoustic emission (AE) signals, this study proposes an ultra-low-speed bearing recognition model with EfficientNet as the backbone feature extraction network and successfully achieves bearing fault diagnosis under small-sample variable working conditions combined with transfer learning. The coordinate attention (CA) mechanism is introduced into the EfficientNet backbone feature extraction network to improve the ability of the model to extract detailed position information. The AdamW optimisation algorithm is introduced to improve the generalisation ability of the model. Combined with the idea of transfer learning, the data under different working conditions are trained and tested to form a high-performance and lightweight small-sample variable condition bearing recognition model called EfficientNet-CA-AdamW (EfficientNet-CAA). Comparison experiments show that the EfficientNet-CAA model proposed in this study has an accuracy of 99.81% for ultra-low-speed bearing recognition when the training samples are sufficient. Furthermore, the recognition accuracy is smoother and the loss function is significantly lower compared with convolutional neural network (CNN) models such as AlexNet, VGG-16, ResNet-34, ShuffleNet-V2 and EfficientNet-B0. In small-sample variable condition fault recognition, it has more powerful advantages compared with the other models. The recognition accuracy under variable conditions can reach more than 98%, which is significantly higher than that of the other models, and effectively improves the bearing fault recognition accuracy under small-sample variable conditions. In this study, the CA mechanism and the AdamW optimisation algorithm are introduced to lessen the difficulty of extracting detailed features and address the lack of generalisation ability of the EfficientNet model, which provides an idea for the application of the deep learning model to small-sample bearing fault diagnosis under variable working conditions. [ABSTRACT FROM AUTHOR]

Climate change is a change in the usual weather found in a place. The climate change has a major impact not only on natural disasters of the Earth but also on human health. The climate crisis is then no longer a future concern. It includes both the global warming driven by human emissions of greenhouse gases (GHG), and the resulting large-scale shifts in weather patterns. Global warming can occur from a variety of causes, both natural and human induced. The primary GHG in Earth's atmosphere, listed in decreasing order of average global mole fraction, are: water vapor (H2O), carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), and ozone (O3). Today, scientists around the world continue to try and solve the puzzle of climate change. It is clear that to address climate change, the amount of CO2 released into the atmosphere by industrial process has to be reduced because once it is added to the atmosphere, it can continue to affect climate for thousands of years. For such a purpose, an approach to intervention using expression vectors for any protein targeting to the cell plasma membrane via the glycosylphosphatidylinositol, GPI, anchor is suggested. The resulting GPI-anchored proteins would be useful for studying intermolecular interactions, especially gene-environment interactions, in investigating the potential impact of any chemical compounds on any genes of interest and could be used for carbonic anhydrase (CA)-based CO2-capture (environmental application). This approach would be crucial not only for capturing CO2via GPI and CA but also for the production of CA enzyme as well as its stabilization and therefore useful for combating the global warming of climate change. [ABSTRACT FROM AUTHOR]

Luvic Greyzemic Phaeozems have been farmed for centuries in Western Ukraine. We investigate their stocks of major nutrients and stoichiometry under arable crops receiving conventional NPK fertilisation and an unfertilised control. Total carbon stocks increase only with parallel increases in total N, P, Ca and Mg. Likewise, total N increases along with parallel increases in total Ca and Mg, P and Ca, P and C. Under winter barley, application of the background fertilisation (N23P60K60) + N97 (urea) before sowing, with or without nitrapyrin as a nitrogen stabiliser, improved the status of C, N, Ca and Mg to P in the 0–20 cm soil layer. The best ratio of total C, N, Ca and Mg to P and the best C:N, C:P, N:P, and Ca:N ratios were achieved with the background fertilisation plus nitrapyrin and urea or ammonium nitrate. The system cannot hold onto nutrients, nitrogen in particular, applied in excess of the harmonic stoichiometry. [ABSTRACT FROM AUTHOR]

Zinc (Zn) deficiency is a widespread problem in agricultural soils all over the globe. As an essential element, Zn plays a decisive role in realization of high yields of wheat, the changes in activities of Zn dependent enzymes and its accumulation in various plant parts of wheat varieties of differential susceptibility. The aim of the study was to examine the activities of Zn dependent enzymes, i.e. superoxide dismutase (SOD), carbonic anhydrase (CA); chlorophyll and grain protein content and to evaluate the pattern of Zn transport in two wheat varieties (UP2628-Zn efficient and UP262-Zn inefficient). All these parameters were evaluated in a pot experiment under different modes of Zn applications viz., control (C), soil application (S), foliar application (F), soil+foliar application (S+F). The accumulation of Zn in different plant parts of both wheat varieties under different Zn supply regimes was monitored in a separate autoradiography experiment where radiolabelled Zn was used. An increased activity of SOD, CA and total chlorophyll content in leaves, high protein content in grains and 65Zn accumulation was observed under S+F mode of Zn application. Zinc efficient variety (UP2628) showed higher SOD, CA activities, chlorophyll content in leaves and grain protein content as compared to UP262. Both soil application + foliar spray of Zn and cultivation of Zn efficient variety (UP2628) can be best approach for Zn biofortification of wheat. [ABSTRACT FROM AUTHOR]

The CO2-assisted oxidative dehydrogenation of propane (ODP) was investigated over titania based composite metal oxides, 10% MxOy-TiO2 (M: Zr, Ce, Ca, Cr, Ga). It was found that the surface basicity of composite metal oxides was significantly higher than that of bare TiO2 and varied in a manner which depended strongly on the nature of the MxOy modifier. The addition of metal oxides on the TiO2 surface resulted in a significant improvement of catalytic performance induced by a synergetic interaction between MxOy and TiO2 support. Propane conversion and propylene yield were strongly influenced by the nature of the metal oxide additive and were found to be superior for the Cr2O3-TiO2 and Ga2O3-TiO2 catalysts characterized by moderate basicity. The reducibility of the latter catalysts was significantly increased, contributing to the improved catalytic performance. This was also the case for the surface acidity of Ga2O3-TiO2 which was found to be higher compared with Cr2O3-TiO2 and TiO2. A general trend was observed whereby catalytic performance increased significantly with decreasing the primary crystallite size of TiO2. DRIFTS studies conducted under reaction conditions showed that the adsorption/activation of CO2 was favored on the surface of composite metal oxides. This may be induced by the improved surface basicity observed with the MxOy addition on the TiO2 surface. The Ga2O3 containing sample exhibited sufficient stability for about 30 h on stream, indicating that it is suitable for the production of propylene through ODP with CO2 reaction. [ABSTRACT FROM AUTHOR]

Safety helmets can reduce head injuries fromobject impacts and lower the probability of safety accidents, as well as being of great significance to construction safety.However, for a variety of reasons, construction workers nowadays may not strictly enforce the rules ofwearing safety helmets. In order to strengthen the safety of construction site, the traditional practice is tomanage it through methods such as regular inspections by safety officers, but the cost is high and the effect is poor.With the popularization and application of construction site videomonitoring,manual video monitoring has been realized for management, but the monitors need to be on duty at all times, and thus are prone to negligence. Therefore, this study establishes a lightweight model YOLO_CA based on YOLOv5 for the automatic detection of construction workers’ helmet wearing, which overcomes the shortcomings of the current manual monitoring methods that are inefficient and expensive. The coordinate attention (CA) addition to the YOLOv5 backbone strengthens detection accuracy in complex scenes by extracting critical information and suppressing noncritical information. Further parameter compression with deeply separable convolution (DWConv). In addition, to improve the feature representation speed, we swap out C3 with a Ghostmodule, which decreases the floating-point operations needed for feature channel fusion, and CIOU_Loss was substituted with EIOU_Loss to enhance the algorithm’s localization accuracy.Therefore, the originalmodelneeds to be improved so as to enhance the detection of safety helmets. The experimental results show that the YOLO_CAmodel achieves good results in all indicators compared with the mainstream model. Compared with the original model, the mAP value of the optimized model increased by 1.13%, GFLOPs cut down by 17.5%, and there is a 6.84% decrease in the total model parameters, furthermore, the weight size cuts down by 4.26%, FPS increased by 39.58%, and the detection effect andmodel size of this model can meet the requirements of lightweight embedding. [ABSTRACT FROM AUTHOR]