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In the polar regions of Titan, the main satellite of Saturn, hydrocarbon seas have been discovered by the Cassini-Huygens mission. RADAR observations have revealed surprising and transient bright areas over Ligeia Mare surface. As suggested by recent research, bubbles could explain these strange features. However, the nucleation and growth of such bubbles, together with their RADAR reflectivity, have never been investigated. All of these aspects are critical to an actual observation. We have thus applied the classical nucleation theory to our context, and we developed a specific radiative transfer model that is appropriate for bubbles streams in cryogenic liquids. According to our results, the sea bed appears to be the most plausible place for the generation of bubbles, leading to a signal comparable to observations. This conclusion is supported by thermodynamic arguments and by RADAR properties of a bubbly column. The latter are also valid in the case of bubble plumes, due to gas leaking from the sea floor., Comment: Published in The Astrophysical Journal

The hydrocarbons seas of Titan, discovered by Cassini/Huygens mission are among the most mysterious and interesting features of this moon. In the future, a possible dedicated planetary probe, will certainly measure the speed of sound in this cryogenic liquid, as it was planned in the case of a Huygens landing into a sea. Previous theoretical studies of such acoustic measurements were based on rather simple models, leading in some cases to unphysical situations. Employed in a vast body of chemical engineering works, the state of the art PC-SAFT model has been recently introduced in studies aimed at Titan. Here, I revisit the issue of the speed of sound in Titan's liquids, in the light of this theory. I describe, in detail, the derivation of the speed of sound from the chosen equation of state and the potential limitations of the approach. To make estimations of the composition of a ternary liquid mixture N2:CH4:C2H6 from speed of sound measurements an original inversion algorithm is proposed. It is shown that 50 measures between 90 K and 100 K are enough to ensure an accuracy of the derived compositions better than 10%. The influence of the possible presence of propane is also investigated., Comment: 7 pages, 5 figures, accepted in MNRAS

There is a growing body of evidences for the presence of crystalline material in comets. These crystals are believed to have been annealed in the inner part of the proto-solar nebula, while comets should have been formed in the outer regions. Several transport processes have been proposed to reconcile these two facts; among them a migration driven by photophoresis. The primarily goal of this work is to assess whether disk irradiation by a Pre-Main Sequence star would influence the photophoretic transport. To do so, we have implemented an evolving 1+1D model of an accretion disk, including advanced numerical techniques, undergoing a time-dependent irradiation, consistent with the evolution of the proto-Sun along the Pre-Main Sequence. The photophoresis is described using a formalism introduced in several previous works. Adopting the opacity prescription used in these former studies, we find that the disk irradiation enhances the photophoretic transport: the assumption of a disk central hole of several astronomical units in radius is no longer strictly required, whereas the need for an ad hoc introduction of photoevaporation is reduced. However, we show that a residual trail of small particles could annihilate the photophoretic driven transport via their effect on the opacity. We have also confirmed that the thermal conductivity of transported aggregates is a crucial parameter which could limit or even suppress the photophoretic migration and generate several segregation effects.

Numerous geological features that could be evaporitic in origin have been identified on the surface of Titan. Although they seem to be water-ice poor, their main properties -chemical composition, thickness, stratification- are essentially unknown. In this paper, which follows on a previous one focusing on the surface composition (Cordier et al., 2013), we provide some answers to these questions derived from a new model. This model, based on the up-to-date thermodynamic theory known as "PC-SAFT", has been validated with available laboratory measurements and specifically developed for our purpose. 1-D models confirm the possibility of an acetylene and/or butane enriched central layer of evaporitic deposit. The estimated thickness of this acetylene-butane layer could explain the strong RADAR brightness of the evaporites. The 2-D computations indicate an accumulation of poorly soluble species at the deposit's margin. Among these species, HCN or aerosols similar to tholins could play a dominant role. Our model predicts the existence of chemically trimodal "bathtub rings" which is consistent with what it is observed at the south polar lake Ontario Lacus. This work also provides plausible explanations to the lack of evaporites in the south polar region and to the high radar reflectivity of dry lakebeds.

The discovery of almost 2000 exoplanets has revealed an unexpectedly diverse planet population. Observations to date have shown that our Solar System is certainly not representative of the general population of planets in our Milky Way. The key science questions that urgently need addressing are therefore: What are exoplanets made of? Why are planets as they are? What causes the exceptional diversity observed as compared to the Solar System? EChO (Exoplanet Characterisation Observatory) has been designed as a dedicated survey mission for transit and eclipse spectroscopy capable of observing a large and diverse planet sample within its four-year mission lifetime. EChO can target the atmospheres of super-Earths, Neptune-like, and Jupiter-like planets, in the very hot to temperate zones (planet temperatures of 300K-3000K) of F to M-type host stars. Over the next ten years, several new ground- and space-based transit surveys will come on-line (e.g. NGTS, CHEOPS, TESS, PLATO), which will specifically focus on finding bright, nearby systems. The current rapid rate of discovery would allow the target list to be further optimised in the years prior to EChO's launch and enable the atmospheric characterisation of hundreds of planets. Placing the satellite at L2 provides a cold and stable thermal environment, as well as a large field of regard to allow efficient time-critical observation of targets randomly distributed over the sky. A 1m class telescope is sufficiently large to achieve the necessary spectro-photometric precision. The spectral coverage (0.5-11 micron, goal 16 micron) and SNR to be achieved by EChO, thanks to its high stability and dedicated design, would enable a very accurate measurement of the atmospheric composition and structure of hundreds of exoplanets., Comment: 50 pages, 30 figures. Experimental Astronomy

We revisit the problem of the split main sequence (MS) of the globular cluster omega Centauri, and report the results of two-epoch Hubble Space Telescope observations of an outer field, for which proper motions give us a pure sample of cluster members, and an improved separation of the two branches of the main sequence. Using a new set of stellar models covering a grid of values of helium and metallicity, we find that the best possible estimate of the helium abundance of the bluer branch of the MS is Y = 0.39 +/- 0.02. For the cluster center we apply new techniques to old observations: we use indices of photometric quality to select a high-quality sample of stars, which we also correct for differential reddening. We then superpose the color-magnitude diagram of the outer field on that of the cluster center, and suggest a connection of the bluer branch of the MS with one of the more prominent among the many sequences in the subgiant region. We also report a group of undoubted cluster members that are well to the red of the lower MS., Comment: 26 pages, 10 figures (4 in low resolution. AJ accepted on March 21, 2012

Hot temperature minerals have been detected in a large number of comets and were also identified in the samples of Comet Wild 2 that were returned by the Stardust mission. Meanwhile, observations of the distribution of hot minerals in young stellar systems suggest that these materials were produced in the inner part of the primordial nebula and have been transported outward in the formation zone of comets. We investigate the possibility that photophoresis provides a viable mechanism to transport high-temperature materials from the inner solar system to the regions in which the comets were forming. We use a grid of time-dependent disk models of the solar nebula to quantify the distance range at which hot minerals can be transported from the inner part of the disk toward its outer regions as a function of their size and density. The particles considered here are in the form of aggregates that presumably were assembled from hot mineral individual grains ranging down to submicron sizes and formed by condensation within the hottest portion of the solar nebula. Our particle-transport model includes the photophoresis, radiation pressure, and gas drag. Depending on the postulated disk parameters and the density of particles, 10-2 to 10-1 m aggregates can reach heliocentric distances up to 35 AU in the primordial nebula over very short timescales (no more than a few hundred thousand years). 10-3 m particles follow the same trajectory as the larger ones but their maximum migration distance does not exceed 26 AU and is reached at later epochs in the disks. On the other hand, 10-5 to 10-4 m aggregates are continuously pushed outward during the evolution of the solar nebula. Our simulations suggest that irrespective of the employed solar nebula model, photophoresis is a mechanism that can explain the presence of hot temperature minerals in the formation region of comets., Comment: Accepted for publication in Astronomy & Astrophysics

Between 2004 and 2007 the instruments of the CASSINI spacecraft discovered hydrocarbon lakes in the polar regions of Titan. We have developed a lake-atmosphere equilibrium model allowing the determination of the chemical composition of these liquid areas. The model is based on uncertain thermodynamic data and precipitation rates of organic species predicted to be present in the lakes and seas that are subject to spatial and temporal variations. Here we explore and discuss the influence of these uncertainties and variations. The errors and uncertainties relevant to thermodynamic data are simulated via Monte-Carlo simulations. Global Circulation Models (GCM) are also employed in order to investigate the possibility of chemical asymmetry between the south and the north poles, due to differences in precipitation rates. We find that mole fractions of compounds in the liquid phase have a high sensitivity to thermodynamic data used as inputs, in particular molar volumes and enthalpies of vaporization. When we combine all considered uncertainties, the ranges of obtained mole fractions are rather large (up to ~8500%) but the distributions of values are narrow. The relative standard deviations remain between 10% and ~300% depending on the compound considered. Compared to other sources of uncertainties and variability, deviation caused by surface pressure variations are clearly negligible, remaining of the order of a few percent up to ~20%. Moreover no significant difference is found between the composition of lakes located in north and south poles. Because the theory of regular solutions employed here is sensitive to thermodynamic data and is not suitable for polar molecules such as HCN and CH3CN, our work strongly underlines the need for experimental simulations and the improvement of Titan's atmospheric models., Comment: Accepted in Planetary and Space Science

Examination of ambient thermodynamic conditions suggest that clathrate hydrates could exist in the martian permafrost, on the surface and in the interior of Titan, as well as in other icy satellites. Clathrate hydrates probably formed in a significant fraction of planetesimals in the solar system. Thus, these crystalline solids may have been accreted in comets, in the forming giant planets and in their surrounding satellite systems. In this work, we use a statistical thermodynamic model to investigate the composition of clathrate hydrates that may have formed in the primordial nebula. In our approach, we consider the formation sequence of the different ices occurring during the cooling of the nebula, a reasonable idealization of the process by which volatiles are trapped in planetesimals. We then determine the fractional occupancies of guests in each clathrate hydrate formed at given temperature. The major ingredient of our model is the description of the guest-clathrate hydrate interaction by a spherically averaged Kihara potential with a nominal set of parameters, most of which being fitted on experimental equilibrium data. Our model allows us to find that Kr, Ar and N$_2$ can be efficiently encaged in clathrate hydrates formed at temperatures higher than $\sim$ 48.5 K in the primitive nebula, instead of forming pure condensates below 30 K. However, we find at the same time that the determination of the relative abundances of guest species incorporated in these clathrate hydrates strongly depends on the choice of the parameters of the Kihara potential and also on the adopted size of cages. Indeed, testing different potential parameters, we have noted that even minor dispersions between the different existing sets can lead to non-negligible variations in the determination of the volatiles trapped in clathrate hydrates formed in the primordial nebula., Comment: Accepted for publication in Faraday Discussions

Favored theories of giant planet formation center around two main paradigms, namely the core accretion model and the gravitational instability model. These two formation scenarios support the hypothesis that the giant planet metallicities should be higher or equal to that of the parent star. Meanwhile, spectra of the transiting hot Jupiter HD189733b suggest that carbon and oxygen abundances range from depleted to enriched with respect to the star. Here, using a model describing the formation sequence and composition of planetesimals in the protoplanetary disk, we determine the range of volatile abundances in the envelope of HD189733b that is consistent with the 20--80 Earth-masses of heavy elements estimated to be present in the planet's envelope. We then compare the inferred carbon and oxygen abundances to those retrieved from spectroscopy and we find a range of supersolar values that directly fit both spectra and internal structure models. In some cases, we find that the apparent contradiction between the subsolar elemental abundances and the {mass of heavy elements predicted in HD189733b by internal structure models} can be explained by the presence of large amounts of carbon molecules in the form of polycyclic aromatic hydrocarbons and soots in the upper layers of the envelope, as suggested by recent photochemical models. A diagnostic test that would confirm the presence of these compounds in the envelope is the detection of acetylene., Comment: Accepted for publication in The Astrophysical Journal

An unexpected feature of Titan's atmosphere is the strong depletion in primordial noble gases revealed by the Gas Chromatograph Mass Spectrometer aboard the Huygens probe during its descent on 2005 January 14. Although several plausible explanations have already been formulated, no definitive response to this issue has been yet found. Here, we investigate the possible sequestration of these noble gases in the liquid contained in lakes and wet terrains on Titan and the consequences for their atmospheric abundances. Considering the atmosphere and the liquid existing on the soil as a whole system, we compute the abundance of each noble gas relative to nitrogen. To do so, we make the assumption of thermodynamic equilibrium between the liquid and the atmosphere, the abundances of the different constituents being determined via {\bf } regular solution theory. We find that xenon's atmospheric depletion can be explained by its dissolution at ambient temperature in the liquid presumably present on Titan's soil. In the cases of argon and krypton, we find that the fractions incorporated in the liquid are negligible, implying that an alternative mechanism must be invoked to explain their atmospheric depletion., Comment: 11 pages, 1 figure

Hundreds of radar-dark patches interpreted as lakes have been discovered in the north and south polar regions of Titan. We have estimated the composition of these lakes by using the direct abundance measurements from the Gas Chromatograph Mass Spectrometer (GCMS) aboard the Huygens probe and recent photochemical models based on the vertical temperature profile derived by the Huygens Atmospheric Structure Instrument (HASI). Thermodynamic equilibrium is assumed between the atmosphere and the lakes, which are also considered as nonideal solutions. We find that the main constituents of the lakes are ethane (C2H6) (~76-79%), propane (C3H8) (~7-8%), methane (CH4) (~5-10%), hydrogen cyanide (HCN) (~2-3%), butene (C4H8) (~1%), butane (C4H10) (~1%) and acetylene (C2H2) (~1%). The calculated composition of lakes is then substantially different from what has been expected from models elaborated prior to the exploration of Titan by the Cassini-Huygens spacecraft., Comment: 5 pages, 2 figures, accepted in ApJL

Cassini-Huygens data are used to re-examine the potential sources of the D/H enhancement over solar, measured in methane, in Titan's atmosphere. Assuming that the system is closed with respect to carbon, the use of constraints from the Huygens probe for the determination of the current mass of atmospheric methane and the most up-to-date determination of D/H from Cassini/CIRS infrared spectra allow us to show that photochemical enrichment of deuterium is not sufficient to be the sole mechanism yielding the measured D/H value. A possible fractionation between CH3D and CH4 during the escape process may slightly enhance the deuterium enrichment, but is not sufficient to explain the observed D/H value over the range of escape values proposed in the literature. Hence, alternative mechanisms such as a primordial deuterium enrichment must be combined with the photochemical enrichment in Titan's atmosphere in order to explain its current D/H value., Comment: 4 pages, 3 figures, accepted in ApJL

We present a new database of stellar evolution models for a large range of masses and chemical compositions, based on an up-to-date theoretical framework. We briefly discuss the physical inputs and the assumptions adopted in computing the stellar models. We explain how to access to the on-line archive and briefly discuss the interactive WEB tools that can be used to compute user-specified evolutionary tracks/isochrones/luminosity functions. The future developments of this database are also outlined., Comment: 5 pages, 1 figure, to appear in the proceedings of the Workshop "Stellar pulsation and evolution", 2005. Monte Porzio Catone, Italy. Eds.: A. R. Walker and G. Bono

Two problems about the faintest Small Magellanic Cloud (SMC) Cepheids are addressed. On one hand evolutionary tracks fail to cross the Cepheid Instability Strip for the highest magnitudes (i.e. I-mag~17) where Cepheids are observed; Mass-Luminosity relations (ML) obtained from evolutionary tracks disagree with Mass-Luminosity relations derived from observations. We find that the above failures concern models built with standard input physics as well as with non-standard ones. The present work suggests that towards highest magnitudes, Cepheids stars undergo a selection effect caused by evolution: only the most metal poor stars cross the Instability Strip during the ``blue loop'' phase and are therefore the only ones which can be observed at low luminosity. This solution enables us to reproduce the shape of the lower part of the Instability Strip and improves the agreement between observed and theoretical ML-relations. Some issues are discussed, among them Beat Cepheids results argue strongly in favor of our hypothesis., Comment: 13 pages, 8 figures

The main scope of this paper is to investigate the possible existence of a metallicity dependence of the overshooting from main sequence stars turbulent cores. We focus on objects with masses in the range ~2.5 Msol - ~25 Msol. Basically, evolutionary time scale ratios are compared with star numbers ratios on the main sequence. Star populations are synthesized using grids of evolutionary tracks computed with various overshooting amounts. Observational material is provided by the large and homogeneous photometric database of OGLE 2 project for the Magellanic clouds. Attention is paid to the study of uncertainties: distance modulus, intergalactic and interstellar reddening, IMF slope and average binarity rate. Rotation and chemical composition gradient are also considered. The result for the overshooting distance is l_over(SMC)= 0.40 +0.12-0.06 Hp (Z=0.004) and l_over(LMC)= 0.10+0.17-0.10 Hp (Z=0.008) suggesting a possible dependence of the extent of the mixed central regions with metallicity within the considered mass range. Unfortunately it is not yet possible to fully disentangle effects of mass and chemical composition., Comment: 13 pages, 8 figures, accepted in Astronomy & Astrophysics