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Natural circulation phenomena have been nowadays largely revisited aiming to investigate the performances of passive safety systems in carrying-out heat removal under accidental conditions. For this purpose, assessment studies using CFD (Computational Fluid Dynamics) and also 3D thermal-hydraulic system codes are considered at different levels of the design and safety demonstration issues. However, these tools have not being extensively validated for specific natural circulation flow regimes involving flow mixing, temperature stratification, flow recirculation and instabilities.In the present study, an experimental test case based on a small-scale pool test rig experiment performed by Korea Atomic Energy Research Institute, is considered for code-to-code and code-to-experimental data comparison. The test simulation is carried out using the FLUENT and the 3D thermal-hydraulic system CATHARE-2 codes. The objective is to evaluate and compare their prediction capabilities with respect to the test conditions of the experiment. It was observed that, notwithstanding their numerical and modelling differences, similar agreement results are obtained. Nevertheless, additional investigations efforts are still needed for a better representation of the considered phenomena.