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We report observations of the atmospheric transmission spectrum of the sub-Neptune exoplanet GJ 3470 b taken using the Near-Infrared Camera (NIRCam) on JWST. Combined with two archival HST/WFC3 transit observations and fifteen archival Spitzer transit observations, we detect water, methane, sulfur dioxide, and carbon dioxide in the atmosphere of GJ 3470 b, each with a significance of >3-sigma. GJ 3470 b is the lowest mass -- and coldest -- exoplanet known to show a substantial sulfur dioxide feature in its spectrum, at $M_{p}$=11.2${\,{\rm M}_{\oplus}}$ and $T_{eq}$=600$\,$K. This indicates disequilibrium photochemistry drives sulfur dioxide production in exoplanet atmospheres over a wider range of masses and temperatures than has been reported or expected. The water, carbon dioxide, and sulfur dioxide abundances we measure indicate an atmospheric metallicity of approximately $100\times$ Solar. We see further evidence for disequilibrium chemistry in our inferred methane abundance, which is significantly lower than expected from equilibrium models consistent with our measured water and carbon dioxide abundances., Comment: 25 pages, 9 figures, 6 tables. Accepted in Astrophysical Journal Letters

Interactions between exoplanetary atmospheres and internal properties have long been hypothesized to be drivers of the inflation mechanisms of gaseous planets and apparent atmospheric chemical disequilibrium conditions. However, transmission spectra of exoplanets has been limited in its ability to observational confirm these theories due to the limited wavelength coverage of HST and inferences of single molecules, mostly H$_2$O. In this work, we present the panchromatic transmission spectrum of the approximately 750 K, low-density, Neptune-sized exoplanet WASP-107b using a combination of HST WFC3, JWST NIRCam and MIRI. From this spectrum, we detect spectroscopic features due to H$_2$O (21$\sigma$), CH$_4$ (5$\sigma$), CO (7$\sigma$), CO$_2$ (29$\sigma$), SO$_2$ (9$\sigma$), and NH$_3$ (6$\sigma$). The presence of these molecules enable constraints on the atmospheric metal enrichment (M/H is 10--18$\times$ Solar), vertical mixing strength (log$_{10}$K$_{zz}$=8.4--9.0 cm$^2$s$^{-1}$), and internal temperature ($>$345 K). The high internal temperature is suggestive of tidally-driven inflation acting upon a Neptune-like internal structure, which can naturally explain the planet's large radius and low density. These findings suggest that eccentricity driven tidal heating is a critical process governing atmospheric chemistry and interior structure inferences for a majority of the cool ($<$1,000K) super-Earth-to-Saturn mass exoplanet population., Comment: This preprint has not undergone any substantive post-submission improvements or corrections. The Version of Record of this article is published in Nature here: https://www.nature.com/articles/s41586-024-07514-w

There are no planets intermediate in size between Earth and Neptune in our Solar System, yet these objects are found around a substantial fraction of other stars. Population statistics show that close-in planets in this size range bifurcate into two classes based on their radii. It is hypothesized that the group with larger radii (referred to as "sub-Neptunes") is distinguished by having hydrogen-dominated atmospheres that are a few percent of the total mass of the planets. GJ 1214b is an archetype sub-Neptune that has been observed extensively using transmission spectroscopy to test this hypothesis. However, the measured spectra are featureless, and thus inconclusive, due to the presence of high-altitude aerosols in the planet's atmosphere. Here we report a spectroscopic thermal phase curve of GJ 1214b obtained with JWST in the mid-infrared. The dayside and nightside spectra (average brightness temperatures of 553 $\pm$ 9 and 437 $\pm$ 19 K, respectively) each show >3$\sigma$ evidence of absorption features, with H$_2$O as the most likely cause in both. The measured global thermal emission implies that GJ 1214b's Bond albedo is 0.51 $\pm$ 0.06. Comparison between the spectroscopic phase curve data and three-dimensional models of GJ 1214b reveal a planet with a high metallicity atmosphere blanketed by a thick and highly reflective layer of clouds or haze., Comment: Published online in Nature on May 10, 2023

The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI LRS observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000 $\times$ solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities $\leq$300 $\times$ solar due to their large corresponding molecular feature amplitudes, preferring values $\geq$1000 $\times$ solar and column haze production rates $\geq$10$^{-10}$ g cm$^{-2}$ s$^{-1}$. The steam atmosphere scenario with similarly high haze production rates also exhibit sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights $\geq$15 g mol$^{-1}$ are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b's atmosphere would likely require multiple transits and eclipses using JWST across the near and mid-infrared, potentially complemented by groundbased high resolution transmission spectroscopy., Comment: 21 pages, 10 figures, 4 tables. Accepted for publication by ApJ