Search

Tap water quality in Wroclaw, Poland was tracked by a two-year monitoring. Samples were taken in 175 points and subjected to multi-elemental analysis. Randomly selected samples underwent microbiolo...

The concept of the research data presented assumes the valorization of goldenrod residues from supercritical CO2 extraction following the circular economy principles. The biomass was enriched with microelements (Cr, Zn, Cu) by biosorption from single and multielemental solutions in batch and packed bed reactors. Modeling of biosorption equilibrium supported by instrumental analysis (SEM and FTIR) of material properties was employed to explain the metal ions binding mechanism. The preferential biosorption of Cr(III) over the divalent ions, allows the possibility of valorization of goldenrod residue in a garden-scale biosorption tank acting as a fixed-bed reactor working in an open circulation run and fed with microelements diluted in rainwater. The use of fertigation solution in optimal doses of micronutrients did not show any phytotoxic effect. Using the post-sorptive solution as a source of micronutrients for plants showed significant effects on growth parameters (increased chlorophyll content by 54%) compared to groups fertilized with commercial formulation (13% higher sprout mass). Additionally, fertigation with the post-sorption solution leads to the biofortification of cucumber sprouts. The recycling process results in two products: enriched biomass as a potential feed additive (with Cr(III), Cu(II), and Zn(II)) and a post-sorption solution (with Zn(II) and Cu(II) only) used in the fertigation of plants. Graphical Abstract

This literature review outlines the most important—agricultural and non-agricultural—types of sewage sludge management. The potential of waste sludge protein hydrolysates obtained by chemical sludge conditioning was reported. The discussed areas include acidic and alkaline hydrolysis, lime conditioning, polyelectrolyte dewatering and other supporting techniques such as ultrasounds, microwave or thermal methods. The legislative aspects related to the indication of the development method and admission to various applications based on specified criteria were discussed. Particular attention was devoted to the legally regulated content of toxic elements: cadmium, lead, nickel, mercury, chromium and microelements that may be toxic: copper and zinc. Various methods of extracting valuable proteins from sewage sludge have been proposed: chemical, physical and enzymatic. While developing the process concept, you need to consider extraction efficiency (time, temperature, humidity, pH), drainage efficiency of post-extraction residues and directions of their management. The final process optimization is crucial. Despite the development of assumptions for various technologies, excess sewage sludge remains a big problem for sewage treatment plants. The high costs of enzymatic hydrolysis, thermal hydrolysis and ultrasonic methods and the need for a neutralizing agent in acid solubilization limit the rapid implementation of these processes in industrial practice. Graphical abstract

Poultry breeding takes place in intensive, high-production systems characterized by high animal density, which is a source of harmful emission of odorous volatile organic compounds (VOCs), ammonia (NH3), hydrogen sulfide (H2S) and greenhouse gases, which in turn sustain animal welfare. This study identified and examined the characteristics of chemical compounds emitted in intensive poultry farming (laying hens, broilers) and their toxicity, which led to recommending methods of deodorization. Emphasis was placed on the law relative to air purification in poultry farms. Various methods of air treatment in poultry farms have been described: the modification of animal diet to improve nutrient retention and decrease the amount of their excrement; chemical oxidation technologies (ozonation, photocatalysis, Fenton reaction); various types/brands of biofilters, bioscrubbers and membrane reactors. Numerous studies show that biofilters can reduce ammonia emissions by 51%, hydrogen sulfide by 80%, odors by 67%, while scrubbers brings down ammonia emissions by 77% and odors by 42%, and the application of UV light lowers ammonia emissions by 28%, hydrogen sulfide by 55%, odors by 69% and VOCs by 52%. The paper presents both the solutions currently used in poultry farming and those which are currently in the research and development phase and, as innovative solutions, could be implemented in the near future.

In recent times, the issue of plastic recycling has become one of the leading issues of environmental protection and waste management. Polymer materials have been found an application in many areas of daily life and industry. Along with their extended use, the problem of plastic wastes appeared because, after withdrawal from use, they became persistent and noxious wastes. The possibility of reusing polymeric materials gives a possibility of valorization—a second life—and enables effective waste utilization to obtain consumable products. The 3D printing market is a well-growing sector. Printable filaments can be made from a variety of thermoplastic materials, including those from recycling. This paper focuses on a review of the available literature on the production of filaments for 3D printers from recycled polymers as the alternative to present approach of central selective collection of plastics. The possibility of recycling of basic thermoplastic materials and the impact of processing on their physicochemical and mechanical properties were verified (Lanzotti et al. 2019). In addition, commercially available filaments produced from recycled materials and devices which allow self-production of filaments to 3D printing from plastic waste were reviewed.

In the present work new universal bench-scale plant for biosorption, useful in production of new micronutrient biocomponents, was described. The new installation enabling working in a fixed bed or stirred tank batch mode. Reactors may also be used in serial or parallel mode, which gives many application possibilities. Copper ions were selected as a sorbate for kinetic modelling. The results of the adsorption capacities of Cu(II) were 13.9 mg/g for fixed bed and 12.8 mg/g for stirred tank. During biosorption of Cu(II) ions from aqueous solution ion exchange and release of Ca(II), K(I), Mg(II), and Na(I) were observed. For kinetics description of stirred tank process pseudo-1st-and pseudo-2nd order models were used. For fixed bed process the Thomas, Yoon-Nelson, Adams-Bohart and Wolborska models were used. The use of blackcurrant seed residues as biosorbents enables the generation of new products from waste biomass, which can become an alternative to the traditional fertilizers with microelements. The presented technology is an attempt to reduce environmental impact of the conventional micronutrient fertilizers, which contain toxic chelators such as EDTA. Minimization of waste and maximization of product output makes it an efficient tool supporting cleaner production.

The potential of biosorption as a process of ions binding from solutions has not yet been fully exploited. So far, the works have focused predominantly on removing ions (heavy metals or dyes) from the solutions, mainly on a laboratory scale. The surface of biomass is rich in functional groups that can bind various ions, including microelements. Biomass enriched in this way can be a carrier of important nutrients for plants and animals. The paper aims to verify the possibility of using plant biomass—post-extraction residues as carriers of microelements for fertilization and nutritional purposes. A literature analysis was carried out concerning the application of biosorption for biomass valorization; in particular, the degree of biomass enrichment and the bioavailability of microelement preparations obtained were examined. Valorization of post-extraction residues is a part of the circular economy concept; it minimizes waste generation and enables the recovery of materials for other purposes. This application of biosorption is a new trend that has the potential to be used in the production of new fertilizers and supplements for precision agriculture.

This work is a systematic review that reports state-of-the-art in removal of pharmaceuticals from water and wastewater by photosynthetic organisms in photobioreactors. The PRISMA protocol-based review of the most recent literature data from the last 10 years (2011–2021) was reported. Articles were searched by the combination of the following keywords: photobioreactor, pharmaceuticals, drugs, hormones, antibiotics, biodegradation, removal, wastewater treatment. The review focuses on original research papers (not reviews), collected in 3 scientific databases: Scopus, Web of Knowledge, PubMed. The review considered the following factors: type of microorganisms, type of micropollutants removed, degradation efficiency and associated products, types of photosynthetic organisms and photobioreactor types. The conclusion from the systematic review is that the main factors that limit widespread pharmaceuticals removal in photobioreactors are high costs and the problem of low efficiency related with low concentrations of pharmaceuticals. The review indicated a need for further research in this area due to increasing amounts of metabolites in the food chain, such as p-aminophenol and estrone, which can cause harm to people and ichthyofauna. Pharmaceuticals removal can be improved by adapting the type of microorganism used to the type of contamination and implementing photoperiods, which increase the removal efficiency of e.g. sulfamethazine by up to 28%. In the future, it is necessary to search for new solutions in terms of the construction of photobioreactors, as well as for more effective species in terms of pharmaceuticals biodegradation that can survive the competition with other strains during water and wastewater treatment.

A technological solution was developed to process slaughter waste and farm manure and transform them into organic and mineral fertilizers. It has been shown that the formation of an enclosure on a goose farm from nitrogen-binding substances (brown coal, a mixture of brown coal with magnesite, used ash substrate) has a positive effect on reducing nitrogen emissions, even to about 80%. The presented solution is in line with ecological trends and ensures comprehensive management of agri-food waste. It reduces the loss of valuable nutrients from renewable sources, increases the efficiency of fertilizers and reduces the environmental nuisance of poultry farms. Organic-mineral fertilizers made from slaughterhouse waste and poultry manure were as effective as expensive commercial mineral fertilizers. New fertilizers helped to obtain a yield similar to the groups fertilized with mineral fertilizers: 11 t per ha for maize (grain), 0.8 t per ha for mustard (seed), 10 kg per 1 m

In the current situation of a serious raw material crisis related to the disruption of supply chains, the bioeconomy is of particular significance. Rising prices and the problem with the availability of natural gas have made N fertilizers production very expensive. It is expected that due to natural gas shortages, conventional production of nitrogen fertilizers by chemical synthesis will be hindered in the coming season. An important alternative and an opportunity to solve the problems of fertilizer nitrogen availability are biological wastewater treatment plants, which can be treated as a renewable biological nitrogen mines. Sewage sludge (including activated sludge) contains up to 6-8% DM. N. Considering the quantity of sewage sludge generated in wastewater treatment plants, it can become an important raw material for the sustainable production of organic-mineral fertilizers from renewable resources available locally, with a low carbon footprint. Furthermore, the sewage sludge management method should take nitrogen retention into account and should not allow the emission of greenhouse gases containing nitrogen. This article analyzes the technological solutions of nitrogen recovery for fertilization purposes from biological wastewater treatment plants in the context of a new and difficult resource situation. Conventional and new nitrogen recovery methods were analyzed from the perspective of the current legal situation. An attempt was made to evaluate the possibility of implementing the assumptions of the circular economy through the recovery of renewable nitrogen resources from municipal wastewater treatment plants.

This work proposes a method to valorize lead slag for fertilizer purposes. The research concept was to selectively recover valuable microelements (Cu(II), Fe(II), Zn(II) in an amount of at least 0.2% m/v of each) by chemical leaching while retaining toxic elements in the slag (i.e. As and Pb). Among acids, hydroxides, salts and their mixtures tested for slag treatment, it was potassium hydrogen sulfate and ammonia liquor under strongly oxidizing conditions (in the presence of hydrogen peroxide) that proved to be the most effective leaching agents. Response Surface Methodology applied to optimize the slag leaching conditions set the most favorable process parameters (concentration of leaching agents, slag to reagent weight ratio, and temperature). As a result, the concentration of Cu(II) in the extract was 3751 mg/L (for ammonia liquor) and Fe(II) and Zn(II) concentrations in potassium hydrogen sulfate were 4738 mg/L and 6102 mg/L, respectively. To close the life cycle of the waste, immobilization in polyethylene and binding to cement were indicated as methods to manage the solid waste material after leaching. The mixed extracts rich in Cu(II), Fe(II) and Zn(II) ions were tested in germination tests on cucumber. No phytotoxic effect was observed, which raises the possibility of utilizing the solutions after chemical leaching of slag as an alternative source of micronutrients for the production of multicomponent fertilizers. The results are promising and fit in the assumptions of circular economy.

Seed coating containing fertilizer nutrients and plant growth biostimulants is an innovative technique for precision agriculture. Nutrient delivery can also be conducted through multilayer seed coating. For this purpose, sodium alginate with NPK, which was selected in a preliminary selection study, crosslinked with divalent ions (Cu(II), Mn(II), Zn(II)) as a source of fertilizer micronutrients, was used to produce seed coating. The seeds were additionally coated with a solution containing amino acids derived from high-protein material. Amino acids can be obtained by alkaline hydrolysis of mealworm larvae (Gly 71.2 ± 0.6 mM, Glu 55.8 ± 1.3 mM, Pro 48.8 ± 1.5 mM, Ser 31.4 ± 1.5 mM). The formulations were applied in different doses per 100 g of seeds: 35 mL, 70 mL, 105 mL, and 140 mL. SEM-EDX surface analysis showed that 70 mL of formulation/100 g of seeds formed a continuity of coatings but did not result in a uniform distribution of components on the surface. Extraction tests proved simultaneous low leaching of nutrients into water (max. 10%), showing a slow release pattern. There occurred high bioavailability of fertilizer nutrients (even up to 100%). Pot tests on cucumbers (Cornichon de Paris) confirmed the new method’s effectiveness, yielding a 50% higher fresh sprout weight and four times greater root length than uncoated seeds. Seed coating with hydrogel has a high potential for commercial application, stimulating the early growth of plants and thus leading to higher crop yields.

The studies presented in this work show that solid tannery waste-like shavings can be used as high-protein materials for fertilizer production following the concept of the circular economy. To select appropriate process parameters (mass ratio of shavings meal to the hydrolyzing agent (S:L), hydrolysis medium concentration, temperature) and to ensure the highest possible hydrolysis efficiency, it is useful to apply the well-known response surface methodology (RSM). The analyses revealed that chromium shavings (SCr) were most preferably treated with 10% KOH in a ratio of S:L 1:1 with the process being carried out at 160 °C (6.59% N). The optimal hydrolysis conditions for non-chromium (S) shavings were: S:L ratio 1:2, 10% H

According to the circular economy concept, the production of fertilizers should be closed in a loop, which prevents excessive emissions and harmful effects to the environment. Biological wastes are problematic to collect and transport. They undergo a biological transformation that causes greenhouse gases emission and sanitary hazards. Biomass sources used for organic or organo-mineral fertilizers must be free of pathogens and rich in macro and microelements. Solid residues can be processed thermally. Biochar is a carbon produced by biomass pyrolysis without oxygen presence and has been used for many years to improve soil quality and enhance the efficiency of fertilization. There are many research works on the use of biochar in fertilization. This study is also extended by the latest developments and technologies from the patent database (recent year) and biochar-based fertilizers market. To the best of our knowledge, there is no such review currently available in scientific databases. Based on the collected data, the best method of biochar management was proposed - soil application. Biochar applied to soil has several advantages: it improves soil structure and its sorption capacity, enhances soil-nutrient retention and water-holding capacity, immobilizes contaminants from soil (sorption), reduces greenhouse gas emissions and soil nutrient leaching losses while stimulating the growth of a plant.

The leather tannery industry generates about 33 Mt/year of solid waste with different properties, turning its management into a challenge. One of the valorization methods of tannery wastes is the production of biochar by pyrolysis of leather scratches. Biochar's sorption properties and its high nitrogen content (10%) make it suitable for its application as a soil conditioner or carrier of microelements for fertilizers. The paper presents an innovative spray method to enrich biochar with cationic micronutrients: Cu, Mn, Zn. Enriched biochar contained 1095 mg/kg Cu(II), 1334 mg/kg Mn(II) and 1205 mg/kg Zn(II). The high bioavailability of nutrients and the effectiveness of the new fertilizer were demonstrated in extraction in vitro tests - the analysis of leachability of elements to water and bioavailability of micro-nutrients. The functional properties of enriched biochar were examined in vivo (germination, pot) tests. A high biomass increase (approximately 10%) was observed compared to the group fertilized with a commercial product. The proposed solution benefits the environment in that it is made from alternative resources from which innovative fertilizers are produced according to the circular economy concept.

The aim of the research work was to present a multilayer hydrogel capsule with controlled nutrient release properties as an innovative fertilizer designed for sustainable agriculture. Preparation of the capsules included the following steps: sorption of micronutrients (Cu, Mn, Zn) on eggshells (1) and their immobilization in sodium alginate, with the crosslinking agent being the NPK solution (2). The capsules were coated with an additional layer of a mixture of biopolymers (0.79% alginate, 0.24% carboxymethylcellulose and 8.07% starch)by means of dipping and spraying techniques. The biocomposites were characterized by limited (10% within 100 h for the structures encapsulated by the dipping method) release of fertilizer ions (except for small K

In circular economy an effective strategy with regard to material valorization for fertilizers is expected to substantially improve sustainability, save resources and offer significant environmental, social and economic benefits. Wastes – especially biomass – are a large reservoir of materials which can be recovered via different technologies and used for manufacturing various fertilizers. Increasing re-use of nutrients from waste biomass is very difficult and requires taking additional steps to effectively use the potential of waste. It is necessary to introduce selective waste collection, increase the efficiency of nutrient recovery, obtain a more concentrated form with good bioavailability. Biomass waste streams carry huge potential, the content of fertilizer components is estimated at approx. 22 million Mg/year for nitrogen and 1.3 million Mg/year for phosphorus. Waste streams with the highest potential are waste from the food chain, manure and sewage, which are further processed and can be used for the production of fertilizers. Further research and experiments should be done to develop technologies that will enable exploitation of materials of high added value from biomass. Careful consideration should be given to energy routes. There is an urgent need for new technologies with which stable market dynamics via new business models could be safeguarded.

1. Praca finansowana ze środkow projektu "Rośliny uprawne oraz produkty naturalne jako źrodla substancji biologicznie aktywnych przeznaczonych do produkcji preparatow kosmetycznych, farmaceutycznych i suplementow diety" (nr BIOSTRATEG2/298205/9/NCBR/2016) przyznanego przez Narodowe Centrum Badan i Rozwoju.

The aim of this study was to examine and quantitatively describe how the coupling phenomenon affects the pervaporation. In the first stage binary water-alcohol (ethanol; isopentanol) and water-ester (methyl butyrate; butyl acetate) mixtures were examined. In the second stage three different ternary water-ester-alcohol solutions have been separated with the use of commercially available PDMS (polydimethyl siloxane) membrane and the effect of separation was expressed with the semi-empirical Arrhenius-like equation and strictly empirical Response Surface Methodology (RSM). Modelling results show that the coupling phenomenon is very case-specific, and the addition of another species to the separated solution could have both a negative and positive impact on the productivity and separation efficiency, depending on the characteristic of penetrant-penetrant and membrane-penetrant interactions. The relationship between process parameters and coupling effects strongly affects pervaporation performance, and yields dissimilar results for various concentrations of feed components in multicomponent systems.

The tremendous amount of waste is an environmental and social problem worldwide. The agri-food sector is the largest producer of waste and requires the extensive use of fertilizers, which entails the need to look for innovative solutions in waste management. Properly recycled bio-waste can be reused as fertilizer. Polymer capsules with immobilized waste biomass can be applied as carriers for fertilizer nutrients. The amount of components exerts a certain influence on the effectiveness of copper ions binding. The most important physicochemical properties of biocomposites, such as swelling, SEM (Scanning Electron Microscopy) and FTIR (Fourier Transform Infrared Spectroscopy) were investigated. FTIR analyzes revealed that carboxyl and hydroxyl groups play a key role in Cu2+ ion binding. Morphology analysis showed that ion binding leads to homogenization of the composite surface, while coating the structure makes it more regular and cohesive. The sorption kinetics and the determination of the process's equilibrium parameters (Qmax = 29.4 ± 0.493 mg g−1) play an important role. The study of Cu2+ ion release in different media showed that the chitosan layer slowed down the diffusion of cations by about 50% in NaNO3 (1% m/m) solution. Preliminary studies of the applicability of the capsules in germination tests demonstrate that the biocomposites have no phytotoxic effects on the test plant. The chitosan coating slows the release of Cu2+ ions by about 20% compared to uncoated capsules. New fertilizer formulations containing chitosan-encapsulated hydrogel with biomass-immobilized micronutrients can be applied for precision agriculture to minimize the loss of fertilizer nutrients to the environment. These fertilizers could be used to cultivate houseplants and greenhouse crops.

The increase in livestock production creates a serious problem of managing animal waste and by-products. Among the wide range of waste valorization methods available, anaerobic digestion is very promising. It is a form of material recycling that also produces renewable energy in the form of biogas, which is reminiscent of energy recycling. The effluent and digestate from the anaerobic digestion process need to be processed further. These materials are widely used in agriculture due to their composition. Both the liquid and solid fractions of digestate are high in nitrogen, making them a valuable source for plants. Before soil or foliar application, conditioning (e.g., with inorganic acids) and neutralization (e.g., with potassium hydroxide) is required to eliminate odorous compounds and microorganisms. Various methods of conducting the process by anaerobic digestion (use of additives increasing activity of microorganisms, co-digestion, multiple techniques of substrate preparation) and the possibility of controlling process parameters such as optimal C/N ratio (15-30), optimal temperature (psychrophilic (20 °C), mesophilic (35-37 °C) and thermophilic (55 °C) for microorganism activity ensure high efficiency of the process. Literature data describing tests of various digestates on different plants prove high efficiency, determined by yield increase (even by 28%), nitrogen uptake (by 20%) or phosphorus recovery rate (by 43%) or increase of biometric parameters (e.g., leaf area).

This paper presents the latest overview of the environmental impact of wastes from the non-ferrous metallurgical industry. Ashes, slags and dusts - by-products from mining and metal processing - are sources of toxic metals, such as Pb, Cd, Hg, As, Al, as well as particulate matter. Physical, chemical and biological processes transform industrial wastes and cause water, soil and air pollution. Improperly protected heaps are subject to wind erosion and rain water leaching. Heavy metals and particulate matter are transported over long distances, contaminating the soil, living areas, watercourses, while in combination with mist they create smog. Water erosion releases heavy metals, which are leached into groundwater or surface runoff. This paper focuses on the range of pollution emissions from non-ferrous metallurgy wastes, hazards, mechanisms of their formation and fallouts, on the current state of technology and technological risk reduction solutions. The impact of pollution on human health and the biosphere, and methods of waste reduction in this industry sector are also presented. A sustainable and modern mining industry is the first step to cleaner production.

Sustainable development in agriculture brings both environmental and economic benefits. Contemporary agriculture is also about increasing nutrient use efficiency, especially nitrogen, as the critical nutrient causing the most significant environmental pressure. This creates the need to produce highly digestible protein feed with high bioavailability, reducing losses of biogenic elements to feces. In this review, the latest trends and the potential for their implementation in sustainable agriculture have been compared, as well as the need to reduce the negative environmental impact of agriculture has been demonstrated. Applying local protein sources to feed animals reduces greenhouse gas emissions associated with transportation. The production of highly digestible fodder leads to a reduction in environmental pollution caused by excessive nitrogen outflows. Another approach indecreasing ammonia emissions from livestock farming is feed protein reduction and amino acid supplementation. All of the aforementioned approaches may result in beneficial long-term changes, contributing to environmental safety, animal welfare and human health.

Graphical abstract, Highlights • Plant extracts are a source of phytochemicals useful in the treatment of coronavirus diseases. • The advantage of using natural plant extracts is their effectiveness and high safety for patients. • Water and ethanol plant extracts contain biologically active substances with antiviral activity. • Phytochemicals are natural inhibitors of viral enzymes., The outbreak of Covid-19 disease caused by SARS-CoV-19, along with the lack of targeted medicaments and vaccines, forced the scientific world to search for new antiviral formulations. In this review, we describe the current knowledge about plant extracts containing polyphenols that inhibit Covid-19. Many plant-derived natural compounds (polyphenols) might provide a starting point for the research on the use of plant extracts in coronavirus treatment and prevention. Antivirus polyphenolic drugs can inhibit coronavirus enzymes, which are essential for virus replication and infection. This group of natural substances (betulinic acid, indigo, aloeemodine, luteolin, and quinomethyl triterpenoids, quercitin or gallates) is a potential key to designing antiviral therapies for inhibiting viral proteases. The known pharmacophore structures of bioactive substances can be useful in the elaboration of new anti-Covid-19 formulations. The benefit of using preparations containing phytochemicals is their high safety for patients and no side effects.

The aim of this work was to prepare an innovative microelemental feed additive for laying hens, based on waste biomass from the agricultural sector (alfalfa and goldenrod after CO2 extraction in supercritical state). The process was optimized by Response Surface Methodology (RSM) and the most favourable enrichment conditions were selected for Cu(II), Mn(II) and Zn(II) ions: pH - 5, sorbate concentration of Cu(II), Mn(II), Zn(II) - 10.0 mg/L for alfalfa and 10.7 mg/L for goldenrod and biomass dose – 0.1 g/L. Physicochemical properties of biomass were studied and functional groups involved in the binding of Cu(II), Mn(II), Zn(II) ions were determined (mainly carboxylic and hydroxylic groups). An interesting and unique element of this work is the verification of the properties of prepared feed additives in conditions simulating the digestive tract of animals. The release of components in solutions simulating conditions in the intestine and stomach (pH 11 and pH 1) was tested (in vitro tests). The best desorption results were achieved at a strongly acidic pH which corresponds to the stomach environment: 9.80, 14.4% Cu(II), 69.0, 66.9% (Zn), 46.5, 31.9 Mn(II) for alfalfa and goldenrod, respectively. It was concluded that the biomass enriched with micronutrients in biosorption has the potential as a feed additive for sustainable agriculture.

The aim of this study was to develop a method for removing phosphate from an aqueous solution using iron (III) chloride-modified eggshells. The physicochemical properties of the modified biomass (FTIR, pHPZC) were examined. The sorption capacity of the modified sorbents was tested. The kinetic rate constant was determined using the general model and equals 1.82 10−10 min−1. The maximum sorption capacity of modified eggshells was determined using the Langmuir model (Qmax = 42.3 mg g−1). Kinetic experiments were also carried out in a fixed-bed column. To establish the adsorption parameters in the bed column, the Thomas, Yoon-Nelson, and MDR models were used to describe the experimental data. The maximum sorption capacity in the column was 58.4 mg g−1. Based on the result, modified eggshells could be used in the future as an effective sorbent for removing phosphate ions from aqueous solutions.

Slaughterhouse waste and dead animals are mainly disposed of by incineration, which generates greenhouse gases and NOx. These wastes are a source of nutrients that can be recovered by circular economy techniques if material recycling is given a priority over energy recovery. To valorize high-protein animal waste (containing bones, meat, feather) for fertilizer purposes, the waste was processed by acid solubilization and neutralized with potassium hydroxide solution, which yielded a liquid fertilizer with plant growth biostimulating properties (due to the amino acids presence). The composition analysis showed that new fertilizers met all quality requirements set by the law, contain ~0.5% m/m amino acids and are microbiologically pure. The fertilizer was enriched with microelements to the level of 0.2% m/m and tested for biological effectiveness in germination tests and field studies. Compared with the commercial formulation, the fertilizer increased stem length and chlorophyll content (by 8.2% and 27.0%, respectively), wheat crop yield and grain micronutrients density (Cu by 31.2%, Mn by 10.5%, Zn by 33.9%) and improved the wheat flour baking properties. The described solution propose a safe way to utilize hazardous waste via technological mobile installation, enabling no transportation of waste, which is an important aspect of sanitary-epidemiological risk minimization.