1. From sequential chemoenzymatic synthesis to integrated hybrid catalysis: taking the best of both worlds to open up the scope of possibilities for a sustainable future
- Author
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Robert Wojcieszak, Damien Delcroix, Alexandra Gimbernat, Nicolas Lopes Ferreira, Franck Dumeignil, Pascal Dhulster, Jean-Sébastien Girardon, Renato Froidevaux, Marie Guehl, Mickaël Capron, Unité de Catalyse et de Chimie du Solide - UMR 8181 (UCCS), Université d'Artois (UA)-Ecole Centrale de Lille-Ecole Nationale Supérieure de Chimie de Lille (ENSCL)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), IFP Energies nouvelles (IFPEN), Institut Charles Viollette (ICV) - EA 7394 (ICV), Université du Littoral Côte d'Opale (ULCO)-Université de Lille-Institut National de la Recherche Agronomique (INRA)-Université d'Artois (UA)-Institut Supérieur d'Agriculture, ANR-11-EQPX-0037/11-EQPX-0037,REALCAT,Plateforme intégREe AppLiquée au criblage haut débit de CATalyseurs pour les bioraffineries(2011), ENSCL, Université de Lille, CNRS, INRA, ISA, Centrale Lille, Univ. Artois, Univ. Littoral Côte d’Opale, Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS], IFP Energies nouvelles [IFPEN], Institut Charles Viollette (ICV) - EA 7394 [ICV], Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, Chevreul Institute [FR 2638], Ministere de l'Enseignement Superieur, de la Recherche, et de l'Innovation, REALCAT platform ('Future Investments' program (PIA)) [ANR-11-EQPX-0037], FEDER, Region Hauts-de-France (CPER ALIBIOTECH), ANR-11-EQPX-0037,REALCAT,Plateforme intégREe AppLiquée au criblage haut débit de CATalyseurs pour les bioraffineries(2011), Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), and Université d'Artois (UA)-Institut National de la Recherche Agronomique (INRA)-Université du Littoral Côte d'Opale (ULCO)-Institut Supérieur d'Agriculture-Université de Lille
- Subjects
soluble iridium complex ,One-pot synthesis ,010402 general chemistry ,01 natural sciences ,Catalysis ,12. Responsible consumption ,dynamic kinetic resolution ,improved hydrothermal stability ,one-pot synthesis ,Disruptive innovation ,solaccatalysts ,Aqueous medium ,Scope (project management) ,biological catalysis ,010405 organic chemistry ,hydrogen-peroxide ,Scale (chemistry) ,in-situ regeneration ,[CHIM.CATA]Chemical Sciences/Catalysis ,Work in process ,Highly selective ,0104 chemical sciences ,enzymatic reduction ,aqueous-media ,Biochemical engineering - Abstract
International audience; Enzymatically catalyzed reactions are highly efficient but higher scale extrapolation is limited to a certain class of stable and easily recyclable enzymes. Homogeneously and/or heterogeneously catalyzed reactions are often limited by the multiphasic nature of catalytic systems and/or variations in the distribution of active sites. For these reasons, the development of highly selective and efficient hybrid catalysts is especially needed, and it is now well admitted that disruptive innovation is highly desirable in process engineering, (bio)catalyst design and materials science. Optimal integration of all types of catalysis is the key for efficient global implementation of sustainable processes. This review gives an overview of all the pathways that integrate chemical and biological catalysis, beginning with combined chemoenzymatic processes in cascade to progressively open the field of hybrid catalysis in a one-pot concomitant execution. We have emphasized the factors that have to be considered to understand the catalytic synergy between these systems. A better understanding of hybrid catalytic systems is an essential tool not only in the choice of the best route of their implementation but also in the synthesis of a wide range of fine chemicals in many fields, with a particular emphasis on their production from renewables.
- Published
- 2018