1. Raman scattering and photophysics in spin-state-labile d6 metal complexes
- Author
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John J. McGarvey, Wesley R. Browne, and Synthetic Organic Chemistry
- Subjects
Spin states ,spin-crossover complexes ,Intercalation (chemistry) ,resonance Raman scattering ,Photochemistry ,Artificial photosynthesis ,Inorganic Chemistry ,Metal ,symbols.namesake ,Spin crossover ,Materials Chemistry ,3MLCT EXCITED-STATES ,DNA-intercalating metal complexes ,Physical and Theoretical Chemistry ,CROSSOVER COORDINATION POLYMERS ,Spectroscopy ,DIPYRIDOPHENAZINE COMPLEXES ,light-switch effect ,Chemistry ,LIGHT-SWITCH MECHANISM ,ARTIFICIAL PHOTOSYNTHESIS ,RESOLVED RESONANCE RAMAN ,ROOM-TEMPERATURE ,d(6) transition metal ions ,visual_art ,visual_art.visual_art_medium ,symbols ,VIBRATIONAL CONTRIBUTIONS ,Raman spectroscopy ,Raman scattering ,COUPLED ELECTRON-TRANSFER ,ENTROPY CHANGE - Abstract
In this review two areas of d(6) transition metal ion chemistry and photophysics are briefly reviewed (i) that of Ru(II)dipyridophenazine (dppz) complexes as DNA intercalators and (ii) spin crossover behavior in Fe(II) complexes. In both areas the role of Raman spectroscopy in providing information concerning the spectroscopy and photophysics of the electronic states involved and the interactions between states of differing spin multiplicity is discussed. (c) 2006 Elsevier B.V. All rights reserved.
- Published
- 2006
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