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Raman scattering and photophysics in spin-state-labile d6 metal complexes
- Source :
- Coordination Chemistry Reviews, 250(13-14), 1696-1709. Elsevier Science
- Publication Year :
- 2006
- Publisher :
- Elsevier BV, 2006.
-
Abstract
- In this review two areas of d(6) transition metal ion chemistry and photophysics are briefly reviewed (i) that of Ru(II)dipyridophenazine (dppz) complexes as DNA intercalators and (ii) spin crossover behavior in Fe(II) complexes. In both areas the role of Raman spectroscopy in providing information concerning the spectroscopy and photophysics of the electronic states involved and the interactions between states of differing spin multiplicity is discussed. (c) 2006 Elsevier B.V. All rights reserved.
- Subjects :
- Spin states
spin-crossover complexes
Intercalation (chemistry)
resonance Raman scattering
Photochemistry
Artificial photosynthesis
Inorganic Chemistry
Metal
symbols.namesake
Spin crossover
Materials Chemistry
3MLCT EXCITED-STATES
DNA-intercalating metal complexes
Physical and Theoretical Chemistry
CROSSOVER COORDINATION POLYMERS
Spectroscopy
DIPYRIDOPHENAZINE COMPLEXES
light-switch effect
Chemistry
LIGHT-SWITCH MECHANISM
ARTIFICIAL PHOTOSYNTHESIS
RESOLVED RESONANCE RAMAN
ROOM-TEMPERATURE
d(6) transition metal ions
visual_art
visual_art.visual_art_medium
symbols
VIBRATIONAL CONTRIBUTIONS
Raman spectroscopy
Raman scattering
COUPLED ELECTRON-TRANSFER
ENTROPY CHANGE
Subjects
Details
- ISSN :
- 00108545
- Volume :
- 250
- Database :
- OpenAIRE
- Journal :
- Coordination Chemistry Reviews
- Accession number :
- edsair.doi.dedup.....1b1bf7444626a0ce8348e20407c06161
- Full Text :
- https://doi.org/10.1016/j.ccr.2006.01.009