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This study presents the detailed characterization of a magnetron-based Ar–N2 plasma discharge used to sputter a liquid Ga target for the deposition of gallium nitride (GaN) thin films. By utilizing in situ diagnostic techniques including optical emission spectroscopy and microwave interferometry, we determine different temperatures (rotational and vibrational of N2 molecules, and electronic excitation of Ar atoms) and electron density, respectively. Beyond providing insights into fundamental plasma physics, our research establishes a significant correlation between gas-phase dynamics, particularly those of gallium atoms (flux and average energy at the substrate) and deposited GaN thin film properties (growth rate and crystalline fraction). These findings underscore the role of plasma conditions in enhancing thin film quality, highlighting the importance of plasma characterization in understanding and optimizing GaN thin film growth processes. [ABSTRACT FROM AUTHOR]

Grafting nanomaterials on the carbon fiber (CF) surface is considered an effective strategy for enhancing the interfacial properties of CF-reinforced polymer composites (CFRPs). However, the mechanical properties of the CFs are often compromised during treatment. A new method for in situ growing silver nanoparticles (AgNPs) on the CF surface is proposed in this study. The CFs are first immersed in a low-viscosity silver nitrate solution to form a thin liquid film on the surface. Subsequently, using the abundant active particles in the plasma, the silver ions are reduced to silver atoms and grown into AgNPs on the CF surface. The tensile strength of CF@Ag was 38.74% greater than that of untreated CF, potentially due to the reparative action of AgNPs on defects in CF. The CF showed an evident improvement in surface wettability because of the AgNPs. Furthermore, the interfacial properties were noticeably improved, with the interfacial shear strength of CF@Ag increasing to 91.59 MPa, which was about twice that of pristine CF. Thus, the mechanical properties of composites are significantly improved (flexural strength increased by 190.74%). This study presents a non-destructive and convenient method for growing nanoparticles onto CF to establish a robust interface in CFRPs. [ABSTRACT FROM AUTHOR]

Crystal surfaces play a pivotal role in governing various significant processes, such as adsorption, nucleation, wetting, friction, and wear. A fundamental property that influences these processes is the surface free energy, γ. We have directly calculated γ(T) for low-index faces of Lennard-Jones (LJ), germanium, and silicon crystals along their sublimation lines using the computational cleavage technique. Our calculations agree well with experimental values for Si(111) and Ge(111), highlighting the accuracy of the method and models used. For LJ crystals, we identified a premelting onset at Tpm = 0.75Tm, marked by a sharp increase in atom mobility within the second outermost surface layer. Notably, Tpm closely aligned with the endpoint of the LJ melting line at negative pressures, Tend = 0.76Tm. We hypothesize that the emergence and coexistence of a liquid film atop the LJ crystal at Tpm < T < Tm correspond to the metastable melting line under negative pressures experienced by stretched crystal surfaces. Furthermore, our study of thin LJ crystal slabs reveals that premelting-induced failure leads to recrystallization below the homogeneous freezing limit, offering a promising avenue to explore crystal nucleation and growth at extremely deep supercoolings. Finally, no evidence of premelting was detected in the model crystals of Ge and Si, which is consistent with the experimental observations. Overall, our findings offer valuable insights into crystal surface phenomena at the atomic scale. [ABSTRACT FROM AUTHOR]

Accurate prediction of the entrained liquid droplet fraction in an annular two-phase flow regime plays a crucial role for estimating the dryout type critical heat flux to identify the optimized flow characteristics in the thermal systems across different industries. Existing studies have provided different correlations based on the limited experimental data. However, these correlations are applicable to certain operating conditions. Therefore, the present study aims at applying a deep learning method, specifically an artificial neural network (ANN), to enhance the prediction of the entrained liquid droplet fraction. Experimental data from various works on annular flow, covering a wide spectrum of pressure and flow conditions, are utilized for training the ANN model. Eight input variables, viz, superficial gas velocity (J S G ), superficial liquid velocity (J S L ), gas viscosity (μ G), liquid viscosity (μ L), gas density (ρ G), liquid density (ρ L), pipe diameter (d) and liquid surface tension (σ L V ) are considered as input features. The entrained liquid droplet fraction is the single output feature. The present model employs the Bayesian regularization backpropagation algorithm for training. The present ANN model is compared against the performance of linear regression, decision tree and support vector machine algorithms, and found that the performance of the present Bayesian regularization neural network (BRNN) model is superior within ∼ 7.5 % deviation. Further, the BRNN model is coupled with the film mass flow rate model to obtain the axial variation of the liquid film mass flow rate and good agreement is noticed when compared against the experimental data. [ABSTRACT FROM AUTHOR]

Many applications involving plasma–liquid interactions depend on the reactive processes occurring at the plasma–liquid interface. We report on a falling liquid film plasma reactor allowing for in situ optical absorption measurements of the time-dependence of the ferricyanide/ferrocyanide redox reactivity, complemented with ex situ measurement of the decomposition of formate. We found excellent agreement between the measured decomposition percentages and the diffusion-limited decomposition of formate by interfacial plasma-enabled reactions, except at high pH in thin liquid films, indicating the involvement of previously unexplored plasma-induced liquid phase chemistry enabled by long-lived reactive species. We also determined that high pH facilitates a reduction-favoring environment in ferricyanide/ferrocyanide redox solutions. In situ conversion measurements of a 1:1 ferricyanide/ferrocyanide redox mixture exceed the measured ex situ conversion and show that conversion of a 1:1 ferricyanide/ferrocyanide mixture is strongly dependent on film thickness. We identified three dominant processes: reduction faster than ms time scales for film thicknesses >100 µm, •OH-driven oxidation on time scales of <10 ms, and reduction on 15 ms time scales for film thickness <100 µm. We attribute the slow reduction and larger formate decomposition at high pH to HO 2 − formed from plasma-produced H2O2 enabled by the high pH at the plasma–liquid interface as confirmed experimentally and by computed reaction rates of HO 2 − with ferricyanide. Overall, this work demonstrates the utility of liquid film reactors in enabling the discovery of new plasma-interfacial chemistry and the utility of atmospheric plasmas for electrodeless electrochemistry. [ABSTRACT FROM AUTHOR]

Moving contact line dynamics calculations include two models: precursor film models and slip models. The lubrication approximation method is used to establish a three-dimensional mathematical model to analyze the droplet thermocapillary migration behavior on a non-uniformly heated solid substrate with a wettability track. The contact line dynamics in the slip model and the disjoining pressure effect in the precursor model are proposed to regulate the substrate wettability. Both models are numerically implemented to investigate droplet spreading for three cases: free spreading on an isothermal substrate, thermocapillary migration on a uniform wettability substrate, and thermocapillary migration on a wettability-confined track. For the case of free spreading on an isothermal substrate, the three-dimensional results of the slip and precursor contact line models are essentially consistent with two-dimensional slip model results. For the case of thermocapillary migration on a uniform wettability substrate, the results of the two models essentially agree with the experimental results. Decreasing the thermal gradient reduces the discrepancies between the two models that result from the coordinate transformation method used in the slip model, which reduces the contact angles measured in the y-direction and enlarges the advancing contact angle in the migration direction. For the case of thermocapillary migration on a wettability-confined track, the slip model gradually shows a "dynamic-pinning" behavior with increasing equilibrium contact angle in the hydrophobic region. By contrast, the precursor film model maintains a stationary pinning behavior but separates a residual liquid outside the track. The precursor film model is preferred over the slip model in lubrication approximations for three-dimensional fluids when calculating complex moving contact dynamics caused by wettability differences. However, the precursor film model must be further optimized to prevent numerical instability. [ABSTRACT FROM AUTHOR]

Glass-forming liquids exhibit long-lived, spatially correlated dynamical heterogeneity, in which some nm-scale regions in the fluid relax more slowly than others. In the nanoscale vicinity of an interface, glass-formers also exhibit the emergence of massive interfacial gradients in glass transition temperature Tg and relaxation time τ. Both of these forms of heterogeneity have a major impact on material properties. Nevertheless, their interplay has remained poorly understood. Here, we employ molecular dynamics simulations of polymer thin films in the isoconfigurational ensemble in order to probe how bulk dynamic heterogeneity alters and is altered by the large gradient in dynamics at the surface of a glass-forming liquid. Results indicate that the τ spectrum at the surface is broader than in the bulk despite being shifted to shorter times, and yet it is less spatially correlated. This is distinct from the bulk, where the τ distribution becomes broader and more spatially organized as the mean τ increases. We also find that surface gradients in slow dynamics extend further into the film than those in fast dynamics—a result with implications for how distinct properties are perturbed near an interface. None of these features track locally with changes in the heterogeneity of caging scale, emphasizing the local disconnect between these quantities near interfaces. These results are at odds with conceptions of the surface as reflecting simply a higher "rheological temperature" than the bulk, instead pointing to a complex interplay between bulk dynamic heterogeneity and spatially organized dynamical gradients at interfaces in glass-forming liquids. [ABSTRACT FROM AUTHOR]

We report on viscous adhesion measurements conducted in sphere-plane geometry between a rigid sphere and soft surfaces submerged in silicone oils. Increasing the surface compliance leads to a decrease in the adhesive strength due to elastohydrodynamic deformation of the soft surface during debonding. The force-displacement and fluid film thickness-time data are compared to an elastohydrodynamic model that incorporates the force measuring spring and finds good agreement between the model and data. We calculate the pressure distribution in the fluid and find that, in contrast to debonding from rigid surfaces, the pressure drop is non-monotonic and includes the presence of stagnation points within the fluid film when a soft surface is present. In addition, viscous adhesion in the presence of a soft surface leads to a debonding process that occurs via a peeling front (located at a stagnation point), even in the absence of solid–solid contact. As a result of mass conservation, the elastohydrodynamic deformation of the soft surface during detachment leads to surfaces that come closer as the surfaces are separated. During detachment, there is a region with fluid drainage between the centerpoint and the stagnation point, while there is fluid infusion further out. Understanding and harnessing the coupling between lubrication pressure, elasticity, and surface interactions provides material design strategies for applications such as adhesives, coatings, microsensors, and biomaterials. [ABSTRACT FROM AUTHOR]

This article presents a two‐way coupling approach to simulate bouncing droplet phenomena by incorporating the lubricated thin aerodynamic gap between fluid volumes. At the heart of our framework lies a cut‐cell representation of the thin air film between colliding liquid fluid volumes. The air pressures within the thin film, modeled using a reduced fluid model based on the lubrication theory, are coupled with the volumetric liquid pressures by the gradient across the liquid–air interfaces and solved in a monolithic two‐way coupling system. Our method can accurately solve liquid–liquid interaction with air films without adaptive grid refinements, enabling accurate simulation of many novel surface‐tension‐driven phenomena such as droplet collisions, bouncing droplets, and promenading pairs. [ABSTRACT FROM AUTHOR]

A pintle injector is a convenient method for adjusting propellant combustion and has received extensive attention in recent years. However, few studies have examined the effects of the injection direction and momentum ratio (ratio of liquid oxygen momentum to kerosene momentum) on the flow field, temperature field, and dual-belt liquid film cooling effect in the combustion chamber. This study verified a new computational fluid dynamics (CFD) engine combustion model based on a pintle injector through a hot-test experiment. A simulation was conducted using this model. With different injection directions, when the momentum ratio was increased, the trends in the combustion efficiency and chamber pressure growth were entirely opposite. For the axial kerosene and radial liquid oxygen injection direction of liquid film cooling, when the momentum ratio was 0.73–0.9, the proportion of the first ring belt liquid film flow was selected as 5–10 %, and the second ring belt liquid film flow proportion was selected as 5–7%. When the momentum ratio was less than 0.73, the liquid film flow proportions for both the first and second ring belts were selected as 5 %. When the total liquid film flow proportion was 10 %, the chamber pressure decreased by 0.2–0.3 MPa, and the combustion efficiency decreased by 8–10 %. This numerical study provides guidance for studying the combustion characteristics and cooling performance of pintle-type rocket combustion chambers. • The change in injection direction results in the momentum ratio having a completely opposite effect. • The momentum ratio should not be too high, as it increases the difficulty of thermal protection. • The proportion of the liquid film should be minimized while still meeting thermal protection requirements. [ABSTRACT FROM AUTHOR]

Diatomite-based porous ceramics were prepared by wet grinding and high temperature calcination with diatomite as the main raw material. The structure and properties of the ceramics were characterized by SEM, XRD, and FI-TR detection techniques. The results show that the diatomite-based porous ceramics are mainly quartz crystal phase and contain a large amount of Si-OH. Their pore size distribution is 500∼3500 nm, the specific surface area is 6.14 m2/g, and the porosity is 47.8 %. The static adsorption process of Cu2+ in water by ceramic particles conforms to the quasi-second-order kinetic model, and the adsorption equilibrium is reached after 6 h with the maximum adsorption capacity of 4.5 mg/g. The Thomas model can be applied to represent the dynamic adsorption of Cu2+ in water. In the adsorption of Cu2+, pH exerts a strong influence. In solution, Cu2+ forms a ligand with hydroxyl surface functional groups on the surface of ceramics and pores through electrostatic interaction, and the hydrogen on the hydroxyl group exchanges with Cu2+, so that Cu2+ can be removed. [ABSTRACT FROM AUTHOR]

Lung alveoli are modeled as spherical caps, lined internally by a thin surfactant-laden liquid film, and the periodic wall shear stress exerted along the epithelium during small-amplitude radial oscillations of their wall is computed. A novel set of boundary conditions, applied at the rim, reveals the dominant role of Marangoni stresses. These stresses develop along the air/liquid interface due to spatial gradients of interfacial surfactant concentration and are transported to the wall by the action of viscosity. The effect of a variety of geometric and functional characteristics, including rim interstitial thickness, alveolar opening angle and liquid film thickness and viscosity, is interrogated, and the results are discussed in relation to the onset and evolution of acute and chronic lung diseases, such as asthmatic attacks, pulmonary emphysema and pulmonary fibrosis. [ABSTRACT FROM AUTHOR]

Hypothesis Foaming in diesel fuels is not well understood and leads to operational challenges. To combat deleterious effects of foaming, diesel formulations can include additives called antifoams. Existing antifoams, unfortunately, are inherently ash-generating when combusted, with unknown environmental impacts. They are prohibited in certain countries, so identifying effective alternative ash-free antifoam chemistries is needed. Experiments We conduct systematic characterization of foam stabilization and antifoaming mechanisms in diesel for two different antifoams (silicone-containing & ashless chemistries). Employing a custom technique combining single-bubble/single-antifoam-droplet manipulation with white light interferometry, we also obtain mechanistic insights into foam stability and antifoam dynamics. Results Coalescence times from both bulk foam and single bubble experiments confirm ashless antifoams are effective at reducing foaming, demonstrating the potential of ashless antifoams. Further, we perform single-antifoam-droplet experiments and obtain direct experimental evidence revealing the elusive antifoaming mechanisms. Interestingly, the silicone-containing and ashless antifoams seemingly function via two different mechanisms: spreading and dewetting respectively. This surprising finding refutes conventional wisdom that spreading is likely the only antifoam mechanism in diesels. These results and the reported experimental framework significantly enhance the scientific understanding of non-aqueous foams and will accelerate the engineering of alternative antifoam chemistries for non-aqueous systems. • Single bubble/drop experiments facilitate mechanistic insight driven research into antifoams across non-aqueous systems. • This ashless antifoam is successfully incorporated as microdroplets and is effective at reducing foam. • Direct evidence of underlying antifoam mechanisms from modified antifoam droplet experiments. • Mechanism of action of tested ashless and silicone-containing antifoams are different. [ABSTRACT FROM AUTHOR]

This paper investigates the effects of hemispherical mounds on filmwise condensation heat transfer in micro-channels. Also investigated were the impacts that spatial orientation of the three-sided condensation surface (i.e., gravitational effects) on steam condensation, where the cooled surfaces were either the lower surface (i.e., gravity pulls liquid towards the condensing surfaces) or upper surface (i.e., gravity pulls liquid away from the condensing surfaces). Two test coupons were used with 1.9-mm hydraulic diameters and either a plain copper surface or a copper surface modified with 2-mm diameter hemispherical mounds. Heat transfer coefficients, film visualization, and pressure drop measurements were recorded for both coupons in both orientations at mass fluxes of 50 kg/m2s and 125 kg/m2s. For all test conditions, the mounds were found to increase condensation heat transfer coefficients by at minimum 13% and at maximum 79%. When the test section was inverted (i.e., condensing surface on the top of flowing steam), minimal differences were found in mound performance, while the plain coupon reduces heat transfer coefficients by as much as 14%. Flow visualization suggests that the mounds enhanced heat transfer due to the disruption of the film as well as by reducing the thermal resistance of the film. Pressure drops followed parabolic behavior with quality, being higher in the mound coupon than the plain coupon. No significant pressure drop differences in the inverted orientation were observed. [ABSTRACT FROM AUTHOR]

Technologies that facilitate recycling are attracting considerable interest from the perspective of resource constraints. In the present study, degradable primer films are to facilitate the removal of strongly bonded joints. This film consists of a light‐cured trifunctional anthracene compound that thermally decomposes to its original liquid state. To demonstrate its function as a degradable primer film and verify its range of applications, various substrates, such as aluminum alloys, stainless steel, carbon fiber‐reinforced plastics, carbon fiber‐reinforced thermoplastics, and polyetheretherketone, are bonded through the primer film using a two‐component epoxy adhesive. All the single‐lap specimens exhibit strengths above 10 MPa, which is sufficient, or base material fracture. When adhesive bonding specimens prepared using the same procedure are heated at 180 °C to transform the coating film to a liquid state, the bond strength is significantly reduced. The primer film is expected to exhibit long‐term stability of more than one year at ≈60 °C. [ABSTRACT FROM AUTHOR]

This study investigates countercurrent air-water two-phase flow in vertical pipes with inner diameters of 26 mm and 44 mm and a height of 2000 mm, under controlled conditions to eliminate heat and mass transfer. Cutting-edge techniques were employed to measure the liquid film thickness (δ) and entrainment (e) within the annular flow pattern. The methodology involved a systematic comparative analysis of experimental results against established models, identifying the most accurate methods for predicting flow behavior. Specifically, the Schubring et al. correlation was found to most accurately predict e in 26 mm pipes, while the Wallis correlation was more accurate for 44 mm pipes. Additionally, interfacial shear stress was analyzed, confirming the high precision of the δ and e parameters. This research enhances the understanding of countercurrent air-water two-phase flow by providing reliable estimation methods for different pipe diameters and emphasizes the significance of accurately determining interfacial shear stress. Key findings include the identification of the most accurate models for different pipe sizes and addressing challenges in measuring δ and e under controlled conditions. The study's novelty lies in its comprehensive comparative analysis of existing models, leading to improved predictions of flow dynamics in vertical pipes, thereby contributing valuable insights into two-phase flow behavior in geosciences and environmental engineering. [ABSTRACT FROM AUTHOR]

In this paper, the corrosion resistance of sheet-gyroid porous structures with different porosities formed by LPBF under static and dynamic conditions was studied, and the mechanism of influence of medium flow on corrosion resistance was explored based on CFD simulation. It was found that the corrosion resistance of porous structures decreased with the increase in porosity in static and dynamic environments, which was mainly related to the increase in forming defects and the decrease in forming quality as the wall thickness of porous structures decreased with the increase in porosity. Under dynamic electrolyte conditions, the wall shear stress generated by the flowing medium on the surface of the porous structures will reduce the stability of the oxide film and increase the corrosion rate. The porous structures exhibited greater corrosion damage in the dynamic electrolyte solution. Based on CFD simulation analysis, it was found that with the increase in porosity, the channel size of porous structures increased, the curvature decreased, the average wall shear stress decreased, and the influence of medium flow on the corrosion rate of porous structure gradually decreased. The relationship model between average wall shear stress and corrosion rate growth rate was established, which provided data support for the subsequent design of porous structures for bone implantation. During the corrosion process, α-Ti and Ti2Cu phase form micro-galvanic corrosion, and the preferential dissolution of Ti2Cu phase leads to the gradual release of Cu2+, which is conducive to improving the antibacterial performance of Ti–Cu implants. [ABSTRACT FROM AUTHOR]

The droplet breakup and distribution of the internal flow field and external spray field of a nozzle were obtained under different pressures. The thickness of the liquid film increased with pressure as a quadratic function. The maximum value of 0.281 mm at 2 MPa decreased to 0.172 mm at 10 MPa, equivalent to 38.8% decrease. The MATLAB was used to obtain the particle size distribution characteristics of the droplets under different pressures. At 2 MPa, droplet breakup dominated the axial interval [0–700 mm]. With the increase of pressure, D50 distribution as a whole continues to decrease, 2–6 MPa change, the particle size reduction is larger, every increase of 2 MPa reduced by about 15%. 6-10 MPa change, the particle size reduction is smaller, every increase of 2 MPa reduced by about 8%. A model to predict the optimal dust reduction areas under varying pressures was developed. The prediction results indicate that at pressures of 5 MPa and 9 MPa, the target dust removal areas were [344 mm, 710 mm] and [424 mm, 942 mm] along the axial direction, respectively. [ABSTRACT FROM AUTHOR]

In this article, surfactants such as cetyl trimethyl ammonium chloride (CTAC) and coconut oil amide propyl betaine (CAB) were compounded (TCJ) and used as a double function with foam drainage and hydrate anti‐polymerization. According to the result it was found that 0.05% of CTAC and 0.7% of CAB exhibited both excellent foam property and hydrate anti‐polymerization property. For further clarifying the stability characteristic of foam, the foam half‐life, drainage process, microcosmic liquid film structure, and stability mechanism were investigated in this article. The high initial foam volume of 415 mL with relatively long half‐life time of 5.5 min under high‐speed agitation at 50°C after 25 min indicated a good temperature resistance. The excellent foam properties still remained even amount of methanol and NaCl was added, which indicated its well stability and salt resistance. Furthermore, it was found that TCJ exhibited high liquid carrying rate of 62.5% at 65°C and good compatibility with poly vinyl pyrrolidone (PVP), which played great potential to the application in oil field. By the results of DSC curves, it can be found that the phase transformation point of hydrate decreases after addition of TCJ, which indicates the inhibition to the formation of hydrate as thermodynamic inhibitors. [ABSTRACT FROM AUTHOR]

Yttrium iron garnet (YIG) has minimum damping factor and low ferromagnetic resonance (FMR) linewidth, making it a preferred material for low loss microwave and spintronic devices. The saturation magnetization of YIG is 1750 Gauss, and for low-frequency devices, a lower saturation magnetization is more suitable. Ga3+ and Al3+ are with smaller radii and non-magnetic moment, so the substitution of Ga3+ and Al3+ can decrease saturation magnetization. Here, 4.8–193.7 nm ultra-thin Y3(GaAlFe)5O12 garnet (GaAl-YIG) monocrystalline films are prepared on gadolinium gallium garnet (GGG) substrates by using the liquid-phase epitaxy (LPE) method. As expected, these films exhibit a low saturation magnetization of almost less than 100 Gauss, while their FMR linewidth remains at levels close to that of YIG. The films show a (111) orientation and in a state of tension, and the diffraction intensity of the films get stronger as films thickness increases. The free energy and density of states are calculated for different Ga/Al substitution position by density functional theory simulations. The elements show a different diffusion distance in the GaAl-YIG/GGG interface, and the variation of magnetization properties with interface width are analyzed. The surface roughness of the films is only a few angstroms. The damping factor of these ultra-thin films are on an order of 10−4 except the 4.8 nm film, which suggests that the minimum thickness of the garnet film with good performance by using the LPE method is about 10 nm. According to the analysis of structure and magnetization properties, it demonstrates that the LPE method has potential to provide nanoscale garnet films for low loss microwave and spintronic devices. [ABSTRACT FROM AUTHOR]

To improve the performance of studless tires on ice surfaces, the mechanism of liquid film removal must be elucidated. In this study, an experimental system is developed to simulate the running conditions of a studless tire, and the microscopic liquid film flow generated between the rubber surface and glass is observed to evaluate the liquid thickness distribution. Liquid film removal by micropores on foamed rubber samples is investigated by visualizing the liquid thickness in the micropores. The proposed system enables variations in the pressure and sliding velocity between the rubber and glass. The liquid thickness in the micropores is measured using laser-induced fluorescence, and the effects of pressure and sliding velocity on the thickness are examined. Water penetrates the micropores on the rubber sample surface, and different liquid thicknesses are obtained for each pore. The amount of liquid penetrating the pores is affected to a greater extent by the sliding velocity than by the pressure. Therefore, liquid penetration is more strongly influenced by the hydrodynamic effect of the increasing inertia of the liquid under high sliding velocities than by the elastic deformation of the pore. [ABSTRACT FROM AUTHOR]

Significance of magnetohydrodynamic effect on a viscous (temperature‐dependent) and chemically reactive thin fluid film flow past an unsteady permeable stretchable plate with Soret–Dufour effects, nonlinear thermal radiative, and suction under the action of a convective type of boundary condition is analyzed. The problem consists of nonlinear governing basic equations that are highly nonlinear due to the existence of nonlinear thermal radiative terms in the energy equation. Analytical solutions are challenging to achieve for such types of problems, so a numerical scheme adopts the numerical solution. Computed solutions indicate that decreasing the Dufour number (and simultaneously increasing the Soret number) enhances heat flux, whereas the reverse trend is estimated for the concentration gradient field. The influence of magnetization indicates a decrement in the thin liquid film velocity distribution, whereas an increment is observed in temperature and solutal gradient profiles. Further, an enhancement in thermoradiative values focuses on decreasing the heat flux profiles, whereas a decreasing trend is determined in the solutal gradient by incrementing the Schmidt number. The variations of the velocity field, temperature, and concentration gradients are shown for the unsteady parameter S $S$ lying in the range [0.8, 1.4]. Similarly, the range of different parameters utilized are θr ${\theta }_{r}$ [0.0, 1.0], Nr $Nr$ [0.0, 2.0], Pr $Pr$ [0.8, 1.5], Sc $Sc$ [0.5, 2.0], B* ${B}^{* }$ [0.0, 1.0], k1 ${k}_{1}$ [0.2, 3.0], fw ${f}_{w}$ [1.0, 2.0], M $M$ [0.0, 3.0], Du $Du$ [0.4, 1.0], and Sr $Sr$ [0.4, 1.0]. The novelty of the present study lies in its analysis of complex fluid dynamics phenomena and their implications for various industrial processes and engineering applications, including coating processes, heat exchangers, microfluidics, and biomedical engineering. The insights gained from the study can contribute to developing more efficient and innovative research in these areas. Further, we have compared the present results with those available in the literature under some special cases and found them to be in excellent agreement. [ABSTRACT FROM AUTHOR]

An insulator‐based spin‐thermoelectric (STE) generator is composed of a thin paramagnetic metal (PM: Pt) layer for generating the STE voltage VSTE via the inverse spin Hall effect and a ferrimagnetic insulator (FMI) film or slab used for producing spin‐wave spin currents due to a temperature gradient ∇T$$ \nabla T $$. Yttrium iron garnet (YIG) is a key material used for the FMI of STE generators. We examined in detail the ferromagnetic resonance (FMR) properties of YIG (Y3Fe5O12), Bi‐substituted YIG (Y3‐xBixFe5O12) and Bi‐ and Al‐substituted YIG (Y3‐xBixFe5‐yAlyO12) films grown by liquid phase epitaxy (LPE). Bi‐substituted YIG films exhibited the large FMR damping and high STE voltage when the films were incorporated in the STE generator. The LPE‐grown Y2.35Bi0.65Fe5O12 film exhibited the FMR linewidth ΔH of 30 mT and the VSTE of 70 μV for the ∇T of 90×10−3°C/μm$$ 90\times {10}^{-3{}^{\circ}}C/\upmu \mathrm{m} $$. This paper comprehensively presents the origin of the STE generation in the insulator‐based generators on the basis of the results of FMR and STE measurements. To clarify the origin of STE generation in the generators fabricated from single crystal YIG (YIG, Bi‐substituted YIG and Bi‐ and Al‐substituted YIG) films grown by LPE, three principal factors are explained: (a) thermal energy transfer from the phonon system to the spin system, which strengthens the heat excitation of spin precession, through the spin–orbit coupling enhanced by the growth‐induced magnetic anisotropy of LPE‐grown YIG films, (b) in the YIG films incorporated in the STE generators, the generation of spin‐wave spin currents owing its origin to the ferromagnetic spin exchange interaction acting between neighboring spins due to ∇T$$ \nabla T $$, and (c) how the spin currents pumped into the Pt layer from the YIG film at the Pt/YIG bilayer interface are affected by the magnetization processes of single crystal YIG films. It is concluded that the STE generation of insulator‐based STE generators can be explained from a viewpoint of the spin dynamics under the effect of ∇T$$ \nabla T $$ in the Pt/YIG bilayer structure. © 2024 Institute of Electrical Engineers of Japan and Wiley Periodicals LLC. [ABSTRACT FROM AUTHOR]

Electrostatically stabilised colloidal particles destabilise when brought into contact with cations causing the particles to aggregate in clusters. When a drop with stabilised colloidal partices is deposited on a liquid film containing cations the delicate balance between the fluid-mechanical and physicochemical properties of the system governs the spreading dynamics and formation of colloidal particle clusters. High-speed imaging and digital holographic microscopy were used to characterise the spreading process. We reveal that a spreading colloidal drop evolves into a ring-shaped pattern after it is deposited on a thin saline water film. Clustered colloidal particles aggregate into larger trapezoidally-shaped 'supraclusters'. Using a simple model we show that the trapezoidal shape of the supraclusters is determined by the transition from inertial spreading dynamics to Marangoni flow. These results may be of interest to applications such as wet-on-wet inkjet printing, where particle destabilisation and hydrodynamic flow coexist. [ABSTRACT FROM AUTHOR]

Liquid jet in crossflow tunnel has widespread applications in various industrial devices, with the measurements of liquid film on the bottom surface pivotal in exploring relevant mechanisms such as heat transfer and film breakup. This work reports the measurements of liquid film on the bottom surface of a crossflow tunnel using the brightness-based laser induced fluorescence method under different flow conditions at ambient pressure and temperature. Film breakup phenomena are observed downstream within the tunnel. Employing the shadowgraph method, two distinct patterns of film breakup associated with the droplet impingement positions on the film wave are identified, i.e. bag breakup and membrane breakup. The film thickness is subsequently calculated, and jet impingement and spray impingement of injected liquid on tunnel bottom surface are classified based on the centerline film thickness. A critical jet-to-crossflow momentum flux ratio (q) is determined to be proportional to the square of tunnel height. The averaged film thickness across the entire cross-section downstream at a distance of 50 mm from the nozzle is found to increase with the logarithm of q. Besides, the film boundaries are also identified under different flow conditions, which can be well predicted by a quadratic fit with the fitting parameters also correlated to the logarithm of q. [ABSTRACT FROM AUTHOR]

Understanding the melting of the deposited layer is crucial for the armature's melting process and sliding electrical contact performance. This study first establishes contact models for both the boundary lubrication state (BLS) and squeezed-film lubrication state (SFLS). A three-dimensional magnetic diffusion model is then constructed to simulate interface current distribution in these contact states. It is discovered that the maximum current density on the surface of the armature shows a decreasing trend as the thickness of the deposited layer grows. Then, a calculation model for the deposited layer's melting thickness under BLS is developed. For SFLS, Reynolds and energy equations are used to construct models for liquid film thickness and the deposited layer's melting thickness. The results indicate that the deposited layer's melting thickness under BLS is significantly greater than that under SFLS. Specifically, the melting thickness decreases with launching displacement in BLS and increases under SFLS. In SFLS, the deposited layer's melting can suppress armature melting, though it remains nearly equivalent to that observed with polished rail. These findings provide a foundation for deposited layer control technology, which is essential for enhancing sliding electric contact performance and launching efficiency. [ABSTRACT FROM AUTHOR]

Immersive human–machine interaction relies on comprehensive sensing and feedback systems, which enable transmission of multiple pieces of information. However, the integration of increasing numbers of feedback actuators and sensors causes a severe issue in terms of system complexity. In this work, we propose a pressure-sensing and feedback glove that enables multi-dimensional pressure sensing and feedback with a minimalist design of the functional units. The proposed glove consists of modular strain and pressure sensors based on films of liquid metal microchannels and coin vibrators. Strain sensors located at the finger joints can simultaneously project the bending motion of the individual joint into the virtual space or robotic hand. For subsequent tactile interactions, the design of two symmetrically distributed pressure sensors and vibrators at the fingertips possesses capabilities for multi-directional pressure sensing and feedback by evaluating the relationship of the signal variations between two sensors and tuning the feedback intensities of two vibrators. Consequently, both dynamic and static multi-dimensional pressure communication can be realized, and the vibrational actuation can be monitored by a liquid-metal-based sensor via a triboelectric sensing mechanism. A demonstration of object interaction indicates that the proposed glove can effectively detect dynamic force in varied directions at the fingertip while offering the reconstruction of a similar perception via the haptic feedback function. This device introduces an approach that adopts a minimalist design to achieve a multi-functional system, and it can benefit commercial applications in a more cost-effective way. [ABSTRACT FROM AUTHOR]

Highlights: Unique inter-skeleton conductive films are constructed in polymer foam. The resistance change of the foam can reach four orders of magnitude under compression. This foam exhibits strain-adaptive electromagnetic interference shielding performance, anti-interference pressure sensor with high sensitivity over a wide pressure range and compression-regulated Joule heating function. Conductive polymer foam (CPF) with excellent compressibility and variable resistance has promising applications in electromagnetic interference (EMI) shielding and other integrated functions for wearable electronics. However, its insufficient change amplitude of resistance with compressive strain generally leads to a degradation of shielding performance during deformation. Here, an innovative loading strategy of conductive materials on polymer foam is proposed to significantly increase the contact probability and contact area of conductive components under compression. Unique inter-skeleton conductive films are constructed by loading alginate-decorated magnetic liquid metal on the polymethacrylate films hanged between the foam skeleton (denoted as AMLM-PM foam). Traditional point contact between conductive skeletons under compression is upgraded to planar contact between conductive films. Therefore, the resistance change of AMLM-PM reaches four orders of magnitude under compression. Moreover, the inter-skeleton conductive films can improve the mechanical strength of foam, prevent the leakage of liquid metal and increase the scattering area of EM wave. AMLM-PM foam has strain-adaptive EMI shielding performance and shows compression-enhanced shielding effectiveness, solving the problem of traditional CPFs upon compression. The upgrade of resistance response also enables foam to achieve sensitive pressure sensing over a wide pressure range and compression-regulated Joule heating function. [ABSTRACT FROM AUTHOR]

Limited quantitative research exists on the complex phenomenon of slag splashing in converters. A comprehensive modeling framework is developed to fill this gap, integrating a 3D two‐phase flow model with a volume of fluid‐discrete phase model two‐way conversion model. This framework explores droplet behavior during splashing for converter protection, encompassing the mutual conversion between slag and discrete droplets induced by top‐blowing oxygen. It also tracks the trajectories of all droplets, enabling a detailed quantitative analysis of the splashing process. The Eulerian wall film model is used to simulate liquid film formation on the converter wall. Model predictions are validated against 1:10 scale experimental data from a 50 t converter. This assessment covers splashing rates, droplet locations, and size distribution under various operating conditions. Parametric studies identified an optimal top‐blowing flow rate of 8.80 Nm3 h−1 and an oxygen lance height of 233.2 mm, balancing splashing effectiveness with production cost and safety. [ABSTRACT FROM AUTHOR]

A combined multi-phase-field/discrete-element method in two dimensions is applied to the liquid phase sintering process of blended elemental powders. The boundary migration, diffusion of elements, and phase transformation between two dissimilar particles are calculated using a multi-phase-field method for sintering based on Gibbs energy functions. The sintering shrinkage is computed with the discrete-element method taking account of the neck size and sintering force, which are obtained from a multi-phase-field simulation. In this study, a pair or small cluster consisting of two elemental powders in a binary eutectic alloy is used as a model system. First, the formation of a liquid phase around the contact area between two dissimilar particles above the eutectic temperature of the system, and the motions of the particles due to grain boundary sliding along the liquid films are confirmed. Second, an Sn–Bi system is selected as the real eutectic system, and the sintering behavior of powder compacts with various mixing ratios of Sn and Bi particles is demonstrated. Finally, transient liquid-phase sintering of Sn–Bi system is simulated, that is, the generation and extinction of the liquid phase due to interdiffusion between Sn and Bi particles are calculated. [ABSTRACT FROM AUTHOR]

This paper reports a comprehensive study of Theobroma cacao pericarp (TCP) residues, which has been prepared, characterized, and tested as an inexpensive and efficient biosorbent of Cr(VI) from aqueous solutions. The maximum adsorption capacity of TCP obtained at optimal conditions (pH = 2, dose = 0.5 g L−1, C0 = 100 mg L−1) was qmax = 48.5 mg g−1, which is one of the highest values reported by the literature. Structural and morphological characterization has been performed by FTIR, SEM/EDX, and pHPZC measurements. FTIR analysis revealed the presence of O–H, –NH, –NH2, C = H, C = O, C = C, C–O, and C–C functional groups that would be involved in the Cr(VI) biosorption processes. The experimental equilibrium data of biosorption process were successfully fitted to non-linear Langmuir (R2 = 0.95, χ2 = 11.0), Freundlich (R2 = 0.93, χ2 = 14.8), and Temkin (R2 = 0.93, χ2 = 14.7) isotherm models. Kinetics experimental data were well adjustment to non-linear pseudo-2nd (R2 = 0.99, χ2 = 2.08)- and pseudo-1st-order kinetic models (R2 = 0.98, χ2 = 2.25) and also to intra-particle Weber-Morris (R2 = 0.98) and liquid film diffusion (R2 = 0.99) models. These results indicate that Cr(VI) biosorption on heterogeneous surfaces as well as on monolayers of TCP would be a complex process controlled by chemisorption and physisorption mechanisms. The thermodynamic results indicate that the Cr(VI) biosorption on TCP is a feasible, spontaneous, and endothermic process. TCP can be regenerated with NaOH and reused up to 3 times. [ABSTRACT FROM AUTHOR]

Implantable flexible electronic has attracted significant research interest in various fields. However, it still faces the challenge of simultaneously achieving tight adhesion to tissues in a mildly wet environment and possessing excellent biocompatibility to reduce immune rejection reactions after implantation. Here, a degradable wet‐adhesive flexible electronic device based on liquid metal and ultrathin gelatin film is developed. The ultrathin gelatin film forms numerous hydrogen bonds with tissue in a slightly humid environment, rapidly constructing a wet‐adhesive interface without damaging tissue structure. Inkjet printing is utilized to pattern the mixture of liquid metal and PVP on the surface of the ultrathin gelatin to create flexible patch. With the excellent conductivity of liquid metal, low toxicity, and similarity to natural tissue components of gelatin, flexible patch exhibits outstanding biocompatibility and fatigue resistance. It can be implanted in the body for up to 6 weeks, retaining monitoring capabilities and resisting 1 000 000 cycles of bending fatigue. This study provides a novel strategy for the future development of implantable flexible electronics. [ABSTRACT FROM AUTHOR]

The article provides a theoretical investigation of the laminar film-condensation of shear-thinning fluids onto an isothermal, vertical plate in the presence of gravity, interfacial shear, wall friction, and inertia. The liquid motion occurs toward gravity, overcoming the resistances of interfacial shear, wall friction, and inertia. The liquid motion induces momentum to the adjacent stagnant saturated vapor by interfacial shear. The vapor motion, in turn, influences the liquid film's heat transfer and fluid dynamics. For film condensation, it is well-known that the film, along the length of the plate, can be grouped in two separate heat transfer regimes, viz. conduction-dominated regime and convection-dominated regime. For the first time, we have identified three distinct fluid dynamic regions across the film (viz. R1, R2, and R3) unique to power-law fluids. R1 is bounded between the condensing surface and the locus of Newtonian shear stress. R2 is bounded between the locus of Newtonian shear stress and the locus of zero shear stress. Beyond R2, R3 is stretched up to the liquid-vapor interface. The transverse temperature gradient is subtly different in these three fluid dynamic regions. We examine flow physics on a non-dimensional platform. The critical role of the power-law index in determining wall-friction and condensate's mass flow rate and the impact of liquid Prandtl number in achieving the degree of subcooling has been nicely illustrated. We expose various limiting conditions for simplifying the robust mathematical theory. An analytical expression for the liquid's longitudinal velocity has been derived, neglecting inertia and interfacial shear. [ABSTRACT FROM AUTHOR]

The research on entropy generation in a mechanical system is quite imperative owing to its immense applications in the production of advanced cooling devices and medical appliances. The basic need on this research is how to optimize the irreversibilities within the systems and channelize that energy towards the benefit. This study elucidates the entropy generation analysis of a Casson nanofluid near a stagnation point over a lubricated vertical wall. A thin film of shear-thinning liquid with power law index of 0.5 is employed on the wall to ensure the lubrication. The effect of induced magnetic field and the chemical reaction stimulated by the activation energy is also incorporated within the flow. The non-linear PDEs of the substantive problem along with the compatible interfacial and boundary conditions are reverted into ODEs with the aid of suitable similarity transformation, and then cracked numerically using the sixth-order Runge Kutta method assisted with Nachtsheim–Swigert shooting practice. One of the significant findings reveals that the fluid friction irreversibilities in the entropy generation are diminished with the magnetic parameter and the Casson parameter, whereas the thermal irreversibility predominates over the total entropy generation for the escalating values of the activation energy parameter. [ABSTRACT FROM AUTHOR]

The nitrogen content and solidification structure of the 1Mn18Cr18N ingots produced by the customized laboratory‐scale vacuum induction melting furnace and the pressure electroslag remelting furnace (PESR) with novel composite electrode under different pressure and the same power consumption are compared and studied. The results show that there are perfectly uniform radial chromium and nitrogen profiles during the PESR process. The nitrogen uptake reaction in the PESR process with composite electrode takes place on the liquid metal film on the electrode. Nitrogen uptake could be improved by increasing the nitrogen partial pressure. In addition, the basin depth at a pressure of 0.1 and 1.22 MPa is about 41 and 38 mm, the angle of the grains with respect to the vertical axis is 35° and 31°, respectively. The flat metal basin profile resulted from the thermal resistance at the slag–mold interface decreasing with increasing pressure. Primary and secondary dendritic arm spacing (PDAS and SDAS) variations exhibit an increasing and subsequently decreasing the trend as they move further away from the center in a horizontal direction. Both PDAS and SDAS decrease with increasing pressure from 0.1 to 1.22 MPa. [ABSTRACT FROM AUTHOR]

The high-frequency and high-quality factor characteristics of bulk acoustic wave (BAW) resonators have significantly advanced their application in sensing technologies. In this work, a fluidic sensor based on a BAW resonator structure is fabricated and investigated. Embedded microchannels are formed beneath the active area of the BAW device without the need for external processes. As liquid flows through the microchannel, pressure is exerted on the upper wall (piezoelectric film) of the microchannel, which causes a shift in the resonant frequency. Using density functional theory, we revealed the intrinsic mechanism by which piezoelectric film deformation influences BAW resonator performance. Theoretically, the upwardly convex piezoelectric film caused by liquid flow can increase the resonant frequency. The experimental results obtained with ethanol solutions of different concentrations reveal that the sensor, which operates at a high resonant frequency of 2.225 GHz, achieves a remarkable sensitivity of 5.1 MHz/% (221 ppm/%), with an ultrahigh linearity of 0.995. This study reveals the intrinsic mechanism of liquid sensing based on BAW resonators, highlights the potential of AlN/Al0.8Sc0.2N composite film BAW resonators in liquid sensing applications and offers insights for future research and development in this field. [ABSTRACT FROM AUTHOR]

The article "Spreading of a viscous drop after impact onto a spherical target" in the Journal of Fluid Mechanics explores the dynamics of liquid droplets colliding with solid spherical particles. It investigates both non-axisymmetric and axisymmetric impacts, analyzing parameters such as drop shape, residual film thickness, and spreading angle. The study introduces a new method for measuring liquid viscosity during drop impacts, with potential applications in industrial processes. The research sheds light on optimizing processes involving drop collisions and offers valuable insights for various industries. [Extracted from the article]

The article delves into the linear stability theory and molecular simulations of nanofilm dewetting, focusing on factors like disjoining pressure, liquid-solid slip, and thermal fluctuations. Molecular dynamics simulations reveal distinct behaviors in nanofilm instability based on slip strength, leading to the derivation of a new stochastic lubrication equation for strong-slip dewetting. The study aims to predict experimental outcomes and offers insights into the behavior of thin liquid films on substrates with varying slip lengths. Additionally, the document provides a list of scientific research articles exploring various aspects of fluid mechanics, including topics like stick-slip motion, thin film rupture, and nanoscale flows, which may be valuable for researchers interested in fluid dynamics and surface phenomena. [Extracted from the article]

The article delves into the behavior of liquid nano-threads under external hydrodynamic perturbations and thermal fluctuations, utilizing a stochastic lubrication equation to analyze instability and rupture dynamics. It identifies two distinct regimes - hydrodynamic and thermal-fluctuation - with the transition influenced by external perturbation characteristics. Molecular dynamics simulations validate theoretical predictions, emphasizing the interplay between external perturbations and thermal fluctuations in perturbation growth evolution and thread breakup patterns. The document also includes a compilation of scientific research articles on fluid dynamics topics like jet breakup length, droplet manipulation, and thermal fluctuations' effects on nanoscale flows, published in reputable journals. [Extracted from the article]

Dynamics of double-droplet off-centered impact on a superhydrophobic substrate is investigated. The effects of the distance between droplets, off-centered distance as well as the Weber number on the impact dynamics are systematically investigated by lattice Boltzmann method simulations. For the off-centered impact of double droplets, two distinct regions are identified, i.e., the contact time increasing region (TIR) and the decreasing region (TDR). For TIR, the liquid film exhibits a "butterfly-like" shape during the spreading and then recoils toward the center, while for TDR, the liquid film presents a "rod-like" shape and then retracts toward the ends of the rod, leading a pancake bounce pattern. Considering the mechanism of the redistribution of liquid volume and the asymmetric of the liquid film, the quantitative expression of contact time for TIR is established. Based on this, the mechanism of the interaction between droplets is further studied to calibrate the expression of the contact time by introducing the center distance between droplets, which is certificated to be used in a large range of distances between droplets, off-centered distance, and the Weber number. [ABSTRACT FROM AUTHOR]

For the issue of jet impingement on the wall in industrial cooling processes, an experimental setup based on high-speed photography for oblique jet impingement onto the wall was constructed. The experimental focus was on the study of liquid droplet splashing behavior after oblique jet impingement on the wall, discussing the liquid droplet splashing behavior under three jet impingement modes: Rayleigh regime, first wind-induced regime, and secondary wind-induced regime. By employing methods such as trajectory imaging and particle image velocity for liquid droplet parameter image measurement, obtaining the particle size, velocity, and distribution of splashed droplets after oblique jet impact on walls under different working conditions. The impact of jet impingement velocity and angle on droplet splashing parameters was analyzed. The results showed that when the impingement point is before the breakup length, with increasing flow velocity, the surface wave of the liquid column, and the spreading liquid film became more pronounced, but the loss of liquid-phase components due to splashing was relatively small. When the impingement point is after the breakup length, the secondary breakup resulting in a "crown"-shaped liquid film after droplet impingement leads to a significant loss of liquid-phase components through splashing. As the inlet velocity of the jet increases, there is a decreasing trend in droplet size and an increasing trend in droplet velocity. With an increase in jet angle, there is a decreasing trend in droplet size and velocity. Based on the concentration, size, and velocity distribution characteristics of splashing droplets, the area after oblique jet impingement on the wall can be divided into the impingement zone, low-concentration low-velocity zone, high-concentration high-velocity zone, and lateral splashing zone. This has significant implications for understanding the splashing mechanism after oblique jet impingement on the wall and optimizing operating conditions. [ABSTRACT FROM AUTHOR]

The critical heat fluxes (CHF) for R245fa flowing inside a horizontal microchannel with diameter of 0.94 mm and heated length of 170 mm under different gravity levels were experimentally studied. Taking the thermal oscillation parameters occurring in the post-dryout region as the research object, which differed from the parameter oscillations during the occurrence of CHF in past literature, and revealing the formation mechanism of thermal oscillations when dryout type CHF occurred, as well as the impact of gravity level on thermal oscillations. The experimental parameters are: mass fluxes of G = 200 and 300 kg/m2 s, inlet pressure of Pin = 211.72 kPa, inlet subcooling of ΔTsub = 5–10 K, and nominal hypergravity of an = 1–1.53 g. The results show that CHF increases with the increase in mass flux, inlet subcooling, and gravity level, which is mainly related to the rates of liquid film evaporation, mainstream droplet entrainment, and droplet deposition onto the wall. The process of post-dryout occurs simultaneously with thermal instability. In addition, the increase in gravity level helps to alleviate the heat transfer deterioration at the test section outlet and suppresses the oscillations in wall temperature and inlet pressure. [ABSTRACT FROM AUTHOR]

Droplet impinging on liquid film is significant for many industrial processes. In this work, the normal impact of a single droplet on different thickness of concave curved liquid films is simulated. Coupled level set and volume of fluid method is used to capture the dynamics of drop impact and crown spreading. The variation of pressure field of droplets impacting the curved liquid film is investigated. The effect of film thickness and wall curvature on the water crown behavior is studied. With the curvature ratio increasing, the elevation angle of the velocity vector at crown rim increases, and the velocity gradient inside the crown decreases. The increase in curvature ratio also makes the crown sheet incline inward and suppresses the splash. The thickness of liquid film will lead to discrepancies in crown behaviors. The thin film makes the spreading speed of crown rim faster, and the crown top will shrink and splash. With the thickening of the liquid film, the influence of the thickness on the shape and size of the crown weakens. The separation of crown influenced by thin film is also analyzed. [ABSTRACT FROM AUTHOR]

In many engineering applications, including coating and lubrication operations, analyzing the temperature behavior of thin film flows on a vertically upward-moving tube is crucial to improving predictive models. This paper examines a steady third-grade fluid film flow with a surface tension gradient on a vertical tube. The mechanisms responsible for the fluid motion are upward tube motion, gravity, and surface tension gradient. This analysis focuses on heat transfer and stagnant ring dynamics. The formulated highly nonlinear ordinary differential equations are solved using the Adomian decomposition method. The conditions for stagnant rings and uniform film thickness are attained and discussed. The inverse capillary number C, Stokes number S t , Deborah number De, and Brinkman number Br emerged as flow control parameters. The temperature of the fluid film rises with an increase in the C, S t , De, and Br, whereas it decreases with an increase in thermal diffusion rate. The radius of stagnant rings tends to shrink by the increase in C, S t , and De. When the value of De is high, third-grade fluid behaves like solids; only free drainage happens with smaller radius stagnant rings and high temperatures. A comparison between Newtonian and third-grade fluids regarding surface tension, velocity, temperature, stationary rings, and fluid film thickness is also provided. [ABSTRACT FROM AUTHOR]

There is a lack of understanding of the physical mechanisms involved in the rupture of a liquid film on a solid surface. This is in part due to the large number of parameters of the liquid film—substrate system on which this complex process is dependent. Due to the thermocapillary effect, local heating can have a destabilizing effect on the stability of the film. In this work, using a numerical model verified by the experimental data, the influence of parameters not available for variation in the experiment has been studied. It was found that the formation of dry spots in a locally heated liquid film occurs only under the influence of thermocapillary forces. In turn, the expansion of the dry spots takes place under the influence of the capillary forces. Thus, until the dry spot appears, the rupture does not differ on either hydrophilic or superhydrophobic substrates, but the contact line velocity during dry spot growth is extremely sensitive to the contact angle. [ABSTRACT FROM AUTHOR]

A fundamental understanding of two-phase flow behavior in microfluidics is crucial for various technological applications across different disciplines, including energy, chemical, and material engineering, as well as biomedical, environmental, and pharmaceutical sciences. In this work, we elucidate the flow fields of low Capillary number [Ca ∼ O (10 − 3) ] segmented Taylor flows of immiscible CO2 emulsions/bubbles transported by water in a low aspect ratio microchannel. We conducted high-resolution two- and three-dimensional (2D and 3D) numerical simulations using an improved volume-of-fluid two-phase flow solver and validated their accuracy against experimental data. Our results show that 3D simulations are necessary to accurately capture the dynamics of liquid and supercritical CO2 emulsions produced at relatively higher Ca. The 3D simulation results also reveal diverse patterns of spanwise vortices, which are overlooked in 2D simulations. Calculating the Q-criterion in 3D revealed that vortices with relatively higher vorticity magnitudes are adjacent to the sidewalls, with the strongest ones emerging across the microchannel in the third dimension. More specifically, gaseous CO2 bubbles display relatively intense vortex patterns near the interfacial region of the bubble body and the cap due to the influence of the surrounding thin liquid film and slug flow. At higher Ca, liquid and supercritical CO2 emulsions exhibit similar flow dynamics, however, with prominent vortex patterns occurring in the upstream cap region. These findings pinpoint specific areas within the emulsions/bubbles that require attention to enhance stabilization or exchanging mechanisms for low-Ca Taylor flow of emulsions/bubbles. [ABSTRACT FROM AUTHOR]

A geometric and physical model for melting ice sliding over inclined superhydrophobic (SH) surfaces with parallel ridges is presented. By analyzing the micro-shear flows of molten liquid films between the ice layer and SH surfaces, the hyperslip velocities of melting ice sliding are investigated. The stick-slip boundary condition of the SH surface is used to establish the dual-series equations analytically, and the numerical solutions are implemented by truncating Fourier series and transforming the dual-series equations into linear algebraic equations to determine the hyperslip velocities of melting ice sliding. The numerical results indicate that the non-dimensional hyperslip velocities increase nonlinearly from near 0 to approximately 1.1 for longitudinal sliding and from near 0 to approximately 0.55 for transverse sliding with an increasing air groove ratio (a). The hyperslip velocities increase with increasing δ at the beginning initially (δ < 1), after which they tend toward asymptotic solutions as δ = 1. The hyperslip velocity ratio (Wh/Uh) shows that longitudinal ridges are at least twice as effective as transverse ridges in enhancing the ice hyperslip velocity, with the velocities accounting for more than 60% of the ice sliding velocities for arbitrary θ at a = 0.95 and δ = 0.1. The relative deviations between the numerical and asymptotic solutions are less than 5% at δ = 1, with the maximum relative deviation occurring at a = 0.65 for arbitrary θ. [ABSTRACT FROM AUTHOR]

This study explores the surface plasmon resonance (SPR) and the electromagnetic field responses of multi-layer structures with incident light to enhance the sensitivity and range for measurement of nanoscale thin liquid film thickness. We assess the effect of metal layer type and its corresponding thickness on the optical responses. Notably, the silver (Ag) layer exhibits a more acute reflectance curve with a thickness of 50 nm, which is attributable to the minimization of non-radiative losses and a substantial real component of the dielectric constant of the Ag layer. Furthermore, a correlation between liquid film thickness and reflectance has been established across different metal layer types at specified thicknesses. The Ag layer demonstrates the broadest measurement range for liquid film thickness due to its extensive penetration depth into the dielectric material. Conversely, the sodium (Na) layer presents the narrowest measurement range, albeit with the highest SPR sensitivity. [ABSTRACT FROM AUTHOR]

This study examines the impact of CO2 concentration on the stability and plugging performance of polymer-enhanced foam (PEF) under high-temperature and high-pressure conditions representative of the steam front in heavy oil reservoirs. Bulk foam experiments were conducted to analyze the foam performance, interfacial properties, and rheological behavior of CHSB surfactant and Z364 polymer in different CO2 and N2 gas environments. Additionally, core flooding experiments were performed to investigate the plugging performance of PEF in porous media and the factors influencing it. The results indicate that a reduction in CO2 concentration in the foam, due to the lower solubility of N2 in water and the reduced permeability of the liquid film, enhances foam stability and flow resistance in porous media. The addition of polymers was found to significantly improve the stability of the liquid film and the flow viscosity of the foam, particularly under high-temperature conditions, effectively mitigating the foam strength degradation caused by CO2 dissolution. However, at 200 °C, a notable decrease in foam stability and a sharp reduction in the resistance factor were observed. Overall, the study elucidates the effects of gas type, temperature, and polymer concentration on the flow and plugging performance of PEF in porous media, providing reference for fluid mobility control at the steam front in heavy oil recovery. [ABSTRACT FROM AUTHOR]

Although various hypergolic propellants like MMH/N2O4 (monomethylhydrazine/dinitrogen tetroxide) are widely used in small rocket engines, there remains a lack of in-depth study conducted on their chemical reactions and spray combustion behaviors. To fill this research gap, a simplified chemical kinetic model that is suitable for three-dimensional simulation was proposed in this paper for MMH/N2O4. Then, numerical investigation was conducted using the Volume of Fluid (VOF) model to explore the transient injection and atomization of MMH/N2O4 impinging jets in a small bipropellant thruster. Also, the instantaneous formation and evolution of the fan-shaped liquid film were analyzed. With the spray distribution determined, the proposed kinetic model and two existing mechanisms were applied to simulate spray combustion and heat transfer within the thruster, respectively, under the Euler–Lagrange framework. According to the research results, the liquid film covered nearly the entire chamber wall with a sawtooth pattern, which protected against the high temperatures of the engine wall. Notably, the two existing mechanisms showed significant errors in predicting temperature changes around the wall due to the excessively simplified reaction pathways. In contrast, the proposed model enabled the accurate prediction of the chamber pressure, wall temperature, and thrust with an error of less than 10%. Given the high accuracy achieved by the proposed numerical method, it provides a valuable reference for the development of advanced space engines. [ABSTRACT FROM AUTHOR]