602 results on '"WANG Kunlin"'
Search Results
252. Improving tensile properties of double-walled carbon nanotube strands by intercalation of epoxy resin
- Author
-
Li, Yijun, primary, Wang, Kunlin, additional, Wei, Jinquan, additional, Gu, Zhiyi, additional, Shu, Qinke, additional, Li, Chuangang, additional, Wang, Wenxiang, additional, Wang, Zhicheng, additional, Luo, Jianbin, additional, and Wu, Dehai, additional
- Published
- 2006
- Full Text
- View/download PDF
253. Strong visible light emission from well-aligned multiwalled carbon nanotube films under infrared laser irradiation
- Author
-
Zhang, Yong, primary, Gong, Tao, additional, Liu, Wenjin, additional, Zhang, Xianfeng, additional, Chang, Jianguo, additional, Wang, Kunlin, additional, and Wu, Dehai, additional
- Published
- 2005
- Full Text
- View/download PDF
254. Coated double-walled carbon nanotubes with ceria nanoparticles
- Author
-
Wei, Jinquan, primary, Ding, Jun, additional, Zhang, Xianfeng, additional, Wu, Dehai, additional, Wang, Zhicheng, additional, Luo, Jianbin, additional, and Wang, Kunlin, additional
- Published
- 2005
- Full Text
- View/download PDF
255. Large-Area Flexible Core-Shell Graphene/Porous Carbon Woven Fabric Films for Fiber Supercapacitor Electrodes.
- Author
-
Li, Xiao, Zang, Xiaobei, Li, Zhen, Li, Xinming, Li, Peixu, Sun, Pengzhan, Lee, Xiao, Zhang, Rujing, Huang, Zhenghong, Wang, Kunlin, Wu, Dehai, Kang, Feiyu, and Zhu, Hongwei
- Subjects
GRAPHENE ,SUPERCAPACITORS ,POROSITY ,ELECTRIC capacity ,AMORPHOUS carbon - Abstract
New porous materials are of great importance in many technological applications. Here, the direct synthesis of multi-layer graphene and porous carbon woven composite films by chemical vapor deposition on Ni gauze templates is reported. The composite films integrate the dual advantages of graphene and porous carbon, having not only the excellent electrical properties and flexibility of graphene but also the porous characteristics of amorphous carbon. The multi-layer graphene/porous carbon woven fabric film creates a new platform for a variety of applications, such as fiber supercapacitors. The designed composite film has a capacitance of 20 μF/cm
2 , which is close to the theoretical value and a device areal capacitance of 44 mF/cm2 . [ABSTRACT FROM AUTHOR]- Published
- 2014
- Full Text
- View/download PDF
256. Laser marking of stainless steel with a Q-switched Nd:YAG laser
- Author
-
Qi, Jun, primary, Wang, Kunlin, additional, Liang, Mianchang, additional, Zhu, Yunming, additional, and Fang, Minggang, additional
- Published
- 1998
- Full Text
- View/download PDF
257. Laser surface clad coatings modified by rare earth
- Author
-
Wang, Kunlin, primary, Zhang, Qingbo, additional, Sun, Manlong, additional, Wei, Xingguo, additional, and Zhu, Yunming, additional
- Published
- 1998
- Full Text
- View/download PDF
258. Effect of rare-earth cerium on microstructure and wear resistance of Ni-based alloy laser-cladded coating
- Author
-
Zhang, Qingbo, primary, Wang, Kunlin, additional, Sun, Manlong, additional, and Wei, Xing G., additional
- Published
- 1996
- Full Text
- View/download PDF
259. Colloidal Antireflection Coating Improves Graphene–SiliconSolar Cells.
- Author
-
Shi, Enzheng, Li, Hongbian, Yang, Long, Zhang, Luhui, Li, Zhen, Li, Peixu, Shang, Yuanyuan, Wu, Shiting, Li, Xinming, Wei, Jinquan, Wang, Kunlin, Zhu, Hongwei, Wu, Dehai, Fang, Ying, and Cao, Anyuan
- Published
- 2013
- Full Text
- View/download PDF
260. Light-Induced Modulation in Resistance Switching of Carbon Nanotube/BiFeO 3 /Pt Heterostructure.
- Author
-
Chen, Yu, Zang, Yongyuan, Xie, Dan, Wu, Xiao, Ren, Tianling, Wei, Jinquan, Wang, Kunlin, Wu, Dehai, and Zhu, Hongwei
- Subjects
ELECTRONIC modulation ,HETEROSTRUCTURES ,PLATINUM isotopes ,PACKET switching ,RAMAN microscopy ,SEMICONDUCTOR junctions - Abstract
We report a light-induced modulation effect in resistance switching of proposed carbon nanotube (CNT)/BiFeO3/Pt heterostructure. XRD, Raman, SEM, and AFM measurements confirm the quality of the BiFeO3 and CNT thin films achieved. Photovoltaic and resistance switching effects are identified in the proposed device structure. Resistance switching upon forward bias can be obviously modulated with light illumination. Dual asymmetric junctions in the heterojunction can be addressed as a critical factor. Our work indicates that CNT/BiFeO3/Pt heterostructure can be utilized in the light-coupled memory and I/O related applications. [ABSTRACT FROM AUTHOR]
- Published
- 2012
- Full Text
- View/download PDF
261. Light-Induced Modulation in Resistance Switching of Carbon Nanotube/ BiFeO 3 /Pt Heterostructure.
- Author
-
Chen, YU, Zang, Yongyuan, Xie, Dan, Wu, Xiao, Ren, Tianling, Wei, Jinquan, Wang, Kunlin, Wu, Dehai, and Zhu, Hongwei
- Subjects
ELECTRONIC modulation ,ELECTRIC resistors ,RAMAN effect ,PHOTOVOLTAIC effect ,THIN films ,BISMUTH iron oxide - Abstract
We report a light-induced modulation effect in resistance switching of proposed carbon nanotube (CNT)/BiFeO3/Pt heterostructure. XRD, Raman, SEM, and AFM measurements confirm the quality of the BiFeO3 and CNT thin films achieved. Photovoltaic and resistance switching effects are identified in the proposed device structure. Resistance switching upon forward bias can be obviously modulated with light illumination. Dual asymmetric junctions in the heterojunction can be addressed as a critical factor. Our work indicates that CNT/BiFeO3/Pt heterostructure can be utilized in the light-coupled memory and I/O related applications. [ABSTRACT FROM AUTHOR]
- Published
- 2012
- Full Text
- View/download PDF
262. Graphene-CdSe nanobelt solar cells with tunable configurations.
- Author
-
Zhang, Luhui, Fan, Lili, Li, Zhen, Shi, Enzheng, Li, Xinming, Li, Hongbian, Ji, Chunyan, Jia, Yi, Wei, Jinquan, Wang, Kunlin, Zhu, Hongwei, Wu, Dehai, and Cao, Anyuan
- Abstract
We have combined two planar nanostructures, graphene and CdSe nanobelts, to construct Schottky junction solar cells with open-circuit voltages of about 0.5 V and cell efficiencies on the order of 0.1%. By covering transparent graphene or carbon nanotube (CNT) films on selected positions along macroscopically long CdSe nanobelts, we have demonstrated the fabrication of active solar cells with many different configurations and parallel connections from individual or multiple assembled nanobelts. The graphene-CdSe nanobelt solar cells reported here show a great flexibility in creating diverse device architectures, and might be scaled up for cell integration based on assembled nanobelt arrays and patterned graphene (or CNT) films. [Figure not available: see fulltext.] [ABSTRACT FROM AUTHOR]
- Published
- 2011
- Full Text
- View/download PDF
263. Fabrication of silicon microwire arrays for photovoltaic applications.
- Author
-
Guo, Ning, Wei, Jinquan, Shu, Qinke, Jia, Yi, Li, Zhen, Zhang, Kun, Zhu, Hongwei, Wang, Kunlin, Song, Shuang, Xu, Ying, and Wu, Dehai
- Subjects
FIBERS ,SILICON ,PHOTOVOLTAIC cells ,PHOTOLITHOGRAPHY ,ETCHING techniques ,OXIDATION ,NANOWIRES ,HETEROJUNCTIONS - Abstract
novel method of combining photolithography, wet chemical etching and oxidation process was proposed to fabricate large area of silicon microwire (SiMW) arrays. The dimensions of the SiMWs can be easily controlled by photomask and etching conditions. Solar cells based on the heterojunction between SiMW and double-walled carbon nanotubes (DWNTs) were constructed. The initial test on the DWNT/SiMW shows efficiency ( η) of 0.59%. By adding a few drops of HBr/B electrolyte, the efficiency was improved to 1.96% with J=19.2 mA/cm and V=0.35 V, FF=29.2%, showing the potential of SiMWs in photovoltaic applications. [ABSTRACT FROM AUTHOR]
- Published
- 2011
- Full Text
- View/download PDF
264. Laser marking of stainless steel with a Q-switched Nd:YAG laser.
- Author
-
Qi, Jun, Wang, Kunlin, Liang, Mianchang, Zhu, Yunming, and Fang, Minggang
- Published
- 1998
- Full Text
- View/download PDF
265. Synthesis, field emission and microwave absorption of carbon nanotubes filled with ferromagnetic nanowires.
- Author
-
Lv, RuiTao, Kang, FeiYu, Gu, JiaLin, Wang, KunLin, and Wu, DeHai
- Abstract
Carbon nanotubes filled with ferromagnetic metal nanowires (M-CNTs) were synthesized by using chlorine-contained benzene (e.g. trichlorobenzene) as precursor. The wall thicknesses of M-CNTs synthesized by trichlorobenzene are much thinner than those by precursor without Cl (e.g. benzene). As-synthesized thin-walled M-CNTs exhibit remarkably enhanced field electron emission performance with a low turn-on field of 0.3 V/μm and better field-emission stability. Microwave-absorption coatings were made by dispersing as-synthesized M-CNTs into epoxy resin matrix. It is found that the reflection losses in S-band (2-4 GHz), C-band (4-8 GHz) and X-band (8-12 GHz) are enhanced in the order of FeCoNi-CNTs < FeNi-CNTs< FeCo-CNTs. The areal density of as-prepared coatings is only 2.35 kg/m when the coating thickness is 2.0 mm. This demonstrates that M-CNTs are promising to be used as lightweight and wide-band microwave absorbers. [ABSTRACT FROM AUTHOR]
- Published
- 2010
- Full Text
- View/download PDF
266. The decisive roles of chlorine-contained precursor and hydrogen for the filling Fe nanowires into carbon nanotubes
- Author
-
Gui, Xuchun, Wang, Kunlin, Wang, Wenxiang, Wei, Jinquan, Zhang, Xianfeng, Lv, Ruitao, Jia, Yi, Shu, Qinke, Kang, Feiyu, and Wu, Dehai
- Subjects
- *
CARBON nanotubes , *NANOWIRES , *CHEMICAL vapor deposition , *INORGANIC synthesis , *ELECTRON spectroscopy , *THERMOGRAVIMETRY - Abstract
Abstract: Fe-filled thin-walled carbon nanotubes (CNTs) were synthesized by chemical vapor deposition. Dichlorobenzene/ferrocene solution was used both for carbon source as well as Fe source. Chlorine-contained precursor is in favor of the fabrication of thin-walled CNTs. The productive HCl in the reaction ambient could etch the CNT wall and growth front-end. Auger electron spectroscopy (AES) results indicated that the Cl atoms were almost entirely carried away by the carrier gas. Thermogravimetric analysis (TGA) showed that the filling rate of the Fe-filled thin-walled CNTs could be adjusted by controlling the flow rate of H2. [Copyright &y& Elsevier]
- Published
- 2009
- Full Text
- View/download PDF
267. Light emission of double-walled carbon nanotube filaments doped with yttrium and europium.
- Author
-
Shu, QinKe, Wang, KunLin, Wei, JinQuan, Zhu, HongWei, Li, XinMing, Chen, Xi, Jia, Yi, Gui, XuChun, Xu, ErYang, and Wu, DeHai
- Abstract
As the potential applications of carbon nanotubes in the field of electroluminescence, elements yttrium and europium were introduced to modify the emission properties of double-walled carbon nanotubes (DWNTs) to obtain higher efficacy and other properties. The light emission spectrum of the Y-Eu-doped DWNT filament is suppressed in the near-infrared range, while enhanced in the mid-infrared range. The doped DWNT filament can reach higher efficacy than that of the pure DWNT filament at the same input power and can work stably as long as 5000 h at 12 V. These filaments could be useful for the light sources with special functions, such as infrared light sources operated at low input power. [ABSTRACT FROM AUTHOR]
- Published
- 2009
- Full Text
- View/download PDF
268. Microwave absorbing properties and magnetic properties of different carbon nanotubes.
- Author
-
Gui, XuChun, Wang, KunLin, Wei, JinQuan, Lü, RuiTao, Shu, QinKe, Jia, Yi, Wang, Chen, Zhu, HongWei, and Wu, DeHai
- Abstract
The microwave absorbing properties and magnetic properties of as-grown Fe-filled carbon nanotubes (CNTs), annealed Fe-filled CNTs, and multi-walled CNTs were studied. Vibrating sample magnetometer results showed that the annealed Fe-filled CNTs have the weakest coercivity and strongest saturation magnetization among the three types CNTs, due to the presence of more ferromagnetic α-Fe nanowires. After annealing, the values increased to 291.0 Oe and 28.0 emu/g and the samples showed excellent microwave absorbing properties. The reflection loss was over 5 dB between 11.6 GHz and 18 GHz with a maximum value of 10.8 dB for annealed Fe-filled CNTs (1.1 wt%)/epoxy composite. [ABSTRACT FROM AUTHOR]
- Published
- 2009
- Full Text
- View/download PDF
269. Tensile properties of ultrathin double-walled carbon nanotube membranes
- Author
-
Gu, Zhiyi, Wang, Kunlin, Wei, Jinquan, Li, Chuangang, Jia, Yi, Wang, Zhicheng, Luo, Jianbin, and Wu, Dehai
- Subjects
- *
CARBON , *NANOTUBES , *DEFORMATIONS (Mechanics) , *ELASTICITY , *FRACTURE mechanics , *STRENGTH of materials - Abstract
Abstract: Direct tensile tests of double walled carbon nanotube (DWCNT) membranes with thickness of 40–80nm were performed using a micro-stress-strain puller. The tensile strength and Young’s modulus are 4.8E2–8.4E2MPa and 4.4–8.8GPa, respectively. The deformation and fracture processes were analyzed using the stress vs. strain curves, and SEM observations of the fracture surface of a membrane. The membrane experienced elastic strain and plastic strain during tensile-loading to fracture, and the plastic process is due to the real plastic deformation of the membrane and the slippage between the DWCNT bundles. Cracks occur and spread during the tensile test which causes the membrane to be mangled. With these excellent mechanical properties, the DWCNT membranes can be used in nanotube-reinforced composites. [Copyright &y& Elsevier]
- Published
- 2006
- Full Text
- View/download PDF
270. Tensile properties of long aligned double-walled carbon nanotube strands
- Author
-
Li, Yijun, Wang, Kunlin, Wei, Jinquan, Gu, Zhiyi, Wang, Zhicheng, Luo, Jianbin, and Wu, Dehai
- Subjects
- *
NANOTUBES , *CARBON , *STRAINS & stresses (Mechanics) , *ELASTICITY , *COMPOSITE materials - Abstract
Abstract: The mechanical properties of well-aligned double-walled carbon nanotube (DWNT) strands with diameters of 3–20μm and lengths of ∼10mm were measured using a stress–strain puller. The average tensile strength and Young’s modulus of the tested strands are 1.2GPa and 16GPa, respectively. Deformation and fracture processes of these samples are discussed. The tensile strength and Young’s modulus of an individual DWNT bundle were estimated, with values comparable to those of SWNT bundles. The superior mechanical strengths of our as-prepared DWNT strands are expected to give them potential as a high-strength material and a reinforcement in composites. [Copyright &y& Elsevier]
- Published
- 2005
- Full Text
- View/download PDF
271. Selective Ion Transport through Functionalized Graphene Membranes Based on Delicate Ion–Graphene Interactions
- Author
-
Sun, Pengzhan, Liu, He, Wang, Kunlin, Zhong, Minlin, Wu, Dehai, and Zhu, Hongwei
- Abstract
Recently, graphene oxide (GO) membranes have been reported with the ability to separate different solutes in aqueous suspensions by a molecular sieving effect. On the other hand, we propose that the chemical interactions between ions and GO membranes might also take effect in selective ion transmembrane transportation. In this paper, on the basis of the permeation of Cu2+and Mg2+sources through hydroxyl-, carboxyl-, and amino-functionalized graphene membranes, the delicate ion–graphene interactions which might be responsible for the selective ion permeation are investigated. We demonstrate experimentally that the coordination between transition-metal cations and carboxyl functionalities and the cation−π interactions between main-group cations and sp2regions are responsible for the selective transport of small ions through graphene-based membranes, which is beyond the scope of molecular sieving effect proposed previously. Notably, by grafting amino groups onto the graphene basal planes, the permeations of Cu2+and Mg2+cations are both weakened. These results not only throw light upon the mechanism for the selective ion permeation through graphene-based membranes but also lay a foundation for the separation of target ions by grafting specific functionalities.
- Published
- 2014
- Full Text
- View/download PDF
272. Core-Double-Shell, Carbon Nanotube@Polypyrrole@MnO2Sponge as Freestanding, Compressible Supercapacitor Electrode
- Author
-
Li, Peixu, Yang, Yanbing, Shi, Enzheng, Shen, Qicang, Shang, Yuanyuan, Wu, Shiting, Wei, Jinquan, Wang, Kunlin, Zhu, Hongwei, Yuan, Quan, Cao, Anyuan, and Wu, Dehai
- Abstract
Design and fabrication of structurally optimized electrode materials are important for many energy applications such as supercapacitors and batteries. Here, we report a three-component, hierarchical, bulk electrode with tailored microstructure and electrochemical properties. Our supercapacitor electrode consists of a three-dimensional carbon nanotube (CNT) network (also called sponge) as a flexible and conductive skeleton, an intermediate polymer layer (polypyrrole, PPy) with good interface, and a metal oxide layer outside providing more surface area. These three components form a well-defined core-double-shell configuration that is distinct from simple core-shell or hybrid structures, and the synergistic effect leads to enhanced supercapacitor performance including high specific capacitance (even under severe compression) and excellent cycling stability. The mechanism study reveals that the shell sequence is a key factor; in our system, the CNT–PPy–MnO2structure shows higher capacitance than the CNT–MnO2–PPy sequence. Our porous core-double-shell sponges can serve as freestanding, compressible electrodes for various energy devices.
- Published
- 2014
- Full Text
- View/download PDF
273. Selective Trans-Membrane Transport of Alkali and Alkaline Earth Cations through Graphene Oxide Membranes Based on Cation−π Interactions
- Author
-
Sun, Pengzhan, Zheng, Feng, Zhu, Miao, Song, Zhigong, Wang, Kunlin, Zhong, Minlin, Wu, Dehai, Little, Reginald B., Xu, Zhiping, and Zhu, Hongwei
- Abstract
Graphene and graphene oxide (G–O) have been demonstrated to be excellent filters for various gases and liquids, showing potential applications in areas such as molecular sieving and water desalination. In this paper, the selective trans-membrane transport properties of alkali and alkaline earth cations through a membrane composed of stacked and overlapped G–O sheets (“G–O membrane”) are investigated. The thermodynamics of the ion transport process reveal that the competition between the generated thermal motions and the interactions of cations with the G–O sheets results in the different penetration behaviors to temperature variations for the considered cations (K+, Mg2+, Ca2+, and Ba2+). The interactions between the studied metal atoms and graphene are quantified by first-principles calculations based on the plane-wave-basis-set density functional theory (DFT) approach. The mechanism of the selective ion trans-membrane transportation is discussed further and found to be consistent with the concept of cation−π interactions involved in biological systems. The balance between cation−π interactions of the cations considered with the sp2clusters of G–O membranes and the desolvation effect of the ions is responsible for the selectivity of G–O membranes toward the penetration of different ions. These results help us better understand the ion transport process through G–O membranes, from which the possibility of modeling the ion transport behavior of cellular membrane using G–O can be discussed further. The selectivity toward different ions also makes G–O membrane a promising candidate in areas of membrane separations.
- Published
- 2014
- Full Text
- View/download PDF
274. A Low-Complexity Beamformer for Ultrasound Imaging Based on Sub-Beamformer and Multi-Apodization With Cross-Correlation.
- Author
-
Shen, Yue, Wang, Ping, Tong, Lin, Chen, Jinghan, Li, Qianwen, Zhu, Jinchan, Wang, Kunlin, and Zeng, Jingya
- Subjects
- *
MATRIX inversion , *ULTRASONIC imaging , *CROSS correlation , *IMAGING systems , *COVARIANCE matrices - Abstract
This paper proposes an ultrasound imaging algorithm based on sub-beamformer and multi-apodization with cross-correlation (SUB-MAX), aiming to achieve high resolution close to the minimum variance (MV) beamforming with low complexity and to enhance image contrast while maintaining background quality. The output of two (N /2)-element DAS beamformers with asymmetric phase centers is subtracted, resulting in a large drop in the main-lobe amplitude, while the sidelobe maintains a relatively high amplitude level. Inspired by this characteristic, the coefficients with opposite trends compared with the subtracted output are obtained and fused with the normalized cross-correlation (NCC) weighting matrix acquired by using multi-pair received apodization, the proposed SUB-MAX obtains a new weighting matrix to weight the output of the DAS beamformer. For ats_wire point targets, the average full-width at half-maximum (FWHM) of SUB-MAX compared with DAS, DMAS, CF, and MAX decreases by 52.7%, 43.5%, 33.3%, and 52.7%, respectively. For geabr_0 cysts, the average contrast ratio (CR) of SUB-MAX compared with DAS, MV, DMAS, and CF increases by 57.7%, 86.8%, 2.5%, and 14.4%, respectively. Experiments on rat_tumor dataset also indicate that SUB-MAX has a superior comprehensive imaging performance. The experimental results indicate that the superior comprehensive imaging performance of the proposed SUB-MAX is expected to be suitable for real-time imaging systems due to its non-reliance on covariance matrix inversion. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
275. Small Temperature Coefficient of Resistivity of Graphene/Graphene Oxide Hybrid Membranes
- Author
-
Sun, Pengzhan, Zhu, Miao, Wang, Kunlin, Zhong, Minlin, Wei, Jinquan, Wu, Dehai, and Zhu, Hongwei
- Abstract
Materials with low temperature coefficient of resistivity (TCR) are of great importance in some areas, for example, highly accurate electronic measurement instruments and microelectronic integrated circuits. In this work, we demonstrated the ultrathin graphene–graphene oxide (GO) hybrid films prepared by layer-by-layer assembly with very small TCR (30–100 °C) in the air. Electrical response of the hybrid films to temperature variation was investigated along with the progressive reduction of GO sheets. The mechanism of electrical response to temperature variation of the hybrid film was discussed, which revealed that the interaction between graphene and GO and the chemical doping effect were responsible for the tunable control of its electrical response to temperature variation. The unique properties of graphene–GO hybrid film made it a promising candidate in many areas, such as high-end film electronic device and sensor applications.
- Published
- 2013
- Full Text
- View/download PDF
276. Highly Twisted Double-Helix Carbon Nanotube Yarns
- Author
-
Shang, Yuanyuan, Li, Yibin, He, Xiaodong, Du, Shanyi, Zhang, Luhui, Shi, Enzheng, Wu, Shiting, Li, Zhen, Li, Peixu, Wei, Jinquan, Wang, Kunlin, Zhu, Hongwei, Wu, Dehai, and Cao, Anyuan
- Abstract
The strength and flexibility of carbon nanotubes (CNTs) allow them to be constructed into a variety of innovated architectures with fascinating properties. Here, we show that CNTs can be made into a highly twisted yarn-derived double-helix structure by a conventional twist-spinning process. The double-helix is a stable and hierarchical configuration consisting of two single-helical yarn segments, with controlled pitch and unique mechanical properties. While one of the yarn components breaks early under tension due to the highly twisted state, the second yarn produces much larger tensile strain and significantly prolongs the process until ultimate fracture. In addition, these elastic and conductive double-helix yarns show simultaneous and reversible resistance change in response to a wide range of input sources (mechanical, photo, and thermal) such as applied strains or stresses, light illumination, and environmental temperature. Our results indicate that it is possible to create higher-level, more complex architectures from CNT yarns and fabricate multifunctional nanomaterials with potential applications in many areas.
- Published
- 2013
- Full Text
- View/download PDF
277. Selective Ion Penetration of Graphene Oxide Membranes
- Author
-
Sun, Pengzhan, Zhu, Miao, Wang, Kunlin, Zhong, Minlin, Wei, Jinquan, Wu, Dehai, Xu, Zhiping, and Zhu, Hongwei
- Abstract
The selective ion penetration and water purification properties of freestanding graphene oxide (GO) membranes are demonstrated. Sodium salts permeated through GO membranes quickly, whereas heavy-metal salts infiltrated much more slowly. Interestingly, copper salts were entirely blocked by GO membranes, and organic contaminants also did not infiltrate. The mechanism of the selective ion-penetration properties of the GO membranes is discussed. The nanocapillaries formed within the membranes were responsible for the permeation of metal ions, whereas the coordination between heavy-metal ions with the GO membranes restricted the passage of the ions. Finally, the penetration processes of hybrid aqueous solutions were investigated; the results revealed that sodium salts can be separated effectively from copper salts and organic contaminants. The presented results demonstrate the potential applications of GO in areas such as barrier separation and water purification.
- Published
- 2013
- Full Text
- View/download PDF
278. Superlow Thermal Conductivity 3D Carbon Nanotube Network for Thermoelectric Applications
- Author
-
Chen, Jikun, Gui, Xuchun, Wang, Zewei, Li, Zhen, Xiang, Rong, Wang, Kunlin, Wu, Dehai, Xia, Xugui, Zhou, Yanfei, Wang, Qun, Tang, Zikang, and Chen, Lidong
- Abstract
Electrical and thermal transportation properties of a novel structured 3D CNT network have been systematically investigated. The 3D CNT net work maintains extremely low thermal conductivity of only 0.035 W/(m K) in standard atmosphere at room temperature, which is among the lowest compared with other reported CNT macrostructures. Its electrical transportation could be adjusted through a convenient gas-fuming doping process. By potassium (K) doping, the original p-type CNT network converted to n-type, whereas iodine (I2) doping enhanced its electrical conductivity. The self-sustainable homogeneous network structure of as-fabricated 3D CNT network made it a promising candidate as the template for polymer composition. By in situ nanoscaled composition of 3D CNT network with polyaniline (PANI), the thermoelectric performance of PANI was significantly improved, while the self-sustainable and flexible structure of the 3D CNT network has been retained. It is hoped that as-fabricated 3D CNT network will contribute to the development of low-cost organic thermoelectric area.
- Published
- 2012
- Full Text
- View/download PDF
279. Light-induced Current in Long Carbon Nanotubes
- Author
-
Wei, Jinquan, Wu, Dehai, Wang, Zhicheng, Luo, Jianbin, and Wang, Kunlin
- Abstract
Evident light-induced current through a long carbon nanotubes (CNTs) bundle was observed when it was induced by a laser from visible to far infrared. The property of the photocurrent is negative for SWNTs, while it is always positive for MWNTs. The photocurrent of the CNTs is strongly influenced by the power and wavelength of the light. The response time of the photocurrent for the SWNTs is much faster than those for the MWNTs.
- Published
- 2007
280. Direct compression tablet formulation of celecoxib enabled with a pharmaceutical solvate.
- Author
-
Wang, Kunlin and Sun, Changquan Calvin
- Subjects
- *
CELECOXIB , *TABLETING , *CYCLOOXYGENASE inhibitors , *DIMETHYL sulfoxide , *ANTI-inflammatory agents - Abstract
Celecoxib, an anti-inflammatory drug for pain and arthritis, is currently only available in capsule form. To reduce the onset time for a faster action and to lower the manufacturing cost, the tablet dosage form is more preferred. However, the commercial celecoxib (Form III) is not suitable for direct compression (DC) tablet manufacture due to poor flow, low bulk density, and tablet lamination. In this work, we overcome these challenges using a pharmaceutically acceptable dimethyl sulfoxide (DMSO) solvate of celecoxib. Aided with the DMSO solvate, an acceptable DC tablet formulation was successfully developed to manufacture tablets containing 200 mg celecoxib, with satisfactory manufacturability, disintegration, and in vitro dissolution performance. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
281. Enabling Direct Compression Tablet Development Of Celecoxib Through Solid State Engineering
- Author
-
Wang, Kunlin
- Subjects
- Amorphous, Celecoxib, Crystal engineering, Direct compression, Structure-property relationship, Tablet
- Abstract
Tablets are the most desirable solid oral dosage form for patients. Direct compression (DC) tablet formulation is the most economical, robust and efficient way of tablet manufacture. Being sensitive to properties of the Active Pharmaceutical Ingredient (API), direct compression tablet formulation is not available for the high dose non-steroidal anti-inflammatory drug, celecoxib (CEL) due to the undesirable properties of the commercial solid form of CEL, including low bulk density, poor flowability and tablet lamination issues. The solid form used in commercially available CEL capsules is a polymorph of CEL, Form III. Form III CEL is a needle shaped crystal, which is exceptionally elastic. This high elasticity, verified by nanoindentation and three-point bending tests, is unfavorable for good tablet quality and performance during high speed tableting. Through understanding the molecular interactions by analyzing the CEL crystal structure, a structural model for high elasticity is built and validated by Raman spectroscopy. Interlocked molecular packing without slip plane and the presence of isotropic hydrogen bond network are major structural features responsible for both the exceptional elastic flexibility and high stiffness of the CEL crystal. CEL Form III exhibits unsatisfactory flowability and tablet lamination issues for DC tablet manufacturing. Pharmaceutically acceptable solvates of CEL offer better flow, compaction and dissolution properties than CEL Form III. Two stoichiometric solvates of CEL and N-methyl-2-pyrrolidone (NMP) are extensively characterized and examined, which establishes a clear crystal structure-property relationship essential for crystal engineering of CEL. Through crystal engineering, a DC tablet formulation of CEL is successfully developed using the dimethyl sulfoxide (DMSO) solvate of CEL. This pharmaceutically acceptable solvate is highly stable and also exhibited much improved manufacturability compared to CEL Form III, including better flowability, lower elasticity and bulk density (superior tablet quality) as well as better dissolution performance. As a Class II drug in the biopharmaceutics classification system with low solubility and high permeability, the high dose of CEL is partially attributed to its limited solubility. Amorphous CEL, although providing solubility advantages as the thermodynamically high energy state, is unstable and prone to crystallization. The study of crystal growth of amorphous CEL reveals a fast glass-to-crystal growth mode at room temperature with a surface-enhanced mechanism. This paves the way for future development of a stable amorphous solid dispersion tablet product of CEL with improved dissolution performance and tablet manufacturability. In summary, by understanding the structural origin of undesired properties of CEL, successful development of the most patient-compliant tablet dosage form by direct compression can be achieved. This sets an excellent example of utilizing a solid state engineering approach to effectively overcome challenges encountered in direct compression tablet development.
- Published
- 2020
282. Correlation between visceral fat area and carotid atherosclerotic plaque in patients with type 2 diabetes mellitus
- Author
-
XU Haibo*, ZAI Guotian, TANG Wei, WANG Kunlin
- Subjects
type 2 diabetes mellitus, atherosclerosis, obesity,visceral fat area, abdominal subcutaneous fat area, body mass index, waist circumference ,Medicine - Abstract
"Objective To investigate the effect of visceral fat area (VFA) on carotid atherosclerotic plaque in patients with type 2 diabetes mellitus(T2DM). Methods From August 2018 to August 2023, 683 T2DM patients included in the database of the National Metabolic Management Center (MMC) were selected from the Department of Endocrinology, the Affiliated Geriatric Hospital of Nanjing Medical University. Medical history, physical examination, serum biochemical indicators, VFA and other data were collected from the study subjects. According to the presence or absence of carotid atherosclerotic plaque, all patients were divided into T2DM patients with plaque (n=342) and T2DM patients without plaque (n=341), and statistical analysis was performed. Results There were statistically significant differences in age, body mass index (BMI), waist circumference, diastolic blood pressure (DBP), total cholesterol (TC), low-density lipoprotein cholesterol (LDL-C), high-density lipoprotein cholesterol (HDL-C), abdominal subcutaneous fat area (SFA) and VFA between the two groups (PConclusion Age and VFA are independent influencing factors for atherosclerotic plaque formation in patients with T2DM,and as a new obesity assessment index, VFA can better predict and assess the risk of atherosclerotic plaque formation in T2DM patients."
- Published
- 2024
- Full Text
- View/download PDF
283. Correction to Crystal Growth of Celecoxib from Amorphous State: Polymorphism, Growth Mechanism, and Kinetics.
- Author
-
Wang, Kunlin and Sun, Changquan Calvin
- Published
- 2019
- Full Text
- View/download PDF
284. Current application of in-hospital informatized glucose monitoring system in Jiangsu
- Author
-
ZHANG Zicheng*, YANG Longxuan, ZHU Xiangyu, WANG Kunlin, YU Yun, LIU Dongmei, MO Yongzhen, TANG Wei
- Subjects
informatized glucose monitoring system,blood glucose data,real-time display, cloud sharing, blood glucose management,regional distribution, distribution of medical units, satisfaction ,Medicine - Abstract
"Objective To investigate the application of in-hospital informatized blood glucose monitoring system (IGMS) in Jiangsu and the satisfaction of medical staff to use IGMS. Methods From August 2021 to July 2022, a survey was conducted among medical staff in 119 secondary and tertiary hospitals in Jiangsu Province. The survey included questions on the application status of IGMS, such as the year of initiation and the medical units using it, and the satisfaction with the use of IGMS in medical staff was investigated by a 5-level Likert scale. Results (1) Utilization rate of IGMS: among the 119 hospitals, 58 (48.7%) utilized IGMS. The utilization rate in Southern Jiangsu (61.0%) was significantly higher than that in Central Jiangsu (34.8%) and Northern Jiangsu (37.8%) (χ2=7.113,P=0.029). (2) Distribution of medical units using IGMS: utilization rate in internal medicine department (96.6%) was significantly higher than that in surgical department (51.7%) and ICU (39.7%) (χ2=44.550,P<0.01), with the highest utilization rate observed in endocrinology department (96.6%). (3) Satisfaction survey: the satisfaction scale had a Cronbach's alpha of 0.702 and a KMO value of 0.742, and Bartlett's sphericity test yielded aχ2 value of 298.268 (P<0.01). Two initial factors with eigenvalues greater than 1 accounted for 72.5% of the variance. Following a scree plot analysis, two factors were extracted ,and the items were deleted according to the reliability and validity, and the satisfaction scale containing two factors and seven items was finally determined. Ninety-seven medical staff completed the scale with a score of 29.0 (25.5, 31.0). There was no significant difference in personal satisfaction with IGMS among medical staff in different regions, hospitals of grades and titles (P>0.05). Conclusion The utilization rate of IGMS in secondary and tertiary hospitals in Jiangsu is approximately 48.7%, with a higher rate in Southern Jiangsu. Endocrinology departments have the highest rate of IGMS usage. Medical staff are satisfied with the use of IGMS, and put forward higher expectations for the stability of networking and the standardization of training."
- Published
- 2024
- Full Text
- View/download PDF
285. Strain Sensors: Large-Area Ultrathin Graphene Films by Single-Step Marangoni Self-Assembly for Highly Sensitive Strain Sensing Application (Adv. Funct. Mater. 9/2016).
- Author
-
Li, Xinming, Yang, Tingting, Yang, Yao, Zhu, Jia, Li, Li, Alam, Fakhr E., Li, Xiao, Wang, Kunlin, Cheng, Huanyu, Lin, Cheng‐Te, Fang, Ying, and Zhu, Hongwei
- Subjects
MATERIALS periodicals - Abstract
High sensitivity, transparent, flexible strain sensors based on ultrathin graphene films are demonstrated by C.‐T. Lin, Y. Fang, H. Zhu, and co‐workers on page 1322. The cost‐effective, ultrathin graphene films are fabricated at the liquid/air interface due to the Marangoni effect. This novel approach makes graphene a promising material for electronic skin, wearable sensors, and health monitoring platforms. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
286. Graphene: High Detectivity Graphene-Silicon Heterojunction Photodetector (Small 5/2016).
- Author
-
Li, Xinming, Zhu, Miao, Du, Mingde, Lv, Zheng, Zhang, Li, Li, Yuanchang, Yang, Yao, Yang, Tingting, Li, Xiao, Wang, Kunlin, Zhu, Hongwei, and Fang, Ying
- Published
- 2016
- Full Text
- View/download PDF
287. Highly selective charge-guided ion transport through a hybrid membrane consisting of anionic graphene oxide and cationic hydroxide nanosheet superlattice units
- Author
-
Sun, Pengzhan, Ma, Renzhi, Ma, Wei, Wu, Jinghua, Wang, Kunlin, Sasaki, Takayoshi, and Zhu, Hongwei
- Abstract
The development of graphene-based functional membranes with the ability to effectively filter and separate molecules or ions in solutions based on a simple criterion (for example, the size or charge of solutes) is crucial for various engineering-relevant applications, ranging from wastewater purification and reuse to chemical refinement. Here, we report a hybrid membrane consisting of anionic graphene oxide (GO) and cationic Co-Al (or Mg-Al) layered double hydroxide (LDH) nanosheet (NS) superlattice units for high selectivity charge-guided ion transport. The hybrid membrane possesses a series of characteristics, including being easy to access, mechanically robust, freestanding, flexible and semitransparent as well as having a large area. The interlayer spacing of the hybrid membrane is insensitive to humidity variations, ensuring the structural stability in solution-based mass transport applications. The concentration gradient-driven ion transmembrane diffusion experiments show that the cations bearing various valences can be effectively separated strictly according to their charges, independent of the cationic and charge-balancing anionic species. The relative selectivity of the hybrid membranes toward monovalent and trivalent cations is as high as 30, which is not achievable by GO multilayer stacks, LDH-NS multilayer stacks or their bulk-stratified membranes, indicating that a synergistic effect originating from the molecular-level heteroassembly of GO and LDH-NS has a dominant role in the high-performance charge-guided ion filtration and separation processes. These excellent properties of GO/LDH-NS hybrid membranes make them promising candidates in diverse applications, ranging from wastewater treatment and reuse and chemical refinement to biomimetic selective ion transport.
- Published
- 2016
- Full Text
- View/download PDF
288. Enhanced Transport of Nanoparticles Across a Porous Nanotube Sponge.
- Author
-
Li, Hongbian, Gui, Xuchun, Zhang, Luhui, Ji, Chunyan, Zhang, Yichi, Sun, Pengzhan, Wei, Jinquan, Wang, Kunlin, Zhu, Hongwei, Wu, Dehai, and Cao, Anyuan
- Subjects
ABSORPTION spectra ,NANOPARTICLES ,NANOTUBES - Abstract
A correction to the article "Enhanced Transport of Nanoparticles Across a Porous Nanotube Sponge" that was published in a 2011 issue is presented.
- Published
- 2014
- Full Text
- View/download PDF
289. Highly efficient quasi-static water desalination using monolayer graphene oxide/titania hybrid laminates
- Author
-
Sun, Pengzhan, Chen, Qiao, Li, Xinda, Liu, He, Wang, Kunlin, Zhong, Minlin, Wei, Jinquan, Wu, Dehai, Ma, Renzhi, Sasaki, Takayoshi, and Zhu, Hongwei
- Abstract
By intercalating monolayer titania (TO) nanosheets into graphene oxide (GO) laminates with mild ultraviolet (UV) reduction, the as-prepared RGO/TO hybrid membranes exhibit excellent water desalination performances. Without external hydrostatic pressures, the ion permeations through the RGO/TO hybrid membranes can be reduced to <5% compared with the GO/TO cases, while the water transmembrane permeations, which are measured using an isotope-labeling technique, can be retained up to ~60%. The mechanism for the excellent water desalination performances of the RGO/TO hybrid laminates is discussed, which indicates that the photoreduction of GO by TO is responsible for the effective rejection of ions, while the photoinduced hydrophilic conversion of TO under UV irradiation is responsible for the well-retained water permeabilities. These excellent properties make RGO/TO hybrid membranes favorable for practical water desalination.
- Published
- 2015
- Full Text
- View/download PDF
290. Flexible graphene woven fabrics for touch sensing.
- Author
-
Lee, Xiao, Yang, Tingting, Li, Xiao, Zhang, Rujing, Zhu, Miao, Zhang, Hongze, Xie, Dan, Wei, Jinquan, Zhong, Minlin, Wang, Kunlin, Wu, Dehai, Li, Zhihong, and Zhu, Hongwei
- Subjects
GRAPHENE ,CHEMICAL vapor deposition ,ELECTRIC properties ,TACTILE sensors ,ELECTRODES - Abstract
Graphene woven fabric (GWF) prepared from chemical vapor deposition was used as smart self-sensing element to assemble piezoresistor through directly transferring onto the flexible substrate poly(dimethylsiloxane) (PDMS) with the deposited Ti/Au electrodes. A rational strategy was proposed to fabricate flexible touch sensors easily and effectively with the full usage of the mechanical and electrical properties of GWF, whose resistance is highly sensitive to macro-deformation or micro-defect. Compared to commercial and traditional touch sensing, the GWF-on-PDMS piezoresistor is structurally flexible that is demanded under special conditions and meanwhile makes the piezoresistor to have excellent durability. [ABSTRACT FROM AUTHOR]
- Published
- 2013
- Full Text
- View/download PDF
291. Ultrafast liquid water transport through graphene-based nanochannels measured by isotope labelling.
- Author
-
Sun, Pengzhan, Liu, He, Wang, Kunlin, Zhong, Minlin, Wu, Dehai, and Zhu, Hongwei
- Subjects
- *
MASS transfer , *WATER , *GRAPHENE , *PERMEATION tubes , *GRAPHENE oxide , *NANOTUBES , *ISOTOPES , *IONS - Abstract
Based on isotope labelling, we found that liquid water can afford an ultrafast permeation through graphene-based nanochannels with a diffusion coefficient 4–5 orders of magnitude greater than in the bulk case. When dissolving ions in sources, the diffusion coefficient of ions through graphene channels lies in the same order of magnitude as water, while the ion diffusion is slightly faster than water, indicating that the ions are mainly transported by water flows and the delicate interactions between ions and nanocapillary walls also take effect in the accelerated ion transportation. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
292. Anti-reflection graphene coating on metal surface.
- Author
-
Jiang, Xin, Cao, Yachang, Wang, Kunlin, Wei, Jinquan, Wu, Dehai, and Zhu, Hongwei
- Subjects
- *
GRAPHENE , *METALLIC surfaces , *METAL coating , *ELECTROCHEMICAL analysis , *METAL etching , *GRAPHENE oxide - Abstract
Electrochemical anisotropic etching, along with prior cathodic polarization during anodic etching, is used to form homogeneous antireflective (AR) structures on metal surfaces. Further electrophoretic deposition forms graphene oxide (GO) nanostructures. The graphene-based AR coating is achieved by electrochemical reduction of GO. Optical metal surfaces with high efficiency of light absorption and low reflectivity are obtained. Our results demonstrate the potential use of graphene in anti-reflection coating. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
293. Recyclable carbon nanotube sponges for oil absorption
- Author
-
Gui, Xuchun, Li, Hongbian, Wang, Kunlin, Wei, Jinquan, Jia, Yi, Li, Zhen, Fan, Lili, Cao, Anyuan, Zhu, Hongwei, and Wu, Dehai
- Subjects
- *
CARBON nanotubes , *CHEMICAL vapor deposition , *GRAPHITE , *ABSORPTION , *SPONGES (Invertebrates) , *FATS & oils , *HEAT - Abstract
Abstract: The recyclability of carbon nanotube (CNT) sponges in terms of oil absorption was studied. The sorption capacities of these sponges are greater than 100gg–1 for many organics and oils with viscosities of 3–200cP, and they maintain sorption capacities of 20–40gg–1 after 10 cycles of absorption. About 98% of absorbed oil can be recovered by squeezing or converted to heat by directly burning the oil within the sponges. The sorption process has been described by a second-order kinetic model. The results demonstrate that CNT sponges are promising oil sorbents with good recyclability. [Copyright &y& Elsevier]
- Published
- 2011
- Full Text
- View/download PDF
294. Ethanol flame synthesis of highly transparent carbon thin films
- Author
-
Li, Zhen, Zhu, Hongwei, Wang, Kunlin, Wei, Jinquan, Gui, Xuchun, Li, Xiao, Li, Chunyan, Fan, Lili, Sun, Pengzhan, and Wu, Dehai
- Subjects
- *
THIN films , *ETHANOL as fuel , *COPPER foil , *AIR masses , *FLAME , *ORGANIC synthesis - Abstract
Abstract: Large area (the order of centimeters), flexible thin films of amorphous carbon were prepared on copper foils by an ethanol flame synthesis method. The carbon films exhibit high transmittance in the visible and near infrared range (up to 90% at 550nm). Schottky diodes formed by combining the carbon films with n-type silicon wafers show high on/off ratio (up to 150) photocurrents at air-mass 1.5 and illumination intensity of 100mW/cm2. [Copyright &y& Elsevier]
- Published
- 2011
- Full Text
- View/download PDF
295. Doped carbon nanotube array with a gradient of nitrogen concentration
- Author
-
Xu, Eryang, Wei, Jinquan, Wang, Kunlin, Li, Zhen, Gui, Xuchun, Jia, Yi, Zhu, Hongwei, and Wu, Dehai
- Subjects
- *
CARBON nanotubes , *CHEMICAL vapor deposition , *NITROGEN , *PYROLYSIS , *XYLENE , *PYRIDINE , *MOLECULAR structure - Abstract
Abstract: Carbon nanotube (CNT) arrays doped with nitrogen were synthesized using chemical vapor deposition by pyrolysis of xylene/pyridine and ferrocene with a modified precursor feeding technique. The system produced a gradient of nitrogen concentration that modified the CNTs from a hollow cylinder to a bamboo-shaped structure which contains a series of compartments whose lengths are gradually reduced as the nitrogen concentration increases. [Copyright &y& Elsevier]
- Published
- 2010
- Full Text
- View/download PDF
296. Super-low turn-on and threshold electric fields of plasma-treated partly Fe-filled carbon nanotube films
- Author
-
Gui, Xuchun, Wei, Jinquan, Wang, Kunlin, Xu, Eryang, Lv, Ruitao, Zhu, Dan, Guo, Zhigang, Kang, Feiyu, Zhu, Yanqiu, Li, Dejie, Zhu, Hongwei, and Wu, Dehai
- Subjects
- *
CARBON nanotubes , *THIN films , *ELECTRIC fields , *NITROGEN plasmas , *NANOSTRUCTURES , *ELECTRIC properties of materials , *VAPOR-plating - Abstract
Abstract: Field emission properties of partly Fe-filled carbon nanotubes (FCNTs) treated with different plasmas have been studied. Super low turn-on (0.24V/μm) and threshold (0.6V/μm) electric fields are identified upon nitrogen plasma treatment for 60min. The field-enhancement factor, as high as 4.8×104, can be attributed to the plasma-induced structural defects and the unique characteristics of thin walled FCNTs with filled Fe nanowires. A model has been proposed to understand the effects of plasma on the CNTs. [Copyright &y& Elsevier]
- Published
- 2010
- Full Text
- View/download PDF
297. Fabrication and field emission properties of multi-walled carbon nanotube/silicon nanowire array
- Author
-
Qinke, Shu, Wei, Jinquan, Wang, Kunlin, Gui, Xuchun, Ma, Chaoran, Zhu, Hongwei, Jia, Yi, Li, Xinming, Guo, Ning, and Wu, Dehai
- Subjects
- *
MICROFABRICATION , *FIELD emission , *CARBON nanotubes , *NANOSILICON , *SEMICONDUCTOR wafers , *ETCHING , *NITRIC oxide , *CHEMICAL vapor deposition - Abstract
Abstract: Silicon nanowire (SiNW) arrays were fabricated on silicon wafers by the metal-assisted chemical etching method. Varied average diameters of SiNW arrays were realized through further treatment in a mixed agent of HF and HNO3 of certain concentrations. After the treatment, there were more than 93% SiNWs with diameters smaller than 100nm. The tip of each SiNW was subsequently wrapped with multi-walled carbon nanotubes (MWCNTs) with chemical vapor deposition method. The as-fabricated MWCNT/SiNW arrays were fabricated into electric field emitters, with turn-on field of 2.0V/μm (current density: 10μA/cm2), much lower than that of SiNW array (5.0V/μm). The turn-on electric field of MWCNT/SiNW array decreased with the decreasing of the average diameter of SiNWs, indicating the performance of the field emission is relative to the morphology of SiNWs. As the SiNW array is uniform in height and easy to fabricate, the MWCNT/SiNW array shows potential applications in flat electric display. [Copyright &y& Elsevier]
- Published
- 2010
- Full Text
- View/download PDF
298. Improved filling rate and enhanced magnetic properties of Fe-filled carbon nanotubes by annealing and magnetic separation
- Author
-
Gui, Xuchun, Wei, Jinquan, Wang, Kunlin, Wang, Wenxiang, Lv, Ruitao, Chang, Jianguo, Kang, Feiyu, Gu, Jialin, and Wu, Dehai
- Subjects
- *
CARBON nanotubes , *MAGNETIC separation , *MAGNETIC properties , *THERMOGRAVIMETRY , *NANOWIRES , *X-ray diffraction - Abstract
Abstract: The filling rate of Fe nanowires in carbon nanotubes (CNTs) was improved by a post-treatment which involved annealing and magnetic separation. The annealing process transformed γ-Fe to ferromagnetic α-Fe, resulting in α-Fe-filled CNTs with improved magnetic properties. The Fe-filled CNTs were then separated from those unfilled CNTs due to the different attractive forces under magnetic field. Thermal gravimetric analysis (TGA) revealed that the purity of CNTs was improved after magnetic separation and the filling rate can be up to 40.0wt.%, which is increased about 8.1% comparing with annealed CNTs. The saturation magnetization of CNTs reached 31.45emu/g after magnetic separation. [Copyright &y& Elsevier]
- Published
- 2008
- Full Text
- View/download PDF
299. Molecular complexes of drug combinations: A review of cocrystals, salts, coamorphous systems and amorphous solid dispersions.
- Author
-
Li, Jinghan, Wang, Xiyan, Yu, Dongyue, Zhoujin, Yunping, and Wang, Kunlin
- Subjects
- *
AMORPHOUS substances , *ITRACONAZOLE , *PATIENT compliance , *MEDICAL technology , *COMMUNICABLE diseases , *INTERMOLECULAR interactions , *DRUG delivery systems , *PILLS - Abstract
[Display omitted] As the advancements in the medical technology and healthcare develop through the years, combinational therapy has evolved to be an important treatment modality in many disease settings, including cancer, cardiovascular disease and infectious diseases. In an effort to alleviate "pill burden" and improve patient compliance, fixed dose combinations (FDCs) have been developed to be used as effective therapeutics. Among all FDCs, the category of drug-drug molecular complexes has been proven an efficient methodology in designing and treating diseases, with many drugs being approved. Among all drug-drug molecular complexes, drug-drug cocrystals, salts, coamorphous systems and solid dispersions have been successfully developed and many have been approved by the FDA. In this review, we dwell deeply into the molecular mechanisms behind the different types of drug-drug molecular complexes, including the key functional groups involved in the intermolecular interactions, the applications of each category of molecular complexes, as well as the advantages and challenges thereof. This comprehensive review provides useful insights into the practical design and manufacture of drug-drug molecular complexes and points out the future direction for the development of new advantageous combinational therapies that benefit more patients. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
300. Design and experimental study of a novel type water-filled submerged flexible bag wave energy converter.
- Author
-
Chen, Xinhui, Wei, Jianfeng, Sheng, Songwei, Wang, Wensheng, Wang, Kunlin, Zhang, Yaqun, and Wang, Zhenpeng
- Subjects
- *
WAVE energy , *ENERGY conversion , *NONLINEAR waves , *EXPERIMENTAL design , *FLEXIBLE structures - Abstract
As a kind of flexible membrane structure, the flexible bag-type wave energy converter (WEC) is currently in the conceptual development stage. This paper presents a novel type of water-filled submerged flexible bag WEC that has successfully generated electricity in a laboratory environment. Experimental studies have been conducted to investigate the hydrodynamic response of the flexible bag and the optimal resistance damping of the power take-off (PTO). The experimental results show that the average displacement of the PTO and power output are nonlinear for different wave heights. Furthermore, the capture width ratio (CWR) of the WEC varies depending on the wave period. The optimal resistance damping for this physical model has been determined to be 80 Ω. These findings can serve as a validation for future numerical simulations, and additional experimental studies will be carried out to optimize the structure of the WEC and enhance its energy conversion efficiency. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
Catalog
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.