151. High Sensitivity Optical Fiber Sensors for Simultaneous Measurement of Methanol and Ethanol
- Author
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Jinhui Yuan, Chongxiu Yu, Dejun Liu, Gerald Farrell, Xingdao He, Fangfang Wei, Wei Han, Zhe Kang, Shengpeng Wan, Qiang Wu, Feng Li, Rahul Kumar, Yuliya Semenova, and Arun Kumar Mallik
- Subjects
Microheater ,Materials science ,Optical fiber ,business.product_category ,H600 ,Analytical chemistry ,02 engineering and technology ,01 natural sciences ,law.invention ,Matrix (chemical analysis) ,chemistry.chemical_compound ,Engineering ,law ,Microfiber ,Materials Chemistry ,Electrical and Electronic Engineering ,Instrumentation ,Volatile organic compounds Optical fiber sensor Tapered fiber Sol-gel silica Nile red ,010401 analytical chemistry ,Metals and Alloys ,Single-mode optical fiber ,Nile red ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry ,Fiber optic sensor ,Methanol ,0210 nano-technology ,business - Abstract
High sensitivity volatile organic compounds (VOCs) sensors based on a tapered small core single mode fiber (TSCSMF) and a microfiber coupler (MFC) are reported. The TSCSMF had a waist diameter of ∼5.1 μm and the MFC had a waist diameter of ∼1.9 μm each and both were fabricated using a customized microheater brushing technique. Silica based materials containing immobilized Nile red prepared by sol-gel method with two different recipes (recipe I and recipe II) are investigated. Initially recipe I based coating materials were applied to the surfaces of the TSCSMF and MFC. The experimental results show that the sensor based on an MFC shows much better sensitivities of −0.130 nm/ppm and −0.036 nm/ppm to ethanol and methanol than those of the TSCSMF based sensor. The corresponding minimum detectable concentration change of the MFC based sensor are calculated to be ∼77 ppb and ∼281 ppb to ethanol and methanol respectively. Both sensors are demonstrated fast response times of less than 5 minutes, while the recovery times varied from 7 minutes to 12 minutes. In addition, another TSCSMF based sample (∼7.0 μm) coated with a mixed layer of sol silica and Nile red prepared by recipe II was fabricated to achieve simultaneous measurement of ethanol and methanol, employing a second-order matrix approach.
- Published
- 2018