151. Growth and magnetic properties of stoichiometric and site-disordered single crystalline MgV2O4
- Author
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Michael Tovar, Bella Lake, Manfred Reehuis, Klaus Kiefer, E. M. Wheeler, Bastian Klemke, Adrian H. Hill, A. T. M. Nazmul Islam, and Konrad Siemensmeyer
- Subjects
Materials science ,Spinel ,Magnetic lattice ,engineering.material ,Condensed Matter Physics ,Heat capacity ,Magnetic susceptibility ,Electronic, Optical and Magnetic Materials ,Crystallography ,Octahedron ,Phase (matter) ,engineering ,Single crystal ,Solid solution - Abstract
We have grown several single crystals of the highly frustrated $S$ = 1 spinel MgV${}_{2}$O${}_{4}$ using different starting compositions and growth conditions. From our study of their physical properties by magnetic susceptibility, heat capacity, and single-crystal neutron and powder-diffraction measurements, we observe that a minute amount of disorder suppresses the structural and magnetic phase transitions. As little as 3$%$ disorder in the octahedral site introduced random strain, which was enough to completely suppress the transitions and induce a spin-glass phase at low temperatures. We believe that the reason is spin-exchange disorder rather than disorder in the weakly diluted magnetic lattice. Our results also show that the MgO-V${}_{2}$O${}_{3}$ system is a solid solution that melts slightly incongruently, and we demonstrate that by using an optimized solvent in the traveling-solvent floating-zone configuration a large single crystal ($l$ = 25 mm, $d$ = 6 mm) with a homogeneous composition, free of site disorders can be grown.
- Published
- 2012