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When scaling the lateral size of a ferroelectric random access memory (FeRAM) device down to the nanometer range, the polarization switching-induced displacement current becomes small and challenging to detect, which greatly limits the storage density of FeRAM. Here, we report the observation of significantly enhanced injection currents, much larger than typical switching currents, induced by polarization switching in BiFeO3 thin films via conductive atomic force microscopy. Interestingly, this injected current can be effectively modulated by applying mechanical force. As the loading force increases from ∼50 to ∼750 nN, the magnitude of the injected current increases and the critical voltage to trigger the current injection decreases. Notably, changing the loading force by an order of magnitude increases the peak current by 2-3 orders of magnitude. The mechanically boosted injected current could be useful for the development of high-density FeRAM devices. The mechanical modulation of the injected current may be attributed to the mechanical force-induced changes in the barrier height and interfacial layer width.

All-dielectric optical metasurfaces are a workhorse in nano-optics, because of both their ability to manipulate light in different degrees of freedom and their excellent performance at light frequency conversion. Here, we demonstrate first-time generation of photon pairs via spontaneous parametric-down conversion in lithium niobate quantum optical metasurfaces with electric and magnetic Mie-like resonances at various wavelengths. By engineering the quantum optical metasurface, we tailor the photon-pair spectrum in a controlled way. Within a narrow bandwidth around the resonance, the rate of pair production is enhanced up to 2 orders of magnitude, compared to an unpatterned film of the same thickness and material. These results enable flat-optics sources of entangled photons - a new promising platform for quantum optics experiments.

When dealing with reactions of a liquid reactant and a solid catalyst, macroreactors with vigorous stirring equipment may be dangerous and cause wastage of energy. Reducing the diffusion distance and promoting reactants to reach the catalyst surface for efficient reaction remain the key challenges. Here, inspired by capillary-driven water motion in plants, we propose to implement a self-driven multiplex reaction (SMR) in nanocatalyst-loaded microchannels. Unlike the classical capillary rise, the droplet in SMR has variable pressure difference, leading to tunable flow velocity for controlling the reaction rate without any auxiliary equipment. The SMR in microchannels contributes to an increase in the reaction rate by more than 2 orders of magnitude compared to that in macroreactors. Specifically, this strategy reduces the reaction volume by 170 times, the catalyst usage by about 12 times, and the energy consumption by 50 times. This apparatus with a small volume and less catalyst content promises to provide an efficient strategy for the precise manipulation of chemical reactions.

Development of memory devices with ultimate performance has played a key role in innovation of modern electronics. As a mainstream technology nonvolatile memory devices have manifested high capacity and mechanical reliability, however current major bottlenecks include low extinction ratio and slow operational speed. Although substantial effort has been employed to improve their performance, a typical hundreds of micro- or even milli- second write time remains a few orders of magnitude longer than their volatile counterparts. We have demonstrated nonvolatile, floating-gate memory devices based on van der Waals heterostructures with atomically sharp interfaces between different functional elements, and achieved ultrahigh-speed programming/erasing operations verging on an ultimate theoretical limit of nanoseconds with extinction ratio up to 10^10. This extraordinary performance has allowed new device capabilities such as multi-bit storage, thus opening up unforeseen applications in the realm of modern nanoelectronics and offering future fabrication guidelines for device scale-up., Comment: Preprint version, to be published in Nature Nanotechnology (Submitted on August 16th, 2020)

The value of the ultimate specific power is determined in capacity electrostatic motors having a metal-thin ferroelectric film with a large specific capacity-nanogap-sliding electrode structure. An estimate is made of the maximum frequency of power conversion in these motors. The value of the ultimate power density previously determined for these designs is used to coin power converters based on these structures exceeding the power of inductive motors by 5 orders of magnitude.

The availability of portable analytical devices for on-site monitoring and rapid detection of analytes of forensic, environmental, and clinical interest is vital. We report the development of a portable device for the detection of biochemiluminescence relying on silicon photomultiplier (SiPM) technology, called LuminoSiPM, which includes a 3D printed sample holder that can be adapted for both liquid samples and paper-based biosensing. We performed a comparison of analytical performance in terms of detectability with a benchtop luminometer, a portable cooled charge-coupled device (CCD sensor), and smartphone-integrated complementary metal oxide semiconductor (CMOS) sensors. As model systems, we used two luciferase/luciferin systems emitting at different wavelengths using purified protein solutions: the green-emitting P. pyralis mutant Ppy-GR-TS (λmax 550 nm) and the blue-emitting NanoLuc (λmax 460 nm). A limit of detection of 9 femtomoles was obtained for NanoLuc luciferase, about 2 and 3 orders of magnitude lower than that obtained with the portable CCD camera and with the smartphone, respectively. A proof-of-principle forensic application of LuminoSiPM is provided, exploiting an origami chemiluminescent paper-based sensor for acetylcholinesterase inhibitors, showing high potential for this portable low-cost device for on-site applications with adequate sensitivity for detecting low light intensities in critical fields.

Raman optical activity (ROA) is effective for studying the conformational structure and behavior of chiral molecules in aqueous solutions and is advantageous over X-ray crystallography and nuclear magnetic resonance spectroscopy in sample preparation and cost performance. However, ROA signals are inherently minuscule; 3–5 orders of magnitude weaker than spontaneous Raman scattering due to the weak chiral light–matter interaction. Localized surface plasmon resonance on metallic nanoparticles has been employed to enhance ROA signals, but suffers from detrimental spectral artifacts due to its photothermal heat generation and inability to efficiently transfer and enhance optical chirality from the far field to the near field. Here we demonstrate all-dielectric chiral-field-enhanced ROA by devising a silicon nanodisk array and exploiting its dark mode to overcome these limitations. Specifically, we use it with pairs of chemical and biological enantiomers to show >100x enhanced chiral light–molecule interaction with negligible artifacts for ROA measurements., Raman optical activity (ROA) is useful for studying conformational structure and behavior of chiral molecules, but is limited by the weak signals. Here, the authors demonstrate 100x signal enhancement via an all-dielectric approach, using a silicon nanodisk array and exploiting its dark mode.

Here, a novel Au Wedge-enhanced Raman spectroscopy (WERS) substrate is proposed. The electric field enhancement factor and the effective mode field radius with varying geometry parameters are investigated. The proper excitation wavelength 633 nm is obtained. The practical application of WERS substrate is discussed. The Au WERS not only can provide a continuous extremely highly localized electric field as surface-enhanced Raman scattering (SERS) hotspots, but also can offer 10 orders of magnitude of SERS enhancement factor. The corresponding results reveal that WERS substrate will be widely applied in optics, biology, chemistry and other fields.

Electro-optic modulation based on a graphene nanoelectromechanical system (NEMS) with superlubricity is proposed and systematically theoretical investigated. We demonstrate that the superlubricity greatly improve the performance of photoelectric modulators based on graphene NEMS due to its extremely low coefficient of friction. The modulation voltage of graphene NEMS electro-optic modulation with superlubricity can be reduced to 200 mV, which is 1–3 orders of magnitude larger lower than that of the traditional electro-optical modulator, giving rise to a dramatic reduction of the power consumption of the modulator by approximately 3 orders of magnitude. The modulation response speed can reach nanoseconds, which is 4 orders of magnitude higher than the speed of traditional mechanical electro-optic modulation. At the same time, this modulator has a very wide modulation wavelength range and is not sensitive to the angle of incident light. Two-dimensional material devices, incorporated with mechanical modulation and superlubricity, will have important applications in optoelectronics and optical communication.

Since modern propulsion systems are insufficient for large-scale space exploration, a breakthrough in propulsion physics is required. Amongst different concepts, the EMDrive is a proposed device claiming to be more efficient in converting energy into propulsive forces than classical photon momentum exchange. It is based on a microwave resonator inside a tapered cavity. Recently, Taylor suggested using a laser instead of microwaves to boost thrust by many orders of magnitude due to the higher quality factor of optical resonators. His analysis was based on the theory of quantised inertia by McCulloch, who predicted that an asymmetry in mass surrounding the device and/or geometry is responsible for EMDrive-like forces. We put this concept to the test in a number of different configurations using various asymmetrical laser resonators, reflective cavities of different materials and size as well as fiber-optic loops, which were symmetrically and asymmetrically shaped. A dedicated high precision thrust balance was developed to test all these concepts with a sensitivity better than pure photon thrust, which is the force equivalent to the radiation pressure of a laser for the same power that is used to operate each individual devices. In summary, all devices showed no net thrust within our resolution at the Nanonewton range, meaning that any anomalous thrust must be below state-of-the-art propellantless propulsion. This puts strong limits on all proposed theories like quantised inertia by at least 4 orders of magnitude for the laboratory-scale geometries and power levels used with worst case assumptions for the theoretical predictions.

An atomic diffusion model is developed to predict the thickness of intermetallic compounds (IMCs) at the interface of aluminum/magnesium alloys in dissimilar friction stir welding. Both the temperature and the strain rate associated with dislocation density at the checking point are used to determine the diffusion coefficients. The variations of the diffusion coefficients and the thickness of IMCs are quantitatively analyzed at selected characteristic time instants during welding process. It is found that the dislocation density can increase the diffusion coefficient and plays a dominant role in the IMCs formation during the plastic deformation stage. Especially in magnesium alloy and Al12Mg17, the diffusion coefficient is increased by two orders of magnitude or even nearly three orders of magnitude by considering the dislocation density. The temperature is the main influencing factor after the end of plastic deformation. The model is validated by comparing the predicted thickness of IMCs with the experimentally measured results.

Radio frequency (RF) microelectromechanical systems (MEMS) based on Al1-xScxN are replacing AlN-based devices because of their higher achievable bandwidths, suitable for the fifth-generation (5G) mobile network. However, overheating of Al1-xScxN film bulk acoustic resonators (FBARs) used in RF MEMS filters limits power handling and thus the phone's ability to operate in an increasingly congested RF environment while maintaining its maximum data transmission rate. In this work, the ramifications of tailoring of the piezoelectric response and microstructure of Al1-xScxN films on the thermal transport have been studied. The thermal conductivity of Al1-xScxN films (3-8 W m-1 K-1) grown by reactive sputter deposition was found to be orders of magnitude lower than that for c-axis-textured AlN films due to alloying effects. The film thickness dependence of the thermal conductivity suggests that higher frequency FBAR structures may suffer from limited power handling due to exacerbated overheating concerns. The reduction of the abnormally oriented grain (AOG) density was found to have a modest effect on the measured thermal conductivity. However, the use of low AOG density films resulted in lower insertion loss and thus less power dissipated within the resonator, which will lead to an overall enhancement of the device thermal performance.

While ionic flow over graphenic structures creates electromotive potential, there is a need to understand the local carrier density induced in graphene without any electrode-induced Fermi-level pinning. Here, we show the electrolyte-flow induced localized doping in graphene via inspecting its Raman phononic energy. Graphene's Fermi energy level has a logarithmic dependence to the flow velocity over 2 orders of magnitude of velocity (∼100 μm s-1 to 10 mm s-1). A theoretical model of the electric double layer (EDL) during ionic transport is used to correlate the Fermi level of graphene with the flow rate and the electronic structure (HOMO-LUMO levels) of the ionic species. This correlation can allow us to use graphene as a reliable, non-invasive, optical flow-sensor, where the flow rates can be measured at high spatial resolution for several lab-on-a-chip applications.

In this issue of Chem, Hess et al. describe a droplet-based microfluidic platform for the acquisition of transient kinetic data of enzyme-catalyzed reactions. Compared with conventional equipment, their platform reduces assay volumes by up to six orders of magnitude and allows up to 9,000 reactions to be screened per minute.

The review contains information on the properties of phase-change materials (PCM) and the possibilities of their use as the basis of thermal energy storage. Special attention is given to PCMs with a phase transition temperature ranging between 20 and 80°C since such materials can be effectively used to reduce temperature variations in residential and industrial rooms. Thus, the application of PCMs in the construction industry enables one to considerably reduce the power consumption and reduce the environmental impact of industrial facilities. Thermophysical characteristics of the main types of PCMs are presented. The heat balance for a room with walls made of PCM-added materials is estimated. The predictions demonstrate that such structures can stabilize the temperature in practical applications as a result of usage of such materials. The potential of wide application of PCMs as a basis for thermal energy storage is limited due to very low conductivity (less than 1 W/(m K)) specific for these materials. Hence, the option of increasing the material conductivity by adding some carbon nanotubes whose thermal conductivity is four to five orders of magnitude greater than that of the base material is examined. The numerical predictions of the heat-conduction enhancement in a PCM doped with carbon nanotubes and the preliminary experiments indicate that a PCM with approximately 20% carbon nanotubes can enhance the material heat conductivity by two to four times.

The present work describes the preparation and the investigation of the room temperature electrical and optical properties of a series of liquid nanocomposites (lnC) prepared with different concentrations of multiwalled carbon nanotubes (MWCNT) in a variety of liquid matrices: glycerin, Vaseline, glucose, propylene glycol and silicone oil (SIO). Special attention is deserved to the SIO matrix, owing to its convenient electrical properties for our purposes. We verified that a small percent fraction of MWCNT dispersed along the SIO matrix is capable of improving the electrical conductivity of the matrix by orders of magnitude, indicating that the MWCNT strongly participates in the electrical conduction mechanism. Also, the application of an external electric field to this lnC resulted in large changes in the optical transmittance, that were interpreted as a consequence of the fieldinduced MWCNT alignment into the liquid matrix. The characteristics of such a new category of nanocomposite in the liquid state suggest further studies.

Ion-exchange membranes are critical components of hydrogen fuel cells, where these ionomers can be confined to nanoscale thicknesses, altering the physical properties of these films from that of bulk membranes. Therefore, it is important to develop methods capable of measuring and elucidating the transport mechanisms under thin film confinement compared to bulk Nafion. In this study, water sorption and diffusion in a Nafion thin film were measured using time-resolved in situ polarization modulation infrared reflection absorption spectroscopy (PM-IRRAS). Interfacial mass transport limitations were confirmed to be minimal, while restricted water diffusion was observed, where the effective diffusion coefficient of water in the thin Nafion film was many orders of magnitude lower (between 4 and 5 orders of magnitude) than those reported for bulk membranes and was dependent on the initial hydration state of the Nafion. Furthermore, the response of the hydrophobic domains (Teflon backbone) to the swelling of the hydrophilic domains (ionic clusters) was shown to be orders of magnitude slower than that of bulk Nafion.

Lisää oa-julkaisu, kun saatavilla. A sensitive photoacoustic detection approach employing a silicon cantilever is investigated for power measurement of electromagnetic radiation. The technique which is actuated by pressure waves generated through radiation-induced heat depicts high sensitivity for a considerably large spectral range from 325 nm to 1523 nm. The implemented method shows linear response in the measurement of radiation power from 15 nW to 6 mW demonstrating a dynamic range of almost six orders of magnitude. A numerical model has been developed to analyze and optimize the measurement sensitivity. The model allows studying different dimensions of the cantilever which is one of the key components of the radiation detection process. The numerical results are in good agreement with experimental results. The electromagnetic power detection technique shows future potential for industrial applications and scientific studies.

Understanding electronic and ionic transport across interfaces is crucial for designing high-performance electric devices. The adjustment of work functions is critical for band alignment at the interfaces of metals and semiconductors. However, the electronic structures at the interfaces of metals and mixed conductors, which conduct both electrons and ions, remain poorly understood. This study reveals that a Schottky barrier is present at the interface of the Nb-doped SrTiO3 metal and a LiCoO2 mixed conductor and that the interfacial resistance can be tuned by inserting an electric dipole layer. The interfacial resistance significantly decreased (by more than 5 orders of magnitude) upon the insertion of a 1 nm thick insulating LaAlO3 layer at the interface. We apply these techniques to solid-state lithium batteries and demonstrate that tuning the electronic energy band alignment by interfacial engineering is applicable to the interfaces of metals and mixed conductors. These results highlight the importance of designing positive electrode and current collector interfaces for solid-state lithium batteries with high power density.

Present GaN technology consists primarily of heteroepitaxial, lateral high electron mobility transistors; however, high-power devices would be much more efficiently manufactured with a vertical geometry due to better blocking voltage scaling. This technology has yet to be realized due to the inconsistency of GaN wafer properties. These inconsistencies can be detected with several long-range, non-destructive techniques including Raman spectroscopy, optical profilometry, and photoluminescence mapping. In particular, Raman spectroscopy is an effective tool for determining the carrier concentration of GaN substrates and whether the wafers are uniform or inhomogeneous. In this work, vertical p-i-n GaN diodes are fabricated using both uniform and inhomogeneous wafers determined by using the A1 Raman peak position to monitor carrier concentration. The inhomogeneous samples have regular patterns of varying conductivity as a result of electron-donating defects brought about by changes in crystal stress. By avoiding these defects, we have found that diode performance improves by increasing the +/− 10 V rectification ratio by up to a factor of 5X and reducing the 200 V reverse bias leakage current by several orders of magnitude. Using the higher quality substrates with uniform electron carrier concentrations can improve the rectification ratio by another order of magnitude.

Dual-color photodetection can increase detection accuracy due to the specific information from different wavelengths. Traditional dual-color detectors are based on double optical modules or photovoltage devices, which suffer from huge system weight or low gain. In this Letter, a novel dual-color photodetector with Ge/Graphene/CdS sandwich profile is proposed. While visible and infrared light is mainly absorbed by the CdS and Ge layers, respectively, photoelectrical signals from two wavelengths both conducted by graphene are extracted on time-sequence with different sampling frequencies. Based on a tailored interface process and epitaxy InGaAs instead of bulk Ge layer, the difference in response speed more than 3 orders of magnitude (76 kHz/14 Hz) was realized. Due to the photogating effect, the high gain was obtained for both wavelengths, and a photoresponse enhancement originated from the overlapping of local photogating field is observed. The device provided a new solution for high-gain and CMOS-compatible dual-color photodetection.

The anisotropic magnetoresistance film is an important core material for developing the magnetic sensors. Here, Ta(5)/MgO(3)/NiFe(10)/MgO(3)/Ta(3) multilayers (in nanometer) were prepared by magnetron sputtering and further applied to construct a sensor element by combining with the Wheatstone bridge. The 1/f noise of the sensor element was greatly reduced by three orders of magnitude after annealing at 400 °C for 7200 s, which was mainly due to the significant microstructural changes during the annealing. However, when the sensor element was applied to detect the magnetic signal of a magnetic code disk with 512 N–S magnetic poles, the output voltage signal of the sensor displayed a large fluctuation of ± 0.05 V. In order to reduce the voltage fluctuation, a magnetic sensor chip by using a parallelly arranged multi-path Wheatstone bridges and auto-gain compensation structure was designed, and magnetic sensor elements and the high-performance computing drive module were prepared. The output voltage fluctuation of the magnetic sensor was reduced by about 90% and approached to ± 0.005 V. These findings provide an important basis for the practical application of NiFe-based magnetic sensing film materials.

Optofluidic biolasers have emerged as promising tools for biomedical analysis due to their strong light-matter interactions and miniaturized size. Recent developments in optofluidic lasers have opened a new Frontier in monitoring biological processes. However, most biolasers require precise recording of the lasing spectrum at the single cavity level, which limits its application in high-throughput applications. Herein, a microdroplet laser array encapsulated with living Escherichia coli was printed on highly reflective mirrors, where laser emission images were employed to reflect the dynamic changes in living organisms. The concept of image-based lasing analysis was proposed by quantifying the integrated pixel intensity of the lasing image from whispering-gallery modes. Finally, dynamic interactions between E. coli and antibiotic drugs were compared under fluorescence and laser emission images. The amplification that occurred during laser generation enabled the quantification of tiny biological changes in the gain medium. Laser imaging presented a significant increase in integrated pixel intensity by 2 orders of magnitude. Our findings demonstrate that image-based lasing analysis is more sensitive to dynamic changes than fluorescence analysis, paving the way for high-throughput on-chip laser analysis of living organisms. Agency for Science, Technology and Research (A*STAR) Nanyang Technological University This research is supported by A*STAR under its AME IRG Grant (project no. A2084c0063). We would like to thank the lab support from Centre of Bio-Devices and Bioinformatics and Internal grant NAP SUG-M4082308.040 from NTU.

Hydrogenation, an effective way to tune the properties of transition metal oxide (TMO) thin films, has been long awaited to be performed safely and without an external energy input. Recently, metal-acid-TMO has been reported to be an effective approach for hydrogenation, but the requirement of acid limits its application. In this work, the reversible and rapid hydrogen doping of WO3 in NaOH(aq) | Al(s) | WO3(s) is revealed by structural and electrical measurements. Accompanied by the structural phase transition identified by in situ X-ray diffraction, the electric resistance of the WO3 film is found to be able to change by 5 orders of magnitude. A significant electrical response of touching, 8-fold in amplitude and 3 s in a cycle, can be achieved in the low-resistance state. These reactions are reversible at room temperature. This study unambiguously proves that the hydrogenation-driven dynamic phase transition of WO3 in metal-solution-WO3 systems could occur not only in acid solutions but also in some non-acid environments. Unlike the monotonic increase of resistance revealed during HδWO3 to WO3 transition, an intriguing non-monotonic evolution was found for crystal lattice parameter c, indicating that the mechanism of WO3 hydrogenation involves a series of metastable states, more comprehensive and reasonable. This work sheds light on the potential applications of metal-solution-TMO hydrogenation in touching sensors, circuits survey, and information storage.

Abstract Surface Free Energy (SFE) has become a relevant design parameter to produce materials and devices with controlled wettability. The non-destructive measurement of SFE in nanopatterned super-hydrophobic hard surfaces is a challenge in both research and industry since in most cases time-consuming contact angle measurements are not feasible. In this work, we present a novel nanoindentation based method for the measurement of pull-off adhesive forces by carefully controlling environmental and instrumentation issues. The method is found to measure SFE over five orders of magnitude, covering hydrophilic to super-hydrophobic surfaces, and has been validated with contact angle measurements. Its limitations and shortcomings are critically discussed, with a specific focus on the experimental issues that could affect the reliability and reproducibility of the results. Finally, the potential applications of the newly developed methodology include fast non-destructive mapping of SFE over heterogeneous surfaces with spatially controlled wettability. Graphic abstract

Tunnel FET is recognized as one of the most promising candidates for ultra-low power applications due to its ultra-low off current and CMOS compatibility. However, some characteristics of TFET caused by asymmetric device structure and special conduction mechanism may make conventional topologies of logic circuits no longer applicable. Our previous work has reported that TFET stacking will result in severe current degradation, which makes traditional logic cells not applicable. In this paper, two solutions are proposed: first, from a logic cell perspective, novel hybrid TFET-MOSFET topologies of standard logic cells are proposed, which achieve more than 2 times lower hardware cost and intrinsic delay, hence up to 4 times lower area-power-delay product (APDP) than that of conventional TFET logic circuits. Compared to MOSFET logic circuits, the designs achieve almost 2 orders of magnitude lower power and up to 34 times lower APDP. Second, from a large-scale circuit perspective, an optimized digital front-end (DFE) is proposed. Taking serial peripheral interface (SPI) as an example, SPI circuit using the optimized DFE achieves 46% lower delay and 4 times lower APDP than that of traditional TFET SPI, and 3 orders of magnitude lower static power and APDP than that of MOSFET SPI.

We present a machine learning based surrogate modeling method for predicting spatially resolved 3D crystal orientation evolution of polycrystalline materials under uniaxial tensile loading. Our approach is orders of magnitude faster than the existing crystal plasticity methods enabling the simulation of large volumes that would be otherwise computationally prohibitive. This work is a major step beyond existing ML-based modeling results, which have been limited to either 2D structures or only providing average, rather than local 3D full-field predictions. We demonstrate the speed and accuracy of our surrogate model approach on experimentally collected data from a face-centered cubic copper sample undergoing tensile deformation.

Optical tweezers are widely used in materials assembly1, characterization2, biomechanical force sensing3,4 and the in vivo manipulation of cells5 and organs6. The trapping force has primarily been generated through the refractive index mismatch between a trapped object and its surrounding medium. This poses a fundamental challenge for the optical trapping of low-refractive-index nanoscale objects, including nanoparticles and intracellular organelles. Here, we report a technology that employs a resonance effect to enhance the permittivity and polarizability of nanocrystals, leading to enhanced optical trapping forces by orders of magnitude. This effectively bypasses the requirement of refractive index mismatch at the nanoscale. We show that under resonance conditions, highly doping lanthanide ions in NaYF4 nanocrystals makes the real part of the Clausius–Mossotti factor approach its asymptotic limit, thereby achieving a maximum optical trap stiffness of 0.086 pN μm–1 mW–1 for 23.3-nm-radius low-refractive-index (1.46) nanoparticles, that is, more than 30 times stronger than the reported value for gold nanoparticles of the same size. Our results suggest a new potential of lanthanide doping for the optical control of the refractive index of nanomaterials, developing the optical force tag for the intracellular manipulation of organelles and integrating optical tweezers with temperature sensing and laser cooling7 capabilities. The resonance of highly doping lanthanide ions in NaYF4 nanocrystals enhances the permittivity and polarizability of nanocrystals, leading to enhanced optical trapping forces by orders of magnitude, bypassing the trapping requirement of refractive index mismatch.

Graphene field-effect transistors (GFETs) are suitable building blocks for high-performance electrical biosensors, because graphene inherently exhibits a strong response to charged biomolecules on its surface. However, achieving ultralow limit-of-detection (LoD) is limited by sensor response time and screening effect. Herein, we demonstrate that the detection limit of GFET biosensors can be improved significantly by decorating the uncovered graphene sensor area with carbon dots (CDs). The developed CDs-GFET biosensors used for exosome detection exhibited higher sensitivity, faster response, and three orders of magnitude improvements in the LoD compared with nondecorated GFET biosensors. A LoD down to 100 particles/μL was achieved with CDs-GFET sensor for exosome detection with the capability for further improvements. The results were further supported by atomic force microscopy (AFM) and fluorescent microscopy measurements. The high-performance CDs-GFET biosensors will aid the development of an ultrahigh sensitivity biosensing platform based on graphene for rapid and early diagnosis of diseases.

This paper reports evidence for enhanced elemental interdiffusion during ultrasonic additive manufacturing (UAM) across metal boundaries of copper-aluminum, nickel-gold, and nickel-gold-aluminum. The high solute interdiffusion measured by energy dispersive X-ray spectroscopy line scans is rationalized with calculated vacancy concentrations orders of magnitude larger than thermal equilibrium values. The above estimates are supported by existing knowledge related to defect physics and UAM thermal cycles. The observation of pronounced elemental mixing are evidence for the presence of enhanced non-equilibrium immiscible metal interdiffusion during UAM processing.

A two-dimensional (2D) model was developed, for the first time, to describe the characteristics of the micromachined thermal expansion-based angular motion (TEAM) sensor, which has been validated by the experimental results. Scaling analysis on the performance characteristics through the 2D model was conducted to optimize the TEAM sensor’s design in terms of the normalized distances between the microheaters and temperature detectors in $x$ and $y$ directions, the thickness of the thin film, the heater width, the cavity depth, and the heater temperature. Furthermore, the proposed 2D model was normalized by two dimensionless numbers, namely Rayleigh number Ra and Peclet number Pe, with a critical Rayleigh number (Ra $^{\ast }_{\mathrm {c}} =18$ ,000) identified to differentiate linear and nonlinear operation regimes of the TEAM sensor. In particular, our 2D model is much faster than the conventional CFD model by three orders of magnitude (18.91s versus 5.5h), enabling rapid system-level optimization of the critical design parameters. Accordingly, the TEAM sensors with three pairs of platinum thermoresistive temperature sensors were designed and fabricated. The fabricated device demonstrated a normalized sensitivity of $11.8~\mu \text{V}$ /°/s/mW based on the working fluid of air, which was more than three times better than previous thermal angular motion sensors. Thus, with the experimental validation, the proposed 2D model should be a reliable tool to realize the systematical design optimization of TEAM sensors integrated with on-chip microelectronics for future industrial IoT applications. [2020-0355]

A new X-ray absorption spectroscopy (XAS) beamline is currently under construction at a bending magnet of the National Synchrotron Radiation Centre SOLARIS. The front end of this beamline was installed in April 2020. This beamline has a few outstanding characteristic features: The monochromator is a fixed exit beam Lemmonier type monochromator allowing to cover the pursued energy range (1 keV to ~15 keV) with 3 sets of crystals: KAP (100) + multilayer, InSb (111) and Ge (220). The monochromator is a high vacuum system allowing the change of crystals in less than an hour. In order to minimize absorption of photons no windows will be installed in the beamline down to the monochromator, and just one thin polypropylene window will be used for separating the vacuum of the monochromator from the ionization chambers and the sample chamber. A special differential ion pump will be installed to maintain the pressure difference of four orders of magnitude between the storage ring and the monochromator. As SOLARIS is a low energy machine, the beamline can be built without any radiation safety hutches without exceeding the strict low radiation safety levels. The straightforward design of the beamline without additional optical elements, its compact overall dimensions and an easy to handle monochromator make this beamline especially user friendly. In combination with the characteristics of the 1.5 GeV SOLARIS storage ring this beamline will be specifically attractive for the tender X-ray range, i.e. the K-edges of important elements such as P, S, Si, Al and Mg.

Developing point-of-care (PoC) diagnostic platforms for carcinoembryonic antigen detection is essential. However, thefew implementations of transferring the signal amplification strategies in electrochemical sensing on paper-based platforms are not satisfactory in terms of detection limit (LOD). In the quest for pushing down LOD, majority of the research has been targeted towards development of improved nanostructured substrates for entrapping more analyte molecules and augmenting the electron transfer rate to the working electrode. But, such approaches have reached saturation. This paper focuses on enhancing the mass transport of the analyte towards the sensor surface through the application of an electric field, in graphene-ZnO nanorods heterostructure. These hybrid nanostructures have been deposited on flexible polyethylene terephthalate substrates with screen printed electrodes for PoC application. The ZnO nanorods have been functionalized with aptamers and the working sensor has been integrated with smartphone interfaced indigenously developed low cost potentiostat. The performance of the system, requiring only 50 µl analyte has been evaluated using electrochemical impedance spectroscopy and validated against commercially available ELISA kit. Limit of detection of 1 fg/ml in human serum with 6.5% coefficient of variation has been demonstrated, which is more than three orders of magnitude lower than the existing attempts on PoC device.

This article reports humidity sensors based on hierarchical gallium nitride (GaN) with flower-like microstructures based on a scalable hybrid approach. We have fabricated 3D dandelion flower-like GaN hierarchical microspheres with an ammonothermal- conjugated ammoni- fication method (750-1150 °C) for the humidity sensors. The GaN microspheres are analyzed by scanning electron microscopy, X-ray diffraction, Raman and Fourier-transform spectroscopic methods. It is found that the use of oleylamine in the ammonothermal-ammonification hybrid approach, plays an essential role in the GaN morphology. The GaN sensors are prepared by dip-coating the sensor materials on the interdigitated electrode and their humidity sensing performance have been characterized. The humidity sensing performance is investigated at an applied 1V AC bias, by measuring the impedance and charge transfer resistance as a function of the broad range (10 to 95%) of RH. The GaN sensor exhibits a high response of above four orders of magnitude with excellent linearity and stability within the whole measurement range, while the bare GaN humidity sensors exhibited a low response of less than two orders of magnitude with poor linearity and stability. We have also proposed a possible charge transfer mechanism and studied the influence of the defect degree on the sensing performance of the GaN humidity sensors.

Magnetic fields play such essential roles in star formation as transporting angular momentum and driving outflows from a star-forming cloud, thereby controlling the formation efficiency of a circumstellar disc and also multiple stellar systems. The coupling of magnetic fields to the gas depends on its ionization degree. We calculate the temperature evolution and ionization degree of a cloud for various metallicities of Z/Zsun = 1e-6, 1e-5, 1e-4, 1e-3, 1e-2, 1e-1, and 1. We update the chemical network by reversing all the gas-phase processes and by considering grain-surface chemistry, including grain evaporation, thermal ionization of alkali metals, and thermionic emission from grains. The ionization degree at nH ~ 1e15-1e19 /cm^3 becomes up to eight orders of magnitude higher than that obtained in the previous model, owing to the thermionic emission and thermal ionization of K and Na, which have been neglected so far. Although magnetic fields dissipate owing to ambipolar diffusion or Ohmic loss at nH < 1e15 /cm^3, the fields recover strong coupling to the gas at nH ~ 1e15 /cm^3, which is lower by a few orders of magnitude compared to the previous work. We develop a reduced chemical network by choosing processes relevant to major coolants and charged species. The reduced network consists of 104 (161) reactions among 28 (38) species in the absence (presence, respectively) of ionization sources. The reduced model includes H2 and HD formation on grain surfaces as well as the depletion of O, C, OH, CO, and H2O on grain surfaces., 23 pages, 12 figures, 3 tables, accepted for publication in MNRAS

When a temperature gradient is applied to a closed circuit comprising two different conductors, a charge current is generated via the Seebeck effect1. Here, we utilize the Seebeck-effect-induced charge current to drive 'transverse' thermoelectric generation, which has great potential for energy harvesting and heat sensing applications owing to the orthogonal geometry of the heat-to-charge-current conversion2-9. We found that, in a closed circuit comprising thermoelectric and magnetic materials, artificial hybridization of the Seebeck effect into the anomalous Hall effect10 enables transverse thermoelectric generation with a similar symmetry to the anomalous Nernst effect11-27. Surprisingly, the Seebeck-effect-driven transverse thermopower can be several orders of magnitude larger than the anomalous-Nernst-effect-driven thermopower, which is clearly demonstrated by our experiments using Co2MnGa/Si hybrid materials. The unconventional approach could be a breakthrough in developing applications of transverse thermoelectric generation.

The friction between a molybdenum disulphide (MoS2) nanoflake and a MoS2 substrate was analyzed using a modified Tomlinson model based on atomistic force fields. The calculations performed in the study suggest that large deformations in the substrate can induce a dramatic decrease in the friction between the nanoflake and the substrate to produce the so-called superlubricity. The coefficient of friction decreases by 1–4 orders of magnitude when a high strain exceeding 0.1 is applied. This friction reduction is strongly anisotropic. For example, the reduction is most pronounced in the compressive regime when the nanoflake slides along the zigzag crystalline direction of the substrate. In other sliding directions, the coefficient of friction will reduce to its lowest value either when a high tensile strain is applied along the zigzag direction or when a high compressive strain is applied along the armchair direction. This anisotropy is correlated with the atomic configurations of MoS2.

We introduce a novel and sensitive ns-resolved atomic magnetometer, which is at least three orders of magnitude faster than conventional magnetometers. We use the magnetic field dependence of the hyperfine beating of high-density spin-polarized H atoms, produced from the rapid photodissociation of HCl gas with sub-ns laser pulses and measured with a pick-up coil, to demonstrate ns-resolved magnetometry, and project sensitivity of a few nT for a spin-projection-limited sensor with 10 nl measurement volume after 1 ns measurement time. The magnetometer will allow ultrafast continuous B-field measurements in many fields, including spin chemistry, spin physics, and plasma physics.

Deciphering the charge carrier dynamics in perovskite solar cells (PSCs) and electrical merits is essential to further improve the performance and operational stability. We investigated the charge carrier dynamics in triple cation-based PSCs through temperature dependent electrochemical impedance spectroscopy, thermal admittance spectroscopy, and space charge limited current (SCLC). The temperature dependent capacitance versus frequency (C–f) spectra reveal two kinds of activation process, one at low frequency and high temperature (>260 K), and the other at high frequency and low temperature (

Electrochemical aptamer-based (E-AB) sensors provide a great opportunity towards the goal of point-of-care and wearable sensing technologies due to their good sensitivity and selectivity. Nevertheless, the output signals from this sensor class remain low when sensors are interrogated via square-wave voltammetry. This low signaling limits the sensor's precision for its capability to detect small changes in target concentrations. To circumvent this, we proposed here the use of a readily shrink-induced, wrinkled Au-coating polyolefin film to immobilize a greater number of DNA probes and thus improve the signaling. Specifically, wrinkled gold film exhibits a 5.5-fold increase of surface area in comparison to the unwrinkled ones. Using these substrates we fabricated a set of E-AB sensors of three biological molecules, including kanamycin, doxorubicin and ATP. We achieved up to 10-fold increase in its current and also good accuracies within ±20% error in the target concentration range across 2 orders of magnitude.

A simple and low-cost fabrication of end-bonded contacts InAsSb NW (nanowire) array detector to weak light is demonstrated in this study. The detector is fabricated using InAsSb NW array grown by molecular beam epitaxy on GaAs substrate. The MIGS (metal-induced gap states) is induced by the end-bonded contact which suppresses the dark current at various temperatures. The existence of the interface dipole due to the interfacial gap states enhances the light excitation around the local field, thus upgrade the photo responsivity and photo detectivity to the weak light. The light intensity of the infrared light source in this report is 14 nW/cm2 which is about 3 to 4 orders of magnitude less than the laser source. The responsivity of the detector has reached 28.57 A/W at room temperature with the light (945 nm) radiation, while the detectivity is 4.81×1011 cm·Hz1/2 W−1. Anomalous temperature-dependent performance emerges at the variable temperature experiments, and we discussed the detailed mechanism behind the non-linear relationship between the photoresponse of the device and temperatures. Besides, the optoelectronic characteristics of the detector clarified that the light trapping effect and photogating effect of the NWs can enhance the photoresponse to the weak light across ultraviolet to near-infrared. These results highlight the feasibility of the InAsSb NW array detector to the infrared weak light without a cooling system.

Easy-to-use and sensitive quantification of biomarkers has a great significance in disease prediction, diagnosis, and monitoring. Here, we report a biosensor for simple and sensitive biomarker detection based on the strong light scattering (brightness) of superradiative plasmonic nanoantennas. This nanoantenna is constructed using antibody-decorated gold nanoparticles (Au NPs) immobilized onto a gold mirror by the target antigen, forming a nanoparticle-on-mirror (NPOM) configuration. The NPOM produces an order of magnitude stronger light scattering in the red region compared with isolated Au NPs on the dielectric substrate, due to the strong near-field coupling of surface plasmons across the gap between the Au NPs and the gold film. The increased brightness allows one to observe the captured Au NPs with the naked eye using a dark-field optical microscope. The particle density of the Au NPs varies linearly with the concentration of the target antigen over a broad dynamic range from 10-3 to 103 ng mL-1. This dynamic range is three orders of magnitude broader than that obtained from the previous work based on a dark-field optical microscope. The limit of detection is 1 pg mL-1 (6.67 fM), which is three orders of magnitude more sensitive than that obtained in the previous work using similar conditions. The uniform spatial distribution of the Au NPs on the gold film was allowed to quantify biomarkers with a relative standard deviation as small as 1-7%. Biosensing using superradiative NPs can lower the detection limit, simplify, and speed up the detection procedure for biomarker detection.

Objective. The article deals with the formation of cost-effective light transistors for creating high-speed energy-efficient computer structures that can solve numerous problems with high speed and accuracy. For this purpose, various types of semiconductor structures are used that can emit and absorb photons for receiving and transmitting digital information.Methods. The use of mirror electrodes allows for repeated re-reflection of the generated photons inside the light transistor to recover all the generated energy into electricity. This increases the energy efficiency of the transistor as a whole and allows implementing computer devices with high efficiency in solving various tasks.Results. Most of the useful energy of the information signal is transferred from one electrode to another, and the movement has a higher speed due to the use of photons, rather than drifting electrons, and this indirectly increases the speed of the light transistor by several orders of magnitude and effectively solves the problem of implementing more powerful and high-speed transistors with greater economic benefits.Conclusion. Prospects for the implementation of high-speed energy-efficient computer structures based on both bipolar transistors and unipolar transistors, as well as thyristors, lasers, and other semiconductor components in light-emitting structures have been developed.

Charged domain walls (CDWs) have attracted considerable attention owing to their tunable properties related to high-density information storage and nanoelectronics devices. The excellent time endurance of conductivity is a pressing need, which is directly related to the domain stability and boundary conditions. In this study, we propose an effective method to promote the permanent formation of charged domain walls aimed with tip-induced electric fields. The permanent domain structures and CDWs are attributed to the robust stimulus with tip dimensions combined with effective screening conditions. This interesting conductivity near the domain walls is three orders of magnitude higher than the domain inner, and exhibits attractive anti-fatigue properties with the value of ∼60 pA for the duration of more than one month. In addition, the tunable mechanism of CDWs in LiNbO3 thin films is related to carrier gathering near the domain walls for the inclined boundary. These inclined head-to-head domain walls exhibit conductive features only along the negative direction, which can be modulated by the application of a sub-coercive voltage. The results demonstrate the stable manipulation of domain reversal and charged domain walls in LiNbO3 thin films, highlighting them as a critical component, especially for multiple-state logic circuits and potential ferroelectric diode applications in non-volatile memories and nanoelectronics devices.

This paper focuses on the development of a thin normal-shear force sensor based on the use of a supercapacitive sensing mechanism. The sensor has a quad structure with four sensing units in which the bottom substrate has four pairs of electrodes while the top deformable portion has a solid-state electrolyte. The application of normal and shear forces increases the contact area between the solid-state electrolyte and the electrodes. Key innovations in the sensing mechanism include the use of a paper-based solid state electrolyte, the use of 3d-printing with a combination of soft and hard polymers to construct the top portion of the sensor, and the use of deep learning to model the sensor response. The sensor can accept any combination of shear and normal forces and can measure both their magnitudes and orientation. The deep learning based sensor response model enables accurate sensor calibration while accommodating the imperfections in the stiffness distribution of the sensor. The normal and shear force sensitivities are of the order of 50 nF/N and 22 nF/N respectively, which are orders of magnitude larger than the sensitivity of a traditional capacitive force sensor.

An all-dielectric nanoantenna is expected to greatly boost the nonlinear performance owing to its large mode volume and low material loss. However, it still suffers from the relatively weak near-field enhancement and the inferior far-field directivity. In this work, by successively introducing an upper metal ring and a bottom metal film, the plasmonic resonance and the perfect electric conductor (PEC) mirror effect are employed to significantly enhance and tailor the third harmonic generation (THG) from the high-index silicon nanoantenna. Numerical results show that benefiting from both of these two metal components, not only the THG efficiency is increased by more than 1 and 3.5 orders of magnitude compared with those with only single metal component and without any metal component, respectively, but also an improved radiation directivity can be obtained. The dependences of geometric parameters are discussed as well. This work suggests a route to enhance and manipulate the nonlinear radiation by a hybrid nanoantenna and facilitates its practical applications such as biosensing and nonlinear light sources.

The endurance of a Mo/Hf0.3Zr0.7O2/Si capacitor was improved up to 109 cycles by using a Ti layer formed prior to the atomic layer deposition of a Hf0.3Zr0.7O2 film to avoid direct exposure of Si to ozone with resulting trap density decrease.

Films of Li2O and Li2S grown by sputter deposition exhibit Li+ conductivity values at room temperature which are enhanced by 3–4 orders of magnitude relative to bulk samples. Possible mechanisms are discussed. The results may help explain the ion transport pathway through passivation layers containing these chalcogenides in batteries.

A high-performance Bloch surface wave (BSW) sensor based on the hollow fiber (HF) inner coated with the one-dimensional photonic crystal (1DPC) consisting of TiO2 and SiO2 bilayers is proposed. Performances including sensitivity and figure of merit (FOM) of the sensor are investigated theoretically with the ray transmission model. Several structure parameters such as the center wavelength of 1DPC, the thickness of the cap layer and the bilayer period are optimized to obtain a best performance of the sensor. The results show that the proposed sensor has an ultra-high FOM over 1100 RIU-1, which is approximately two and one orders of magnitude higher than that of the HF surface plasmon resonance (SPR) sensor and HF long-range SPR sensor, respectively. Moreover, the proposed sensor has a much broader practical RI detection range, which makes it more useful in sensing applications. The performance of the proposed sensor applicated in temperature sensing is also estimated to prove its application potential.

Nonlinear diffraction of a plane electromagnetic wave from multilayer nonlinear metasurfaces consisting of double-period lattices of rectangular finite-length graphene ribbons on dielectric spacer layers is investigated in the terahertz (THz) frequency range. An increase in the third-harmonic generation efficiency by several orders of magnitude at the surface plasmon–polariton resonance frequencies is demonstrated. It is demonstrated that the third-harmonic frequency can be controlled by dynamic tuning of chemical potential without changing geometry or dimensions of the graphene metasurface.