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This study aims to determine the highest cellulose purity based on variations in NaOH concentration and to characterize nanocellulose fiber from corn cob waste. Nanocellulose fiber was obtained using chemical-mechanical treatments. Chemical treatment consists of pretreatment, de-lignification, and bleaching stages. While mechanical treatment consists of stirrer and ultrasonication methods, The results showed that the highest cellulose purity was 75.32% using 60% NaOH. In addition, FTIR test results showed that lignin and hemicellulose compounds were successfully removed during chemical treatment, and functional groups from the typical structure of cellulose, which are OH, C-H, and C-O-C groups, with their respective wavenumbers, did not show significant changes during mechanical treatment. Nanocellulose fibers have been successfully formed. It was evident from the morphology of the fibers, which had an average diameter of 120.57±14.05 nm. Additionally, the nanocellulose fiber has excellent colloidal stability with a potential zeta value of -72.5 mV. Based on these results, biopolymer nanocellulose fiber has been successfully obtained from corn cob waste through chemical-mechanical treatments. [ABSTRACT FROM AUTHOR]

By employing Plackett–Burman design (PBD) to investigate the qualitative interactions between eleven parameters [potato shell weight, incubation time, glucose, lactose, baker's yeast, peptone, (NH4)2SO4, CuSO4, FeSO4, CaCl2, KCl], and central composite design (CCD), the production of α-amylase by a local bacterial isolate Bacillus spp. NRC1 using agro-industrial wastes was improved. Using a variety of waste materials, including corn cobs (CC), onion peels (OP), rice straw (RS), potato shells (PS), Molokhia stem (MS), okra suppression (OS), lemon peels (LP), and pea peels (PP), Bacillus spp. NRC1 was tested in the production of amylase. Out of the eight agro-industrial wastes tried, the highest amylase yield (6.99 U/ml) was reached using potato peels. The statistical optimization of enzyme production was carried out using PBD followed by CCD design, causing 2.06-fold and 1.51-fold increase, respectively. The overall increase was 3.11-fold. In PBD design, potato peels, peptone and (NH4)2SO4 were positive factors for amylase production. The crude enzyme was tested for its ability to desize cotton fabric and subsequently studying its effect on fabric dyeability. The produced amylase proved its potentials in textile industry. [ABSTRACT FROM AUTHOR]

Agricultural solid waste (ASW) is a serious concern globally, specifically in agricultural countries like India, China, Japan, Indonesia, Malaysia, etc. A lot of agricultural waste like the remain of crop plants, peels, leaves, corn cob, decayed crops, etc., is produced directly or indirectly every year affecting the environment and is not appropriately managed. Therefore, to overcome this problem, there is a need to develop waste redemption techniques to transform solid waste into value-added products. The wastes are generally rich in carbohydrates, lipids, proteins, and many other organic and inorganic constituents. This composition allows us to produce numerous value-added products like livestock feed, bio-preservatives, biofuels, biofertilizers, single-cell proteins, nanoparticles, biodegradable plastic, chitosan, collagen, and antibodies. Additionally, various start-ups leading to new beneficial products from agricultural solid waste should be promoted. This review intends to explore the sources of agricultural solid waste generation and to provide a solution to manage the waste through modern technologies, saving the environment and boosting a country's economy. The outcome of our study will lead toward a sustainable approach to waste management as we have comprises the most innovative and successful working models in one place. This newly developed technique will help to achieve the greater goal of sustainable development. [ABSTRACT FROM AUTHOR]

Toluene, a hydrocarbon frequently found in water due to human activities and accidents like oil spills, can pose health risks, such as nervous system irritation and liver lesions. This study aimed to develop cost-effective adsorption techniques using activated carbon from corn biomass to remove toluene from water. The activated carbon, synthesized with zinc chloride surface modification and carbonization, was tested in a continuous fluidized bed column. The adsorbents effectively removed toluene, with optimal conditions identified as a bed height of 10 cm, a temperature of 30 °C, and a flow rate of contaminated water at 15 L/h. Operational parameters, like flow rates (15-25 l/h), bed heights (6-10 cm), and temperature (30-40 °C), were varied to assess their impact on toluene adsorption efficiency. Increasing flow rate and temperature reduced toluene removal, while higher bed height improved removal efficiency. However, column adsorption showed lower efficacy due to limited access of adsorbates to surface sites caused by low retention times within the column. On the basis of the breakthrough curve of 0.2 mm AC particles, the maximum adsorption capacity for toluene was 0.15643 mg/g with a total removal efficiency of 44.894%. The analysis, using various kinetic models like Thomas and Adams-Bohart, correlated strongly with the Thomas model (R2 > 0.89), indicating Langmuir isotherm behavior and a second-order kinetic reaction. These findings demonstrate the potential of using the activated carbon from corn biomass in adsorption processes for removing toluene from contaminated water. [ABSTRACT FROM AUTHOR]

Objective: To evaluate the compatibility of hydrosols from aromatic plants on the growth of T. harzianum. Design/Methodology/Approach: All hydrosols of Foeniculum vulgare, Plectranthus coleoides, Tagetes arenicola, T. coronopifolia, T. erecta, and T. lucida were evaluated in vitro on the mycelium Trichoderma harzianum. Their growth rates and inhibition percentages were recorded. T. harzianum was inoculated in 50 g of sterilized corn cob enriched with F. vulgare hydrosol (3, 5 and 7%), this mixture was incubated at 28 ± 2 °C; spore counting, and viability tests were performed on PDA medium. The Tukey test (p ≤ 0.05) was used for mean comparisons. Results: All hydrosols inhibited in vitro the mycelial growth of T. harzianum at 100%, but at 5% concentration, some hydrosols promoted the growth of the fungus more than the control. The concentration of F. vulgare hydrosol influenced the production and viability of T. harzianum spores in the cob substrate. Study Limitations/Implications: This study provides information on the use of hydrosol, which are typically considered waste products. Findings/Conclusions: At low concentration, F. vulgare hydrosol can be used to enrich corn cob and promote the growth of T. harzianum. [ABSTRACT FROM AUTHOR]

Silver nanoparticles (AgNPs) are widely used in the field of biomedicine. However, the synthesis of AgNPs by traditional physical and chemical methods has problems such as pollution, product toxicity, and time-consuming. Therefore, it is extremely important to explore the preparation of AgNPs. Silver nanoparticles (AgNPs) of sweet corncob poly- saccharide (SCP-AgNPs) were successfully synthesized by green method using sweet corncob polysaccharide (SCP) as raw material and the reaction conditions were optimized. The generated AgNPs were characterized by transmission electron microscopy (TEM), X-ray diffraction, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy, and their antioxidant and anti-diabetic abilities in vitro were investigated. The results showed that the optimum reaction conditions of SCP-AgNPs were as follows: The concentration of silver nitrate in the solution was 0.75x10-3 mol/L, the pH was 10.0, and the reaction time was 80 min. The prepared SCP-AgNPs were spherical with an average particle size of 13.5 nm. The structure showed a face-centered cubic crystal structure, and Ag was determined to be Ag0 state. The synthesized SCP-AgNPs had strong free radical scavenging effect in vitro. At the same time, SCP-AgNPs had a good inhibitory effect on the activity of α-glucosidase and α-amylase. SCP-AgNPs has a significant inhibitory effect on key enzymes of diabetes and has potential anti-diabetic activity. It is a nano-drug suitable for nano-biomedical applications and will be widely used in food processing, medicine and other fields in the future. [ABSTRACT FROM AUTHOR]

In Tuban, farmers have great potential to manage corn cob waste into alternative fuels, but there is still a lack of experience and awareness of waste management. This research aims to develop an educational model that can increase the utilization of waste. The method used is Design-Based Research (DBR) with a qualitative approach, including problem identification, needs analysis, model development, and model testing through workshops. The survey results show that most farmers have not managed corn cob waste properly. The workshop succeeded in increasing farmers' knowledge about waste management and producing alternative fuel products. The educational model developed is effective in increasing farmers' awareness and skills in waste management. In conclusion, this sustainable consumption education model is effective in increasing the use of corn cob waste as an alternative fuel. For long-term success, it is necessary to pay attention to the aspects of technology, flexibility of participation, and freedom of expression in the Generation Z farming community. [ABSTRACT FROM AUTHOR]

A sustainable bioeconomy in agricultural and agro-industrial production must inevitably involve the sustainable use of agricultural residues through zero-waste processes. Corn cob is considered crucial agricultural waste as 278 and 293 million tons were produced worldwide in 2022 and 2023, respectively. Corn cob hydrolysates, which are abundant in xylose and glucose, could be efficiently utilized for xylitol and ethanol production through the cultivation of recycling the yeast strain Candida magnoliae TISTR 5664 in the single-stage and sequential-stage co-production of these products. The statistically significant maxima (p ≤ 0.05) ethanol concentrations were improved by 7.8% (49.9–51.7 g/L or 91.3–95.6% of the theoretical) from the single stage of ethanol production employing recycled cells and 9.9% (50.9–54.1 g/L or 77.3–83.9% of the theoretical) from the second step of sequential-stage co-production using recycled cells without xylitol accumulation. Conversely, the single-stage xylitol production utilizing recycled cells under microaerobic conditions resulted in a statistically significant lower (p ≤ 0.05) xylitol concentration by two folds relative to the control, while ethanol concentration was elevated by almost double. The statistically significant maximum (p ≤ 0.05) xylitol was achieved at 25.9 g/L (58.6% of the theoretical) when sequential-stage co-production was initiated in the first step with fresh inoculum only and not recycled cells. The sequential-stage co-production of xylitol and ethanol presented the potential for statistically significant improvement (p ≤ 0.05) of both xylitol and ethanol production processes. [ABSTRACT FROM AUTHOR]

The threshing rate is one of the important indexes to evaluate the effect of corn threshing. The weighing method is often used to calculate the depuration rate of maize at present. This method is time-consuming and laborious and can only calculate the overall threshing rate but does not give the threshing rate of individual corn ears. Different parameters of corn ears have complex effects on the threshing rate. By analyzing the threshing rate of each corn ear, we can choose the appropriate ear treatment method, optimize the processing equipment and process flow, and improve the threshing performance. This paper presents a method based on machine vision to detect the threshing rate of corn ears. In this method, machine vision was used to measure the parameters of the corncob and the area of the top of residual kernels. The area of the top of all kernels was restored based on the parameters of the corncob. The threshing rate of corn ears was calculated by the ratio of the area of the top of the missing kernel to the area of the top of all kernels after threshing. A bivariate linear regression area model was established to restore the area of the top of all corn kernels based on corncob parameters. The R2 was more significant than 0.98, and the goodness of fit was good. The machine vision inspection results showed that the maximum relative error of length and midsection radius was 7.46% and 5.55%, and the mean relative error was 2.58% and 2.23%. The maximum relative error of the corn ear threshing rate was 7.08%, and the mean relative error was 2.04%. When the residual kernels were concentrated in the midsection, the inspection result of the corn ear threshing rate was better. The maximum relative error was 3.98%, and the mean relative error was 1.07%. This paper provides a new idea and reference for measuring the threshing rate of corn ears. [ABSTRACT FROM AUTHOR]

The influence of 2 wt.% additives of expired paracetamol and naproxen on the thermal behaviour of densified samples of pea husks (PH), corncobs (CC), and sunflower inflorescences (SI) was studied using an analytical TG/FTIR unit. Gaseous, liquid, and solid pyrolysis products were evaluated using XRD, SEM, and EDX techniques along with FT-IR, ATR, and UV spectroscopies. It was found that the additives changed the yield and composition of pyrolysis products differently. The addition of paracetamol increases the contribution of guaiacyl rings in the condensed material of all samples, and the addition of naproxen—that of chromophores originating from the decomposition of lignin. The additives diversely affected the contribution of hydrocarbons in the composition of volatile products of pyrolysis: they decreased this contribution in PH samples, increased it in SI samples, and did not change in CC samples. The additives used changed the morphology and composition of organic and inorganic parts of pyrolyzed biomass. These changes in inorganics caused the changes in the composition of pyrolysis products. The conducted research proves not only the possibility of the utilization of expired pharmaceuticals during their pyrolysis with densified PH and CC samples but also the ability to reduce the undesirable hydrocarbons in the obtained volatile products. [ABSTRACT FROM AUTHOR]

Nitrate contamination in groundwater is a global concern due to its widespread presence and consequential social, environmental, and economic ramifications. This study investigates the efficacy of biological denitrification in a humid tropical setting, utilizing corn cob in batch and column tests to assess nitrate removal under varying conditions. Batch tests demonstrated the nitrate removal efficiencies of 93.14%, 91.58%, 90.77%, and 98.74% for initial concentrations of 22.18 ± 2.82 mg/L, 27.3 mg/L, 69.1 ± 1.2 mg/L and 115.08 ± 1.88 mg/L, respectively. In the column test, the removal efficiency was 99.86%, 87.13%, and 74%, and the denitrification rate was 32.82, 53.43, and 83.53 mg NO3−-N/L d, for a hydraulic retention time (HRT) of 24 h, 16 h, and 7 h, respectively. Predominantly, nitrate removal occurred via biological denitrification, particularly favoring a 24 h HRT. The corn cob effectively removed high nitrate concentrations of up to 115 mg NO3−-N/L. Scanning electron microscopy and Fourier transform infrared spectroscopy revealed surface characteristic changes of the carbon source pre- and post-denitrification. This research sheds light on the potential of biological denitrification using corn cob in humid tropical environments, offering a promising avenue for addressing nitrate contamination challenges in groundwater systems. [ABSTRACT FROM AUTHOR]

A greater contribution energy production in the future should be expected from agricultural biomass, because current research indicates low utilization of agricultural biomass specifically in the direct combustion process. The paper presents an example of energy integration of the corn cob in the process of drying seed corn. The paper presents the efficient method of drying corn seed with one's own corn cob. The technological process of drying is presented through the technological process of operation of the corn seed dryer on the corn cob, the energy industrial plant of the dryer and the technological process of two-pass drying of the cob. The main characteristic of a given dryer is the process of two-pass drying of the cob, because the air passes through the cob layer twice and in that way energy is saved. The drying time on the presented dryer has been shortened from the usual time from 90-80 hours, i.e. by 11%. This increase in performance results in a 15% reduction in dryer operating costs. [ABSTRACT FROM AUTHOR]

Due to environmental pollution and global warming, the use of renewable energy sources such as agricultural residues is gaining attention. Corn is the main source of food in many countries, and after harvesting it, the agricultural and industrial sectors generate significant amounts of residues. This study focused on corncob processing, its preparation, and the evaluation of its characteristics for energy needs. There was no significant difference between drying with active ventilation in the dryer and outdoor drying conditions. The adequate moisture content of corncob pellets is 12.39% at a compression ratio of 3.43 ± 0.011 and a maximum pellet density of 1012.96 ± 3.35 kg m−3. The variation in pellet density at a given adequate moisture content is at least 0.78%. The compression ratio of the pellets compacted on the horizontal matrix granulator is 9.75% higher than that of the pellets produced on the laboratory automatic press. The corncob's lower calorific value was 17.35 ± 0.14 MJ kg−1, and the ash content was 1.78 ± 0.24%. The produced pellets are strong enough and can be used for combustion. This research may help to better understand the properties of corncobs and their energy potential. [ABSTRACT FROM AUTHOR]

Adequate bowel cleansing is crucial for endoscopic diagnosis and treatment, and the recovery of gut microbiota after intestinal cleansing is also important. A hypertonic syrup predominantly comprising l-arabinose and d-xylose (20% xylo-oligosaccharides) can be extracted from the hemicellulose of corn husks and cobs. l-Arabinose and xylo-oligosaccharides have been reported to relieve constipation and improve the gut microbial environment. This study evaluated the bowel cleansing effect of the aforementioned syrup and its influence on the organism and intestinal microbiota after cleansing in comparison with polyethylene glycol-4000 (PEG-4000) in mice. Bowel cleansing was performed using syrup or PEG-4000 in C57BL/6J mice, and the effect of intestinal preparation and its influence on serum electrolytes and gut microbiota after bowel cleansing were evaluated. The volume of intestinal residual feces in the syrup group was significantly lower than that in the PEG-4000 group. Additionally, syrup disturbed serum electrolytes more mildly than PEG-4000. Alpha diversity in the gut microbiota was significantly higher in the syrup group than in the PEG-4000 group on the first day after bowel cleansing. However, no difference in beta diversity was observed between the two groups. Syrup increased the abundance of Bifidobacteria and Christensenella and decreased the abundance of Akkermansia in comparison with PEG-4000 on the first day after bowel cleansing. Thus, this syrup has potential clinical use as a bowel cleansing agent given the above effects, its benefits and safety, and better taste and acceptability. [ABSTRACT FROM AUTHOR]

In this study, a novel radio‐frequency cold plasma‐assisted extraction (CPAE) process was developed for the extraction of anthocyanins from a type of agricultural biomass waste, purple corncob. The effects of cold plasma pretreatment on anthocyanin extraction were investigated, and this process was further optimized using response surface methodology. The components of purple corncob anthocyanins (PCAs) were analyzed by super‐high performance liquid chromatography‐mass spectrum. The antioxidant activity of PCAs was evaluated through 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) and 2′‐azinobis‐(3‐ethylbenzthiazoline‐6‐sulfonate) (ABTS) scavenging capacity assays in vitro and physiological behaviors in vivo for Caenorhabditis elegans. The results showed that the optimal conditions of cold plasma pretreatment were discharge power 127 W, working pressure 150 Pa, and the treatment time 75 s. The maximum yield of PCAs was about 4.05 ± 0.05 mg/g corncob, much higher than that of the conventional solvent extraction and ultrasonic‐assisted extraction. PCAs were mainly composed of pelargonidin‐3‐galactoside (66.02 wt.%), cyanidin‐3‐galactoside (25.95 wt.%), cyanidin (8.02 wt.%), and petunidin‐3‐galactoside (0.02 wt.%). The extracted anthocyanins reflected the superior antioxidant activity. In terms of in vitro antioxidant ability, the half maximal inhibitory concentration (IC50) of PCAs for DPPH and ABTS were slightly lower than those of ascorbic acid. Meanwhile, C. elegans exhibited positive effects on several physiological behaviors by feeding PCAs, including a 29.25% increase in lifespan, and increases in antioxidant capacity, superoxide dismutase, and catalase (CAT) activity of 26.28%, 28.93%, and 22.24%, respectively. The CPAE process is therefore a highly competitive candidate for the realization of industrial PCAs extraction, combining some additional advantages of cold plasma treatment such as green process, low cost, short treatment time, and scale‐up production. Practical applications: Agricultural biomass wastes (e.g., corncob, straws, and husks) contain a large number of high value‐added natural active ingredients (e.g., polysaccharides, anthocyanins, and polyphenols). However, a highly efficient extraction of these natural active ingredients is always sought, as the protection of lignocellulosic cell walls hinders the extraction of intracellular products. In this work, the cold plasma‐assisted extraction (CPAE) process showed a comparatively higher anthocyanin yield than the conventional solvent extraction and ultrasonic‐assisted extraction processes. This was due to the fact that the high‐energy helium plasma attack readily broke down the lignocellulosic structure of the plant cell walls, resulting in the rapid release of intracellular purple corncob anthocyanins into the extraction medium. This study suggests that the CPAE process will become an emerging application for the industrial extraction of high value‐added natural active ingredients from agricultural biomass wastes. [ABSTRACT FROM AUTHOR]

Background and objectives: The possibility of using agricultural lignocellulosic residues as a complementary raw material for the production of wood composite products can have a good economic justification. This will be possible if the manufactured product exhibit the desired and standard quality. However, woody material can impose a detrimental effect on the physical and mechanical properties of the final product. Therefore, conducting laboratory and research studies in order to recommend a raw material is essential for consumption in industry. The utilization of agricultural lignocellulosic residues in wood composite products industries has been the subject of various research activities in different parts of the world. In this research, in order to improve the mechanical and physical properties of wood-plastic, nanoclay particles have been used as reinforcements and corncob residues have been used with poplar wood. Methodology: The amount of polypropylene and lignocellulosic material were 60 wt% and 40 wt% respectively. The Nano-clay was added in three levels 0, 2 and 4 wt% and the amount of coupling agent was fixed and set to 2 wt% for all treatments. The control samples were made using polypropylene material. Results: The results showed that the tensile and flexural strengths were increased at the mixture of 25 corncob residues and 75 poplar wt% particles. For tensile and flexural modulus, adding 2 wt% nano-clay led to an increase in strength and modulus but there was a decrease when 4 wt% nano-clay was used. The impact strength increased by adding nano-clay. Conclusion: According to the mechanical and physical properties of all the treatments, the samples which were made of 25 corncob and 75 poplar wt% particle with 2 wt% of Nano-clay had better results compared to other samples. [ABSTRACT FROM AUTHOR]

There has been a recent increasing interest in Zn–air batteries as an alternative to Li-ion batteries. Zn–air batteries possess some significant advantages; however, there are still problems to solve, especially related to the tuning of the properties of the air–cathode which should carry an inexpensive but efficient bifunctional oxygen reduction (ORR) and oxygen evolution (OER) reaction electrocatalyst. Biochar can be an alternative, since it is a material of low cost, it exhibits electric conductivity, and it can be used as support for transition metal ions. Although there is a significant number of publications on biochars, there is a lack of data about biochar from raw biomass rich in hemicellulose, and biochar with a small number of heteroatoms, in order to report the pristine activity of the carbon phase. In this work, activated biochar has been made by using corncobs. The biomass was first dried and minced into small pieces and pyrolyzed. Then, it was mixed with KOH and pyrolyzed for a second time. The final product was characterized by various techniques and its electroactivity as a cathode was determined. Physicochemical characterization revealed that the biochar had a hierarchical pore structure, moderate surface area of 92 m2 g−1, carbon phase with a relatively low sp2/sp3 ratio close to one, and a limited amount of N and S, but a high number of oxygen groups. The graphitization was not complete while the biochar had an ordered structure and contained significant O species. This biochar was used as an electrocatalyst for ORR and OER in Zn–air batteries where it demonstrated a satisfactory performance. More specifically, it reached an open-circuit voltage of about 1.4 V, which was stable over a period of several hours, with a short-circuit current density of 142 mA cm−2 and a maximum power density of 55 mW cm−2. Charge–discharge cycling of the battery was achieved between 1.2 and 2.1 V for a constant current of 10 mA. These data show that corncob biochar demonstrated good performance as an electrocatalyst in Zn–air batteries, despite its low specific surface and low sp2/sp3 ratio, owing to its rich oxygen sites, thus showing that electrocatalysis is a complex phenomenon and can be served by biochars of various origins. [ABSTRACT FROM AUTHOR]

This research work focuses on the preparation and characterization of activated carbons derived from biomass residues as potential adsorbents for carbon dioxide (CO2) capture applications under ambient conditions. Three abundantly available and inexpensive raw materials, viz., (i) corn cob, (ii) sugarcane bagasse, and (iii) wheat straw, are used to prepare activated carbon using carbonization and activation methods. Characterization techniques such as (a) Nitrogen (N2) adsorption/desorption, (b) Scanning Electron Microscopy, (c) Fourier Transform Infrared Spectra, (d) Thermogravimetric Analysis, and (e) proximate and ultimate analyses are used to examine the surface texture and physiochemical parameters of the adsorbents, including surface area, pore volume, pore diameter, surface morphology, structural features, thermal stability, and quantitative and elemental compounds. The adsorption–desorption isotherms of CO2 uptake capabilities of adsorbents are evaluated at 1 bar pressure, with temperatures varying from 0 to 90 °C. The significant parameters of adsorbents' adsorption, such as (i) CO2 adsorption–desorption isotherms, (ii) CO2/N2 adsorption, (iii) recyclability, (iv) breakthrough curve and (v) isosteric heat of adsorption (△Hads) are determined. The N2 adsorption/desorption investigation shows that the tested adsorbents are highly porous and crucial for post-combustion carbon capture. Values of △Hads for activated carbon samples are below 40 kJ/mol, which ensures the physical adsorption process. The findings suggest that adsorbents are most appropriate for multiple gas sorption applications. The anticipated characteristics will benefit for actual system development. [ABSTRACT FROM AUTHOR]

In 2021, Mexico produced approximately 24.2 million tons of white corn, generating 3.6 million tons of corn cob residue. The final disposal of corn cob poses an environmental challenge in certain regions. This study examines the technical–economic feasibility and the greenhouse gas (GHG) mitigation potential of integrating a small-scale cogenerating gasifier fueled by corn cob into a nixtamalized corn flour manufacturing small and medium-sized enterprise (SME). This integration enables the generation of heat and electricity from the produced synthesis gas. Moreover, the process yields residual carbon, which can be used as biochar for soil restoration and removing atmospheric CO2. This option holds significance for the corn flour agroindustry in Mexico, as, in 2021, it consumed approximately 601.9 GWh of electrical energy and 938,279 GJ of thermal energy from LP Gas in its manufacturing processes to produce 2.6 million tons of nixtamalized white corn flour. These processes contributed to a total emission of 410,232 tons of CO2 into the atmosphere. The findings of this study demonstrate a cumulative reduction of 51.7% in CO2 emissions, resulting in economic benefits of USD 85,401 in 2017 for a case study SME that annually produces 1039 tons of corn flour. This study reveals the integration of a gasifier–cogenerator system fueled by corn cob as an economically viable low-carbon technology in the corn flour manufacturing industry. [ABSTRACT FROM AUTHOR]

This study reported the isolation of cellulose from corn cob by using microwave-assisted alkaline treatment and bleaching. The Central Composite Design (CCD) approach of Response Surface Methodology (RSM) was applied to study the effect of sodium hydroxide (NaOH) concentrations (1.5-2.5M), duration of alkaline treatment (4-8 min), hydrogen peroxide (H2O2) concentrations (7-9 wt%) and bleaching time (3-7 min) on the removal percent of non-cellulosic components and impurities from corn cob. The optimized conditions obtained from this study were 2.37M NaOH, 9 wt% H2O2, alkaline treatment time of 4 min, and bleaching time -- 4.20 min. The non-cellulosic part and the impurities removed under the optimized conditions in microwave-assisted alkaline treatment and bleaching amounted to 72.26 ± 0.15%. The cellulose content in the thus purified corn cob material was determined as 92.47%. The isolated corn cob cellulose was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), and the thermogravimetric analysis (TGA). These characterizations confirmed that the alkaline treatment and microwave-assisted bleaching under the optimized conditions achieved the optimal removal percent of the non-cellulosic components and impurities from the corn cob biomass to achieve highly purified cellulose. [ABSTRACT FROM AUTHOR]

This study investigates the combustion of agricultural biomass rich in alkali elements in the fluidized bed. The experiments were performed with smashed corn cob in a 500 kW fluidized bed combustor which was designed for work under low bed temperatures (650–700 °C). During the experiments, the formed compounds from corn cob combustion were measured by sampling particulate matter, and mineral compositions were determined. Also, the temperature profile of the FBC was established. It was determined that the emissions of K and Na elements from the FBC increased from 4 to 7.3% and from 1.69 to 3%, respectively, changing the bed temperature from 650 to 700 °C. Though alkali emissions are reduced at a 650 °C bed temperature, CO emissions are higher by about 50% compared to the case of 700 °C. The addition of 3% of dolomite reduced the pollutant emissions and alkali emissions as well. Potassium content decreased by about 1% and 4%, respectively, at the bed temperatures of 650 °C and 700 °C. The NOx emissions were less than 300 mg/m3 and did not exceed the limit for medium plants regarding DIRECTIVE (EU) 2015/2193. During extended experiments lasting 8 h, no agglomeration of the fluidized bed was observed. Moreover, the proposed configuration of the FBC and its operational parameters prove suitable for facilitating the efficient combustion of agricultural biomass. [ABSTRACT FROM AUTHOR]

Aiming at the high crushing rate and impurity rate of corn kernel machine harvesting in the Huanghuaihai region, a longitudinal flow conical variable pitch threshing device is designed, which adopts the combined threshing element of "plate teeth + ribs" and the combined threshing concave plate of "leftward round tube type + vertical round tube type". The cob model was established, and the force analysis of the cob threshing process was carried out, and the type of threshing drum and the installation angle of the threshing concave plate round tube were determined as the main influencing factors, and the collision force on the corn cob was taken as the test index. Using EDEM discrete element simulation software, simulation tests were carried out on different types of threshing drums and threshing concave plates with different installation angles of round tubes with corn cobs, and the better threshing method was finally determined: a conical threshing drum at a drum speed of 450 r/min, and a combination of left-facing round-tube-type + vertical round-tube-type threshing concave plates with an installation angle of 10° (front-sparse and back-dense type) were used. Compared with the vertical circular tube type threshing concave plate, the corn cob contact force decreased from 313.5 N to 247.3 N, which was optimal for threshing in the range allowed by the corn kernel destructive force. [ABSTRACT FROM AUTHOR]

Nebraska is the number one producer of food‐grade white corn in the United States. Pollen‐mediated gene flow (PMGF) from genetically engineered high alpha‐amylase corn, known as Enogen corn, to food‐grade white corn can have undesirable outcomes. Alpha‐amylase can convert starch in white corn to sugar during or after its processing, degrading the quality of processed products. Thus, proximity to Enogen corn puts white corn production at risk. The objectives of this study were to evaluate the PMGF from herbicide‐resistant yellow corn to food‐grade white corn and assess the significance of wind speed and direction. Field experiments were set up using a Nelder‐wheel design in 2021 and 2022 in Nebraska, with yellow field corn as pollen donor in the center and white corn surrounding it as pollen receptor. At the end of the season, samples of white corn cobs were collected up to 50 and 70 m from four cardinal and ordinal directions, respectively. PMGF was detected by counting the number of yellow kernels on the white cobs. More than 4 million kernels were screened and the highest frequency of PMGF (0.0621–0.1950) was detected at the nearest distance (1 m). PMGF decreased exponentially with distance; however, it was still observed (0.0020–0.0032) at the greatest distance (70 m) evaluated in this study. Wind profile played a significant role in PMGF. Wind frequency (r = 0.58 ≤ 0.86) and wind run (r = 0.36 ≤ 0.95) were moderately to strongly correlated with PMGF in 2021 and 2022, respectively. The results are concerning for white corn growers due to the coexistence of Enogen corn and food‐grade white corn. Core Ideas: The pollen‐mediated gene flow (PMGF) from yellow corn to white corn was greatest at the nearest distance (1 m).The exponential decay model was the best fit to explain PMGF with distance from the yellow corn.Wind parameters such as wind speed, direction, and frequency affected PMGF, signifying the role of wind in PMGF in corn. [ABSTRACT FROM AUTHOR]

Solar-driven seawater desalination has been one of the most promising approaches to alleviate energy pressure, freshwater resource shortage and environmental crisis. Solar interfacial evaporation can be confined the heat into the evaporation surface, in order to avoid the bulk water heating for the energy saving. In this study, the dopamine was used to modify the natural corncobs, in order to reduce the degradation of natural biomass for the high evaporation efficiency in seawater desalination. A solar interfacial evaporator was prepared to integrate the photothermal conversion, water transportation, and thermal insulation. The substrate was selected as the carbon black-cellulose film coating on the modified corncob. The light absorptance of natural corncobs with/without the carbon black-cellulose film were measured using a UV-visible spectrophotometer. The corncobs with carbon black-cellulose film was significantly improved the absorption performance, with an average absorption rate of 94% in the entire solar radiation band. The contact angle of water droplets on the modified corncobs was about 29.9°, which was reduced significantly. The hydrophilicity of the modified corncobs was enhanced for the transfer of water in the corncobs. The water transportation along the corncob was visually displayed using infrared images. Once the bottom of the corncob came into the contact with water, no water transport was observed within the unmodified corncob in 60 min. By contrast, the water was observed at a lower temperature along the dopamine modified corncob, indicating the better performance of water transport than before. The evaporation mass of modified and unmodified corncobs was measured under the same conditions. Both the corncobs were covered with the carbon black-cellulose film. The evaporation rates were 1.38 and 1.25 kg/(m²·h) in the modified and unmodified corncob evaporator respectively. There was the increase by about 10.4% in the modified corncob, compared with unmodified ones. Another indicator was the stability of evaporators in seawater environment under cyclic operation for a long time, in order to evaluate the performance of evaporators. There was no salt crystallization on the surface after continuous irradiation of the modified corncob evaporator with a light intensity of 1 kW/m² for 8 hours. 30 cycle experiments were conducted on the modified corncob evaporator. The evaporation rate was 1.374 kg/(m²·h) in the first test, and the second after 30 cycles, the evaporation rate was 1.36 kg/(m²·h). The fluctuation of evaporation rate was with 1% over the 30 cycle experiments, indicating the stable evaporation rate. Moreover, the adhesion of dopamine was remained intact without salt deposition in the multiple cyclic experiments. There was no softening or material degradation in the modified corncob under seawater environments, indicating the long-term stability. Seawater distillation experiments was conducted in outdoor environments, in order to analyze the water production and ion removal of corncob evaporators. The daily water production reached 10.171 kg/m². The various ions in seawater and condensate were measured using the Varian 720-ES inductively coupled plasma emission spectrometer (ICP-OES). The concentrations of the main ions Na+, K+, Mg2+, and Ca2+ in condensate significantly decreased by about four orders of magnitude, reaching the limits of the drinking standards released by the World Health Organization (WHO). The evaporating seawater through corncobs can obtain the fresh water to fully meet drinking standards. The modified corncob evaporator was simple preparation, cost-effective and stable evaporation performance. The finding can provide an effective way to expand the application of biomass materials in the field of seawater desalination. [ABSTRACT FROM AUTHOR]

In this paper, a series of corncob carbon modified g-C 3 N 4 composite catalyst with excellent visible light response properties was synthesized via a simple one-pot co-solvothermal method. The catalysts displayed enhanced adsorption performance and photocatalytic activity of 98.89 % and 99.08 % on Rhodamine B (RhB) and methyl orange (MO) removal efficiency under visible light irradiation, respectively. The superoxide radical and hydroxyl radical were the dominant reactive oxygen species involved in the photocatalysis reaction. The significantly enhanced adsorption and photocatalytic performance of the catalysts was ascribed to the porous structure and the strong interactions between g-C 3 N 4 and corncob carbon. After six cycles of experiments, the catalysts still exhibit stable and high performance for the removal efficiency of RhB and MO. Based on the analytical results, a possible mechanism of photocatalytic degradation was proposed in detail. The corncob carbon modified g-C 3 N 4 composites can be regarded as a potential catalyst in the application of the dye wastewater treatment. [ABSTRACT FROM AUTHOR]

In recent years, the production of municipal sludge has gradually increased, and finding suitable sludge treatment and disposal technologies is an urgent problem that needs to be solved. Bio-drying of sludge is a relatively efficient and convenient drying method, but currently, there are still problems with unstable drying effects and high moisture content of dried products, which limits the subsequent utilization of bio-drying products. This article uses a thermal assisted bio-drying device that simulates carbonization waste heat reflux, and uses corncob, straw, sawdust, and rice husk as conditioners to carry out bio-drying of dehydrated sludge. The influence of the types and ratios of conditioner under thermal assistance on the bio-drying of dehydrated sludge is explored. The results showed that the moisture removal efficiency of the corncob and straw groups was better, and their material moisture content could be reduced to below 10% within 24 h. The lower calorific value of straw-sludge drying products was the highest, at 11,608.8 kJ/kg. The best conditioner under the conditions of this experiment was straw, and the drying effect was best when the mass ratio of dehydrated sludge to straw was 4:1. The research results contribute to promoting the development of sludge bio-drying technology. [ABSTRACT FROM AUTHOR]

Waste management and recycling have led to numerous studies on particleboard production. This study attempted to use milled corncob (MCC) and waste ceramic tiles (WCTs) to produce particleboard. The MCC (100−70 wt.%) and WCT (0–30 wt.%) were mixed at different ratios, mixed and compressed at a pressure of 0.25 MPa using urea formaldehyde (UF) resin as adhesive. The physicomechanical and thermal properties of the particleboards produced were investigated. The physical properties (bulk density, water absorption, and thickness swelling) improved with composite particleboard compared to the 100% MCC particleboard. The increase in WCT yielded improved density and lowered the particleboard's water absorption and thickness swelling. The mechanical tests showed that MOE values were below the recommended standard, which makes them unsuitable for structural use. However, MOR revealed values above the recommended standard. The thermal conductivity of the particleboards was reduced with increased WCT, and the required standard was found to be met. Hence, the particleboards produced are found helpful as thermal wall insulators. Based on the experiments done, sample R7 (70% MCC and 30% WCT) was considered the most preferable since it achieved the most preferable physicomechanical and thermal conductivity performance. The particleboards produced are recommended for wall partitioning and other internal and external purposes. [ABSTRACT FROM AUTHOR]

This study investigates gasification using wood chips (WC) and corn cobs (CC) for hydrogen-rich syngas production. A simulation model developed in Aspen Plus was used to evaluate the performance of biomass gasification. The model incorporates a system of Fortran subroutines that automate the definition of input parameters based on the analysis of biomass composition. Furthermore, the model's equilibrium constants were adjusted based on experimentally measured gas concentrations, increasing the precision of the variations. The numerical results predicted hydrogen yields of 65–120 g/kg biomass, with 60–70% energy efficiency for steam gasification (versus 40–50% for air gasification). The hydrogen concentration ranged from 34% to 40%, with  C O  (27–11%),  C O 2  (9–20%), and  C H 4  (<4%). The gasification temperature increased hydrogen production by up to 40% but also increased  C O 2  emissions by up to 20%. Higher biomass moisture content promoted hydrogen production by up to 15% but reduced energy efficiency by up to 10% if excessive. Steam gasification with wood chips and corn cobs shows promising potential for hydrogen-rich syngas production, offering benefits such as reduced emissions (up to 30% less  C O ) and sustainability by utilizing agricultural residues. [ABSTRACT FROM AUTHOR]

Four novel magnetic-activated carbons (MACs) were prepared, characterised, and used as adsorbents to remove heavy metal ions from wastewater samples. The MACs prepared, are advanced adsorbents for the removal of Hg(II), Cr(III), Cd(II), and Pb(II). The nature of the acid, amount, composition of the MACs, and the remotion time were evaluated in aqueous solutions. The ions removal percentages obtained, under the best conditions, were 93% for Hg(II) and higher than 99% for Pb(II), Cr(III), and Cd(II) (100 mg L−1, initial concentration in solution), with 100 mg of the MAC-3 in HNO3 3 mM. The capacity of the best adsorbent, MAC-3, for removing heavy metals ions Hg(II), Cr(III), Cd(II), and Pb(II) was studied using Langmuir and Freundlich adsorption isotherms under the best condition. The maximum adsorption capacities of Hg(II), Cr(III), Cd(II), and Pb(II) were found to be 10.72, 11.51, 11.49 and 11.49 mg g−1, the values of constants of Freundlich models were 17.98, 26.83, 9.18, and 7.18 mg g−1 respectively. For Hg(II) and Pb(II) the correlation factor (R2) was better for Freundlich model, while Cr(III) and Cd(II) showed better R2 with Langmuir model. Finally, the treatment for the elimination of heavy metal ions was carried out, with wastewater samples of industrial and domestic origin, and used for crop irrigation. The samples were collected in Irrigation District 003, Hidalgo, Mexico. The MAC-3 removes heavy metal ions from the wastewater matrix above 99%. [ABSTRACT FROM AUTHOR]

Industrial wastewater from various manufacturing sectors poses a significant environmental concern due to the release of dyes, heavy metals, and pollutants into natural water streams. Effective treatment of large volumes of industrial wastewater is crucial to mitigate this issue. Conventional industrial wastewater filtration systems often prove to be inefficient, necessitating the exploration of alternative and cost‐effective water filtration methods. In this study, we drew inspiration from the natural adsorption and purification properties of corncob to develop a novel green composite membrane filter. The composite membrane filters, named MCAPCB and MCATPCB, were formulated by incorporating powdered corncob (PCB) and alkali/hydrogen peroxide‐treated powdered corncob (TPCB) into cellulose acetate. The adsorption properties of the composite filters were evaluated using UV–Vis spectrophotometry for dye adsorption and inductively coupled plasma optical emission spectroscopy (ICP‐OES) and atomic absorption spectroscopy (AAS) for heavy metal adsorption. The results demonstrated that MCATPCB20, incorporating 20 wt% TPCB, exhibited remarkable performance in the removal of methylene blue dye, with an adsorption efficiency of 97.46%. In comparison, MCAPCB20, incorporating 20 wt% PCB, achieved a dye adsorption efficiency of 80.15%. Moreover, MCATPCB20 displayed exceptional heavy metal removal capabilities, effectively rejecting 98% and 95% of cadmium and lead, respectively, from water samples containing 1 ppm of each metal. The composite filter membranes containing 20 wt% TPCB exhibited superior adsorption efficiency, flexibility, and stability. This enhanced performance can be attributed to the higher carboxyl content in TPCB, achieved through alkali treatment, which significantly increased the adsorption capacity of MCATPCB20. Characterization studies employing XRD, SEM, contact angle, BET, ICP‐OES, and UV measurements further supported the efficacy of MCATPCB as an effective filter system for water purification. [ABSTRACT FROM AUTHOR]

Backround: Helicoverpa armigera is major maize pest, while Conopomorpha cramerella is cocoa is main insect pest. Their larvaes lie in corn cob and cocoa pulp which can be controlled using egg parasitoids. Methods: Exploring H. armigera eggs on female flowers on a corn plant along the 50 m line at 10 points with a 4 m distance to obtain parasitoids. C. cramrella. Egg parasitoids were obtained by taking eggs from cacao pod, while Corcyra cephalonica from egg traps along a straight line with 10 points with 3 m distance. Result: H. armigera egg parasitoids include Trichogramma sp. and Trichogrammatoidea armigera. Corn grown in between coconut palms has higher parasitism than without coconut palm shade and highest parasitism was in Bolaang (60.91±2.52%). Parasitoids of Trichogaramma sp. produce unrearable female offsprings in C. cephalonica eggs. Dominant Trichogrammatoidea sp. were found in egg traps while only two C. cramerella parasitized eggs were found in cacao pod. Dominant Trichogaramma sp. Parasitoids in egg traps were found in Tombariri. C. cephalonica egg trap is the latest method for monitoring Trichogrammatoidea sp parasitoid The parasitism of Trichogrammatoidea sp. on C. cramerella eggs and C. cephalonica egg traps is low. [ABSTRACT FROM AUTHOR]

In response to the escalating costs and diminishing efficiency of nitrogen fertilizers, the agricultural community is actively seeking sustainable alternatives that leverage natural nitrogen sources derived from biological N-fixation processes to enhance crop yield. This study investigates the combined effects of Klebsiella quasipneumoniae inoculation and varying nitrogen fertilizer doses on soil fertility, nutrient availability, and the yield and quality parameters of baby corn (Zea mays. L). The study involved the application of five nitrogen levels (0, 75, 150, 225, and 300 kg N ha-1) in conjunction with Klebsiella quasipneumoniae inoculum on HM-4 variety of baby corn, employing a comprehensive experimental design with five treatments and four replications. All treatments demonstrated increased ear count and weights of ear, silk, husk, edible cob, and biomass compared to the control. The study highlights the potential of Klebsiella quasipneumoniae inoculation in synergy with reduced nitrogen fertilizer to enhance total N contents in soil and positively impact baby corn yield and cob quality parameters. Optimal results were achieved with a 50% reduction in nitrogen fertilizer (150 kg N ha-1), emphasizing the importance of integrated nutrient management. The findings contribute valuable insights to sustainable agriculture, offering a promising strategy for increased baby corn production, improved nutritional quality, and environmental conservation. This integrated approach, involving microbial inoculation and nitrogen management, emerges as a key element in modern agricultural practices, promoting both productivity and nutritional content in baby corn crops. [ABSTRACT FROM AUTHOR]

The search for innovative technology or materials that will reduce the challenges of demulsification of emulsions for better efficiency is intensively ongoing in the petroleum industry. It is therefore pertinent to develop innovative materials to achieve the effective separation of emulsions. In this work, two different methods of acid-hydrolyzed process (microwaved and furnace) at different temperatures (180 and 250 °C) were evaluated for the preparation of environmentally friendly biodemulsifier: microwaved ash (MVA) and furnace-based ash (FBA) demulsifiers from corncob. The eco-friendly demulsifiers were characterized by Fourier transform infrared spectroscopy (FT-IR), Gas chromatographic-mass spectroscopic (GC-MS) and Scanning electron microscopy (SEM) and their chemical content and physico-chemical properties compared with a commercial chemical demulsifier (Phase treat). The SEM analysis reveal distinct variation in the morphology of the hydrolyzed ashes, attributed to differences in the hydrolysis conditions, specifically temperature and heating method. The FT-IR spectra of the biodemulsifiers were found to contain functional groups such as OH, C=O and C-O similar to that of the chemical demulsifier. The GC-MS results reveal the presence of amphiphilic compounds in both biodemulsifiers with the ability to break the water-in-oil emulsion as observed in the chemical demulsifier. In the bottle test analysis carried out to determine the efficacy of the biodemulsifiers, it was observed that the MW-based demulsifier performed better with a separation efficiency of 72 % when compared to 60 % and 39% for the chemical demulsifier and FBA -based demulsifier respectively. This work not only promote the efficient utilization of agricultural waste (corncob), but also provides an insight into the exploration of new demulsifying materials with excellent performance. [ABSTRACT FROM AUTHOR]

BACKGROUND AND OBJECTIVES: Preliminary studies on the exploration of carbonaceous materials from agricultural waste and their use as adsorbents for antibiotic removal have shown the potential to address a new threat to human health due to antibiotic residue. Therefore, this study developed and synthesized graphene oxide from corn cob for its efficiency in removing ceftriaxone and ciprofloxacin. METHODS: The Hummers methods were used to synthesize graphene oxide from corn cobs. Graphene oxide was characterized using Fourier transform infrared, scanning electron microscope-energy dispersive x-ray, and x-ray diffraction instruments. During the synthesis process, antibiotic adsorption tests were extensively conducted by exploring four variables, namely dosage of adsorbent, potential hydrogen, concentration, and contact time. FINDINGS: The result showed that graphene oxide from corn cob effectively removed 47 percent of ceftriaxone and 92.62 percent of ciprofloxacin. Furthermore, to ensure optimum use of the adsorbents, antibiotics ceftriaxone and ciprofloxacin weighing 40 milligrams and 20 milligrams. This is in addition to the initial concentrations of 14 and 2 parts per million, the potential of hydrogen 4, and contact times of 50 and 40 minutes, respectively. CONCLUSION: In conclusion, adsorbents made from corn cobs are better at the removal of ciprofloxacin from water than the antibiotic ceftriaxone. The difference in molecular structure affected the percentage of antibiotic adsorption onto graphene oxide derived from corn cob. This study underscores the potential of the derived material as a promising adsorbent for efficiently removing ciprofloxacin from aquatic environments. The use of agricultural waste as advanced materials to address antibiotic residue pollution provided additional environmental pollution. [ABSTRACT FROM AUTHOR]

Composites based on recycled polypropylene (PP) reinforced with cellulose nanocrystals whit lignin corncob were prepared. The effect of the ratio composites prepared via a compression molding process on the mechanical and thermal properties was analyzed. Corncobs is a little-used agroindustrial residue with a high cellulose content. The corncob was milled and then delignified via the organosolve process in order to get the cellulose unbleached. An acid hydrolysis process was then carried out to obtain lignocellulose nanocrystals (LCNCs). Subsequently, LCNC/PP composites were obtained via termocompression molding using different concentrations of LCNC (0, 0.5, 1 and 2% by weight) previously mixed via extrusion. The residual lignin present in the LCNCs improved the compatibility between the reinforcement and the PP matrix. This was evidenced by the increase in mechanical properties and the stabilization of thermal properties. The results of the mechanical tests showed that the LCNC increases the tensile and flexural modules and strength with respect to neat PP. Composites with 2% of LCNC showed an increase of 36% and 43% in modulus and tensile strength, respectively, while the flexural modulus and strength increased by 7.6%. By using reinforcements of natural and residual origin (corncob) and improving the properties of recycled polymers, their reuse will increase, and this can lead to reducing waste in the environment. [ABSTRACT FROM AUTHOR]

This study aimed to evaluate the effects of dietary levels of soluble and insoluble fibre on the performance and digestive development of slow-growing broilers during the starter period. A total of 400 one-day-old Isa LabelTM male chicks were used that were distributed in a completely randomized factorial design 2 × 2 + 1 (inclusion of 2% or 4% of corncobs as a source of insoluble fibre IF and citrus pulp as a source of soluble fibre (SF); and a control treatment) with eight replicates of 10 birds each. The addition of IF to diets improved the weight gain and feed conversion of broilers at 7 and 21 days of age. Both fibre sources added to diets resulted in higher relative weights of proventriculus + gizzard, liver, small and large intestine. The diets containing an SF source presented positive effects on the duodenal mucosa. In addition, positive effects on the caecal villus to crypt ratio were observed in broilers fed diets containing different types of fibre. It is concluded that dietary inclusion of IF up to 4% maintains the performance, nutrient metabolism and improves the development of the proventriculus + gizzard in slow-growing broilers. However, for improving the morphological and histomorphological parameters of slowgrowing broilers in the starter phase the addition of SF sources is recommended. [ABSTRACT FROM AUTHOR]

This research investigated the effect of Waste Marble Dust (WMD) and Corncob Ash (CCA) on expansive soil's engineering and microstructural properties. Various laboratory experiments were performed on the natural soil to ascertain its characteristics. The corncobs underwent pre-water treatment for fourteen days to remove excess potassium and increase their silica content, resulting in a rise in the silica level from 0% to 50%. At first, only WMD was added to the soil in increments of 5% to 30% using compaction and California bearing tests. The optimum dosage of 15% WMD addition yielded the best result. CCA was then incorporated by the weight of the soil from 2% to 10% in increments of 2% to the first optimum (15% WMD) to obtain the overall optimum for the study (15% WMD and 8% CCA). Stabilization of the natural soil using both materials led to the modification and solidification of the soil mass, evident by the rise in California bearing ratio values from 1.68% to 15.53% and unconfined compressive strength from 41.33 kN/m2 to 174.68 kN/m2. There was also a decrease in the soil's free swell from 120% to 15% as well as reductions in the liquid limits from 56.23% to 36.01% and in the plasticity index from 29.74% to 8.72%, respectively. The microstructural images showed the formation of cementitious compounds in the form of calcium silicate hydrate and calcium aluminate hydrate gels. The findings indicate that using WMD and CCA as a unit has great potential in enhancing engineering properties, like strength parameters and the swell potential of expansive soils. [ABSTRACT FROM AUTHOR]

The artificial plywood industry in our country relies heavily on industrial flour as a filler for adhesives. Using abundant corn cob powder as the main raw material, corn cob powder was modified by impregnation with a sodium-based bentonite/bayberry tannin and used as filler for urea–formaldehyde resin (UF) adhesive, with NH4Cl as the curing agent and poplar veneer as the raw material to prepare plywood. The results showed that the modified corn cob powder with a particle size of 250 mesh was uniformly dispersed in the UF adhesive. When used as a filler, the modified corn cob powder effectively prevented the premature curing of the UF adhesive and significantly reduced its viscosity. Compared with flour filler, the bonding strength of the prepared plywood increased by 12.1%–19.6% while the formaldehyde emission decreased by 12.7%–27.8%. The cold pressing performance of the plywoods prepared with modified corn cob flour was comparable to the performance of plywood produced with industrial flour. [ABSTRACT FROM AUTHOR]

A corncob-derived magnetic solid acid catalyst was synthesized through the sulfonation method and an impregnation process, respectively. In the sulfonation process, the concentrated H2SO4 was utilized as an activation agent to obtain acidic properties. The solution of ferric sulphate-ferrous sulphate was utilized for impregnation to generate the magnetic behaviour of the material. The prepared magnetic acid solid catalyst had a high saturation magnetisation value of 16.48 emu/g and a total acidity of 1.43 mmol/g. The performance of the catalyst was evaluated in the esterification reaction of waste cooking oil. The best result presented 86.12% FFA conversion under reaction conditions of 5% catalyst loading and a 1:15 oil-tomethanol molar ratio at 60oC for 4 h. The catalyst was separated magnetically from the reaction solution and exhibited a good reusability with 61% remaining active after 5 consecutive cycles of reaction. This study resulted in a promising method to obtain magnetic-sulfonated carbonbased catalyst from corncob residue, and it is economical potentially and environmentally friendly for the esterification of low-quality feedstock for biodiesel production. [ABSTRACT FROM AUTHOR]

In this study, palladium particles supported on carbon black (Vulcan XC-72) (Pd/C) and corncob biochar (Pd/CB800, Pd/CB900, and Pd/CB1000) were successfully synthesized using borohydride reduction. The biochar support was obtained from corncob waste via pyrolysis from 800 to 1000°C. Scanning electron microscopy with energy dispersive x-ray (SEM–EDX) revealed successful deposition of Pd metal particles on the carbon support materials. X-ray diffraction (XRD) analysis confirmed the crystalline structures of Pd, and the crystallite size was found to be smallest in Pd/CB900. The electrocatalytic activity of the Pd electrocatalyst composites towards ethanol oxidation reaction (EOR) in an alkaline medium was investigated using cyclic voltammetry (CV). CV analysis has shown that Pd/CB900 gave the least positive onset potential (Eonset = −0.587 ± 0.0065 V), highest electrochemically active surface area (EASA = 31.51 ± 2.24 m²·g−1), and highest anodic peak current density (If = 20.77 mA·cm−2) compared with Pd/CB800, Pd/CB1000, and Pd/C. Furthermore, the Tafel plot and chronoamperometry have shown that Pd/CB900 exhibited faster kinetics (Tafel slope = 297.6 ± 4.62 mV·dec−1) and durability (% current retention = 50.64 ± 2.99%) than Pd/C towards EOR in an alkaline medium. This study highlights the simple and straightforward synthesis of the anode electrocatalyst material for direct ethanol fuel cell application. [ABSTRACT FROM AUTHOR]

Microcystins (MCs) and nodularins (NODs) are cyanotoxins that can be found in water bodies during cyanobacterial harmful algal blooms (cyanoHABs). Consumption of water contaminated with cyanotoxins leads to health risks for humans and animals. Herein, corncob-based biochar and activated carbon (AC) were initially investigated for the sorption of six common MC congeners (MC-RR, MC-YR, MC-LR, MC-LA, MC-LW, and MC-LF) and nodularin-R (NOD-R) from spiked water. Biochar was prepared by refluxing commercial corncob with HCl and heating it to 250, 300, or 350 °C. AC was prepared by chemical activation of corncob with H3PO4 at 500 °C under a nitrogen atmosphere. Low-temperature nitrogen adsorption measurements confirmed that H3PO4-AC has a higher specific surface area (≈1100 m2/g) and total pore volume (≈0.75 cm3/g) than biochar and commercial AC. H3PO4-AC showed the maximum efficacy, among all corncob-based sorbents, to remove MCs and NOD-R from water as confirmed by experiments that involved sample analyses by ultrahigh-pressure liquid chromatography-mass spectrometry (UHPLC-MS). The effect of natural organic matter (NOM) on the adsorption of MCs was checked by incubating sorbents with Lake Erie water collected during cyanoHABs from 2020 to 2022. The total concentration (extracellular and intracellular) of studied MC congeners ranged from 1.37 µg/L to 438.51 µg/L and 50 mg of H3PO4-AC completely removed them from 3 mL of lake water. The effect of water pH on cyanotoxin adsorption was studied at pH values of 5.5, 7.0, and 8.5 at both a lower (10 μg/L each) and a higher (50 μg/L each) toxin concentration. Removal was influenced by solution pH at both concentrations when using biochar, while only at higher toxin concentration when using H3PO4-AC. At higher MC and NOD-R concentrations, competitive adsorption was prominent, and overall, the adsorption increased at acidic pH (5.5). The study results suggest that processed corncobs can remove a significant amount of MCs and NOD-R from water, and the measured sorption capacity of H3PO4-AC was ~20 mg of MC-LR and NOD-R per g of this sorbent. [ABSTRACT FROM AUTHOR]

Burning corncob for energy requirements caused a huge waste of biomass resources and serious environment pollution. Herein, this study provided a high-value utilization strategy for corncob. Corncob was first pretreated by hydrothermal process. The collected hydrolysates were converted into furfural by a recyclable solid acid with a yield of 52.35%. The pretreated solid was disintegrated into fibers by disc grinding. When corncob fiber addition is below 15%, the ring crush index, tear index, and tensile strength index of the prepared handsheets increased by 1.43 N·m/g, 0.43 mN·m2/g, and 4.66 N·m/g, respectively, compared with that using pure softwood fibers. Besides, corncob fibers were hydrophilically modified with aminosulfonic acid. Water retention value of paper with the modified fiber addition increased by 48.35%. Therefore, this study provided a method of corncob utilization toward two purposes: furfural production and papermaking. [ABSTRACT FROM AUTHOR]

Maize ranks as the second most widely produced crop globally, yielding approximately 1.2 billion tons, with corn cob being its primary byproduct, constituting 18 kg per 100 kg of corn. Agricultural corn production generates bioactive polysaccharide-rich byproducts, including xylan (Xyl). In this study, we used the redox method to modify corn cob xylan with gallic acid, aiming to enhance its antioxidant and protective capacity against oxidative stress. The conjugation process resulted in a new molecule termed conjugated xylan–gallic acid (Xyl-GA), exhibiting notable improvements in various antioxidant parameters, including total antioxidant capacity (1.4-fold increase), reducing power (1.2-fold increase), hydroxyl radical scavenging (1.6-fold increase), and cupric chelation (27.5-fold increase) when compared with unmodified Xyl. At a concentration of 1 mg/mL, Xyl-GA demonstrated no cytotoxicity, significantly increased fibroblast cell viability (approximately 80%), and effectively mitigated intracellular ROS levels (reduced by 100%) following oxidative damage induced by H2O2. Furthermore, Xyl-GA exhibited non-toxicity toward zebrafish embryos, offered protection against H2O2-induced stress, and reduced the rate of cells undergoing apoptosis resulting from H2O2 exposure. In conclusion, our findings suggest that Xyl-GA possesses potential therapeutic value in addressing oxidative stress-related disturbances. Further investigations are warranted to elucidate the molecular structure of this novel compound and establish correlations with its pharmacological activities. [ABSTRACT FROM AUTHOR]

Agricultural crops produce large number of agricultural wastes. Some of this waste is reused as fertilizers for the agricultural areas, but the remaining amount which represents the majority of the wastes is incinerated in uncontrolled and random ways and has a negative impact on the environment. One of these methods is to burn the maize and sorghum wastes to get rid of the stalks s and corn cob after use. The process of burning results in excessive production of carbon dioxide that pollutes the environment significantly. This study aims to investigate the use of Corn Cob Ash (CCA) as well as Sorghum Stalks Ash (SSA) as a partial replacement of cement in concrete. XRF chemical analysis was carried out on both SSA and CCA, and the results showed that both materials contained high percentages of silica oxide which indicates that these ashes can exhibit pozzolanic activity. The aim of this study is to investigate the effect of using the ashes of corn cobs and sorghum stalks as supplementary cementitious materials on the mechanical properties of concrete. In this study, the ashes of sorghum stalks and corn cobs were used to partially replace the cement in mortar and concrete mixtures. For mortar mixtures the replacement ratios were 5%,10%,20% and 40% while in concrete mixtures the replacement ratios were 5%,10% and 20%. Different concrete and mortar mixtures were tested in compression at different ages and the results showed that CCA and SSA can be used as a partial replacement of cement in both mortar and concrete as there was a significant improvement in the compressive strength, as for mortar mixtures the maximum increase in strength was 22% while the maximum increase in strength of concrete mixtures was 30%. [ABSTRACT FROM AUTHOR]

Sago starch and cellulose fiber can be used as a raw material for making degradable plastics to replace commercial plastics. This research used corn cob fiber and sugarcane bagasse fiber as filler to improve the properties of degradable plastic. The research method consists of several stages, cellulose fiber preparation, degradable plastic synthesis and plastic characterization. The result showed tensile strength of plastic with corn cob and sugarcane bagasse filler was 6.37–11.5 MPa and 9.70–16.47 MPa, respectively. The compound composition test through Fourier Transformation Infra-Red (FTIR) exhibited hydrophilic behavior, hence plastic easily degraded by soil. Differential Scanning Calorimetry (DSC) shows that degradable plastic with corn cob fiber filler denoted a melting point of 163.84 ℃, while sugarcane bagasse fiber filler at 163.47 ℃. Thermogravimetric Analysis (TGA) analysis indicated degradable plastic had a good thermal stability. Scanning Electron Microscopy (SEM) exhibited few white lumps and indentations on the surface, indicating that the solubility was not homogeny and could be due to the influence of stirring process. In term of ability to absorb water, both plastic with fiber filler had a small water absorption with a range of 5–6%. Melt Flow Rate (MFR) analysis of degradable plastics with corn cob fiber and sugarcane bagasse pointed the value that was suitable for injection molding processing technique. The degradation of both plastics ranged about 50–85 days to completely decomposed naturally in soil, as supported by FTIR analysis. [ABSTRACT FROM AUTHOR]