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Photoinduced processes governed by light activated TiO2 have been studied in many ways. One of the most active areas is the development of TiO2 photocatalysis technologies on their application for reducing environmental impacts. The immobilization of TiO2 on solid support, such as cementitious materials, greatly enhances its use in practical applications. In this review, a wide range of applications for achieving eco-efficient building using cementitious composite materials containing TiO2 photocatalyst was presented. The basic mechanism of photocatalysis, such as electron excitation, charge transfer process, reactive oxygen species (ROS) generation, and its role to oxidize the pollutant and microorganisms were extensively discussed. Unlike self-cleaning and air purification systems, the study on the antibacterial function of a cement-based surface containing TiO2 is very limited. In photocatalytic cementitious materials, the key element affecting the photocatalytic performance is the accessible active surface area. However, microstructure of cementitious materials changes with age due to hydration and surface carbonation. Hence, surface area reduction and mass transfer limitation become the main drawbacks of incorporating TiO2 in cementitious materials. This review, therefore, provides the state of the art in photocatalytic cement-based composite materials and identifies the areas in which future improvement is needed.

Changes in climatic conditions are expected globally resulting in a higher rainfall intensity and longer duration of rainfall. The increase in the rainwater infiltration into the soil contributes to many geotechnical issues, such as excessive settlement, retaining wall failure and rainfall-induced slope failures. These geotechnical problems could be mitigated by the improvement of the problematic soil with the incorporation of the unsaturated soil mechanic principles. Dual-porosity soils or soils with bimodal water retention curve (WRC) are able to retain more water during prolonged drying and they would be able to drain out water faster during intense rainfall to maintain the slope stability. The objective of this study is to investigate the characteristics of the unsaturated shear strength of soil with bimodal WRC. In addition, the new mathematical equation is proposed to estimate the unsaturated shear strength of soils with a bimodal WRC. The results of the study indicated that the nonlinearity of the unsaturated shear strength is a function of the shape of bimodal WRC limited by the first and second air-entry value (AEV) of dual-porosity soils. The proposed equation agreed well with the experimental data of the unsaturated shear strength for dual-porosity soil.

Energy storage pile foundations are being developed for storing renewable energy by utilizing compressed air energy storage technology. Previous studies on isolated piles indicate that compressed air can result in pressure and temperature fluctuations in the pile, which can further affect safety of the pile foundation. Meanwhile, the temperature changes and distributions for the pile and surrounding soil also are influenced by adjacent piles in typical group pile constructions. Therefore, dynamic thermal transfer simulations were conducted in this paper to investigate the temperature changes and distributions in the concrete pile and surrounding soil for group pile construction. The main parameter in this study is the spacing of the piles. The analysis results show that the group pile effect significantly increases the temperature up to more than 100 °C depending on the location and changes its distribution in both concrete and soil due to the heat transferred from the adjacent piles. The final stabilized temperature can be as high as 120 °C in the concrete pile and 110 °C in the soil after numerous loading cycles, which is about 4 times higher than typical thermo-active energy pile applications. Thus, it is important to include the group pile effect for design and analysis of the energy storage pile foundation.

The role of buildings in the context of addressing the consequences of climate change and the energy deficit is becoming increasingly important due to their share in the overall amount of green house gas (GHG) emissions and rapidly growing domestic energy consumption worldwide. Adherence to a sustainability agenda requires ever-increasing attention to all stages of a building′s life, as such approach allows for the consideration of environmental impacts of a building, from design, through construction stages, until the final phase of a building′s life—demolition. A life cycle assessment (LCA) is one of the most recognized and adopted models for the evaluation of the environmental performance of materials and processes. This paper aims to perform an LCA of four different types of residential buildings in Nur-Sultan, Kazakhstan. The assessment primarily considered embodied energy and GHG emissions as key assessment indicators. Findings suggest that the operational stage contributed to more than half of the GHG emissions in all the cases. The results of the study indicate that there is a dependence between the comfort levels and the impact of the buildings on the environment. The higher the comfort levels, the higher the impacts in terms of the CO2 equivalent. This conclusion is most likely to be related to the fact that the higher the comfort level, the higher the environmental cost of the materials. A similar correlation can be observed in the case of comparing building comfort levels and life-cycle impacts per user. There are fewer occupants per square meter as the comfort level increases. Furthermore, the obtained results suggest potential ways of reducing the overall environmental impact of the building envelope components.

A new pile foundation system is being developed for renewable energy storage through a multi-disciplinary research project. This system utilizes the compressed air technology to store renewable energy inside the reinforced concrete pile foundation configured with hollowed sections. The compressed air can result in high air pressure to which the structural response of the pile foundation subjected has been studied. However, the temperature in the pile foundation can be affected by the compressed air if sufficient cooling is not provided. The temperature change can generate thermal stresses and affect the structural safety of the pile foundation. As a first step to investigate this thermal effect, this paper studies temperature distributions inside the concrete section for the pile foundation through non-steady state heat transfer analyses. Several parameters were considered in the study, including thermal conductivities of the concrete, specific heat capacities of the concrete, and dimensions of the pile foundation. It has been found that the temperature distribution along the concrete section varies significantly during a daily energy storage cycle as well as subsequent cycles due to the cumulative effect of residual temperatures at the end of each cycle. The temperature distribution is largely affected by the thermal conductivity of the concrete and the geometry of the pile foundation. The obtained temperature distribution can be used for investigation of the thermal stress inside the foundation and surrounding soil.

Reactive Powder Concrete (RPC) is a newly emerging concrete material that is being used for various applications where high-strength concrete is required. RPC is obtained by removing coarse aggregates and adding fine powders such as silica fume into the concrete mixture. This research has focused on the proportioning and characterization of RPC mixture to be used as a material for energy storage pile application. For mixture parameters, the water-to-binder ratio (WB), silica fume (SF) content, and normal and warm temperature curing have been selected. The relative flowability, penetration resistance, setting time, drying shrinkage, and compressive and flexural strengths were evaluated. Based on the test results, the mixture with WB = 0.22 and SF = 20% was the best mixture with the highest tensile strength and other characteristics. Response surface methodology (RSM) was used to design the experiments and find the optimum mixture proportions to achieve the highest compressive strength. The optimum WB and SF content to achieve the highest strength for combined ages (7 days, 28 days, and 56 days) was determined to be WB = 0.213 and SF = 20%. Through the comparison between the test results and the required strength from analytical simulations, the RPC studied in this paper was deemed to be suitable for the energy storage pile.