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In this report, a pulsed electro-acoustic (PEA) device is modified to test the charge profile in epoxy resin at 77 K (-196°C) and successfully obtains the charge signal. A piezoelectric material suitable for cryogenic application is chosen for the measurement. In the experiment, the polarization and depolarization tests are operated with different voltage supply procedures. After initial wave recovery, the waveforms are discernable enough to identify the charge information. It is found that the charges are much less active at the low temperature with both slow dissipating rate and low injection quantity, comparing to the case at 293 K.

The development of a system to measure simultaneously the current and space charge in a dielectric is described. The results obtained for low density polyethylene samples show that the relationship between space charge accumulation and the time-dependent current is not straightforward. In accord with previous work on space charge limited currents, the transient currents initially decreased, but after a while an increment or peak appeared. Additionally, the generation and extraction of space charge packets caused an impulse-like current peak such as previously observed. By comparing the electric field and current at the anode, it was found that the increment and the peak of the anode current are determined by injected negative carriers reaching the anode rather than the increase of electric field at the anode. It is shown that the dynamical evolution of the current can be divided into three stages similar to transient space charge limited current theory.

As an interface between the different insulating polymers exists in the joints of High Voltage Direct Current (HVDC) cables, the differences in the field-and-temperature dependence of the conductivities of the materials is regarded as a problem leading to interface charge accumulation and field distortion. In this report, using blocking materials to prevent charge injection from one or both sides of the electrodes, the contributions of charge injection and ionization in low-density polyethylene (LDPE), cross-linked polyethylene with nanoparticles (nano-XLPE) and ethylene propylene diene monomer (EPDM) are distinguished and evaluated based on the results from pulsed electro-acoustic (PEA) method. It is found that the contributions of charge injection and ionization behave differently in different materials. The mechanism behind the field-and-temperature dependences of the conductivities of the three materials is explained successfully. This study helps to clarify the charge transfer mechanism, and thus supports the quantitative calculation of the space charge and electric field distribution in cable joints.

In this research, the equivalence of space charge for coaxial cables and plane samples are analyzed through simulation. Bipolar charge transport models of coaxial cables and plane samples are established with the same material-dependent parameters, the bulk charge and total space charge distributions are simulated and comparatively researched under isothermal and temperature gradient conditions. The presented results indicate that the space charge behavior shows a basic equivalence in terms of charge variation laws and distribution. In addition, few discrepancies in the heterocharge amount and charge waveform amplitude are observed and mainly ascribed to the sample geometry, mobility gradient distribution and the spatial resolution of the measuring system, respectively. Investigations of space charge characteristics with a plane pulsed electro-acoustic measurement system may be accepted as a practice for providing the space charge characteristics of coaxial cable insulation, unless it is necessary to investigate the cable space charge distribution under actual operating conditions.

The mobility of positive and negative charge carriers has been separately measured independently of carrier concentration in low-density polyethylene (LDPE) and its nanocomposites using space charge measurements in a bilayer system. It was found that the carrier mobility of positive charge carriers was larger than that of negative charge carriers for both LDPE and its nanocomposites and that the carrier mobility was one to two orders of magnitude less in the nanocomposite than unfilled LDPE under the same conditions. The mobility is interpreted in terms of a field-assisted hopping model whose estimated activation energies were verified by measurements at different temperatures. The form of the charge traps and carrier transport is interpreted in terms of known features and electron and hole traps and the effect of nano-particles upon these features is discussed.

The effect of DC bias on electrical tree growth and partial discharge (PD) characteristics in epoxy resin (Araldite LY ® 5052/Aradur® HY 5052 supplied by Huntsman) is investigated using three waveforms: AC, AC with positive DC bias, and AC with negative DC bias. Needle-plane samples are used. Tree growth is shown to be accelerated by the combined effect of DC and 50 Hz AC, beyond the AC growth rate. Positive and negative DC biased tests result in 62% and 54% reductions in average time to breakdown, respectively. Different tree structures and stages of development are associated with different partial discharge characteristics, with thick dark tree branches associated with high PD magnitudes, whereas fine tree channel growth is linked with PD magnitudes below 1 pC. AC tests showed five distinct stages of tree growth compared to four stages seen in DC biased tests. In particular, trees growing in the ‘reverse direction’ from the planar to the point electrode, which is observed in the latter stages of AC tests, is not seen in the DC biased tests. It is concluded that for composite voltages, the AC component is the essential driver of tree growth but the DC component can accelerate propagation. AC noise may therefore compromise the reliability of insulation in HVDC networks.

Space charge accumulation is an important issue for HVDC cable design. The space charge accumulation are determined by the charge transport property which can be monitored by the space charge and conduction current measurement. In this paper, based on PEA system and three-electrode system, the modified combined measurement system was developed to measure the space charge and current in LDPE samples simultaneously. The results show that the current gradually decreased with the accumulation of homocharges; the generation and movement of space charge packet resulted in the current peaks; the reduction of homocharge accumulation and the increase of heterocharge tends to increase the current.

EPDM, as a high-quality insulation material, is widely used in cable joints, but it bears a large compression force in the working environment, which may affect its insulation performance. We study the effect of pressure on charge transport in EPDM by calculating the change in the key parameter of carrier mobility in EPDM at different pressures. In this paper, by designing a unipolar carrier blocking experiment and combining improved PEA measurement equipment, the mobility of electrons in EPDM at six pressures of 0.2 MPa-1.2 MPa (interval 0.2 MPa) is calculated. In addition, the mobility data is analyzed in-depth through the hopping conduction model. It was found that the mobility in EPDM at different pressures did not change significantly, and the electronic transition distance and energy required for hopping after fitting the hopping conduction model also did not change much under different pressures. It is indicated that under normal working conditions, pressures will not affect the electrical performance of EPDM.

The effect of temperature gradient on space charge behavior is necessary to investigate for HVDC insulation. In this paper, space charge distributions in neat epoxy resin (EP) and EP/SiO 2 nanocomposites (NC) were measured under different DC stresses and temperature gradients. We found that different temperature conditions applied to the electrodes had a great impact on space charge distributions: Only homocharge accumulated near anode at isothermal conditions, on the contrast, at temperature gradient of 60 °C, negative charge injected from cathode (high temperature side) and accumulated in the bulk, heterocharge appeared near anode (low temperature side). Moreover, SiO 2 nano-fillers added to NC could suppress the space charge accumulation significantly, and the pattern of space charge distribution in NC at temperature gradient of 60 °C also shows differently from that of EP. Numerical simulation based on the bipolar charge transport model was employed to study the experimental results. It shows that under temperature gradient, charge extraction plays an important role in heterocharge accumulation near the low temperature side. Moreover, it indicates that unlike the apparently measured conductivity, the charge mobility of NC does not increase rapidly with temperature in the range from 20 °C to 80 °C.

XLPE and its nanocomposites have been subjected to a progressive step voltage until failure occurred, and the results analyzed in terms of an inverse power law ageing expression. The step-stress tests have been conducted at three temperature 20°C,40°C and 60°C, and the exponent n of the inverse power law ageing expression has been estimated for the two materials by a new method, which fully considers the contribution to the failure of the whole sequence of voltage steps, including ageing processes at the lower voltages, the final step and the process of voltage increase. It was found that the value of exponent n increases slightly with increasing temperature for both XLPE and its nano-composites. More importantly the value of n for the nano-composites was found to be substantially lower than that for XLPE at all temperatures. A complementary experiment in which the space charge distribution was measured under the same step-stress protocol as the breakdown tests has also been carried out and the results of both experiments are discussed.

The effects of charge carrier injection and intrinsic ionic carriers on the conduction process in superclean low-density polyethylene and cross-linked polyethylene (LDPE and XLPE) and the associated development of space charge are investigated. The carrier mobility is measured directly by space charge measurements in a double- and triple-layer structure. It is shown that the difference between superclean LDPE and XLPE in the field-dependence of the current density results from the dominance of ions in XLPE introduced by cross-linking as compared to injected carriers in the case of superclean LDPE.

Partial discharge (PD) characteristics are inherently linked to associated electrical tree growth characteristics. This paper employs both phase-resolved patterns and pulse-sequence analysis (PSA) to study PDs in a short branch-tree grown from a metallic needle tip. It is found that the shape of PSA dV-dV patterns vary with applied voltage; in particular the values of characteristic voltage difference increase with applied voltage. At 10 kV the value of characteristic voltage difference decreases with tree growth, the average number of PDs per cycle increases, the PD magnitudes decrease, and the characteristic wing-like phase-resolved pattern evolves into a turtle-like pattern. This paper proposes a physical model relating PD activity to tree development, considering space charge accumulation inside the tree channel. All key features of experimental results are explained by the model. It is shown that the characteristic voltage differences are determined by the local PD inception and extinction electric fields. These key parameters determining the PD events can be calculated giving a clear physical interpretation of PD measurements, which is invaluable to those using PD as a condition monitoring or asset management tool.

As the temperature gradient always exists in the insulation of power equipment, the influence of temperature gradient on oil-impregnated paper insulation is studied by experiments and simulation. It's found that in the both single-layer and double-layer structures, the heterocharges always appear near the lower temperature electrode, and increase with the enhancement of temperature gradient and field stress, resulting in more considerable field distortion. However, there are more heterocharges in the single-layer samples while the field distortion is more severe in double-layer samples. Numerical simulations were carried out to investigate the mechanism of temperature gradient effect. It is indicated that the space charge accumulation is mainly due to the temperature dependence of the charge injection and conduction. The behavior of interface charges can be well described by assuming an energy barrier for charge transportation at the interface.

The movement of space charge packets has been reported in polyethylene and epoxy resin under high electric fields by several groups, and has been characterized by the speed of propagation. A number of explanations of the formation and transport of slow space charge packets has been proposed. However, the mechanisms creating fast space charge packets are not clear. Dissado et al have suggested that the formation of fast charge packets is due to discontinuous electromechanical compression and charge injection at the electrode-insulation interface, and the transport of charge packets is related to corresponding relaxation processes. In that model, charges travel in packets because of group polarization. This paper gives an alternative model considering the reduction of charge carrier activation energy due to charge density triggered polymer chain movement and subsequent chain relaxation times. It is shown that the generation and transport of fast charge pulses are readily simulated by a bipolar charge transport model with three additional parameters: reduced activation energy, a charge density threshold, and a polymer chain relaxation time.

Two mechanisms have been proposed to explain the suppression of space charge in polyethylene by the addition of nano-fillers, i.e. an interface change that reduces charge injection and a bulk modification that affects charge migration and recombination. The relative importance of each mechanism in Low Density Polyethylene (LDPE) nanocomposites is investigated by the measurement of space charge in samples of double-layer and triple-layer structures. The experimental results show that the nano-fillers reduce charge injection, but do not entirely eliminate the space charge. Bulk changes also play an important role in space charge suppression. The space charge near the interface between the unfilled LDPE and nanocomposites shows a surface charge at 20 °C, but at 60 °C a bipolar blocking phenomenon is observed in some circumstances. It is shown that these space charge distributions can be reproduced using a band theory approach with the assumption that the introduction of deep traps by nano-fillers raises the Fermi level of the nanocomposite towards the conduction level.

The effect on space charge accumulation of the introduction of nano-filler into polyethylene is usually studied using thin 100 μm samples in electric fields reaching 100 kV/mm. However, the insulation thickness in an actual HVDC cable is usually some centimeters. Thus there is a great thickness difference between the experiment sample and the insulation application. Here we investigate the thickness dependence of space charge accumulation in unfilled and LDPE doped with nano-SiO2 over a range of temperatures in a field of 50 kV/mm. It is found that the space charge in LDPE/SiO2 nanocomposites exhibits marked thickness dependence whereas in the unfilled LDPE it shows very little thickness dependence. A simulation based on the bipolar injection model and Takada's trapping potential model has been carried out in order to explain the differences. It is found that when the simulation included the effects of charge injection, extraction, trapping, recombination, mobility and diffusion, it is able to explain the heterocharge formation in the unfilled LDPE, and the thickness dependence in the two kinds of materials.

In order to restrict the field distortion in the insulation of high voltage direct current (HVDC) cable under temperature gradient, this paper proposes a nano-filler, the addition of which can restrict the space charge accumulation of low density polyethylene (LDPE) under temperature gradient. To reveal the mechanism of the nannocomposite, the trap depth distribution of the pure LDPE and LDPE nannocomposites under different temperatures were tested based on the Pulsed Electro-Acoustic (PEA) method. The parameters of trap depth distribution were achieved by PEA method under different temperatures(20°C,40°C,60°C and 80°C), and the trap depth distribution under different temperatures were all calibrated to that of 20°C. The results indicated that the trap depths of LDPE decrease with increasing temperature, whereas the trap depths of LDPE nanocomposites changes inobviously with temperature variation. It is considered that, the result contributes to the restriction of space charge accumulation under temperature gradient.

The aging parameter n can reflect the aging property of material to some degree and determine the test voltage of the type test and prequalification test of HVDC cables. However, the aging parameter has rarely been studied systematically, especially under temperature gradient. In this paper, step-stress test was carried out to estimate the ageing parameter n of two materials, XLPE and its nanocomposites under temperature gradient. A new method based on the cumulative damage has been used to obtain the ageing parameters, which can fully take the consideration of the voltage procedure and avoid the errors brought by the approximation. Aging parameters of XLPE and its nanocomposite under temperature gradient ΔT =0, 20, 40°C are 13, 15.4, 17.7 and 8.6, 9.4, 10, respectively. The aging parameter n reduces when nano-fillers are introduced into XLPE. As XLPE nonocomposites can depress space charge availably, the larger aging parameter n of XLPE may be explained in terms of space charge effect and thus more severe field distortion at higher DC voltage. It is also suggested that the electrostatic force induced by space charge can contribute to material aging.

Space charge will accumulate within polyethylene when stressed under DC high voltage, and a temperature gradient will form throughout the insulation when a HVDC cable is in service. Previous research has revealed that temperature gradient can enhance hetero charge accumulation at the low temperature end, but the high temperature only helps a small quantity of homo charge accumulate, and the mechanism was explained for hetero charge formation due to ionization of impurities within the insulation and blocked extraction of injected carriers. However there is no direct evidence to distinguish whether the hetero charge is injected carriers or the ions. This paper intends to investigate and explain the influence of temperature gradient onto hetero charge formation. It was concluded that temperature gradient across the sample thickness could affect the space charge through its influence to the mobility of carriers, and the temperature difference between two electrodes could also influence the entire space charge distribution through its influence to the charge injection and extraction. The space charge distribution in cross-linked polyethylene (XLPE) samples with different thickness under different temperature differences and temperature gradient was investigated. The results show that both the temperature difference between the electrodes and the temperature gradient across the thickness can enhance the hetero charge accumulation.

have not yet been clarified. The experimental results for PE under a temperature gradient show clear evidence of heterocharge next to the electrodes. This feature has been simulated previously using a bipolar injection model that includes blocked extraction. A direct comparison with PEA experiments however is difficult because the finite spatial resolution of the measurement causes the bulk space charge to overlap with that of the electrodes leaving the experimental values as a mixture of the two quantities that are generated separately in the simulation. Here we allow for the finite spatial resolution of the experimental technique by broadening the simulated charge density values using a Gaussian function. This allows us to compare the simulation and the measurements more effectively. The space charge distribution in PE is simulated by including a temperature dependent charge injection and charge transportation. Under these conditions it is found that the simulation results give a detailed match to the experimental results. They also show that both the temperature dependent charge injection and temperature dependent charge transportation are of importance in determining the space charge distribution in PE under a temperature gradient.

Polyethylene (PE) and oil impregnated paper are widely used as insulation materials in high voltage power equipment however, at high voltages the space charge inside the insulating material can distort the electric field distribution and thus greatly influence aging and degradation. Moreover, there is usually a temperature gradient across the insulation when the equipment is in service, and this can also influence the space charge accumulation. In order to study the effect of temperature gradient systematically a PEA system suitable for measurement under a temperature gradient has been developed and appropriate corrections for the measurement error introduced by the temperature gradient implemented. Separate determinations of the space charge distributions of PE and oil-impregnated paper at different temperatures and voltages have been made. The results for both materials showed some similar characteristics. Obvious heterocharge accumulates at the low temperature side and the higher the temperature difference between the two electrodes or the higher the applied voltage, the more the heterocharge accumulates. As a result the electric field is greatly distorted and the maximum field always appears at the low temperature side. The effects of temperature gradient on the space charge distribution are discussed in detail, and the differences between the two materials are identified. The conductivity of both materials has also been investigated, and the space charge induced by the conductivity gradient produced by a temperature gradient in both materials has also been evaluated. The results show that in oil-impregnated paper the space charge induced by a conductivity gradient plays a great part in space charge formation, while in LDPE the conductivity gradient contributes much less to the space charge. These differences are discussed.

The effect of the introduction of nano-fillers into polyethylene on space charge accumulation is usually studied in electric fields reaching 100kV/mm using thin 100 μm samples, which is much thinner than the insulation in actual HVDC cables. Our previous work showed that space charge distributions in LDPE and its nanocomposites have different thickness dependences at isothermal temperature (20°C and 60°C). This was explained using the bipolar model and trapping potential model. However, in actual cables the temperature is not isothermal, but has a gradient, so we have investigated the space charge distribution in unfilled XLPE and its SiO2 nanocomposites under different temperature gradients at 50kV/mm. It is found that the unfilled XLPE space charge distributions definitely have thickness dependence under a temperature gradient. The XLPE/SiO2 nanocomposites also show strong thickness dependence: the thin samples accumulate large heterocharge densities, but the thicker the sample is, the less the heterocharge accumulates and even under a temperature gradient the 0.5mm nanocomposites still suppress most of the heterocharge.

The introduction of nano-fillers into polyethylene can suppress space charge accumulation. The mechanism of this phenomenon hasn't been understood clearly, and has been explained in two different ways, i.e. an interface behavior that reduces charge injection and a bulk property that affects charge migration. In order to investigate which factor determines the space charge behavior in LDPE nano-composites, samples of triple-layer structure are measured. The experimental results show that the nano-fillers can reduce charge injection. However, the reduced charge injection cannot entirely remove the space charge. The bulk property also plays an important role in space charge suppression. Furthermore, a bipolar blocking phenomenon is found in our triple layer sample at high temperature. This can be explained by a shift in the apparent Fermi (charge demarcation) level near the electrode due to the trapping of injected charge, which increases the interface barrier.