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Diffusivity of Er3+ into LiNbO3 crystal has been studied as a function of Li2O content and crystal orientation. The Li2O content in single-crystal LiNbO3 plates was adjusted by Li-rich vapor transport equilibration (VTE) technique. Five X-cut and five Z-cut congruent substrates were VTE treated at first at 1100 °C for different durations ranging from 6 to 74 h, and then were subjected to a special post-VTE anneal procedure at the same temperature for 60 h to obtain homogeneous Li2O content. The Li2O content was determined from the measured fundamental optical absorption edge. Its homogeneity is verified by measuring the optical absorption edge as a function of the crystal thickness. After the composition characterization, the substrates were coated with 45 nm thick Er film and annealed at 1130 °C for 40 h in argon atmosphere. The Er3+ profile was analyzed by secondary ion mass spectrometry. The results show that the Er3+ diffusivity decreases monoexponentially with the increase in the Li2O content in both cases of X- and Z-cut. As the Li2O content is increased from the congruent point (48.4 mol %) to the near-stoichiometric composition (∼49.9 mol %), the diffusivity decreases from 0.107 (0.072) to 0.017 (0.018) μm2/h for the Z (X)-cut substrate. The diffusion shows considerable anisotropy for the lower Li2O content and the diffusivity in a Z-cut substrate is larger. The anisotropy weakens gradually with the increase in the Li2O content, and the diffusivities in the X- and Z-cut substrates ultimately tend to a same value (∼0.02 μm2/h) at the Li-rich phase boundary. After the Er diffusion procedure, endface coupling experiment was carried out to check if a planar waveguide layer was formed near the Er-diffused surface due to the Li outdiffusion. The results show that the Li outdiffusion did not accompany the Er diffusion procedure. [ABSTRACT FROM AUTHOR]

Standard thermal diffusion of Er3+ into X-cut congruent LiNbO3 crystal with the MgO doping level close to the antiphotorefractive threshold concentration, 4.5 mol%, was attempted at the temperature close to Curie point of the crystal. Single-crystal x-ray diffraction, photoluminescence spectroscopy and secondary ion mass spectrometry (SIMS) were used to study the crystalline phase with respect to Er3+ ions and the depth profile of the diffused Er3+ ions. The results show that the thickness of the Er metal film coating should not be thicker than 4.6 nm. In this case, the diffusion is complete, the diffused surface is clean, and the Er3+ ions in the diffused layer still retain the LiNbO3 phase. On the other hand, the diffusion will be incomplete if the initial thickness of the Er metal film is thicker than 4.6 nm. The residual Er3+ ions form ErNbO4 grains on the surface of the crystal. SIMS analysis shows that the diffused Er3+ ions follow a monoexponential decay profile. The experimental results also show that the diffusivity of Er3+ in the X-cut congruent Mg(4.5 mol %):LiNbO3 is similar to 4.69×10-3 μm2/h at 1130 °C. Further vapor transport equilibration treatment following the standard diffusion procedure results in transformation of the diffused Er3+ ions from LiNbO3 into the ErNbO4 phase and, hence, substantial spectral change of the 1.5 μm emission. [ABSTRACT FROM AUTHOR]

The visible and infrared transmission spectra of vapor transport equilibration (VTE) treated Er:LiNbO[sub 3] crystals, which have different doping levels (0.2%, 0.4%, and 2.0% Er per cation site), different cut orientation (X and Z cut) and different VTE duration (80, 120, 150, and 180 h), were recorded at room temperature in the wavelength range of 250-3700 nm. All of 2.0 mol % doped VTE crystals have precipitated whether X cut or Z cut, while the others have not. Their absorption characteristics were summarized and discussed in contrast to those of corresponding as-grown crystals. The OH[sup -] absorption feature of VTE treated Er:LiNbO[sub 3] is found to be different from that of pure VTE LiNbO[sub 3] crystal. The significant reduction of OH[sup -] absorption band implies that the hydrogen content in the VTE crystals has been reduced substantially whether the crystal precipitates or not. The electron transition absorption characteristics of the lower-doped, not precipitated crystals mainly include the higher transmittance, slight shift of peak or band position, slight absorption intensity change, the appearance of some additional peaks or bands, the narrowing of the peak width (full width at half maximum), and the definite blueshift of the optical absorption edge. The spectral changes are associated with the redistribution of Er[sup 3+] spectroscopic sites induced by the VTE procedure. In comparison with those lower-doped VTE crystals, the highly doped VTE crystals display more significant absorption characteristics: the significant enhancement of 1480 nm pumping band and the obvious weakening of 1531 nm peak, the appearance of many additional peaks in the infrared region, and the interesting evolution of the transmittance with the wavelength. These substantial spectral changes are unambiguously conducted with the formation of a precipitate ErNbO[sub 4] induced by the VTE treatment in these crystals. The mechanism for the formation of the precipitate has... [ABSTRACT FROM AUTHOR]

Discusses a study which characterized fabricated waveguides in iron doped KTiOPO[sub4] substrates. Background on the sample materials; Methodology; Findings.

A polarization-isotropic two-colour light-induced diffraction (LID) phenomenon from thermally reduced congruent and near-stoichiometric Er:LiNbO3 crystals was observed when these crystals were exposed to superposed 632.8  nm probe and 488  nm pump beams. The LID is characterized by expansion of the probe beam spot and the appearance of alternate bright and dark diffraction rings at higher pump light intensities. This phenomenon is absent not only in all other Er-doped crystals which either were as grown or had experienced other post-growth treatments such as vapour transport equilibration (VTE), oxidation and strong annealing but also in a pure VTE-treated crystal even though the crystal was subjected to the same reduction procedure. The LID characteristics of five reduced crystals, which have different Li-to-Nb ratios and different doping levels of Er 3+ , were studied in detail by changing the light intensity, polarization state and wave vector direction of both the pump and the probe beams. The origin of the LID was investigated from the viewpoints of the red fluorescence of Er 3+ excited by a 488  nm pump beam, light-induced scattering and light-induced thermal nonlinearity. The results have shown that the thermal nonlinearity mechanism is preferred as it can reasonably explain almost all the observed experimental phenomena. [ABSTRACT FROM AUTHOR]

Near-stoichiometric planar and strip LiNbO3 optical waveguides were demonstrated using vapor transport equilibrium process and co-diffusion of titanium metal. Optical confinement is better in z-cut substrates than in x-cut substrates, and the waveguides were characterized optically. Spectral measurements, such as OH- absorption, optical absorption near the fundamental edge, and Raman scattering, were carried out to examine the Li-composition and crystalline phase inside and outside the guiding layer. The results have shown that the vapor transport equilibration process has brought these waveguides toward stoichiometric composition, the Li content inside and outside the waveguide layer is essentially identical, and the LiNbO3 phase is still retained within the waveguide layer. [ABSTRACT FROM AUTHOR]