1. Light-activated cellulose nanocrystals/fluorinated polyacrylate-based waterborne coating: Facile preparation, mechanical and self-healing behavior.
- Author
-
Li H, Zhou J, Yu J, and Zhao J
- Subjects
- Emulsions chemistry, Spectroscopy, Fourier Transform Infrared, Cellulose chemistry, Nanoparticles chemistry
- Abstract
The development of environmental-friendly self-healing nanocomposites has attracted much attention. In this paper, the light-activated cellulose nanocrystals/ fluorinated polyacrylate-based waterborne coating based on the reversible cycloaddition reaction of the coumarin groups was prepared via Pickering emulsion polymerization. The cellulose nanocrystals (CNCs) modified by the PDMAEMA-b-PGMA-b-P(HFBA-co-VBMC) copolymer were studied via FT-IR and TGA. In addition, the dispersity and interface behavior of CNCs before and after modification were investigated by DLS and interfacial tension measurements. Afterwards, we focused on the influence of modified CNCs, PDMAEMA-g-CNC-g- P(HFBA-co-VBMC) (MCNC) dosage on the Pickering emulsion, emulsion polymerization and properties of latex film. The droplet diameter of Pickering emulsion gradually reduced with the increase of MCNC dosage. The MCNC dosage for the minimum average size and optimum stability of latex particles was 1.0 wt%. Moreover, the latex film comprising 1.0 wt% MCNC presented not only high tensile stress (6.0 MPa), large elongation at break (567.70 %) and superior oil/water repellency but also excellent self-healing properties. The outstanding self-healing capability of latex film was attributed to the reversible light-activated dimerization of coumarin groups. The preparation method for the advanced performance waterborne cellulose nanocrystals/fluorinated polyacrylate will provide valuable guidance for the development of versatile materials., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)
- Published
- 2023
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