1. Ligand field and intermolecular interactions tuning the magnetic properties of spin-crossover Fe(II) polymer with 4,4′-bipyridine.
- Author
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Luo, Yang-Hui, Liu, Qing-Ling, Yang, Li-Jing, Ling, Yang, Wang, Wei, and Sun, Bai-Wang
- Subjects
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INTERMOLECULAR interactions , *LIGANDS , *SPIN crossover , *BIPYRIDINE , *COORDINATION polymers , *HYDROGEN bonding - Abstract
A new spin crossover coordination polymer (SCO-CPs) of Fe(II)-4,4′-bipyridine (4,4′-bipy) family: {Fe(4,4′-bipy) 2 (H 2 O) 2 }·(4,4′-bipy)· 8(H 2 O)·2(ClO 4 ) ( 3 ), which displays half spin transitions between 100 and 300 K, has been synthesized and structurally characterized. Compound 3 featured with two-dimensional (2-D) grids connected by hydrogen bonds and π … π packing between one-dimensional (1-D) chains, the 2-D grids expand to three-dimensional (3-D) architecture supported by a “S-shaped holder” involving lattice 4-4′-bipy, water molecules and perchlorate anion. We compared 3 with the other two analogous complexes: ({Fe(4,4′-bipy) (H 2 O) 2 (NCS) 2 }·4,4′-bipy, 1 and {Fe(4,4′-bipy) 2 (NCS) 2 }·mSolv, 2 ) through Hirshfeld surfaces analysis, which revealed that the low ligand field strength (NCS − ) and lone-pair…H contacts contribute to the stabilization of HS (high-spin) state of the Fe(II) ion, while the high ligand field strength (4,4′-bipy) and strong intermolecular contacts (hydrogen bonds and π … π packing interactions) make for the LS (low-spin) state. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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