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Synthesis, crystal structure and Hirshfeld surfaces of a CuII complex with an ICL670-related ligand.
- Source :
-
Journal of Chemical Research . Dec2012, Vol. 36 Issue 12, p697-700. 4p. 4 Diagrams, 3 Charts, 1 Graph. - Publication Year :
- 2012
-
Abstract
- The complex [Cu2(μ-L)2]. DMF (L = 2, 2'-[1-(2, 4, 6-trichlorophenyl)-1H-1, 2, 4-triazole-3, 5-diyl] diphenolate) has been prepared and its structure determined. The two CuII ions are four-coordinated in a planar structure, with the DMF molecule wrapped in the 'wings' of ligand L. Hirshfeld surface and fingerprint plots reveal that the complex structure is stabilised mainly by H···H, C-H ... Cl, C-H···π,π···π and lone-pair···π (C-Cl) intermolecular interactions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 17475198
- Volume :
- 36
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Research
- Publication Type :
- Academic Journal
- Accession number :
- 84420574
- Full Text :
- https://doi.org/10.3184/174751912X13503977364032