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Synthesis, crystal structure and Hirshfeld surfaces of a CuII complex with an ICL670-related ligand.

Authors :
Luo, Yang-Hui
Xu, Jian
Sun, Bai-Wang
Source :
Journal of Chemical Research. Dec2012, Vol. 36 Issue 12, p697-700. 4p. 4 Diagrams, 3 Charts, 1 Graph.
Publication Year :
2012

Abstract

The complex [Cu2(μ-L)2]. DMF (L = 2, 2'-[1-(2, 4, 6-trichlorophenyl)-1H-1, 2, 4-triazole-3, 5-diyl] diphenolate) has been prepared and its structure determined. The two CuII ions are four-coordinated in a planar structure, with the DMF molecule wrapped in the 'wings' of ligand L. Hirshfeld surface and fingerprint plots reveal that the complex structure is stabilised mainly by H···H, C-H ... Cl, C-H···π,π···π and lone-pair···π (C-Cl) intermolecular interactions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
17475198
Volume :
36
Issue :
12
Database :
Academic Search Index
Journal :
Journal of Chemical Research
Publication Type :
Academic Journal
Accession number :
84420574
Full Text :
https://doi.org/10.3184/174751912X13503977364032