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In this paper, the model of a three-terminal quantum dot heat engine consists of two quantum dots with a single energy level, a cavity and two electron reservoirs is established. According to Landauer formula the expressions for the heat current, the output power and the efficiency are derived analytically. The performance characteristic curves of the output power versus the efficiency are plotted by numerical calculation. Moreover, the optimal performance parameters are determined. Then we optimize the output power and the efficiency respectively, the influence of the width of energy level and the heat leak on performance of the three-terminal thermoelectric heat engine is discussed. Lastly, the variation of the corresponding efficiency at the maximum power output with the Carnot efficiency between two reservoirs is discussed and the corresponding efficiency is compared with Carnot efficiency and CA efficiency. It is shown that this three-terminal heat engine is irreversible due to the existence of the width of energy level and the heat leak. Thus the curve of the power output versus the efficiency is a loop-shaped one. And due to the heat leak, the characteristics of the efficiency and the width of energy level is a non-monotone curve. The efficiency at the maximum power will be greater than the CA efficiency when the heat leak and the width of energy level are not taken into account.

We investigate the finite-power performance of quantum heat engines working in the linear response regime where the temperature gradient is small. The engine cycles with working substances of ideal harmonic systems consist of two heat transfer and two adiabatic processes, such as the Carnot cycle, Otto cycle, and Brayton cycle. By analyzing the optimal protocol under maximum power we derive the explicitly analytic expression for the irreversible entropy production, which becomes the low dissipation form in the long duration limit. Assuming the engine to be endoreversible, we derive the universal expression for the efficiency at maximum power, which agrees well with that obtained from the phenomenological heat transfer laws holding in the classical thermodynamics. Through appropriate identification of the thermodynamic fluxes and forces that a linear relation connects, we find that the quantum engines under consideration are tightly coupled, and the universality of efficiency at maximum power is confirmed at the linear order in the temperature gradient.

We study the minimally nonlinear irreversible heat engines in which the time-reversal symmetry for the systems may be broken. The expressions for the power and the efficiency are derived, in which the effects of the nonlinear terms due to dissipations are included. We show that, as within the linear responses, the minimally nonlinear irreversible heat engines can enable attainment of Carnot efficiency at positive power. We also find that the Curzon-Ahlborn limit imposed on the efficiency at maximum power can be overcome if the time-reversal symmetry is broken.

We study the performance of a cyclic heat engine which uses a small system with a finite number of ultracold atoms as its working substance and works between two heat reservoirs at constant temperatures T h and T c (

We analyze general models of quantum heat engines operating a cycle of two adiabatic and two isothermal processes. We use the quantum master equation for a system to describe heat transfer current during a thermodynamic process in contact with a heat reservoir, with no use of phenomenological thermal conduction. We apply the endoreversibility description to such engine models working in the linear response regime and derive expressions of the efficiency and the power. By analyzing the entropy production rate along a single cycle, we identify the thermodynamic flux and force that a linear relation connects. From maximizing the power output, we find that such heat engines satisfy the tight-coupling condition and the efficiency at maximum power agrees with the Curzon-Ahlborn efficiency known as the upper bound in the linear response regime.

A numerical model of a nano-scaled thermoelectric heat engine with InP/InAs/InP trilayer quantum well (QW) is investigated. The expressions of those performance parameters, such as current, power output, and efficiency are expressed. By numerical calculation, the resonant tunneling behavior of electrons in the QW is described, which seems like a very good energy selective electron mechanism for the heat engine. After considering the radiation heat leakage, for fixed layer thicknesses of the QW, the optimum working regions of the heat engine with respect to the chemical potentials and the bias voltage are obtained numerically under the economic criterion. From these results, the power output can be increased by narrowing down the layer thicknesses. In addition, owing to the radiant heat leakage, the efficiency initially increases in the working regions and then decreases when the layer thicknesses increase gradually, from which one can obtain a maximum efficiency by optimizing layer thicknesses of QW. These results calculated here may provide a guide for the optimum designs of tunneling thermoelectric devices.

A model of thermionic heat engine with the energy selective electron mechanism is studied. Analytical expressions of the power output and efficiency of this device are derived at low temperature, where the chemical potentials of the reservoirs are assumed to be constant. After discussing the impact of the energy spectrum width of the energy selective electron mechanism, we find two bounds ( η ± ) of efficiency at maximum power exist naturally. When the energy spectrum width increases gradually from zero and then to the semi-infinite case with the infinite upper limit, the efficiency at maximum power decreases monotonously from the upper bound η + to the lower bound η − at a given temperature ratio of the cold and hot reservoirs. The two bound are given by numerical simulation and by an analytical expression respectively. These results may provide some guidance for the application of the practical energy selective electron heat engines.

Based on a two-qubit Heisenberg XY model, we construct a four-level entangled quantum heat engine (QHE). It is an interesting quantum Otto cycle where the exchange constant is fixed and only the magnetic field is varied during the adiabatic steps. The expressions for several thermodynamic quantities such as the heat transferred, the work and the efficiency are derived. Moreover, the influence of the entanglement on the thermodynamic quantities is investigated numerically. Several interesting features of the variation of the heat transferred, the work and the efficiency with the concurrences of the thermal entanglement of different thermal equilibrium states are obtained. Finally, we discussed the maximum efficiency of the QHE.

Based on a two-qubit isotropic Heisenberg XXX model with a constant external magnetic field, we construct a four-level entangled quantum heat engine (QHE). The expressions for several thermodynamic quantities such as the heat transferred, the work and efficiency are derived. Moreover, the influence of the entanglement on the thermodynamic quantities is investigated analytically and numerically. Several interesting features of the variation of the heat transferred, the work and the efficiency with the concurrences of the thermal entanglement of different thermal equilibrium states are obtained.

The influence of both the quantum degeneracy and the finite rate heat transfer between the working substance and the cylinder wall on the optimal performance of an Otto engine cycle is investigated. Expressions for several important parameters such as the power output and efficiency are derived. By using numerical solutions, the curves of the power output and efficiency varying with the compression ratio of two isochoric processes are presented. It is found that there are optimal values of the compression ratio at which the power output and efficiency attain their maximum. In particular, the optimal performance of the cycle in strong and weak gas degeneracy and the high temperature limit are discussed in detail. The distinctions and connections between the quantum Otto engine and the classical are revealed. Moreover, the maximum power output and efficiency and the corresponding relevant parameters are calculated, and consequently, the optimization criteria of some important parameters such as the power output, efficiency and compression ratio of the working substance are obtained.

The local stability of an irreversible Carnot heat engine has been studied based on the linearization technique for dynamical systems and local stability analysis. At two steady-states of the maximum power output and the maximum efficiency the expressions of the relaxation time of an irreversible Carnot heat engine are derived. It is found that the relaxation time is a function of the heat-transfer coefficient α and β, heat capacity C, temperatures of the heat reservoirs TH and TL, the degree of internal irreversibility ϕ and the internal heat conductance k. The influence of heat resistance, internal irreversibility and heat leak on the relaxation time is discussed. Phase portraits for the trajectories are presented in some representative cases. The results obtained here are more general and useful for the realistic irreversible heat engine than endoreversible heat engine.

In a recent paper [A. Sisman, I. Muller, Phys. Lett. A 320 (2004) 360] the thermodynamic properties of ideal gases confined in a narrow box were examined theoretically. The so-called “thermosize effects” similar to thermoelectric effects, such as Seebeck-like thermosize effect, Peltier-like thermosize effect and Thomson-like thermosize effect, were analyzed. Like the thermoelectric generator, based on the thermosize effects we have established a model of micro/nano scaled ideal gas heat engine cycle which includes two isothermal and two isobaric processes. The expressions of power output and efficiency of this cycle in the two cases of reversible and irreversible heat exchange are derived and the optimal performance characteristics of the heat engine is discussed by some numerical example. The results obtained here will provide theoretical guidance for the design of micro/nano scaled device.

A cycle model of an irreversible heat engine working with harmonic systems is established in this paper. Based on the equation of motion of an operator in the Heisenberg picture and semi-group approach, the first law of thermodynamics for a harmonic system and the time evolution of the system are obtained. The general expressions for several important parameters, such as the work, efficiency, power output, and rate of entropy production are derived. By means of numerical analysis, the optimally operating regions and the optimal values of performance parameters of the cycle are determined under the condition of maximum power output. At last, some special cases, such as high temperature limit and frictionless case, are discussed in brief.

An irreversible cycle model of a quantum heat engine with internal friction is established, which is composed of two adiabatic and two isomagnetic field processes. The working substance of the cycle consists of an ensemble of many non-interacting spin-1/2 systems. Based on a quantum master equation and semi-group approach, the general performance characteristics of the heat engine are investigated. The general expressions for several important parameters, such as the efficiency, power output, and rate of the entropy production, are derived. The performance of the cycle is optimized with respect to the temperatures of the working substance. By numerical solutions, the maximum power output and the corresponding parameters are calculated. The optimal regions of efficiency, temperatures of the working substance, and cycle period are determined. Moreover, the performance of the heat engine in the frictionless case is obtained, which is different from that in the friction case. Finally, the results obtained are generalized to the performance optimization of the heat engine working with spin-J systems.

We propose and theoretically investigate a system of two coupled harmonic oscillators as a heat engine. We show how these two coupled oscillators within undamped regime can be controlled to realize an Otto cycle that consists of two adiabatic and two isochoric processes. During the two isochores the harmonic system is embedded in two heat reservoirs at constant temperatures T(h) and T(c)(

We propose an Otto heat engine that undergoes processes involving a special class of feedback and analyze theoretically its response. We use stochastic thermodynamics to determine the performance characteristics of the heat engine and indicate the possibility that its maximum efficiency can surpass the Carnot value. The analytical expression for efficiency at maximum power, including the effects resulting from feedback, reduces to that previously derived based on an engine without feedback.

Theoretical thermoelectric nanophysics models of low-dimensional electronic heat engine and refrigerator devices, comprising two-dimensional hot and cold reservoirs and an interconnecting filtered electron transport mechanism have been established. The models were used to numerically simulate and evaluate the thermoelectric performance and energy conversion efficiencies of these low-dimensional devices, based on three different types of electron transport momentum-dependent filters, referred to herein as: kx, ky and kr filters. Assuming the Fermi-Dirac distribution of electrons, expressions for key thermoelectric performance parameters were derived for the resonant transport processes, in which the transmission of electrons has been approximated as a Lorentzian resonance function. Optimizations were carried out and the corresponding optimized design parameters have been determined, including but not limited to the universal theoretical upper bound of the efficiency at maximum power for heat engines, and the maximum coefficient of performance for refrigerators. From the results, it was determined that kr filter delivers the best thermoelectric performance, followed by the kx filter, and then the ky filter. For refrigerators with any one of three filters, an optimum range for the full width at half maximum of the transport resonance was found to be, no layout, 20 pages, 8 figures, 2 tables

We consider the finite-time operation of a quantum heat engine whose working substance is composed of a two-level atomic system. The engine cycle, consisting of two quantum adiabatic and two quantum isochoric (constant-frequency) processes and working between two heat reservoirs at temperatures T(h) and T(c)(

We generalize the quantum heat engine (QHE) model which was first proposed by Bender et al. [J. Phys. A 33, 4427 (2000)] to the case in which an ideal Fermi gas with an arbitrary number N of particles in a box trap is used as the working substance. Besides two quantum adiabatic processes, the engine model contains two isoenergetic processes, during which the particles are coupled to energy baths at a high constant energy E(h) and a low constant energy E(c), respectively. Directly employing the finite-time thermodynamics, we find that the power output is enhanced by increasing particle number N (or decreasing minimum trap size L(A)) for given L(A) (or N), without reduction in the efficiency. By use of global optimization, the efficiency at possible maximum power output (EPMP) is found to be universal and independent of any parameter contained in the engine model. For an engine model with any particle-number N, the efficiency at maximum power output (EMP) can be determined under the condition that it should be closest to the EPMP. Moreover, we extend the heat engine to a more general multilevel engine model with an arbitrary 1D power-law potential. Comparison between our engine model and the Carnot cycle shows that, under the same conditions, the efficiency η = 1 - E(c)/E(h) of the engine cycle is bounded from above the Carnot value η(c) =1 - T(c)/T(h).

We study the efficiency at maximum power, $\eta_m$, of irreversible quantum Carnot engines (QCEs) that perform finite-time cycles between a hot and a cold reservoir at temperatures $T_h$ and $T_c$, respectively. For QCEs in the reversible limit (long cycle period, zero dissipation), $\eta_m$ becomes identical to Carnot efficiency $\eta_{_C}=1-\frac{T_c}{T_h}$. For QCE cycles in which nonadiabatic dissipation and time spent on two adiabats are included, the efficiency $\eta_m$ at maximum power output is bounded from above by $\frac{\eta_{_C}}{2-\eta_{_C}}$ and from below by $\frac{\eta_{_C}}2$. In the case of symmetric dissipation, the Curzon-Ahlborn efficiency $\eta_{_{CA}}=1-\sqrt{\frac{T_c}{T_h}}$ is recovered under the condition that the time allocation between the adiabats and the contact time with the reservoir satisfy a certain relation., Comment: to be published in Phys. Rev. E (2012)

We establish a quantum Otto engine (QOE) of a two-level atom, which is confined in a one-dimensional (1D) harmonic trap and is coupled to single-mode radiation fields. Besides two adiabatic processes, the QOE cycle consists of two isochoric processes, along one of which the two-level atom as the working substance interacts with a single-mode radiation field. Based on the semigroup approach, we derive the time for completing any adiabatic process and then present a performance analysis of the heat engine model. Furthermore, we generalize the results to the performance optimization for a QOE of a single two-level atom trapped in a 1D power-law potential. Our result shows that the efficiency at maximum power output is dependent on the trap exponent $\ensuremath{\theta}$ but is independent of the energy spectrum index $\ensuremath{\sigma}$.

A new cycle model of an irreversible quantum harmonic heat engine is established in this paper, which is composed of two isothermal processes, an adiabatic process and a constant frequency process. Based on the quantum master equation and semi-group approach, the general optimal performance characteristics of the cycle are investigated. Expressions for several important performance parameters such as the efficiency, the power output and the ecological function are derived analytically in high temperature limit. By numerical calculation, a set of performance characteristic curves is plotted, such as the optimal curves between the power output and efficiency, the ecological function and efficiency. A comparison of the corresponding efficiencies at the maximum ecological function and power output is also presented.

We present a performance analysis of a two-state heat engine model working with a single-mode radiation field in a cavity. The heat engine cycle consists of two adiabatic and two isoenergetic processes. Assuming the wall of the potential moves at a very slow speed, we determine the optimization region and the positive work condition of the heat engine model. Furthermore, we generalize the results to the performance optimization for a two-state heat engine with a one-dimensional power-law potential. Based on the generalized model with an arbitrary one-dimensional potential, we obtain the expression of efficiency as $\ensuremath{\eta}=1\ensuremath{-}\frac{{E}_{C}}{{E}_{H}}$, with ${E}_{H}$ (${E}_{C}$) denoting the expectation value of the system Hamiltonian along the isoenergetic process at high (low) energy. This expression is an analog of the classical thermodynamical result of Carnot, ${\ensuremath{\eta}}_{c}=1\ensuremath{-}\frac{{T}_{C}}{{T}_{H}}$, with ${T}_{H}$ (${T}_{C}$) being the temperature along the isothermal process at high (low) temperature. We prove that under the same conditions, the efficiency $\ensuremath{\eta}=1\ensuremath{-}\frac{{E}_{C}}{{E}_{H}}$ is bounded from above the Carnot efficiency, ${\ensuremath{\eta}}_{c}=1\ensuremath{-}\frac{{T}_{C}}{{T}_{H}}$, and even quantum dynamics is reversible.

An irreversible Braysson heat engine cycle model, in which the heat transfer obeys a linear heat transfer law between the working fluid and the external heat reservoirs, with heat resistance, heat leak and internal irreversibility is established in this paper. The analytical expressions of power output, efficiency and ecological objective function are derived. These performance parameters are maximized with respect to the cycle temperatures along with the isobaric temperature ratio. The performance characteristic curves are obtained by numerical calculation. The optimal operating regions of the important parameters are determined.

An irreversible model of the air-standard Diesel heat engine cycle is established, in which the primary irreversibilities, such as the heat leak loss through the cylinder wall, friction loss, internal irreversibility and temperature-variable heat capacities, are considered. The analytic expressions of the power output and efficiency are derived. The relations between the power output and the ratio of the highest to the lowest pressure of the working fluid, between the efficiency and the ratio of the highest to the lowest pressure of the working fluid, as well as the optimal relation between the power output and the efficiency of the Diesel cycle are shown by numerical example. Moreover, the influence of these primary irreversible factors on the performance parameters of the Diesel heat engine is discussed. The results obtained here may provide some significant guidelines for the optimal design and operation of the practical Diesel heat engines.

Based on quantum thermodynamic processes, we make a quantum-mechanical (QM) extension of the typical heat engine cycles, such as the Carnot, Brayton, Otto, Diesel cycles, etc., with no introduction of the concept of temperature. When these QM engine cycles are implemented by an ideal gas confined in an arbitrary power-law trap, a relation between the quantum adiabatic exponent and trap exponent is found. The differences and similarities between the efficiency of a given QM engine cycle and its classical counterpart are revealed and discussed.

In this paper, we establish a nanothermoelectric engine consisting of two discrete energy levels embedded between two reservoirs at different temperatures and chemical potentials. Based on master equation, the expressions for the power output and efficiency of the nanothermoelectric engine are derived. The characteristic curves between the power output and the efficiency are plotted. Moreover, the optimal performance parameters are obtained by the numerical calculation. The influence of the strength of variations in electron–electron interactions on the optimal performance parameters is analyzed in detail.

We setup a three-level heat engine model that works with two noninteracting fermions in a one-dimensional box trap. Besides two quantum adiabatic processes, the quantum heat engine cycle consists of two isoenergetic processes, along which the particles are coupled to energy baths at a high constant energy EH and a low constant energy EC, respectively. Based on the assumption that the potential wall moves at a very slow speed and there exists a heat leakage between two energy baths, we derive the expressions of the power output and the efficiency, and then obtain the optimization region for the heat engine cycle. Finally, we present a brief performance analysis of a Carnot engine between a hot and a cold bath at temperatures TH and TC, respectively. We demonstrate that under the same conditions, the efficiency η=1-(EC/EH) of the engine cycle is bounded from above the Carnot efficiency ηc=1-(TC/TH).

An irreversible cycle model of a Bose–Otto engine is established, in which finite time thermodynamic processes and the irreversibility result from the nonisentropic compression and expansion processes are taken into account. Based on the model, expressions for the power output and efficiency of the Bose–Otto engine are derived. On the basis of the thermodynamic properties of ideal Bose gas, the effects of the irreversibility and the compression ratio of the two isochoric processes on the performance of the Bose–Otto engine are revealed and some important performance parameters are optimized. Furthermore, some optimal operating regions including those for the power output, efficiency, and the temperatures of the cyclic working substance at two important state points are determined and evaluated. Finally, several special cases are discussed in detail.

In this paper, the work output (W) and efficiency (η) of a Carnot cycle in micro-/nanoscale are calculated, in which the quantum boundary effect of gas particles as a working substance of cycle is considered. It is found that under the quantum boundary effect conditions, the work output of cycle depends sensitively on the surface area of the system (boundary of cycle) and cannot be predicted by the classical approximate result (WC), while the efficiency of cycle is independent of the surface area of the system and equals the Carnot efficiency (ηC). Further, the difference of work output of the micro-/nanoscaled Carnot cycle to that of the classical one, ΔW=W−WC, is introduced and can be expressed as the function of the temperature ratio τ=TL/TH of the two heat reservoirs, the volume ratio rV=V3/V1, and the surface area ratio rA=A3/A1 of the two isochoric processes. Variations of difference of work output, ΔW, with the temperature ratio τ and volume ratio rV for the different surface ratio rA are examined,...