1. Thermoelectric Properties of Flexible PEDOT:PSS/Polypyrrole/Paper Nanocomposite Films
- Author
-
Shirley Shen, Runping Jia, Jiayue Xu, Jun Li, and Yong Du
- Subjects
Materials science ,Composite number ,02 engineering and technology ,engineering.material ,010402 general chemistry ,Polypyrrole ,lcsh:Technology ,01 natural sciences ,Article ,chemistry.chemical_compound ,polypyrrole ,PEDOT:PSS ,Coating ,Electrical resistivity and conductivity ,paper ,composite films ,flexible ,thermoelectric properties ,Seebeck coefficient ,Thermoelectric effect ,General Materials Science ,Composite material ,lcsh:Microscopy ,lcsh:QC120-168.85 ,Nanocomposite ,lcsh:QH201-278.5 ,lcsh:T ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,chemistry ,lcsh:TA1-2040 ,engineering ,lcsh:Descriptive and experimental mechanics ,lcsh:Electrical engineering. Electronics. Nuclear engineering ,lcsh:Engineering (General). Civil engineering (General) ,0210 nano-technology ,lcsh:TK1-9971 - Abstract
Flexible poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/polypyrrole/paper (PEDOT:PSS/PPy/paper) thermoelectric (TE) nanocomposite films were prepared by a two-step method: first, PPy/paper nanocomposite films were prepared by an in situ chemical polymerization process, and second, PEDOT:PSS/PPy/paper TE composite films were fabricated by coating the as-prepared PPy/paper nanocomposite films using a dimethyl sulfoxide-doped PEDOT:PSS solution. Both the electrical conductivity and the Seebeck coefficient of the PEDOT:PSS/PPy/paper TE nanocomposite films were greatly enhanced from 0.06 S/cm to ~0.365 S/cm, and from 5.44 μV/K to ~16.0 μV/K at ~300 K, respectively, when compared to the PPy/paper TE nanocomposite films. The thermal conductivity of the PEDOT:PSS/PPy/paper composite film (0.1522 Wm−1K−1 at ~300 K) was, however, only slightly higher than that of the PPy/paper composite film (0.1142 Wm−1K−1 at ~300 K). As a result, the ZT value of the PEDOT:PSS/PPy/paper composite film (~1.85 × 10−5 at ~300 K) was significantly enhanced when compared to that of the PPy/paper composite film (~4.73 × 10−7 at ~300 K). The as-prepared nanocomposite films have great potential for application in flexible TE devices.
- Published
- 2017