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An 18-metal lanthanide nanoring [Yb18(L1)8(HL2)2(OAc)20(MeOH)8(EtOH)6(H2O)4] (1), which shows a ratiometric fluorescent response to DPA, was constructed through the strategy of using two types of polydentate organic ligands. The addition of DPA increases the visible ligand-centered emission, but decreases the NIR lanthanide luminescence of 1. The limit of luminescent detection of 1 for DPA is 1.5 μM. The high fluorescence sensitivity of 1 to DPA is not affected by the existence of interferents such as aromatic carboxylates and ions. [ABSTRACT FROM AUTHOR]

Main observation and conclusion: One near‐infrared (NIR) luminescent octanuclear Zn(II)‐Yb(III) complex [Zn6Yb2L4(OAc)2(DMF)EtOH] (1) was obtained from a new multidentate Schiff base ligand. It exhibits interesting luminescent sensing activity to antibiotics, in particular to nitrofuran antibiotics (NFAs) with high sensitivity due to the inner filter effect. The NIR luminescence quenching constants and limits of the detection of the complex towards NFAs are 2.9 × 104—5.5 × 104 L/mol and 1.27—2.38 μmol/L, respectively. Its high luminescence sensitivity to NFAs is not changed with the existence of other antibiotics. [ABSTRACT FROM AUTHOR]

One NIR luminescent 14-metal Nd(III) nanoring (1, molecular size: 1.0 × 2.2 × 2.6 nm) was obtained from a rigid tridentate ligand, which can absorb and transfer light energy to the Nd(III) ions. 1 shows interesting luminescence sensing activity to antibiotics, in particular to NFAs with high sensitivity due to the inner filter effect. The quenching constants and the limits of detection of 1 to NFAs are 1.05 × 104 M−1–2.33 × 104 M−1 and 3.05 μM–6.75 μM, respectively. The high fluorescence sensitivities of 1 to NFAs are not changed by the existence of other antibiotics. It also exhibits high sensitivity in the luminescent detection of NFAs contained in real antibiotic drugs. [ABSTRACT FROM AUTHOR]