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Pore-size distribution (PSD) of soil is a fundamental property that determines flows of water, heat, chemicals, and electricity and controls distributions of stress and deformation. PSD can be intrinsically related to the soil–water retention curve (SWRC), which is a constitutive relationship describing how the soil skeleton retains pore water via adsorption and capillarity. A general framework to quantify soil's PSD is proposed by first fitting an analytical SWRC model to experimental water retention curves that explicitly separate the SWRC into an adsorptive SWRC and a capillary SWRC. The PSD is then estimated at incremental steps by combining the capillary SWRC and the conventional Young–Laplace equation relating capillary pressure to pore size. Cumulative and density PSD curves for 11 soils covering a wide spectrum of soil types are determined and compared with the PSD functions independently measured using mercury intrusion porosimetry (MIP). Good agreement is observed in the estimated pore size range, distribution pattern, and peak position determined from the two different methods. Differences observed in the methods are attributed to differences inherent in the use of wetting and nonwetting fluids to probe the pore space. The SWRC-based method generally characterizes pore sizes ranging from 100 to 0.02 μm with a major peak located within a pore diameter range of 1–10 μm. As the clay content increases, a secondary peak becomes evident at smaller pore sizes (about 0.01–0.1 μm), where the bimodal pattern reflects the dual-porosity microstructure commonly observed for clayey soils. For soils containing swelling clays, PSD can change substantially with variation in water content; thus, the water-based method is more appropriate than MIP for applications to geotechnical engineering practice. [ABSTRACT FROM AUTHOR]

A soil water unit weight of 9.8 kN/m3 has been universally considered to quantify soil volumetric phase properties such as void ratio and degree of saturation, but has been found to greatly vary depending on soil type and the volume scale with which it is defined. Recent experimental and theoretical evidence has indicated that the unit weight of soil water can be significantly greater than 9.8 kN/m3 for clayey soils when gravimetric water content is less than 30%. A soil water unit weight as high as 18.8 kN/m3 is evident for some expansive soils at low water content. The significance of abnormally high water unit weight in quantifying soil phase volumes, saturation, and void ratio was experimentally assessed for various clayey soils and theoretically interpreted as a function of water content and soil type. For clayey soils with low liquid limit, average soil water unit weight can be as high as 12.5 kN/m3 for gravimetric water content less than 10%. This leads to an overestimation of liquid-phase saturation and void ratio by as much as 8% if a soil water unit weight of 9.8 kN/m3 is used. For clayey soil with a high liquid limit, the average soil water unit weight can be as high as 18.8 kN/m3 for water content less than 18%, leading to overestimation of liquid-phase saturation by as much as 36% and void ratio by as much as 20% if 9.8 kN/m3 is used. Charts were developed to estimate average soil water unit weight as a function of soil specific surface area and water content, and as a function of liquid limit and water content. The commonly used value of 9.8 kN/m3 for water unit weight can lead to significant errors in estimating phase volumes, void ratio, and saturation for clayey soils. [ABSTRACT FROM AUTHOR]

Pore-water pressure in soil is caused by three physically distinguishable sources: ambient (environmental) pressure, surface tension–induced capillary pressure, and the soil's electromagnetic potential–induced adsorptive pressure. The former two form the conventional concept of pore-water pressure, which is considered a constant within a soil-water-air representative elementary volume and can be directly measured by piezometer (under saturated and compressive states) or tensiometer (under unsaturated and tensile states). The third one can be called adsorption-induced pore-water pressure and is localized within a certain distance to the particle surface of soil or intercrystalline surface of swelling clay. The adsorption-induced pore-water pressure is always compressive and dictates the water phase transition in soil by altering water's freezing point, density, and viscosity, among other physical properties. A framework of quantifying the adsorption-induced pore-water distribution via the measured soil water isotherm is presented for any soil type under any given water content. It is demonstrated that the adsorption-induced pore-water pressure can be up to 1.6 GPa in the first few layers of hydration, but will diminish to zero at a distance equivalent to the gravimetric water content >1% for sandy soil and greater than a few percent for silty soil. In clayey soil, the adsorption-induced pore-water pressure can sustain tens of megapascals even at much farther distance, equivalent to ∼30% water content. In expansive clay, the adsorption-induced pore-water pressure inside the crystalline lamellae can exceed 800 MPa. The soil water density functions of a silty soil and a bentonite clay predicted by the proposed framework matched well with that measured independently from the conventional consolidation testing, validating the framework to determine the spatial distribution of the adsorption-induced pore-water pressure in soil. [ABSTRACT FROM AUTHOR]