1. Recovery of critical metals from dilute leach solutions - Separation of indium from tin and lead
- Author
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Abdul J. Chaudhary, Nael G. Yasri, and Sue Grimes
- Subjects
Metallurgy ,electro-winning ,chemistry.chemical_element ,02 engineering and technology ,010501 environmental sciences ,021001 nanoscience & nanotechnology ,01 natural sciences ,cylindrical mesh electrode electrolysis cell ,Inorganic Chemistry ,indium tin oxide thin films ,chemistry ,indium recovery ,0399 Other Chemical Sciences ,Materials Chemistry ,0302 Inorganic Chemistry ,Physical and Theoretical Chemistry ,0210 nano-technology ,Tin ,critical metals ,Indium ,selective metal separation ,0105 earth and related environmental sciences - Abstract
The strategic metal indium is recovered from solutions containing tin and lead that are typical of those obtained from leach solutions of metal component fractions of electronic waste including the leach solutions from indium tin oxide thin film conductive layers that contain only indium and tin. Almost total recovery of the metals can be achieved from nitric, perchloric and acetic acid leach solutions using a novel cylindrical mesh electrode electrolysis cell under appropriate conditions. The optimum separation of indium from tin and lead is achieved by a novel three-stage process from nitric acid media in the presence of SCN− as a complexing agent. Lead is removed from dilute indium-tin-lead solutions in the first stage from 0.1 mol L−1 nitric acid solution by electrodeposition over an 8 h period in the absence of SCN− to give a residual solution containing a maximum of 2 mg L−1 of lead (97% recovery). Tin is removed in the second stage by electrodeposition over an 8 h period from the solution after addition of 0.02 mol L−1 SCN− to give a maximum residual electrolyte tin concentration of 3 mg L−1 (94% recovery). In the third stage indium is recovered at the anode of the cylindrical mesh electrode cell as an oxy-hydroxide phase by increasing the SCN− concentration to 0.1 mol L−1 and carrying out the electrolysis for a period of 24 h to give a residual solution containing 1 mg L−1 of indium (98% recovery). We acknowledge the support of an EPSRC/LINK WMR3 grant (GR/L03217) with Fluid Dynamics International Limited. We wish to thank Aleppo University for a scholarship to NY and Professor. J. D. Donaldson for all his advice and support.
- Published
- 2017