1. Standard Gibbs energies of transfer of rubidium tetraphenylborate from water to straight-chain n-alkanols
- Author
-
Guo Xiang-Kun, Zhang Pi-Jian, Wang Xiao-Ling, Qu Song-Sheng, Zhou Bao-Xue, Zou Li-zhuang, and Wang Feng-Ge
- Subjects
Tetraphenylborate ,medicine.diagnostic_test ,Inorganic chemistry ,Analytical chemistry ,chemistry.chemical_element ,General Chemistry ,Gibbs free energy ,Rubidium ,symbols.namesake ,chemistry.chemical_compound ,chemistry ,Straight chain ,Spectrophotometry ,medicine ,symbols ,Methanol ,Solubility ,N alkanols - Abstract
Solubilities of ribidium tetraphenylborate in water, methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol and l-octanol at 288.15, 298.15, 308.15, 318.15, 328.15 K have been determined by spectrophotometry. The standard Gibbs energy of transfer of ribidium tetraphenylborate from water to straight-chain n-alkanols and the primary medium effect of rubidium tetraphenylborate from 288.15 to 328.15 K have been calculated. Furthermore, the contribution of microscopic interactions to the standard Gibbs energy of transfer of rubidium tetraphenylborate in calculated and discussed.
- Published
- 2010