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Standard Gibbs energies of transfer of potassium tetraphenylborate from water to (water+t -butyl alcohol) mixtures and the primary medium effect

Authors :
Zhou Bao-Xue
Zhang Pi-Jian
Wang Feng-Ge
Wang Xiao-Ling
Zou Li-zhuang
Yu Qingjiang
Source :
Scopus-Elsevier
Publication Year :
1999
Publisher :
Elsevier BV, 1999.

Abstract

Standard Gibbs energies of transfer of potassium tetraphenylborate from water to (water + t -butyl alcohol) (TBA) mixtures at T = 298.15 K have been studied. The mole fractions of TBA in the mixed solvent are 0.00, 0.01, 0.02, 0.03, 0.04, 0.045, 0.05, 0.06, 0.07, 0.08, 0.09, 0.10, 0.20, 0.40, 0.60, 0.80, and 1.00, respectively. The primary medium effect of potassium tetraphenylborate in the mixed solvent is discussed.

Details

ISSN :
00219614
Volume :
31
Database :
OpenAIRE
Journal :
The Journal of Chemical Thermodynamics
Accession number :
edsair.doi.dedup.....4f1f4a447a2d337d3a3734760426f22c