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Calcium nitrate (CN: Ca(NO3)2) has been shown to mitigate alkali–silica reaction (ASR) in concrete. Such ASR mitigation has been suggested to be on account of precipitate (i.e., barrier or passivation layer) formation‐induced dissolution inhibition of reactive/dissolving aggregate surfaces. Herein, we examine the ability of CN to mitigate ASR across two cements (Type I/II and Portland Limestone Cement), for aggregates of varying reactivity, and across different types and dosages of SCMs (supplementary cementitious materials, i.e., amorphous steel slag and Class C and Class F fly ashes). Based on expansion measurements carried out as per ASTM C1260/C1567, it is observed that CN, as a function of dosage, substantively mitigates ASR in mortar formulations across aggregate types. Careful microstructural examinations, dissolution studies, and thermodynamic calculations indicate that CN induces the formation of C–S–H, portlandite (Ca(OH)2), and calcite (CaCO3) precipitate mixtures, which form on aggregate surfaces at the expense of typical ASR gels. Such precipitates create a dissolution barrier and inhibit ASR in both SCM‐free and SCM‐containing formulations. The outcomes indicate that CN is an efficient and cost‐effective ASR mitigation additive (∼$250–$600 per tonne), particularly in a time of dwindling fly ash supplies and unaffordable lithium prices (>∼$12 000 per tonne). [ABSTRACT FROM AUTHOR]

Cement plays a crucial role in mortar composition, and its particles exhibit a strong tendency to flocculate when mixed with water. This flocculation necessitates the addition of substantial water to improve the workability of mortar or concrete. However, this extra water does not contribute to the hydration reaction, potentially weakening the mechanical properties of the mortar. The introduction of superplasticizers has addressed this issue by reducing the water demand. Nevertheless, a common practice in construction is to use a standard dosage of superplasticizers for the same type of cement, even when sourced from different cement factories, which may affect material performance. This study investigated the influence of varying superplasticizer dosages on Portland pozzolana cement from different Ethiopian cement factories, examining the morphological characteristics of masonry mortar. Specifically, it evaluated the impact on cracks, porosity, and surface structure across different curing ages, as well as assessed the mortar's physical and mechanical properties. Mortar samples prepared using cement from three factories, labeled A, B, and C, with constant cement‐to‐sand ratios of 1:3 and water‐to‐cement ratios of 0.5. Superplasticizer added in varying amounts 0%, 0.6%, 0.8%, and 1%. The morphological analysis conducted using a 3D optical surface profiler microscope at 1, 7, 21, and 28 days. Besides these standard physical and mechanical tests also performed on all samples. The results demonstrated that addition of superplasticizers significantly influenced the surface morphology of mortar samples. Mortars A and B exhibited denser structures with superplasticizer dosages 0.8% and 1%, respectively, whereas mortar C displayed a denser structure in its control state (without superplasticizer). The flexural and compressive strength tests also revealed notable differences. Sample A2 (0.8%) from group A, sample B3 (1%) from group B, and sample C0 (0%) from group C achieved the highest strength within their respective groups at 28 days. The findings suggest that it is essential to evaluate the specific properties of cement before applying a standardized superplasticizer dosage, as variations in cement production can significantly influence the performance of the mortar. [ABSTRACT FROM AUTHOR]

The effects of micro-sized montmorillonite clay (MMT) on Portland cement concrete were examined in this study, focusing on regular and calcined MMT as partial cement replacements. Key properties assessed include consistency, setting time, flexural strength, and compressive strength at 7 and 28 days. Regular MMT initially acts as an inert filler, potentially reducing compressive strength, while calcined MMT improves compatibility and strength. Both types extend the setting time, with regular MMT causing more delay. The study highlights that the regular MMT increases water demand and setting time, whereas calcined MMT enhances strength and mitigates these issues. The results emphasize the importance of carefully choosing MMT type and dosage. [ABSTRACT FROM AUTHOR]

Sustainable structures are an important area of research, particularly for anticipated extended human presence on the Moon or Mars. Persistent human presence on the Moon will require building materials that are already present at the site to construct bases. The high cost associated with reinforcing metal (rebar) in mission payloads necessitates the exploration of alternative reinforcement methods for sustained lunar bases. Human hair is strong in tensile strength and will become available in any long-term mission. By using otherwise wasted hair instead of heavy metal, mission payloads and costs could be lowered. Concrete workability, compressive strength, and porosity were measured for a series of different cement compositions. These compositions consisted of combinations of Ordinary Portland Cement (OPC), lunar regolith, deionized (DI) water and human hair. Increased workability and porosity were found for increasing hair concentrations. Compressive strength slightly decreased with increased hair concentration. [ABSTRACT FROM AUTHOR]

The release of Neogene volcanism in the southeastern part of the Iberian Peninsula produced a series of volcanic structures in the form of stratovolcanoes and calderas; however, other materials also accumulated such as large amounts of pyroclastic materials such as cinerites, ashes, and lapilli, which were later altered to form deposits of zeolites and bentonites. This work has focused on an area located on the northern flank of the San José-Los Escullos zeolite deposit, the only one of its kind with industrial capacity in Spain. The main objective of this research is to characterize the zeolite (SZ) of this new area from the mineral, chemical, and technical points of view and establish its possible use as a natural pozzolan. In the first stage, a study of the mineralogical and chemical composition of the selected samples was carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray fluorescence (XRF), and thermogravimetric analysis (TGA); in the second stage, chemical-qualitative and pozzolanicity technical tests were carried out at 8 and 15 days. In addition, a chemical analysis was performed using XRF on the specimens of mortars made with a standardized mixture of Portland cement (PC: 75%) and natural zeolite (SZ: 25%) at the ages of 7, 28, and 90 days. The results of the mineralogical analyses indicated that the samples are made up mainly of mordenite and subordinately by smectite, plagioclase, quartz, halloysite, illite, and muscovite. Qualitative chemical assays indicated a high percentage of reactive silica and reactive CaO and also negligible contents of insoluble residues. The results of the pozzolanicity test indicate that all the samples analyzed behave like natural pozzolans of good quality, increasing their pozzolanic reactivity from 8 to 15 days of testing. Chemical analyses of PC/SZ composite mortar specimens showed how a significant part of SiO2 and Al2O3 are released by zeolite while it absorbs a large part of the SO3 contained in the cement. The results presented in this research could be of great practical and scientific importance as they indicate the continuation of zeolitic mineralization beyond the limits of the San José-Los Escullos deposit, which would result in an increase in geological reserves and the extension of the useful life of the deposit, which is of vital importance to the local mining industry. [ABSTRACT FROM AUTHOR]

This study presents the feasibility of improving some selected mechanical strengths and the inner-structural analyses of cement matrix by electrospun nanofibers containing nylon 66, nanosilica, and carbon nanotube. The hybrid electrospun nanofibers were fabricated and mixed into ordinary Portland cement. From the mechanical strength test results, the hybrid nanofibers have shown their role in improving the tensile, compressive, and toughness behavior of the mixed cement material. The improvements of 62%, 38%, and 69%, respectively, were observed compared to those of the control paste. The novelty of the surface and inner structure of the hybrid fibers, as well as the modified cement matrix, were observed by the scanned images from electron microscopes. Besides, the additional pozzolanic reaction between the generated calcium hydroxide and the attached silica was clarified thanks to the results of energy dispersive spectroscopy, X-ray diffraction, and thermal gravimetric analysis. Finally, the consistency between mechanical strength results and inner-structure analyses showed the potential of the proposed fiber to improve cement-based materials. [ABSTRACT FROM AUTHOR]

This research aims to comprehensively evaluate the performance of cold recycled mixtures treated with cement and plasticizer in laboratory and field settings. The study employed two recycled asphalt fractions, 0–40 mm and 0–20 mm, combined with varying proportions of portland cement (M500), water, and a plasticizer (ZHBI-S). Initial performance assessments were conducted using standard tests, followed by additional tests focusing on rutting resistance, beam fatigue, and elastic modulus of selected recycled asphalt pavement (RAP) compositions. Furthermore, field performance evaluation involved the collection of RAP mixture samples from the asphalt paver's bunker and core samples from the finished pavement. The investigation's outcomes suggest that the cold RAP mixture treated with cement and plasticizer can be applied as a binder or base course. [ABSTRACT FROM AUTHOR]

Cement and concrete are the most crucial and dominating engineering materials in the construction sector. Cement serves as an excellent binder for concrete and when it is treated under unusual conditions either to satisfy accelerating or retarding requirements by the construction industries, admixtures role comes into the effect. The construction industry has been searching for retarding admixtures and the optimal dosage level, particularly for ready mix concrete applications. Generally the retarding admixtures such as organic retarders (lignosulphonates, hydroxycarboxylic acids and their salts, phosphonates, sugars) or inorganic retarders (phosphonates, borates) were generally used to reduce the speed of the reaction between cement and water by altering the growth of the hydration products and/or limiting the rate of water penetration to the cement particles. The research was still in its infancy stage in terms of determining not just the appropriate dosage amount, but also the ideal retarder materials for the aforementioned uses. In considering this industrial need, an attempt was made on utilizing the usage of sugar in the concrete to study the retarding effect without affecting the strength properties of cement. The sugars usage levels were at 5, 10, 15, and 20% of the usage of cement to investigate consistency, setting time, compressive strength and micro structure properties at the curing age of 7, 14 and 28 days on the mortar specimens. The conclusions of the study reported that setting time was extended with increase of the dosage levels of sugar. However in considering the strength property, less than 5% of sugar dosage level can be better for the application as retarding agent in the industry applications. [ABSTRACT FROM AUTHOR]

Sulfate plays a critical role in portland cement. The internal gypsum (CaSO4·2H2O) incorporating with clinker controls the hydration of cement, while the external gypsum can attack the hydration products. Magnesium sulfate is renowned for sulfate attack on concrete. This study aims to investigate the impact of the internal Mg2+ addition on the composition and microstructure of hardened portland cement paste. Notably, the test results demonstrate that internal Mg2+ does not show the same aggressive effect as external Mg2+ on the destabilization of portland cement. Instead, internal Mg2+ infiltrates into the calcium-silicate-hydrate (C-S-H) gels, displacing the Al-O tetrahedra on the Si chain, forming C-(A, M)-S-H gels by converting Ca octahedra to Mg octahedra or Al-O tetrahedra to Mg-O tetrahedra. This process contributes to a decrease in the Al/Si ratio and mean chain length of the C-S-H gels. Additionally, the displaced Al-O tetrahedra from the C-S-H gels react with AFt, resulting in the AFm formation. Consequently, these structural changes in the C-S-H gels, along with additional pore filling through AFm precipitation, play a significant role in refining the pore structure. [ABSTRACT FROM AUTHOR]

Fly ash (FA) increases the performance of cement concrete through pozzolanic reaction and microstructure development at later ages. FA is usually associated with lower early age compressive strength especially at higher replacement levels. This study attempts at improving the early age strength of FA portland pozzolana cement with limestone calcined clay pozzolan (LC2). Different proportions of limestone and calcined clay (1∶1 , 1∶2 , and 2∶1) in tandem with FA at various replacements of cement clinker (30%, 40%, and 50%) were tested. The combined effect of using LC2 with FA has shown to enhance the early age hydration of cement along with improved compressive strength. Heat of hydration results showed increased heat release in FA mixes blended with LC2. Thermodynamic modeling analysis was used to study the change in phase assemblage of these mixtures. A higher solid volume observed in the thermodynamic simulations in the combined blends of FA and LC2 is hypothesized to be the cause of improved performance compared with only FA blended cement. Mercury intrusion porosimetry (MIP) results further confirmed an improvement in pore structure characteristics of FA cement blended with LC2. The possibility of reducing associated carbon emissions without compromising in strength are highlighted by using FA and LC2. [ABSTRACT FROM AUTHOR]

This study examined the chloride binding properties of slag-blended cement at different replacement ratios with two water-to-binder (w/b) ratios and two curing temperatures. Hydrated samples were immersed in NaCl solutions, and bound chloride at equilibrium was determined, respectively. It is found that at each w/b and temperature, chemically and physically bound chloride increased with increasing slag ratio up to 50%, whereas a further increase of slag ratio to 70% tended to reduce chloride binding. Physically bound chloride accounted for a major portion in total binding. Moreover, Ca(OH)2 content and slag reaction degree were analyzed, indicating that slag reaction degree decreased with increasing slag ratio. According to the results, the influence of slag ratio on chloride binding is discussed. The relatively low chloride binding at 70% slag ratio is partially attributed to the low reaction degree of slag, resulting in a lower amount of C-S-H and AFm phase. It is also inferred that the decreased physical binding at 70% slag ratio is closely related to the changed surface electrical property of C-S-H. [ABSTRACT FROM AUTHOR]

The article assesses the feasibility of rice husk ash (RHA) as an additive material in binary blended Portland Pozzolana Cement for road pavement applications. The experiment examines the impact of RHA on the tensile, split tensile and compressive strengths of the concrete at five replacement levels and various curing durations. It determines the optimal quantity and flexural strength of RHA as a cement substitute.

Basalt powder (BP) is the residue of a plant that crushes basalt stones. This work deals with the effect of waste BP on the properties of cement mortars and the physical properties of hardened mortars. Modified concrete was prepared by partial replacement of BP in amount of 5, 10, 20% by weight of cement. Physico-mechanical properties and corrosion resistance were investigated. Electrochemical impedance spectroscopy (EIS) was used to examine the corrosion behavior of cement pastes with a partial addition of basalt powder in aggressive solutions of 5% NaCl and 5% MgCl2 for up to 270 days. Infrared spectroscopy (IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were also performed to investigate the hydration process and microstructure formation of the basalt blended paste. Results indicate that the addition of basalt powder as a partial replacement of cement influences the microstructure of the interfacial transition zone (ITZ), which is denser and stronger than in cement paste without basalt powder. The filler effect of the basalt powder improves the compressive strength of cement paste. Also, comparing BP0 and BP20 in 5% NaCl after 270 days, the partial substitution of cement with BP resulted in a higher compressive strength of 671 and 895 kg/cm2, respectively. The EIS results also showed the highest values of Rp 953 ohms cm2 after 270 days. This high corrosion resistance might indicate the binding by high Al2O3 that reduced the free aggressive chloride ions in the solution. Article Highlights: The addition of basalt powder as a partial replacement of cement, improved the compressive strength of the concrete. The physicochemical and mechanical investigations showed that the basalt addition led to physical densification and more ITZ robust of cement matrix. EIS measurements showed that BP20 sample in 5% NaCl had a high Rp, 953 ohms cm2 after 270 days indicated higher corrosion resistance. [ABSTRACT FROM AUTHOR]

There are many environmental problems caused by factory waste. Sugar factory waste, in the form of bagasse ash, and PLTU factory waste, in the form of fly ash, are currently in the spotlight of science studies. This study used waste bagasse and fly ash to substitute Portland cement as the main ingredients for mortar. Baggash and fly ash waste were collected, processed, and then used to replace cement by up to 40% to determine to what extent they could be used in brick masonry work, wall plastering, and masonry paste. Experimental tests were carried out on mortar cube samples measuring 5×5×5 cm, comparing four types of samples consisting of Portland cement, bagasse ash, and fly ash. The compressive strength results were obtained after 28 days. Normal Mortar (MN=11.75 MPa) had higher compressive strength than the substitute mortar types MA (3.23 MPa), MB (3.09 MPa), and MC (2.98) MPa. According to SNI 6882- 2014, MA, MB, and MC mortars can be used as O-type mortar (2.4 MPa). Therefore, they can be applied to wall plastering or walls not bearing loads. [ABSTRACT FROM AUTHOR]

This study aimed to obtain and characterize a mortar with perlite aggregate and thermal-treated materials that could substitute for Portland cement. First, the thermally treated materials were obtained by calcinating old Portland cement (OC-tt) and concrete demolition waste (CC-tt) at 550 °C, for 3 h. Second, plastic mortars with a perlite: cement volume ratio of 3:1 were prepared and tested for water absorption, mechanical strength, and thermal conductivity. The microstructure was also analyzed. Portland cement (R) was partially substituted with 10%, 30%, and 50% OC-tt. Thermal-treated materials negatively influenced the compressive and flexural strengths at 7 and 28 days. With an increase in the substitution percentage to 50%, the decrease in the compressive strength was 40% for OC-tt and 62.5% for CC-tt. The presence of 10% OC-tt/CC-tt positively influenced the water absorption. The thermal conductivity of the tested mortars was in the range of 0.37–0.48 W/m·K. SEM analysis shows the expanded perlite pores remained unbroken. [ABSTRACT FROM AUTHOR]

This study aimed to investigate the effect of calcined clay as supplementary cementitious material on thermogravimetric analysis and compressive strength. Thai iron-rich Lopburi calcined clay was used as Portland cement replacement in the study at 5%, 10%, 15% and 20% by mass. Mortar and paste samples were water cured for 3, 7 and 28 days. The results showed that compressive strength increased when replacement level of Portland cement with calcined clay increased. The change in compressive strength with calcined clay content is discussed in relation to the acceleration in Portland cement hydration and pozzolanic reaction. Thermogravimetric analysis detected many phases such as calcium silicate hydrate (C–S–H), calcium aluminum silicate hydrate (C–A–S–H), monocarboaluminate and hemicarboaluminate hydrate, calcium hydroxide (Ca(OH)2) and calcium carbonate (CaCO3). In addition, thermogravimetric analysis showed the most hydration products which enhance the compressive strength such as C–S–H and C2ASH8 were found in the 20% calcined clay mix. [ABSTRACT FROM AUTHOR]

The AFm phase found in hydrated Portland cements refers to a family of calcium aluminate phases. Their layer structure is derived from that of portlandite (calcium hydroxide (Ca(OH)2)), but with one third of the Ca2+ ions replaced by a trivalent ion, nominally Al3+ or Fe3+. The resulting charge imbalance gives the layers a positive charge, which is compensated by intercalated anions; the remaining interlayer space is filled with water (H2O). Hydrated cements will contain mixtures of AFm phases and their solid solutions. Portland cement is often modified by addition of soluble nitrate or nitrite salts to protect embedded steel or to shorten the setting time. These nitrate and nitrite ions are capable of entering and occupying AFm anion sites, hence impacting overall phase balances between cement hydrates. In this study AFm phases and solid solution formations were investigated between AFm phases containing SO42−, CO32−, OH−, Cl− and NO2− NO3− ions. Samples were synthesised and subsequently characterised using X-ray diffraction and through the measurement of aqueous solution compositions after 180 days of equilibration in water. [ABSTRACT FROM AUTHOR]

For the first time, this paper explores the role of hydration kinetics on microcrack development in cement mortars using the μ-CT technique with a resolution of 2.2 µm. Three binders were tested: fine-grained ordinary Portland cement (OPC) with Blaine fineness of 391 m2/kg, coarse-grained OPC made from the same clinker with Blaine fineness of 273 m2/kg, and H-cement as a representative of the alkali-activated binder. It was found that most microcracks have a width in the range of 5–10 µm, increasing their occurrence with the progress of sealed hydration. While H-cement and coarse-grained OPC showed a comparable number of microcracks, fine-grained OPC exhibited more than twice the number of microcracks. In this sense, high hydration kinetics induce more microcracks, promoting later coalescence into visible cracks and disintegration of concrete at the end. Therefore, durable concrete with minimum microcracks should be derived from slow hydration kinetics or alkali-activation processes. [ABSTRACT FROM AUTHOR]

The limited early strength of low-heat cement (LHC) restricts its extensive application. This work compared the hydration degree, hydration products, and pore structure of the early strength of low-heat cement (ESHLC) in standard (P) and low-pressure (0.5P) curing by XRD, TG, SEM, and MIP. Also, the mechanical strength under different curing conditions was tested and compared. The results showed that compared with standard curing, the hydration degree of the early strength low-heat cement (ESLHC) lessens at 0.5P. Besides, by 90 days, the quantity of AFt had significantly declined, and the C─ S─ H gel displayed a loose cluster-like structure at 0.5P, showing that low atmospheric pressure has the potential to hasten the development of defects in hydration products. The ESLHC paste cured at 0.5 P displayed a coarser pore structure than that cured at P. At last, the low atmospheric pressure adversely affected the ESLHC mortar's strength. This work delves into the hydration characteristics of ESLHC under low-atmospheric-pressure conditions, providing theoretical support for applying ESLHC in plateau areas. [ABSTRACT FROM AUTHOR]

In this study, the hydration kinetics of ultrahigh-performance concrete (UHPC) with carbon nanofibers (CNFs) are investigated. According to classic nucleation theory, nanomaterials, such as CNFs applied in cementitious materials, can act as nucleating sites for hydration products, accelerating the hydration process. While the increased surface area governs the hydration reaction rate in classic nucleation theory, test results for CNFs in UHPC have provided the opposite trend. Namely, the addition of CNFs caused retardation of the hydration reaction. This observation could be due to the pretreatment of CNFs: the application of chemical surfactant and the ultrasonic dispersion process (UDP). Due to van der Waal's forces and the hydrophobic property of the fibers, CNFs tend to bundle together during the mixing stage with cementitious material. The chemical surfactants and UDP are applied to CNFs to avoid this agglomeration and enable dispersion. The selected chemical surfactant, a polycarboxylate-ether-based high-range water reducer (HRWR), has been proven to retard the hydration process. In this study, we find that the UDP further enhances the functionality of the effects of the HRWR, such that the retardation action of the HRWR dominates the hydration kinetics. Different amounts of HRWR and CNFs were used in this study, and their effect on hydration kinetics was studied using an isothermal conduction calorimeter (ICC). The behavior of the modified samples was compared with UHPC controls without any modifications. A new hydration model was developed based on the data collected from the ICC results. This model enables the prediction of the heat production rate as a function of the fineness modulus and the HRWR:CNF ratio (R). [ABSTRACT FROM AUTHOR]

This study examines cement and ceramic waste (CW) for the sub-base layer of roads. This innovative method can do away with the risks associated with improper disposal of industrial waste. To achieve this objective, several proportions of cement and CW were used, ranging from 1.5 to 2% and 5% to 15%, respectively. The aim of the work was to examine the influences of CW and ordinary Portland cement (OPC) on the unconfined compressive strength (UCS), permeability, consolidation, and microstructures of untreated and treated soil of road sub-base layer. The Guelph permeameter, UCS, permeability, and onedimensional consolidation were among the laboratory and in-situ tests that were examined; the microstructures were characterised using SEM, infrared (IR), and mercury intrusion porosimetry (MIP). The findings indicated that the high permeability of the natural soil caused harm to our road soon after construction. Applying 5 to 15% CW reduced permeability by approximately 100% and settlement by around 43%. Furthermore, under wet and immersed conditions, mixing CW and OPC with soil raised UCS by approximately 182% and 20 times, respectively. This study demonstrated that by enhancing the geotechnical properties of soil, CW and OPC combined with it could be used as a road sub-base layer material. [ABSTRACT FROM AUTHOR]

Tailings disposal is a major concern of the mining industry worldwide. After the recent upstream dam failures, the main tailings disposal method studied in Brazil is dry stacking. The mechanical behaviour of tailings disposed of by dry stacking can be enhanced by ground improvement techniques such as compaction effort, cement, and fibre insertion. Accordingly, the study was carried out herein to analyse the mechanical behaviour of a fibre-reinforced cemented iron ore tailings (IOT) through unconfined compression tests in specimens moulded at different points on the compaction curve using 1%, 3% and 5% of Portland cement and zero and 0.5% of polypropylene fibres as an alternative to enhance the overall performance of dry tailings storage facilities. The results showed that compacted fibre-reinforced cemented IOT strength and stiffness vary according to the dry unit weight and moisture content moulding point on the standard Proctor compaction curve. In addition, adding fibres to the compacted cemented IOT turns the brittle behaviour into a ductile one, especially for 1% of cement. Such enhancement is fundamental to guarantee the safety of iron dry stacks. Also, failure patterns are directly related to the moulding point on the compaction curve. Moreover, adding fibres has increased the strength of cemented and uncemented IOT, thus allowing the adoption of smaller cement contents. Therefore, for the first time, the behaviour of fibre-reinforced cemented IOT was presented and its dependency on moulding characteristics based on compaction curves position. [ABSTRACT FROM AUTHOR]

The experimental research focused on the influence of solutions containing chicken manure, pig slurry, and silage on the hydration processes of cements and clinker minerals such as C3S, β-C2S, C3A, and C4AF. The results showed that the hydration of C3S and β-C2S led to the formation of various phases, including Ca(OH)2, CaCO3, and various types of poorly crystalline C-S-H phases contaminated with Mg, S, P, Ti, K, and Cl elements. The C3A phase was the most susceptible to biological corrosion, while the C4AF phase was the most resistant. Studies on model cement demonstrated a significant influence of solution pH on bacterial presence, where pH ≥ 9 prevented their occurrence, while pH ≤ 4 and pH 6-7 favored their presence. The addition of γ-C2S and C12A7 phases to the model cement caused a modification of the sample's microstructure and revealed exceptional density, where all spaces were fully occupied by hydration products. Such a model of cement matrix construction prevents and limits the penetration of the corrosive agent into the sample interior. The obtained research results suggest the possibility of using such cement for bioreactor construction and employing additions of calcium aluminates and calcium ferrites to further enhance cement resistance to biological corrosion. [ABSTRACT FROM AUTHOR]

Self-cleaning cementitious materials have gained significant attention due to urban environmental pollution. In this study, nano-TiO2 (NT) was first mixed with cement mortar. Second, NTs were coated on fresh cast mortars and on hardened surfaces. Photocatalytic efficiency was evaluated using Rhodamine B under natural sunlight with three types of cement: white Portland (WPC), ordinary Portland (OPC), and Portland pozzolana cement (PPC). Among them, PPC cement mortars exhibited superior photocatalytic performance compared to WPC and OPC even with lower dosages of NT. The order of photocatalytic efficiency was highest for the hard-coat followed by fresh-coat and then intermix sample. Furthermore, Rietveld analysis for crystal structure refinement was used, and crystallography analysis (VESTA software) confirmed the presence of specific atoms and bonds in the crystal structure of PPC with NT. Microstructural analysis using XRD, SEM, and EDAX revealed underlying structural changes and thus quantified the hydration products. [ABSTRACT FROM AUTHOR]

In China, airports predominantly utilize airport cement concrete pavement, which inevitably undergoes deterioration in service. To uphold pavement durability and functionality, and ensure aircraft operational safety, prompt repairs of affected areas are imperative. Therefore, ordinary Portland cement mortars were used as the control group to compare and analyze the bonding performances of two common airport pavement repair materials: modified Portland cement mortars and phosphate cement mortars. Meanwhile, through microscopic experiments, the microscopic characteristics of the interfacial transition zone (ITZ) were studied, and the interface bonding mechanism was analyzed. The research results indicate that the interface bonding strength between phosphate cement mortar and old concrete pavement is the highest. This was because the elements in phosphate cement penetrated the old concrete pavement through hydration reactions, forming van der Waals forces and chemical bonding forces. In addition, the research results indicated that the presence of old concrete pavement made the three repair materials produce similar sidewall effects with the old concrete pavement, leading to a low hydration degree of the repair materials. However, the chemical bonding and penetrating structure of phosphate cement compensated for the weakening effect of the ITZ in the repair materials. [ABSTRACT FROM AUTHOR]

This study investigates the relationship between the molecular structure and foaming of poly(ethylene glycol) and poly(propylene glycol) triblock copolymers in Portland cement pastes. Four copolymers with different molecular structures were studied at varying concentrations. All copolymers showed a reduction in surface tension of the cement pore solution; however, only some of them demonstrated foaming and air entraining in cement paste. The results indicated that the molecular structure parameter, hydrophilic-to-lipophilic balance (HLB), has a direct relationship with the foaming and air-entraining performance of the copolymers. The total organic carbon measurements showed very small adsorption of these non-ionic copolymers on hydrating cement particles due to the lack of surface charge needed to interact with the heterogeneously charged surface of hydrating cement. In addition, these copolymers did not seem to affect the flow of cement paste due to a lack of adsorption on cement particles. The cement paste modified with the copolymers showed increased water sorption compared to the control paste due to the increased capillary porosity and slight increase in pore surface hydrophilicity. However, the freeze-thaw resistance was shown to improve with an increase in the number of air voids in the modified cement pastes. The findings establish the relationship between molecular properties of copolymers and their air-entraining performance in cement paste to mitigate the damages caused by freeze-thaw action. [ABSTRACT FROM AUTHOR]

Recent literature has exhibited a growing interest in the utilization of ground glass powder (GP) as a supplementary cementitious material (SCM). Yet, the application of SCMs in stabilizing heavy metallic and metalloid elements remains underexplored. This research zeroes in on zinc stabilization using a binder amalgam of GP and ordinary Portland cement (OPC). This study juxtaposes the stability of zinc in a recomposed binder consisting of 30% GP and 70% OPC (denoted as 30GP-M) against a reference binder of 100% CEM I 52.5 N (labeled reference mortar, RM) across curing intervals of 1, 28, and 90 days. Remarkably, the findings indicate a heightened kinetic immobilization of Zn at 90 days in the presence of GP—surging up to 40% in contrast to RM. Advanced microstructural analyses delineate the stabilization locales for Zn, including on the periphery of hydrated C3S particles (Zn–C3S), within GP-reactive sites (Si*–O–Zn), and amid C–S–H gel structures, i.e., (C/Zn)–S–H. A matrix with 30% GP bolsters the hydration process of C3S vis-à-vis the RM matrix. Probing deeper, the microstructural characterization underscores GP's prowess in Zn immobilization, particularly at the interaction zone with the paste. In the Zn milieu, it was discerning a transmutation—some products born from the GP–Portlandite reaction morph into GP–calcium–zincate. [ABSTRACT FROM AUTHOR]

Although quartz powder is a common concrete filling material, the importance and originality of this study lies in the development of a hydration model for quartz powder–cement binary mixtures and the adoption of this model to predict the development of concrete material properties. The purpose of this study is to use this model to promote the material design of environmentally friendly concrete and to elucidate the relationships in the development of the various properties of quartz powder concrete. The method used in this study was as follows: The parameters of the hydration model were obtained through seven days of hydration heat experiments. The hydration heat up to 28 days was also calculated, and the various properties of the concrete were predicted from the heat of hydration. The main findings of this study were as follows: (1) The ultimate hydration heat released per gram of cement for the different quartz powder substitution rates and quartz powder particle fineness was the same, at 390.145 J/g cement, as was the shape index of the hydration model at −1.003. (2) Moreover, through the model calculations, we found that, at the twenty-eighth day of the curing period for the quartz powder specimens with different quartz powder substitution amounts and different fineness, the reaction level of the cement was similar, at 0.963, as were the values of the cumulative heat of hydration, with both at 375.5 J/g cement. (3) The model showed that, in the late stage (28 days) of hydration for quartz powders of different fineness and when the substitution amount was the same, the cumulative heat of hydration over 28 days was similar. (4) The properties of concrete were evaluated using the calculated hydration heat. Overall, the predictive performance of the power and linear functions was similar, with no significant differences being found. [ABSTRACT FROM AUTHOR]

In this research, the properties and cementitious performance of thermally activated cement pastes (referred to as DCPs) are investigated. Hydrated pastes prepared from Portland cement and slag blended cement were subjected to different thermal treatments: 350 °C for 2 h, 550 °C for 2 h, 550 °C for 24 h and 750 °C for 2 h. The properties and the reactivity as SCM of the DCPs were characterised as well as their effect on the mechanical performance and hydration of new blended cements incorporating the DCPs as supplementary cementitious materials (SCMs). It was observed that the temperature and duration of the thermal treatment increased the grindability and BET specific surface area of the DCP, as well as the formation of C2S phases and the reactivity as SCM. In contrast, the mechanical strength results for the blended cements indicated that thermal treatment at 350 °C for 2 h provided better performance. The hydration study results showed that highly reactive DCP interfered with the early hydration of the main clinker phases in Portland cement, leading to early setting and slow strength gain. The effect on blended cement hydration was most marked for binary Portland cement–DCP blends. In contrast, in the case of ternary slag cement–DCP blends the use of reactive DCP as SCM enabled to significantly increase early age strength. [ABSTRACT FROM AUTHOR]

This study investigated the influences of ultrafine fly ash (UFA) and ultrafine slag powder (USL) on the compressive strengths, autogenous shrinkage, phase assemblage, and microstructure of magnesium potassium phosphate cement (MKPC). The findings indicate that the aluminosilicate fractions present in both ultrafine fly ash and ultrafine slag participate in the acid–base reaction of the MKPC system, resulting in a preferential formation of irregularly crystalline struvite-K incorporating Al and Si elements or amorphous aluminosilicate phosphate products. UFA addition mitigates early age autogenous shrinkage in MKPC-based materials, whereas USL exacerbates this shrinkage. In terms of the sustained mechanical strength development of the MKPC system, ultrafine fly ash is preferred over ultrafine slag powder. MKPC pastes with ultrafine fly ash show greater compressive strength compared to those with ultrafine slag powder at 180 days due to denser interfaces between the ultrafine fly ash particles and hydration products like struvite-K. The incorporation of 30 wt% ultrafine fly ash enhances compressive strengths across all testing ages. [ABSTRACT FROM AUTHOR]

Molybdenum tailings are accumulated in large quantities, occupying the land and polluting the environment. Therefore, the resource utilization of molybdenum tailings is imperative. In this paper, the influence of molybdenum tailings powder (MTs) as admixture on hydration characteristics, including hydration heat, hydration products, phase composition, and mechanical properties evolution of cement paste were investigated. Results showed that the early hydration of cement paste can be promoted when the content of MTs is not more than 15%. The compressive strength of cement paste with 15% MTs at 3, 28, and 120 days was 89.37%, 96.14%, and 91.68% of that of the portland cement (PC) group, respectively. When the content of MTs does not exceed 15%, the second exothermic peak of hydration heat of cement paste appears ahead of time and the peak value increases. With the increase of MTs content, the cumulative heat release of 72 h gradually decreased. The addition of MTs does not produce new hydration products, but introduces the mineral phase of MTs itself, and leads to the early transformation of ettringite (AFt) into monosulfoaluminate (AFm) in paste. There is still a close linear relationship between the compressive strength and cumulative heat release and chemically bound water content after addition of MTs into cement paste. It was also discovered that the pozzolanic activity of MTs in cement paste mainly occurred from 3 to 28 days. After 28 days, the particle-filling effect of MTs was dominant mainly. The research results are expected to provide basic research for the resource utilization of MTs. [ABSTRACT FROM AUTHOR]

Red mud has been used as a supplement substitute material in the fabrication of concrete. However, the influence mechanism of red mud on the film-forming performance of cement paste is still unclear. In this study, red mud with different substitution rates (by cement mass) was added to cement paste to investigate the influence of red mud on the film-forming performance. The addition of red mud increased the cohesiveness and reduced the fluidity of cement paste. It showed that low fluidity reduced the film thickness of cement paste, and the film thickness decreased gradually with the increase of red mud substitution. Moreover, thermogravimetric analysis, X-ray diffraction, and scanning electron microscopy results demonstrated that red mud promotes the hydration process of cement by providing hydration nucleation sites, making the interfacial transition zone denser, which is important for improving the mechanical properties of cement paste. It is expected that this study improves the application of red mud in concrete. [ABSTRACT FROM AUTHOR]

To enhance the application of coal series kaolinite clay in the cement industry, the properties and hydration of ternary system based on calcined coal series metakaolin (CMK), limestone (LS), and Portland cement were investigated in this work. The results showed that the kaolinite phase transformed into an amorphous phase for coal series kaolinite clay calcined over a wide temperature range. The negative effects of the CMK on the early (3 and 7d) compressive strength of mortars and of LS on the later (28 and 90 d) compressive strength of mortars could be offset by using a combination of LS and the CMK. The combined incorporation of the CMK and LS promoted the hydration of cement at an early hydration age, and the pozzolanic reaction of the CMK generated additional hydration products. In the ternary system, the use of LS weakened the influence of the calcination temperature of the CMK on the early hydration of cement; similar heat release and strength development can be observed for all CMK-LS content blends. At a late hydration age, the incorporation of LS resulted in the formation of carboaluminate instead of monosulfoaluminate, and the CMK enhanced this reaction. As a result, the hydration of Portland cement, CMK, and LS was improved due to the synergistic effect of the CMK and LS, and the mixture of CMK and LS is expected to be a promising supplementary material. [ABSTRACT FROM AUTHOR]

Cement-stabilized soil retaining wall structures are becoming increasingly popular for high-speed railway lines. However, the widely used Portland cement is heavily associated with carbon dioxide (CO2) emissions. Additionally, the rising cost and scarcity of sand traditionally used as fill material is becoming a concern. Besides, the geomechanical performances of the cement-stabilized soil retaining walls using three-dimensional (3-D) finite element method (FEM) numerical analysis have seldom been investigated. To address these issues, this study investigates the geomechanical performances of geocell-reinforced soil (GRS) backfilled with magnesia-based cement-stabilized marine fill using the nonlinear stress-strain relationship and 3-D FEM models as an alternative to the traditional earth GRS walls. The study finds satisfactory results regarding stability, deformation, and settlement. Only nominal facing reinforcements may be required as the magnesia cement mechanically stabilizes the fill. Moreover, the strength and stiffness properties improve with increased curing duration. The safety factors and observed displacements were within acceptable limits. However, the critical region for the cement-stabilized marine fill GRS wall showing a rupture zone was identified at the toe of the structure. Finally, the study developed a load-displacement model for settlement predictions and uncertainty interpretations, and explained the strength development and deformation mechanisms. The results suggest that cement-stabilized soil retaining walls using magnesia-based cement could be a viable alternative to traditional earth GRS walls, while mitigating environmental concerns and reducing costs. [ABSTRACT FROM AUTHOR]

The purpose of this research was to study the influence of multifunctional anatase–silica photocatalytic materials (ASPMs) with various photocatalytic and pozzolanic activities on the properties of white portland cement and fine-grained concrete. ASPMs were synthesized by a sol–gel method, during which the levels of photocatalytic and pozzolanic activity were regulated by a certain amount of solvent. ASPMb, obtained with the use of a smaller amount of solvent, was characterized by increased pozzolanic activity due to the lower degree of coating of the surface of diatomite particles with titanium dioxide and the higher content of an opal–cristobalite–tridymite-phase and Bronsted acid sites. They promoted the reaction of diatomite with portlandite of cement stone and allowed significant decreases in the strength of cement–sand mortar to be avoided when replacing 15% of the cement with ASPMs. This allowed self-cleaning fine-grained concrete to be produced, which, after forced carbonization, simulating the natural aging of the product during operation, retained the ability of self-cleaning without changes. ASPMc, produced with the use of a larger amount of solvent with a more uniform distribution of titanium dioxide on the surface of diatomite, allowed fine-grained concrete with a high self-cleaning ability to be obtained, but with a lesser manifestation of the pozzolanic effect. [ABSTRACT FROM AUTHOR]

Desert areas contain abundant desert sand (DS) resources, and high-volume recycling of DS resources as components of cement-based materials can achieve high-value applications. In this paper, DS was processed into desert sand powder (DSP) and replaced with cement in high volumes (20 wt.%–60 wt.%) to produce cement pastes. The mechanical properties, heat evolution, nanomechanical characteristics, microstructure, and economic and environmental impact of cement pastes were studied. The results show that adding 20 wt.% DSP increases the compressive strength of pastes and accelerates cement hydration, compared with the control group (0 wt.% DSP). Meanwhile, incorporating an appropriate amount of DSP (20 wt.%) effectively reduces porosity, increases the proportion of harmless and less harmful pores, and reduces the proportion of more harmful pores. From the perspective of nanoscopic properties, the addition of 20 wt.% DSP increases the C-S-H volume fraction, especially enhancing the transformation of low-density C-S-H to high-density C-S-H. Notably, the sample incorporating 60 wt.% DSP exhibits the lowest values for CI coefficients (13.02 kg/MPa·m3) and Cp coefficients (2.29 USD/MPa·m3), thereby validating the application of high-volume DSP feasibility in cement-based materials. [ABSTRACT FROM AUTHOR]

Steel slag is a significant environmental liability generated by pyrometallurgical processes. Residue generation, such as granulated blast furnace slag and basic oxygen slag (BOF), is intrinsic in steel production. Blast furnace slag, generated in the carbothermal reduction of iron ore, is almost entirely used as a supplementary cement material in Portland cement. BOF slag, produced in the conversion of pig iron into steel in a basic oxygen converter, is still not consolidated or valued for reuse. This research proposes the reuse and valorization of BOF slag combined with blast furnace slag in clinker-free cement production. Cement formulations were produced with different slag and gypsum contents, ranging from 80 to 90% blast furnace slag, 10 to 20% gypsum, and 10 to 15% BOF slag. All formulations were evaluated for compressive strength at ages of 3, 7, 14, 28, 91, and 180 days of curing. At the initial ages, the cement formulations exhibited high resistance. On the 3rd day, the cement formulations reached up to 10 MPa, and on the 7th day, 40 MPa. At late ages, the best-performing formulation, ECO2, showed, after 28 days of hydration, a compressive strength greater than 50 MPa, and at 180 days, a compressive strength greater than 80 MPa. It was possible to understand that BOF slag acts in cement alkaline activation with pH increase, more or less actively due to the presence of lime, portlandite, and calcite. [ABSTRACT FROM AUTHOR]

Rice husk ash (RHA) is a promising pozzolanic alternative material for partial replacement of ordinary Portland cement to increase the durability and strength of concrete and, at the same time, to decrease the corrosion effect caused by the harsh environment conditions. In this study, the impact of adding RHA in different ratios (0%, 7%, and 14%) as a replacement of ordinary Portland cement with different water–cement ratios (0.3, 0.5, and 0.7) and cured in water for different periods (10, 20, and 30 days) both on the durability and strength of the concrete and on its corrosion was investigated. The prepared specimens were tested by flexural, compressive, and tensile strength tests, slump test, and Rapid Chloride Ion Penetration test to determine the suitability of the partial replacement of ordinary Portland cement by RHA in concrete. The most important findings of this work, which is considered novel in this field, are that adding fine (instead of more extensive) RHA particles enhances the flexural, compressive, and tensile strength values and limits the chloride ion penetration with time. An adverse impact was found to increase the water–cement ratio, which is assigned to the effect of water on RHA and as a result on the porosity of the concrete.

Abstract One strategy to reduce CO2 emissions from cement production is to reduce the amount of Portland cement produced by replacing it with supplementary cementitious materials (SCMs). Biochar is a potential SCM that is an eco-friendly and stable porous pyrolytic material. However, the effects of biochar addition on the performances of Portland cement composites are not fully understood. This meta-analysis investigated the impact of biochar addition on the 7- and 28-day compressive strength of Portland cement composites based on 606 paired observations. Biochar feedstock type, pyrolysis conditions, pre-treatments and modifications, biochar dosage, and curing type all influenced the compressive strength of Portland cement composites. Biochars obtained from plant-based feedstocks (except rice and hardwood) improved the 28-day compressive strength of Portland cement composites by 3–13%. Biochars produced at pyrolysis temperatures higher than 450 °C, with a heating rate of around 10 C min-1, increased the 28-day compressive strength more effectively. Furthermore, the addition of biochar with small particle sizes increased the compressive strength of Portland cement composites by 2–7% compared to those without biochar addition. Biochar dosage of

To address the increasing demand for cement and promote sustainable development, the utilization of igneous rock powder as a supplementary material to partially replace cement has emerged as an effective strategy. In this study, the fluidity and mechanical properties of the igneous rock powdercement (IRP-OPC) composite system were investigated, and the hydration product and microstructure of IRP-OPC were analyzed by using TG/DSC, N2 adsorption-desorption curve (BET) and SEM. The experimental findings demonstrate that the performance of the andesite powder-cement composite cementing system (AP-OPC) surpasses that of tuff powder-cement slurry (TP-OPC) and granite powder-cement slurry (GP-OPC). When the dosage of andesite powder (AP) is 5%--15%, the flowability, flexural strength and compressive strength of cement mortar are improved. When the dosage is 10%, the 28-day compressive strength is 48.3 MPa. Under the condition of low content (10%), part of Ca(OH)2 is fully consumed by active SiO2 in AP and reacts to form C-S-H. Hydration products and AP particles with small particle size are filled into the structural gap, which refines the pore structure of cement slurry, and the increase in compactness provides support for the development of strength in the later stage. The use of 5%--15% AP instead of OPC can improve fluidity and meet the strength requirements of P.O 42.5 Portland cement. This substitution not only reduces engineering costs but also enhances resource utilization. [ABSTRACT FROM AUTHOR]

The co-processing of different wastes as fuels in the manufacture of cement clinker not only meets the objectives of a circular economy but also contributes to the reduction in CO2 emissions in the manufacture of Portland cement. However, waste used as alternative fuels, such as sludge or organic-rich residues, may contain naturally occurring radionuclides that can be concentrated during the combustion process. In this study, the presence of natural radionuclides (radioactive series of uranium, thorium, and 40K) and anthropogenic radionuclides (137Cs) in these wastes has been investigated by gamma spectrometry. Possible relationships between the radioactive content and the obtained chemical composition, determined by X-ray fluorescence, have also been studied by applying a principal component analysis (PCA). The results showed that the wastes with the highest radioactive content were sewage sludge with activity concentrations of 238U and 210Pb of 321 ± 38 Bq kg−1 and 110 ± 14 Bq kg−1, respectively. A correlation between radioactive content and Fe2O3 concentration was also observed. The annual effective dose rates to workers for the ashes estimated from the ash content ranged from 0.0033 mSv to 0.092 mSv and therefore do not pose a risk to workers as they are lower than the 1 mSv per year limit for the general public (DIRECTIVE 2013/59/EURATOM). [ABSTRACT FROM AUTHOR]

The change in the corrosion activities of SS304 and the carbon steel A36 were studied during their exposure for 30 days to hybrid pumice-Portland cement extract (CE), to simulate the concrete–pore environment. The ionic composition and the initial pH (12.99) of the CE were influenced by the reduction of Portland cement (PC) content, volcanic pumice oxides and alkaline activators. Because of the air CO 2   dissolution, the pH decreased and maintained a constant value ≈ 9.10 (established dynamic ionic equilibrium). The CE promoted the passivation of both steels and their free corrosion potential (OCP) reached positive values. On the surfaces, Fe and Cr oxides were formed, according to the nature of the steel. Over the time of exposure, the presence of chloride ions in the pumice caused a localized pitting attack, and for carbon steel, this fact may indicate an intermediate risk of corrosion. The chloride effect was retarded by the accumulation of SO 4 2 − ions at the steel surfaces. Based on electrochemical impedance (EIS), the polarization resistance (Rp) and the thickness of the passive layers were calculated. Their values were compared with those previously reported for the steels exposed to CEs of Portland and supersulfated cements, and the hybrid cement was considered as a PC "green" alternative. [ABSTRACT FROM AUTHOR]

Super sulphated cement (SSC) is a very promising substitute for traditional construction materials (i.e. Portland cement), due to its enhanced durability and particularly low environmental impact. This paper explores the microstructure and certain properties of SSC, focusing on the particular complexities of its microstructure and the difficulties of microanalysis of its hydrates. To do so, SSC paste samples were first cast to identify hydration products using X‐ray diffraction, then observed at early age using confocal laser scanning microscopy (CLSM) and at early and late age using scanning electron microscopy. In addition, concrete cores impregnated with fluorescein in order to highlight porosity, cracking and aggregates debonding were observed under UV light using optical microscopy (OM), showing a complete absence of cracking and aggregate debonding. Both microscopy techniques (CLSM and UV light OM) have been applied to this type of binder for the first time. The results show that SSC microstructure is characterised by a sophisticated intergrowth of various phases, including ettringite and amorphous calcium‐(alumina)‐silicate hydrate gels. Finally, Monte–Carlo simulation of electron‐matter has been provided for a better understanding of EDS analysis. LAY DESCRIPTION: This work focuses on the study of a particular construction material known as super sulphated cement (SSC). SSC appears to be a promising alternative to traditional building materials as it offers improved durability reduced and environmental impact attributed to its composition comprising at least 75% of a by‐product of the steel industry. This study investigates the microstructure and properties of this type of cement, focusing particularly on its complex microstructure and the challenges posed by the analysis of its hydration products. To do this, samples of SSC cement paste were first cast to identify hydration products using X‐ray diffraction. They were then examined at early stages using confocal laser scanning microscopy (CLSM) and at early and late stages using scanning electron microscopy (SEM). In addition, fluorescein‐impregnated SSC concrete cores were observed under ultraviolet (UV) light using optical microscopy (OM) to highlight porosity, cracking and delamination of aggregates, phenomena that may be present in such materials. These observations revealed the absence of these problems on this type of cement in this work. This research marks the first application of CLSM and OM under UV light to this type of cement. These microscopic techniques enabled us to understand the hydration phenomenon of this type of cement and its highly complex morphology. Finally, Monte–Carlo simulation was used in this study to model electron‐matter interaction, enabling us to understand the elemental analyses obtained and to gain a better understanding of the microstructure of SSC samples. [ABSTRACT FROM AUTHOR]

This research investigated the synergistic adoption of sodium silicate (SS) and the synthetic calcium silicate hydrates (C-S-Hs)/polycarboxylate (PCE) nanocomposites on the hydration behavior of portland cement containing 20% by weight of lithium slag (LS). Effects of SS and C-S-Hs-PCE on rheological performance, mechanical strength development, and hydration process were evaluated. Results showed that C-S-Hs-PCE was advantageous for modifying the rheological performance of fresh LS-cement binder, while SS increased the rheology and yield stress and shortened setting time of the LS-cement binder. C-S-Hs-PCE promoted the hydration of silicates to form abundant CH, and SS generated the dissolution of metallic ions from LS. The hastened dissolution of LS accelerated the formation of ettringite (AFt) as well as C-S-H gel. Because the hydration of cement and pozzolanic reaction of LS were both promoted, the hydration products of hardened matrix were increased, and the interlaced combination structure of hydrates in the matrix was greatly improved, which was favorable for the development of mechanical strength. The findings provide theoretical guidelines for modifying the properties of blended cements by uniting nanoparticles and chemicals. [ABSTRACT FROM AUTHOR]

This study aims at the evaluation of different formulations of concrete made with calcined clays and limestone (LC3 cement) exposed to aggressive environments. The study includes the evaluation of fresh and hardened properties and a comprehensive evaluation of durability over 24 months. The inclusion of calcined clays in cement increases the specific surface area of the cements, and thus the water demand. However, the high reactivity of calcined clays compared to any other pozzolan, and the synergy that occurs with limestones, enables the use of cements with very low clinker content that achieve strengths similar to those of Portland. Comparisons of LC3 formulations with Portland cement and with concrete containing silica fume prove the superiority of calcined clays in terms of strength and durability. The best results are obtained with LC3-50 cement with 50% clinker produced through co-grinding. Results of concrete made with a blend of 70% Portland cement with 30% LC2 (60% calcined clay, 35% limestone, 5% gypsum, separate ground) are also promising. All concretes made with LC3 show good durability in terms of the results of effective porosity, chloride permeability, and resistivity tests. [ABSTRACT FROM AUTHOR]

Rice husk ash (RHA) is a promising pozzolanic alternative material for partial replacement of ordinary Portland cement to increase the durability and strength of concrete and, at the same time, to decrease the corrosion effect caused by the harsh environment conditions. In this study, the impact of adding RHA in different ratios (0%, 7%, and 14%) as a replacement of ordinary Portland cement with different water–cement ratios (0.3, 0.5, and 0.7) and cured in water for different periods (10, 20, and 30 days) both on the durability and strength of the concrete and on its corrosion was investigated. The prepared specimens were tested by flexural, compressive, and tensile strength tests, slump test, and Rapid Chloride Ion Penetration test to determine the suitability of the partial replacement of ordinary Portland cement by RHA in concrete. The most important findings of this work, which is considered novel in this field, are that adding fine (instead of more extensive) RHA particles enhances the flexural, compressive, and tensile strength values and limits the chloride ion penetration with time. An adverse impact was found to increase the water–cement ratio, which is assigned to the effect of water on RHA and as a result on the porosity of the concrete. [ABSTRACT FROM AUTHOR]