1. Fractional-order model identification for state of health assessment of solid-oxide fuel cells
- Author
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Boštjan Dolenc, Pavle Boškoski, Christoph Hochenauer, Gjorgji Nusev, Nicole Gehring, Vanja Subotić, and Đani Juričić
- Subjects
Materials science ,Hydrogen ,business.industry ,020209 energy ,System identification ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Transfer function ,Dielectric spectroscopy ,Identification (information) ,chemistry ,Control and Systems Engineering ,Hydrogen fuel ,Frequency domain ,0202 electrical engineering, electronic engineering, information engineering ,Energy transformation ,0210 nano-technology ,Process engineering ,business - Abstract
Solid-oxide fuel cells (SOFCs) represent a group of electrochemical conversion devices that utilise hydrogen rich fuels and are characterised by their high efficiency of energy conversion. For optimal exploitation of SOFCs, accurate and online state-of-health (SoH) assessment is of utmost importance. SoH assessment is usually performed through the frequency domain analysis by characterising the changes of the Nyqvist curves, a process also known as electrochemical impedance spectroscopy. Such an approach is time consuming and suffers from low accuracy particularly at low frequencies. Methodologies for time-domain identification of fractional-order systems offer a way of resolving these issues. Using an algebraic approach to identification, the complete fractional-order transfer function is identified from a series of several step responses. The SoH can be estimated from the identified parameters of the fractional-order transfer function either in a form of a Nyqvist curve or by directly linking particular parameter values to electrochemical processes. The proposed approach was validated on a 300 W SOFC using pure hydrogen fuel.
- Published
- 2018
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