1. Performance properties, lactic acid specific migration and swelling by simulant of biodegradable poly(lactic acid)/nanoclay multilayer films for food packaging.
- Author
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Scarfato P, Di Maio L, Milana MR, Giamberardini S, Denaro M, and Incarnato L
- Subjects
- Polyesters, Biodegradable Plastics, Food Packaging instrumentation, Food Packaging methods, Green Chemistry Technology, Lactic Acid chemistry, Polymers chemistry
- Abstract
The aim of the study was the development of a multifunctional, high-performance, fully biodegradable multilayer polylactic acid (PLA) film for food packaging applications. In particular, sealable multilayer PLA-clay nanocomposite systems with different layouts in terms of composition and relative thickness of the layers, all consisting of a PLA-clay nanocomposite layer between two pure PLA layers for direct food contact, were designed and produced by blown film co-extrusion. The films obtained were analysed for their morphology, functional properties and lactic acid (LA)-specific migration in 50% ethanol. The results showed that, with respect to the unfilled multilayer system, taken as a reference, the nanocomposite films had significant improvements, up to about 40%, in their barriers to oxygen and tensile strengths, and resulted in being more easily sealable over a wide heat-sealing temperature range (80-100°C) with higher seal strength. Moreover, all films had LA migrations always well below the former generic overall migration limit of 60 mg kg
-1 food (10 mg dm- 2 ) of European Union Regulation No. 10/2011 (deleted by the amending Regulation No. 2016/1416), even if their morphology was strongly modified during the migration tests due to the strong swelling action of the used simulant (simulant D1 = 50% ethanol (aq.) (v/v)) towards PLA.- Published
- 2017
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