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Under the background of carbon neutral, hydrogen-fueled Wankel rotary engine (WRE) with high power density and compact layout has the potential to become a substitute for current fossil engines. Ammonia as a carbon-free renewable energy is considered alternative energy used in vehicles, however, its application on WRE is lacking. Therefore, the present work aims to investigate the performance of ammonia-enriched hydrogen-fueled WRE to analyze the feasibility of ammonia applied in hydrogen-fueled WRE. The main conclusions are as follows: Under test conditions, the maximum brake torque and thermal efficiency are obtained at about 30% and 40% volume fraction of ammonia in fuel, and compared with pure hydrogen conditions, achieving relative improvements of 21% and 29%, respectively. Slightly rich combustion is recommended to increase power and decrease NO emissions with an acceptable economic loss. In addition, ammonia enrichment can prevent the occurrence of abnormal combustion. [Display omitted] • Performance analysis of NH3-enriched hydrogen-fueled Wankel rotary engine. • NH3 enrichment can improve dynamics and economy with penalties for NO emission. • Slightly rich combustion is recommended for NH3-enriched hydrogen-fueled WRE. • NH3 enrichment is an effective way to prevent abnormal combustion. [ABSTRACT FROM AUTHOR]

As a hydrogen carrier, ammonia can suppress knock and enhance thermal efficiency of the hydrogen-fueled Wankel rotary engine (WRE), and achieve zero carbon emissions. This research established a three-dimensional fluid dynamics model coupled with detailed reaction kinetics of ammonia and hydrogen and verified it based on experiments. Incorporating 10% volume fraction of ammonia into the hydrogen-fueled WRE eliminates knock and decreases the excess air ratio (λ) from 1.8 to 1.4, effectively improving the indicated mean effective pressure (IMEP). The results indicate that when λ exceeds 1.4, flame propagation accelerates with higher concentration of the mixture. This enhances peak in-cylinder pressure and heat release rate, but it results higher NOx emissions. As λ varies from 1.8 to 1.4, NOx emission levels rise by 47.4%. At λ ≤ 1.2, the rapid flame propagation leads to short combustion duration, diminishing the power output. At this stage, the NO formation is dominated by H radicals, and the NOx production reaches its minimum value at λ of 1.0. In summary, the ammonia-hydrogen WRE achieves optimal performance at λ of 1.4 and ignition timing of −5 °CA after top dead center, the indicated thermal efficiency reaches 36.9% and the IMEP achieves 0.683 MPa. • The effect of ammonia addition on hydrogen-fueled WRE is analyzed. • The addition of ammonia is an effective way to prevent abnormal combustion. • The effects of excess air ratio on combustion and emission are analyzed. • The optimum ignition timing corresponding the optimal performance is given. • The optimum IMEP and ITE is obtained when the excess air ratio equals 1.4. [ABSTRACT FROM AUTHOR]

This paper aims to numerically investigate the effects of high compression ratio (CR) on the performance of ammonia-hydrogen engines. In this work, four CRs from 10.7 to 13.7 with scanning spark timing (ST) from 28°CA to 0°CA BTDC were analyzed. The main results are as follows: As the CR increases, there is a trade-off relationship between the dissipation rate of turbulence and the turbulent kinetic energy (TKE). Initially, the TKE rises as the CR increases. As the CR continues to rise, the tendency for an increase in TKE diminishes, while the turbulent dissipation rate consistently rises. Additionally, there is an escalation in heat transfer loss. Therefore, there is a trend of rising and then falling in the flow velocity and turbulence intensity with the increase of the CR. Ammonia-hydrogen flame propagation is susceptible to temperature and flow field, and a high CR can improve ignition stability, shorten combustion duration, minimize cooling loss, and enhance output power. Unfortunately, the emission of NOx gradually rises as the CR increases. At high CR, the combustion performance is optimized by adjusting ST, and the maximum IMEP and ITE are 4 bar and 38.3 %, respectively. The ST for maximum braking torque (MBT) should be gradually delayed toward TDC as the CR increases. • As the compression ratio increases, the flow velocity first rises and then decreases. • The turbulent dissipation rate increases with increasing compression ratio. • A high compression ratio improves ignition stability and combustion velocity. • The NOx gradually increases with the increase of the compression ratio. • A high compression ratio improves the power and economy of NH3-H2 engines. [ABSTRACT FROM AUTHOR]

Ammonia and hydrogen are two carbon-free alternative fuels for engines. Considering that there are few studies on improving an ammonia-hydrogen engine's lean combustion performance, this investigation based on an engine with the Miller cycle employs hydrogen direct injection (HDI) and NH 3 port injection and then proposes an adjustment strategy to vary the start of injection (SOI) of HDI for affecting the engine combustion process. When ammonia volume share (AVS) is greater than 50%, the engine shows poor performance. Nevertheless, the stratification effect of hydrogen jets may be used to elevate the hydrogen concentration around spark plug by properly delaying SOI and then creating the locally rich mixture with a high hydrogen share, which prominently promotes the flame kernel formation, shortens CA0-90, reduces C o V P m a x , and enables the engine to reach approximately 36% BTE. It is notable that very late SOI can slightly deteriorate the heat release process and lower engine performance. • Ammonia-hydrogen engines have poor combustion process under lean conditions. • A strategy to improve the lean combustion performance of the engine is proposed. • Effects of NH 3 –H 2 premixing and H 2 stratification effect on the engine are balanced. • Properly delaying SOI enhances the ignition and combustion process of the engine. [ABSTRACT FROM AUTHOR]

• Combustion characteristics of NH 3 /H 2 /air with SI and TJI methods were compared. • Effect of fuel composition and equivalence ratio was evaluated under TJI conditions. • Different ignition mechanisms of NH 3 /H 2 /air were found. • Effect of orifice number on ignition and combustion characteristics was evaluated. The mixture of ammonia (NH 3) and hydrogen (H 2) is the potential alternative fuel for internal combustion engines (ICEs). The turbulent jet ignition (TJI) system can provide high ignition energy and turbulent disturbance to promote the combustion of the mixture for NH 3 /H 2 ICEs. Therefore, the combustion characteristics of NH 3 /H 2 /air under passive TJI conditions were experimentally studied in the present study. The experiment was conducted in a constant volume combustion bomb, and the effect of fuel composition and equivalence ratio was investigated. The experimental results show that compared to spark ignition, the combustion of NH 3 /H 2 can be effectively improved by using TJI, especially under high NH 3 fraction conditions. The addition of H 2 has a significant positive effect on the ignition and combustion performance. With the addition of H 2 , the ignition delay and combustion duration decrease evidently. And the H 2 addition is beneficial for improving the ignition mechanism and achieving flame ignition. In addition, poor ignition performance may occur under rich conditions due to the fluid-dynamic quenching of the jet. However, the high flame propagation rate on the rich side still leads to lower combustion duration. Moreover, increasing the orifices number appropriately can enhance the ignition and combustion performance. The jet strength is weakened by the increased total orifice area and the ignition of NH 3 /H 2 can be improved. [ABSTRACT FROM AUTHOR]

Hydrogen internal combustion engines (ICE) will play an important role in reducing carbon emissions, but low power density and abnormal combustion problems are the main obstacles restricting the promotion of hydrogen ICE. Ammonia is a low-reactivity renewable fuel. The purpose of this study is to study the effect of different ammonia-added volume fractions on hydrogen ICE. In this experimental study, the combustion and emission characteristics of an engine fueled by a hydrogen/ammonia mixture were evaluated at part-load operating conditions. The experiment was carried out on a modified engine, the engine speed was 1300 rpm, the absolute pressure of the manifold was 61 kPa, and the volume fraction of ammonia added was 5.2%, 7.96%, and 10.68%, respectively. The test results show that the addition of ammonia changes the combustion characteristics of hydrogen. As the volume fraction of ammonia added increases, the flame development period and flame propagation period are both prolonged, and the peak heat release rate decreases. The addition of ammonia increases the power of the engine and reduces the indicated thermal efficiency. At the ignition timing of the maximum braking torque, as the volume fraction of ammonia added increases, the indicated mean effective pressure and indicated thermal efficiency increase. Adding ammonia volume fraction has little effect on Nitrogen oxides (NOx) emissions, and NOx emissions gradually increase with the delay of ignition timing. • Study the effect of ammonia addition on hydrogen-fueled engines. • The addition of ammonia improves the IMEP of hydrogen-fueled engines. • The addition of ammonia reduces the heat release rate of hydrogen-fueled engines. • Ammonia addition fraction has less effect on NOx emission. [ABSTRACT FROM AUTHOR]

Hydrogen (H 2) is a carbon-free fuel with many excellent combustion characteristics, but abnormal combustion is one of the main obstacles to the promotion and application of hydrogen-fueled engines. This experimental study aims to investigate the suppression of the heat release rate (HRR) of a hydrogen-fueled engine through the addition of ammonia (NH 3). The engine was run at 1300 rpm, with manifold absolute pressure (MAP) of 61 kPa and NH 3 addition ratio of 0% and 2.2%, under lean-burn conditions. The results showed that the addition of small amounts of ammonia reduced the combustion rate of the fuel mixture, prolonged the flame development period (CA0-10) and propagation durations (CA10-90) of the engine, and reduced the peak in-cylinder pressure and peak HRR under lean-burn conditions. The addition of ammonia increased the peak indicated mean effective pressure (IMEP) and the peak indicated thermal efficiency (ITE) of the engine. The addition of ammonia resulted in increased nitrogen oxides (NOx) emissions. • The effect of ignition timing of an H 2 /NH 3 dual-injection engine was studied. • Reduces the peak heat release rate after ammonia was added. • CA0-10 and CA10-90 were extended after ammonia was added. • The peak IMEP and ITE were increased after ammonia was added. [ABSTRACT FROM AUTHOR]

The development of alternative fuels is important in the fight against climate change. Both hydrogen and ammonia are renewable energy sources and are carbon-free combustible fuels. In a recent experimental study, the performance and emission characteristics of a spark-ignition engine burning a premixed hydrogen/ammonia/air mixture were evaluated. The manifold absolute pressure was adjusted to 61 kPa and the engine speed was stabilized at 1300 rpm. The difference between a mixture with a 2.2% volume fraction of ammonia and a pure hydrogen fuel was analyzed in comparison. Specifically, the addition of ammonia increased the ignition delay and flame development periods and reduced the rate of in-cylinder pressure rise. In conjunction with the ignition timing strategy, the addition of ammonia did not affect the engine performance. Nitrogen oxides emissions are increased due to the addition of ammonia. The experimental results suggest that ammonia can be used as a combustion inhibitor, which provides a new reference for the development of hydrogen-fuelled engines. • The effect of ammonia addition on hydrogen-fueled engines was studied. • Direct injection and port injection were used for H 2 and NH 3 respectively. • Reduces the rate of pressure rise after ammonia was added. • The addition of ammonia has little effect on peak IMEP and ITE. [ABSTRACT FROM AUTHOR]

[Display omitted] • Optimized injection strategies affect CA0-90 by varying NH 3 -H 2 premixing degree. • Multiple injection mode is more suitable for an ammonia-hydrogen dual-fuel engine. • Oxygen enrichment strategy improves the flame kernel formation and cyclic variation. • Oxygen-enriched levels of about 34.3% can elevate BMEP by more than 42%. • A hypothesis is proposed for the use of NH 3 -H 2 engines in hybrid power systems. Ammonia with low reactivity still faces some challenges as the main fuel for engines. Hydrogen and oxygen, as two combustion improvers, are expected to solve ammonia's reluctance to combust. To date, the application of oxygen enrichment strategies in ammonia-hydrogen dual-fuel engines is very rare, which motivates this study. The main objective of this investigation is to explore optimal hydrogen injection strategies and evaluate the effectiveness of oxygen enrichment strategies for the engine. Optimizing hydrogen injection parameters can vary the ammonia-hydrogen premixing degree, thus improving the flame kernel formation and flame propagation velocity. This is supported by the shortened CA0-90, lowered cyclic variation, and elevated thermal efficiency and power. Oxygen-enriched strategies enhance the heat release process and mitigate the negative effects of ammonia on the ignition process, which reduces cyclic variation and prominently increases power. However, the elevated oxygen concentration may increase the adiabatic flame temperature of the mixture and thus heat transfer loss, which decreases brake thermal efficiency. Moreover, a hypothesis that an ammonia-hydrogen engine may be employed in a hybrid power system in the future is proposed. The results of this work can be used as raw data for developing a hybrid power system. [ABSTRACT FROM AUTHOR]

Recently, ammonia is considered to be an energy medium for hydrogen or energy storage and ammonia/hydrogen can be a potential fuel blend for the spark-ignition engine. Nevertheless, the combustion properties of ammonia/hydrogen mixtures could be distinctive under different initial conditions. In this study, several essential combustion properties, including laminar burning velocity, minimum ignition energy, NOx and ammonia emissions, combustion efficiency, and mixture heating values of ammonia/hydrogen/air premixed combustion were extensively studied under a wide range of equivalence ratios (ϕ), hydrogen fractions (α) and different compression ratio using one-dimensional laminar planar flame and compared with stoichiometric methane, methanol, and ethanol combustion. The behavior of NOx generation changing with ϕ and α was analyzed in detail. Results showed that most properties of ammonia/hydrogen combustion could be comparable to that of hydrocarbon fuels under engine-relevant conditions, except for the mixture heating value is slightly lower in all conditions. Besides, the NO mole fraction non-monotonically changes with ϕ and α due to the competition between the effects caused by the reduction of nitrogen-atom species and the enrichment of H/O radicals. The NO mole fraction of stoichiometric ammonia/hydrogen could be even lower than that of hydrocarbons. Considering the properties of hydrocarbon fuels as a reference, promising working conditions for ammonia/hydrogen mixtures are ϕ from 1.0 to 1.05 and α from 40% to 60%. Besides, a high compression ratio is more suitable for ammonia/hydrogen mixtures due to the excellent knock resistance ability of NH 3 /H 2 and better improvement than hydrocarbon fuels under high compression ratio. • Combustion properties of premixed NH 3 /H 2 /air were assessed under engine conditions. • One dimensional steady flame was simulated under different initial conditions. • NOx generation of NH 3 /H 2 /air combustion is analyzed in detail. • Most combustion properties, including NOx are comparable to light hydrocarbon fuels. • Potential working conditions are suggested based on the analysis. [ABSTRACT FROM AUTHOR]

[Display omitted] • Consider using rich-burn strategy to control the performance of an ammonia-hydrogen engine. • The rich burn strategy can reduce NOx of ammonia-hydrogen internal combustion engine. • The rich burn strategy can increase the exhaust temperature of the ammonia-hydrogen engine. In order to achieve climate goals as soon as possible, it is necessary to reshape the energy mix to replace fossil energy with carbon–neutral fuels as soon as possible. Ammonia is a good medium for energy storage, has a large industrial scale and a well-developed infrastructure. To address the problems of NOx emission and low exhaust energy of ammonia-hydrogen engines, this study proposes a rich burn strategy. Firstly, a commercial spark ignition (SI) internal combustion engine (ICE) was modified to achieve a dual fuel supply of ammonia and hydrogen. The engine was run at a steady state of 1500 rpm with the intake manifold absolute pressure (MAP) maintained at 60 kPa, and the ammonia and hydrogen supplies were adjusted to achieve different mixing ratios and excess air ratios. The experimental results showed that the rich burn strategy could significantly reduce the NOx emission and increase the exhaust temperature of the ammonia-hydrogen engine when the excess air coefficient was below 0.8. The rich burn strategy can appropriately increase the engine power output, but it has some influence on the brake thermal efficiency (BTE). [ABSTRACT FROM AUTHOR]

[Display omitted] • Proposed VVT as a method of load regulation for ammonia-hydrogen engines. • Comparing the load control effects of MAP, α NH 3 , λ and VVT. • Proposed load control strategy for ammonia-hydrogen hybrid system. The development of hybrid technology and the use of zero-carbon fuels are effective means to improve energy efficiency and reduce carbon emissions. In this study, the Miller cycle spark ignition engine was used, and four load control strategies of throttle, ammonia-hydrogen ratio, air–fuel ratio, and variable valve timing were used to conduct experimental research on the ammonia-hydrogen engine. The experimental results show that the throttle strategy provides the widest output range, and the BMEP is raised from a minimum of 1 bar to 7.4 bar. The ammonia-hydrogen mixing ratio strategy is suitable for cold start conditions, fully utilizing the good combustion characteristics of hydrogen, and at the same time reducing the amount of hydrogen used in the heat engine process as much as possible. The air–fuel ratio strategy provides the highest thermal efficiency with a maximum BTE approaching 40%. It satisfies the energy-saving demand under the single-point working condition of the engine in the series mode. The variable valve timing strategy can realize switching between BMEP between 3.5 bar and 6.5 bar, and keep BTE above 33%. The valve timing strategy can not only provide a wider load adjustment range but also maintain high thermal efficiency. Finally, combining the effects of the four control strategies and the typical operating modes of the hybrid system, this study suggests that the throttle strategy is suitable for the feed mode, the VVT strategy is suitable for the parallel mode, the ammonia-hydrogen mixture ratio strategy is suitable for the cold start condition, and the air–fuel ratio control is suitable for the series mode. [ABSTRACT FROM AUTHOR]

Hydrogen and ammonia, as two renewable carbon-free combustibles, are considered to be potentially excellent alternative fuels for internal combustion engines. Since hydrogen and ammonia have opposite and complementary combustion characteristics, the co-combustion of ammonia with hydrogen is reasonable. However, there are few detailed experimental studies of load control strategies for an ammonia‑hydrogen engine. In this study, four load control strategies including the variation of ammonia volume share (AVS), qualitative control, quantitative control, and adjustment of intake variable valve timing (VVT) are proposed and assessed for their applicability in an ammonia/hydrogen dual-fuel engine. The ignition and combustion characteristics of ammonia do not allow for high thermal efficiency, so the Miller cycle is introduced to improve engine performance. The engine employs fuel supply modes of ammonia port injection and hydrogen direct injection at 1500 rpm. In general, the engine achieves higher brake mean effective pressure (BMEP) and brake thermal efficiency (BTE) at different AVS. Moreover, qualitative control and adjustment of intake VVT allow the engine to own a wide regulation range of BMEP and maintain the BTE of more than 37% under most conditions. However, quantitative control appears to be an inadequate strategy for the engine due to the lower BMEP and BTE. • The co-combustion of ammonia with hydrogen and hydrogen direct injection are crucial. • Four load control strategies are proposed for an ammonia/hydrogen dual-fuel engine. • Technologies of the Miller cycle and variable valve timing are used in the engine. • Higher cyclic variation should be avoided when using various load control strategies. [ABSTRACT FROM AUTHOR]

• The effect of intake valve timing on hydrogen-rich ammonia engines was studied. • Delaying the valve timing to increase the power of hydrogen-rich ammonia engines. • Advanced valve timing to improve BTE of hydrogen-rich ammonia engine. • Increasing valve overlap increases the cycle variation of hydrogen-rich ammonia engines. To reduce carbon emissions and increase the efficiency of internal combustion engines (ICEs), it is necessary to use renewable alternative fuels and to use Miller cycle technology. Ammonia is an energy storage medium as well as a hydrogen storage medium. In this experiment, a Miller cycle ICE using ammonia-hydrogen fuel was investigated at 1500 rpm and 60% throttle opening. The excess air factor of 1 and the ammonia volume share of 70% were maintained during the experiment. The objective of the experiment was to vary the intake valve timing and investigate its effect on engine performance. The results show that when the intake valve timing is advanced and the valve overlap angle is kept larger, the combustion stability deteriorates, the flame development period (CA0-10) is prolonged, the cycle variation increases, COV pmax will exceed 25%, and the brake thermal efficiency (BTE) quickly dropped from 32.8% to 30%. When the intake valve timing is retarded by 25°CA, IMEP and BMEP can be increased by 8% and 16% compared with the minimum values. Generally speaking, the Miller cycle hydrogen-enriched ammonia engine is not suitable for the early opening strategy of the intake valve. [ABSTRACT FROM AUTHOR]

[Display omitted] • Ammonia-hydrogen fuel used in miller cycle internal combustion engine. • The stoichiometric and lean-burn conditions of the ammonia-hydrogen engine were compared. • For Miller Cycle ammonia engines, about 20% of hydrogen is required. • Expanded ammonia energy ratio can improve engine BMEP and ITE. Reducing carbon emissions in the transport sector requires technology upgrades to engines and the use of carbon–neutral fuels. Ammonia is a zero-carbon renewable fuel that complements hydrogen. This study is based on a Miller cycle spark ignition engine using ammonia-hydrogen fuel. The effects of the mixture ratio of ammonia and hydrogen under stoichiometric ratio and lean burn condition on the performance of the Miller cycle engine are focused. First, a commercial Miller-cycle ICE was modified to allow a dual fuel supply of ammonia and hydrogen. The engine was run steadily at 1500 rpm with the manifold absolute pressure (MAP) maintained at 60 kPa, and the ammonia and hydrogen supplies were adjusted to achieve different mixing ratios and excess air ratios. The test results showed that an increased ammonia percentage under stoichiometric ratio conditions significantly improved the Braking mean effective pressure (BMEP) and Braking thermal efficiency (BTE) of the ICE. Under lean burn conditions, the changes of BMEP and BTE are small with the increase of the ammonia ratio. The exhaust temperature of the ammonia-hydrogen engine is relatively low, so it is necessary to consider matching a small inertia turbocharger. Ammonia ratios above 80 % by volume resulted in erratic engine operation and even misfires. Ammonia-hydrogen fuel blends lead to higher Nitrogen oxide (NOx) emissions. [ABSTRACT FROM AUTHOR]

Ammonia is considered as a carbon-free alternative fuel and hydrogen carrier to realize green and renewable energy conversion, but the oxidation mechanism of NH 3 still needs to be improved and validated by more experimental data. In this study, the laminar burning velocity (LBV) was measured in a constant volume vessel at various equivalence ratios, initial temperatures, and oxygen fractions up to undiluted condition. Thirteen latest NH 3 kinetics mechanisms were collected and compared with each other and the experiments. Results showed that large discrepancies of predictions presented between different mechanisms. The maximum LBV of undiluted NH 3 /O 2 mixtures could reach 125.05 cm/s. The maximum predicted LBV of NH 3 /O 2 is nearly two times higher than the minimum one for NH 3 /O 2 mixtures. The reduced Okafor (2019) and Zhang (2017) mechanism gave the best agreement with experiments for lean and rich mixtures, respectively. Sensitivity analysis of rate constant, species thermal, and transport parameters were adopted to identify the critical reactions and species in the premixed flame. It was found that because of the coupled nature of the properties mentioned above in the premixed flame, the species involved in the essential reactions also exhibit substantial thermal and transport sensitivities. [ABSTRACT FROM AUTHOR]