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International audience; While the Ariel mission is primarily designed for the study of warm and hot objects, with an equilibrium temperature above 500 K, in this paper we want to explore a larger sample of possible colder targets. We thus investigate the detectability with Ariel of “temperate” exoplanets (with an equilibrium temperature of 400 K). We first consider the case of hydrogen-rich exoplanets (from Jupiters to sub-Neptunes) and we calculate their infrared transmission spectrum for several classes of stars. We consider the Tier 2 mode of Ariel, for which the resolving power (R = 50 for l < 4 mm and R=15 for l > 4 mm) is sufficient to get information about the chemical composition of the objects. Results show that temperate Jupiters and sub-Neptunes around all types of stars from G2 to M8, with revolution periods of a few tens of days and transit durations of a few hours, could be observed with Ariel, up to distances of about 50 pc for Jupiters and 25 pc for sub-Neptunes. In the case of temperate super-Earths, we estimate that they will not be observable in the Ariel Tier 2 mode. In a study of currently available target candidates, we find one sub-Neptune (TOI-178 g) as possibly observable in Ariel’s Tier 2. This study, a follow-up of “Transit spectroscopy of temperate Jupiters with ARIEL: A feasibility study” (Encrenaz et al., Exp. Astr. 46:31-44, 2018), is submitted to the ARIEL special issue of Experimental Astronomy (manuscript under revision)

Massive and water-rich planets should be ubiquitous in the universe. Many of those worlds are expected to be subject to important irradiation from their host star, and display supercritical water layers surrounded by extended steam atmospheres. Irradiated ocean planets with such inflated hydrospheres have been recently shown to be good candidates for matching the mass-radius distribution of sub-Neptunes. Here we describe a model that computes a realistic structure for water-rich planets by combining an interior model with an updated equation of state (EoS) for water, and an atmospheric model that takes into account radiative transfer. We find that the use of non appropriate EoSs can lead to the overestimation of the planetary radius by up to $\sim$10\%, depending on the planet size and composition. Our model has been applied to the GJ 9827 system as a test case and indicates Earth- or Venus-like interiors for planets b and c, respectively. Planet d could be an irradiated ocean planet with a water mass fraction of $\sim$$20\pm10\%$. We also provide fits for the mass-radius relationships, allowing one to directly retrieve a wide range of planetary compositions, without the requirement to run the model. Our calculations finally suggest that highly irradiated planets lost their H/He content through atmospheric loss processes, and that the leftover material led to either super-Earths or sub-Neptunes, depending on the water mass fraction., Accepted for publication in ApJ

Context. Sulphur dioxide (SO2) is highly variable above the clouds of Venus, yet no spatial or temporal variability below the clouds had been known until now. Aims. In order to constrain Venus’s atmospheric circulation and chemistry (including possible volcanic outgassing), more accurate SO2 measurements below the clouds are therefore needed. Methods. We used the high-resolution iSHELL spectrometer located at the NASA IRTF to record thermal night-side spectra, which we fitted using an updated forward radiative transfer model that was previously employed to process SpeX/IRTF and VIRTIS-H/Venus Express spectra. Results. We report, for the first time, an increase in SO2 with increasing latitude (+30% between the minimum near 15°S and > 35°N). This is consistent with the interaction between the Hadley-cell circulation and a postulated vertical profile in SO2 estimated to increase between 30 and 40 km in altitude, as previously suggested by in situ ISAV measurements. Conclusions. This SO2 variability challenges our current understanding of Venus’s tropospheric thermochemistry and underlines the high scientific return from high-resolution spectroscopy from, for example, future orbiters.

International audience; Ultraviolet spectral imaging has been a powerful tool to investigate the cloud top of Venus, allowing for measurement of several minor gases (especially SO2, SO, O3), of cloud top aerosol’s microphysical properties and of atmospheric dynamics through tracking of the unevenly distributed UV absorber. After a brief review of recent UV instruments that orbited around Venus, we present the results of a state-of-the-art radiative transfer model from Marcq et al. (2020) to derive the spectral resolution and Signal-to-Noise ratio (SNR) required to derive abundances of these gases, retrieve optical properties of the aerosols beyond our current knowledge. This leads us to propose a two-channel UV hyperspectral push-broom imager called VeSUV (standing for Venusian Spectroscopy in UV) whose technical characteristics will improve on existing measurements by a factor of at least 2, and which is well suited to the integration into the payload of future low Venus orbit platforms such as the proposed EnVision mission to ESA M5 call.

Understanding Venus will benefit from a dedicated effort through an international program of missions that are coordinated and offering opportunities for coooperation. The recent discovery of phosphene in the Venus clouds and possibility of life will increase the exploration missions and cooperation and coordination will be very benefical.

International audience; The nighttime ozone and sulfur dioxide distributions were analyzed using the entire SPICAV‐UV/Venus Express stellar occultation dataset. After the discovery of an ozone layer at 100 km in the mesosphere reported by Montmessin et al. (2011), 132 other detections were made during the entire 8 years long observing period of the SPICAV UV instrument. In the rare detections the peak abundances of O3 accumulating in the mesosphere are observed with densities from 107 to 108 molecules⋅cm‐3 at 85‐110 km. The ozone layer is estimated to vary from 1 ppbv to 30 ppbv at 85‐95 km while at 95‐105 km the VMR is expected within an interval from 6 ppbv to 120 ppbv. Below 93 km, a puzzling decrease of mixing ratio is observed toward midnight at 30°N. Our work also provides an improved sequel to the analysis of the sulfur dioxide survey previously made in the upper mesosphere by Belyaev et al. (2017). On average, the SO2 content is found to remain constant throughout the vertical profile at a value of around 135±21 ppbv between 85 and 100 km. Rapid and large variations prevent to conclude firmly on any time or space pattern of SO2.

We present an atmospheric characterization study of two medium sized planets bracketing the radius of Neptune: HD 106315 c (R$_{\rm{P}}$=4.98 $\pm$ 0.23 R$_{\oplus}$) and HD 3167 c (R$_{\rm{P}}$=2.740$_{-0.100}^{+0.106}$ R$_{\oplus}$). We analyse spatially scanned spectroscopic observations obtained with the G141 grism (1.125 - 1.650 $\mu$m) of the Wide Field Camera 3 (WFC3) onboard the Hubble Space Telescope. We use the publicly available Iraclis pipeline and TauREx3 atmospheric retrieval code and we detect water vapor in the atmosphere of both planets with an abundance of $\log_{10}[\mathrm{H_2O}]=-2.1^{+0.7}_{-1.3}$ ($\sim$5.68$\sigma$) and $\log_{10}[\mathrm{H_2O}]=-4.1^{+0.9}_{-0.9}$ ($\sim$3.17$\sigma$) for HD 106315 c and HD 3167 c, respectively. The transmission spectrum of HD 106315 c shows also a possible evidence of ammonia absorption ($\log_{10}[\mathrm {NH_3}]=-4.3^{+0.7}_{-2.0}$, $\sim$1.97$\sigma$ -even if it is not significant-), whilst carbon dioxide absorption features may be present in the atmosphere of HD 3167 c in the $\sim$1.1-1.6~$\mu$m wavelength range ($\log_{10}[\mathrm{CO_{2}}]= -2.4^{+0.7}_{-1.0}$, $\sim$3.28$\sigma$). However the CO$_2$ detection appears significant, it must be considered carefully and put into perspective. Indeed, CO$_2$ presence is not explained by 1D equilibrium chemistry models, and it could be due to possible systematics. The additional contribution of clouds, CO and CH$_4$ are discussed. HD 106315 c and HD 3167 c will be interesting targets for upcoming telescopes such as the James Webb Space Telescope (JWST) and the Atmospheric Remote-Sensing Infrared Exoplanet Large-Survey (Ariel)., Comment: Accepted for publication in AJ

Context. LHS 1140 is an M dwarf known to host two transiting planets at orbital periods of 3.77 and 24.7 days. They were detected with HARPS and Spitzer. The external planet (LHS 1140 b) is a rocky super-Earth that is located in the middle of the habitable zone of this low-mass star. All these properties place this system at the forefront of the habitable exoplanet exploration, and it therefore constitutes a relevant case for further astrobiological studies, including atmospheric observations. Aims. We further characterize this system by improving the physical and orbital properties of the known planets, search for additional planetary-mass components in the system, and explore the possibility of co-orbitals. Methods. We collected 113 new high-precision radial velocity observations with ESPRESSO over a 1.5-yr time span with an average photon-noise precision of 1.07 m s-1. We performed an extensive analysis of the HARPS and ESPRESSO datasets and also analyzed them together with the new TESS photometry. We analyzed the Bayesian evidence of several models with different numbers of planets and orbital configurations. Results. We significantly improve our knowledge of the properties of the known planets LHS 1140 b (Pb ∼ 24.7 days) and LHS 1140 c (Pc ∼ 3.77 days). We determine new masses with a precision of 6% for LHS 1140 b (6.48 ± 0.46 Mpdbl) and 9% for LHS 1140 c (mc = 1.78 ± 0.17 Mpdbl). This reduces the uncertainties relative to previously published values by half. Although both planets have Earth-like bulk compositions, the internal structure analysis suggests that LHS 1140 b might be iron-enriched and LHS 1140 c might be a true Earth twin. In both cases, the water content is compatible to a maximum fraction of 10-12% in mass, which is equivalent to a deep ocean layer of 779 ± 650 km for the habitable-zone planet LHS 1140 b. Our results also provide evidence for a new planet candidate in the system (md = 4.8 ± 1.1Mpdbl) on a 78.9-day orbital period, which is detected through three independent methods. The analysis also allows us to discard other planets above 0.5 Mpdbl for periods shorter than 10 days and above 2 Mpdbl for periods up to one year. Finally, our co-orbital analysis discards co-orbital planets in the tadpole and horseshoe configurations of LHS 1140 b down to 1 Mpdbl with a 95% confidence level (twice better than with the previous HARPS dataset). Indications for a possible co-orbital signal in LHS 1140 c are detected in both radial velocity (alternatively explained by a high eccentricity) and photometric data (alternatively explained by systematics), however. Conclusions. The new precise measurements of the planet properties of the two transiting planets in LHS 1140 as well as the detection of the planet candidate LHS 1140 d make this system a key target for atmospheric studies of rocky worlds at different stellar irradiations., With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737)

Small planets ($\sim$1--3.9 $\Rearth$) constitute more than half of the inventory of the 4000-plus exoplanets discovered so far. Smaller planets are sufficiently dense to be rocky, but those with radii larger than $\sim$1.6 $\Rearth$ are thought to display in many cases hydrogen/helium gaseous envelopes up to $\sim$30\% of the planetary mass. These low-mass planets are highly irradiated and the question of their origin, evolution, and possible links remains open. Here we show that close-in ocean planets affected by greenhouse effect display hydrospheres in supercritical state, which generate inflated atmospheres without invoking the presence of large hydrogen/helium gaseous envelopes. We present a new set of mass-radius relationships for ocean planets with different compositions and different equilibrium temperatures, which are found to be well adapted to low-density sub-Neptune planets. Our model suggests that super-Earths and water-rich sub-Neptunes could belong to the same family of planets, i.e. hydrogen/helium-free planets, with differences between their interiors simply resulting from the variation in the water content., Accepted for publication in The Astrophysical Journal Letters

Since January 2012, we have been monitoring the behavior of sulfur dioxide and water on Venus, using the Texas Echelon Cross-Echelle Spectrograph imaging spectrometer at the NASA InfraRed Telescope Facility (IRTF, Mauna Kea Observatory). Here, we present new data recorded in February and April 2019 in the 1345 cm−1(7.4μm) spectral range, where SO2, CO2, and HDO (used as a proxy for H2O) transitions were observed. The cloud top of Venus was probed at an altitude of about 64 km. As in our previous studies, the volume mixing ratio (vmr) of SO2was estimated using the SO2/CO2line depth ratio of weak transitions; the H2O volume mixing ratio was derived from the HDO/CO2line depth ratio, assuming a D/H ratio of 200 times the Vienna standard mean ocean water. As reported in our previous analyses, the SO2mixing ratio shows strong variations with time and also over the disk, showing evidence for the formation of SO2plumes with a lifetime of a few hours; in contrast, the H2O abundance is remarkably uniform over the disk and shows moderate variations as a function of time. We have used the 2019 data in addition to our previous dataset to study the long-term variations of SO2and H2O. The data reveal a long-term anti-correlation with a correlation coefficient of −0.80; this coefficient becomes −0.90 if the analysis is restricted to the 2014–2019 time period. The statistical analysis of the SO2plumes as a function of local time confirms our previous result with a minimum around 10:00 and two maxima near the terminators. The dependence of the SO2vmr with respect to local time shows a higher abundance at the evening terminator with respect to the morning. The dependence of the SO2vmr with respect to longitude exhibits a broad maximum at 120–200° east longitudes, near the region of Aphrodite Terra. However, this trend has not been observed by other measurements and has yet to be confirmed.

International audience; Large planetesimals and planetary embryos ranging from several hundred to a few thousand kilometers can develop magma oceans through mutual collisions, gravitational energy, and the heating of short-lived radioactive elements. During their solidification after the dissipation of the disk a steam atmosphere will be catastrophically outgassed and may be lost efficiently via hydrodynamic escape, as long as it does not condense. The escaping H-atoms that originate from the dissociation of H2O and H2 will drag heavier trace elements like noble gases such as Ne and Ar and outgassed moderately volatile rock-forming elements such as K, Na, Si, Mg, etc. into space. Under consideration of various EUV flux evolution scenarios of young solar-type stars, we apply an upper atmosphere hydrodynamic escape model that includes the dragging of heavier species by escaping H-atoms. We investigate the atmospheric/elemental escape and fractionation from planetary embryos with masses of 1 MMoon, 0.5 MMars, 1 MMars, and 1.5 MMars at different orbital distances between the orbits of Venus and Mars. Our results indicate that the steam atmospheres and the embedded trace elements will be lost efficiently before they condense for masses ≤0.5 MMars and orbital distances up to 1 AU. For heavier embryos of up to 1.5 MMars almost all of the considered steam atmospheres can be lost within ≈12 Myr, which lies within the time frame of the formation of the first Martian protocrust after ≈20 Myr, i.e. for such steam atmospheres to be lost completely a shallow magma ocean must remain below the atmosphere, which might be achieved through frequent impacts onto the planetary embryo. The considered outgassed noble gases and rock-forming elements will be completely dragged away together with the steam atmospheres under the assumption that the trace elements will reach the thermosphere. For embryos with masses ≤MMoon the gravity is too weak for a dense atmosphere to build up for the high magma ocean related surface temperatures and all outgassed elements will escape immediately to space. For all considered planetary masses and orbits the loss rates of Ar and Ne are so high that there will be no fractionation of their isotopes. The studied planetary embryos, even though not isotopically fractionated, will therefore be severely depleted in noble gases and moderately volatile elements. Hydrodynamic escape might then also affect the final composition of terrestrial planets that accrete out of such planetary embryos, such as the volatile content and the Fe/Mg ratio of a planet.

International audience; Hubble Space Telescope Imaging Spectrograph (HST/STIS) observations were obtained on 3 dates in December 2010 and January 2011 recording the cloud top properties over Aphrodite Terra and a low elevation region downwind of Aphrodite through LSTs extending from 7 to 11 a.m. From these data we trace the cloud top sulfur-oxide chemistry and UV albedo sensitivity to LST, latitude and topography. Above regions co-located in LST and latitude, albedo variations observed at 245 nm parallel those observed at 365 nm-following the pattern expected from Hadley cell circulation. However, darkening of the cloud top albedo at LSTs between 9.5 and 11 h beyond that expected from simple Hadley circulation was also observed. Above the plains the albedo darkening intensified rapidly with LST and was observed at latitudes extending as high as ~30 N; however, above the mountains the darkening was either entirely absent or evident only at 0 N at an intensity 2× lower than that observed over the plains. Because the observed 245 nm albedo LST variations were inconsistent with that expected from multiple scattering of the coincidently retrieved SO2 gas abundance, we conclude that the 245 nm albedo is diagnostic of the vertical and spatial distribution, abundance (and potentially the identity) of Venus' unidentified UV absorber—rather than SO2 gas. The LST albedo trends are best explained by the onset of subsolar convective activity that intensifies with LST expanding vertically from the boundary between the middle and upper clouds to the cloud tops and increasing the detectability of the unknown absorbing species at the cloud tops. The terrain dependence in the observed intensity implies the time at which the expansion reaches the cloud tops is later above the mountains than over the plains. Additionally, at the time of observation, the low-latitude large-scale vertical mixing rates that control the latitudinal gradients of the SO2 and unknown absorber abundances above and within the cloud top region were lower over Aphrodite Terra than the plains, to the extent that photochemical processing destroyed the spatial correlation between those absorbing species. These observations show the power of UV spectroscopy to diagnose the distinct influences of deep (Hadley-cell type) and shallow convective mixing processes on the vertical and horizontal distribution of Venus' unknown absorbing species, and the sensitivity of these processes to LST and topography, relative to the sulfur oxide chemistry. These results are essential for accurate climate modeling—and when compared to recent Venus missions motivate a need for additional follow-on observing campaigns that simultaneously trace key cloud top chemistry and dynamic processes including the LST dependent evolution of planetary scale gravity waves (GWs). With the inevitable aging of the Hubble Telescope, follow-on observations providing temporally coincident traces of the cloud top albedo, sulfur-oxide chemistry and GW features will require a new age of space-based telescopes and Venus orbiting mission with sensitivity to UV, visible and IR wavelengths.

Following the announcement of the detection of phosphine (PH$_3$) in the cloud deck of Venus at millimeter wavelengths, we have searched for other possible signatures of this molecule in the infrared range. Since 2012, we have been observing Venus in the thermal infrared at various wavelengths to monitor the behavior of SO$_2$ and H$_2$O at the cloud top. We have identified a spectral interval recorded in March 2015 around 950 cm$^{-1}$ where a PH$_3$ transition is present. From the absence of any feature at this frequency, we derive, on the disk-integrated spectrum, a 3-$\sigma$ upper limit of 5 ppbv for the PH$_3$ mixing ratio, assumed to be constant throughout the atmosphere. This limit is 4 times lower than the disk-integrated mixing ratio derived at millimeter wavelengths. Our result brings a strong constraint on the maximum PH$_3$ abundance at the cloud top and in the lower mesosphere of Venus., Comment: Astronomy & Astrophysics, in press

International audience; Following our previous work (Marcq et al., 2013, Marcq et al., 2011), we have updated our forward radiative transfer code and processed the whole SPICAV-UV/Venus Express nadir dataset (2006-2014) in order to retrieve SO2 abundance at cloud top – assuming a SO2 decreasing scale height of 3 km and a ratio SO/SO2 tied to 10% – as well as the imaginary index of scattering mode 1 particles, representative of the remaining UV absorption, since the OSSO vertical profile found by Frandsen et al. (2016) cannot account for our observations. Our main results mostly confirm and extend the validity of those discussed by Marcq et al. (2013), namely: (i) long-term variations of low latitude SO2 at 70 km between ∼ 100 ppbv (2007, 2009) and less than 10 ppbv (2014); (ii) in average, decreasing SO2 with increasing latitude and depletion near the sub-solar point, consistent with a competition between advection and photo-chemical destruction; (iii) secular increase of mode 1 imaginary index at 250 nm, from 10−2 to 5 ⋅ 10−2 between 2006 and 2010; (iv) if not related instead to long-term variability, a possible localized enrichment of SO2 and UV brightness increase above the western slopes of Aphrodite Terra, consistent with Bertaux et al. (2016) supply mechanism through orographic gravity waves. This spatial and temporal variability underlines the need for a long term monitoring of Venus SO2 and cloud top from ground-based facilities until the next generation of Venusian orbiters is operational.

How the volatile content influences the primordial surface conditions of terrestrial planets and, thus, their future geodynamic evolution is an important question to answer. We simulate the secular convective cooling of a 1-D magma ocean (MO) in interaction with its outgassed atmosphere. The heat transfer in the atmosphere is computed either using the grey approximation or using a k-correlated method. We vary the initial CO2 and H2O contents (respectively from 0.1 × 10−2 to 14 × 10−2 wt % and from 0.03 to 1.4 times the Earth Ocean current mass) and the solar distance—from 0.63 to 1.30 AU. A first rapid cooling stage, where efficient MO cooling and degassing take place, producing the atmosphere, is followed by a second quasi steady state where the heat flux balance is dominated by the solar flux. The end of the rapid cooling stage (ERCS) is reached when the mantle heat flux becomes negligible compared to the absorbed solar flux. The resulting surface conditions at ERCS, including water ocean's formation, strongly depend both on the initial volatile content and solar distance D. For D > DC, the “critical distance,” the volatile content controls water condensation and a new scaling law is derived for the water condensation limit. Although today's Venus is located beyond DC due to its high albedo, its high CO2/H2O ratio prevents any water ocean formation. Depending on the formation time of its cloud cover and resulting albedo, only 0.3 Earth ocean mass might be sufficient to form a water ocean on early Venus.

This paper presents an updated version of the simple 1D radiative-convective H2O-CO2 atmospheric model from Marcq [2012] and used by Lebrun et al. [2013] in their coupled interior-atmosphere model. This updated version includes a correction of a major miscalculation of the outgoing longwave radiation (OLR), and extends the validity of the model (P-coordinate system, possible inclusion of N2, improved numerical stability). It confirms the qualitative findings of Marcq [2012], namely (1) the existence of a blanketing effect in any H2O-dominated atmosphere: the outgoing longwave radiation (OLR) reaches an asymptotic value, also known as Nakajima's limit and first evidenced by Nakajima et al. [1992], around 280W/m2 neglecting clouds, significantly higher than our former estimate from Marcq[2012]. (2) The blanketing effect breaks down for a given threshold temperature Tϵ, with a fast increase of OLR with increasing surface temperature beyond this threshold, making extrasolar planets in such an early stage of their evolution easily detectable near 4μm provided they orbit a red dwarf. Tϵ

During accretion, the young rocky planets are so hot that they become endowed with a magma ocean. From that moment, the mantle convective thermal flux control the cooling of the planet and an atmosphere is created by outgassing. This atmosphere will then play a key role during this cooling phase. Studying this cooling phase in details is a necessary step to explain the great diversity of the observed telluric planets and especially to assess the presence of surface liquid water. We used here a radiative-convective 1D atmospheric model (H2O, CO2) to study the impact of the Bond albedo on the evolution of magma ocean planets. We derived from this model the thermal emission spectrum and the spectral reflectance of these planets, from which we calculated their Bond albedos. Compared to Marcq et al. (2017), the model now includes a new module to compute the Rayleigh scattering, and state of the art CO2 and H2O gaseous opacities data in the visible and infrared spectral ranges. We show that the Bond albedo of these planets depends on their surface temperature and results from a competition between Rayleigh scattering from the gases and Mie scattering from the clouds. The colder the surface temperature is, the thicker the clouds are, and the higher the Bond albedo is. We also evidence that the relative abundances of CO2 and H2O in the atmosphere strongly impact the Bond albedo. The Bond albedo is higher for atmospheres dominated by the CO2, better Rayleigh scatterer than H2O. Finally, we provide the community with an empirical formula for the Bond albedo that could be useful for future studies of magma ocean planets., 16 pages, 10 figures, 5 tables. Accepted for publication in the Journal Icarus the 27 August 2018

International audience; After the first sporadic detections of an ozone (O33 volume mixing ratio peaks in the 10 to 20 ppbv range, yielding observable column densities in the 0.1 to 0.5 Dobson units (DU), comparable to nominal values on Mars but much smaller than for Earth ( ∼ 300 DU). These measurements are supported by our 3D-photochemical model coupled with the LMD-IPSL GCM (Lebonnois et al., 2010), which indicates that the ozone layer identified by SPICAV results from downward transport of O2 ( ∼ 50 ppmv) molecules over the poles by the mean meridional circulation. Our findings do not contradict previous upper limits (

Since January 2012 we have been monitoring the behavior of sulfur dioxide and water on Venus, using the Texas Echelon Cross-Echelle Spectrograph (TEXES) imaging spectrometer at the NASA InfraRed Telescope Facility (IRTF, Mauna Kea Observatory). We present here the observations obtained between January 2016 and September 2018. As in the case of our previous runs, data were recorded around 1345 cm−1 (7.4 μm). The molecules SO2, CO2, and HDO (used as a proxy for H2O) were observed, and the cloudtop of Venus was probed at an altitude of about 64 km. The volume mixing ratio of SO2 was estimated using the SO2/CO2 line depth ratios of weak transitions; the H2O volume mixing ratio was derived from the HDO/CO2 line depth ratio, assuming a D/H ratio of 200 times the Vienna Standard Mean Ocean Water (VSMOW). As reported in our previous analyses, the SO2 mixing ratio shows strong variations with time and also over the disk, showing evidence of the formation of SO2 plumes with a lifetime of a few hours; in contrast, the H2O abundance is remarkably uniform over the disk and shows moderate variations as a function of time. We performed a statistical analysis of the behavior of the SO2 plumes, using all TEXES data between 2012 and 2018. They appear mostly located around the equator. Their distribution as a function of local time seems to show a depletion around noon; we do not have enough data to confirm this feature definitely. The distribution of SO2 plumes as a function of longitude shows no clear feature, apart from a possible depletion around 100E–150E and around 300E–360E. There seems to be a tendency for the H2O volume mixing ratio to decrease after 2016, and for the SO2 mixing ratio to increase after 2014. However, we see no clear anti-correlation between the SO2 and H2O abundances at the cloudtop, neither on the individual maps nor over the long term. Finally, there is a good agreement between the TEXES results and those obtained in the UV range (SPICAV/Venus Express and UVI/Akatsuki) at a slightly higher altitude. This agreement shows that SO2 observations obtained in the thermal infrared can be used to extend the local time coverage of the SO2 measurements obtained in the UV range.

Context. Planetary mass and radius data are showing a wide variety in densities of low-mass exoplanets. This includes sub-Neptunes, whose low densities can be explained with the presence of a volatile-rich layer. Water is one of the most abundant volatiles, which can be in the form of different phases depending on the planetary surface conditions. To constrain their composition and interior structure, it is required to develop models that calculate accurately the properties of water at its different phases. Aims. We present an interior structure model that includes a multiphase water layer with steam, supercritical and condensed phases. We derive the constraints for planetary compositional parameters and their uncertainties, focusing on the multiplanetary system TRAPPIST-1, which presents both warm and temperate planets. Methods. We use a 1D steam atmosphere in radiative-convective equilibrium with an interior whose water layer is in supercritical phase self-consistently. For temperate surface conditions, we implement liquid and ice Ih to ice VII phases in the hydrosphere. We adopt a MCMC inversion scheme to derive the probability distributions of core and water compositional parameters Results. We refine the composition of all planets and derive atmospheric parameters for planets b and c. The latter would be in a post-runaway greenhouse state and could be extended enough to be probed by space mission such as JWST. Planets d to h present condensed ice phases, with maximum water mass fractions below 20%. Conclusions. The derived amounts of water for TRAPPIST-1 planets show a general increase with semi-major axis, with the exception of planet d. This deviation from the trend could be due to formation mechanisms, such as migration and an enrichment of water in the region where planet d formed, or an extended CO$_{2}$-rich atmosphere., 11 pages, 7 figures. Accepted by Astronomy & Astrophysics (in press)

Based on the analysis of UV images (at 365 nm) of Venus cloud top (altitude 67 ± 2 km) collected with VMC (Venus Monitoring Camera) on board Venus Express (VEX), it is found that the zonal wind speed south of the equator (from 5°S to 15°S) shows a conspicuous variation (from -101 to -83 m/s) with geographic longitude of Venus, correlated with the underlying relief of Aphrodite Terra. We interpret this pattern as the result of stationary gravity waves produced at ground level by the up lift of air when the horizontal wind encounters a mountain slope. These waves can propagate up to the cloud top level, break there and transfer their momentum to the zonal flow. Such upward propagation of gravity waves and influence on the wind speed vertical profile was shown to play an important role in the middle atmosphere of the Earth by Lindzen [1981], but is not reproduced in the current GCM of Venus atmosphere from LMD. In the equatorial regions, the UV albedo at 365 nm varies also with longitude. We argue that this variation may be simply explained by the divergence of the horizontal wind field. In the longitude region (from 60° to -10°) where the horizontal wind speed is increasing in magnitude (stretch), it triggers air upwelling which brings the UV absorber at cloud top level and decreases the albedo, and vice-versa when the wind is decreasing in magnitude (compression). This picture is fully consistent with the classical view of Venus meridional circulation, with upwelling at equator revealed by horizontal air motions away from equator: the longitude effect is only an additional but important modulation of this effect. This interpretation is comforted by a recent map of cloud top H2O [Fedorova et al., 2015], showing that near the equator the lower UV albedo longitude region is correlated with increased H2O. We argue that H2O enhancement is the sign of upwelling, suggesting that the UV absorber is also brought to cloud top by upwelling.

We present results from a NO airglow inversion method based on Venus Express data acquired from 2006 to 2010, during the last solar minimum period. We retrieve an altitude of 114 ± 10 km for the emission peak of the NO layer, with an associated scale height of 20 ± 10 km and an average limb brightness of 59.3 kR with a standard deviation of 63 kR. The inversion method allows for the quantification of the horizontal homogeneity of the NO layer. Images of the SPICAV field of view show a great variability of airglow morphologies, with NO layers that can be horizontally homogenous and continuous over distances exceeding 100 km, as well as sporadic patches of NO on a smaller horizontal scale. Frequent secondary emissions seen at lower tangent altitudes are the signatures of the complex dynamics of the upper Venusian atmosphere.

International audience; The atmospheric noble gas isotope and elemental bulk ratios on Venus and Earth provide important information on their origin and evolution. If the protoplanets grew to a certain mass (i.e. > 0.5 MEarth), they could have captured H2-dominated primordial atmospheres by accreting gas from the circumstellar disk during the formation of the Solar System, which were then quickly lost by hydrodynamic escape after the disk dissipated. In such a case, the EUV-driven hydrodynamic flow of H atoms dragged heavier elements with it at different rates, leading to changes in their initial isotope ratios. For reproducing Earth and Venus present atmospheric 36Ar/38Ar, 20Ne/22Ne, 36Ar/22Ne, isotope and bulk K/U ratios we applied hydrodynamic upper atmosphere escape and Smooth Particle Hydrodynamics (SPH) impact models for the loss calculations of captured H2-dominated primordial atmospheres for various protoplanetary masses. We investigated a wide range of possible EUV evolution tracks of the young Sun and initial atmospheric compositions based on mixtures of captured nebula gas, outgassed and delivered material from ureilite, enstatite and carbonaceaous chondrites. Depending on the disk lifetime of ≈ 3–5 Myr (Bollard et al., 2017; Wang et al., 2017) and the composition of accreted material after disk dispersal, we find from the reproduction of the present atmospheric Ar, Ne, and bulk K/U ratios, that early Earth's evolution can be explained if proto-Earth had accreted masses between ≈ 0.53 − 0.58 MEarth by the time the nebula gas dissipated. If proto-Earth would have accreted a higher mass during the disk lifetime the present atmospheric Ar and Ne isotope ratios can not be reproduced with our model approach. For masses > 0.75 MEarth, Earth would have had a problem to get get rid of its primordial atmosphere. If proto-Earth accreted ≈ 0.53 − 0.58MEarth of enstatite-dominated material as suggested by Dauphas (2017) during the disk lifetime, it would have captured a tiny primordial atmosphere that was lost ≈ 3 Myr after the disk dissipated. In such a case we find that the present-day atmospheric Ar and Ne isotope ratios can be best reproduced if the post-nebula impactors contained ≈ 5% weakly depleted carbonaceous chondritic material and ≈ 95% enstatite chondrites that are strongly depleted in Ar, Ne and moderately volatile elements like potassium. If higher amounts of carbonaceous chondrites were involved in early Earth's accretion as recently suggested by Schiller et al. (2018), then the Earth's present atmospheric Ar and Ne ratios can only be reproduced if the involved carbonaceous chondritic post-nebula material was also highly depleted in these noble gases and/or had to be partially be delivered as long as the primordial atmosphere was yet escaping. As long as primordial atmospheres surround the growing protoplanets the abundance of their volatile elements is overwritten by their respective captured solar-like atmospheric abundances. Therefore the initial composition of the protoplanets at the disk dispersal time can not be identified by our method. For masses < 0.5 MEarth atmospheric escape cannot explain the present-day ratios, i.e. if Earth grew slower then these ratios have to be explained differently (Marty, 2012). If proto-Venus captured a primordial atmosphere it should have grown to masses of ≈ 0.85− 1.0 MVenus during the time until the disk dissipated and if early Venus accreted its main mass during the disk lifetime than the present atmospheric Ar and Ne isotope ratios and the observed K/U ratios on Venus surface can also be reproduced by the escape of a captured primordial atmosphere that is lost within ≤ 100 Myr, if the Sun was born as a weakly to moderately active young G star. New precise re-measurements of atmospheric noble gases are necessary by future Venus missions to better constrain the material that was involved in the planet's accretion history and possibly also the EUV activity evolution of the young Sun. In addition, measurements of other moderately volatile element and isotope ratios on the surface such as Rb/U, 64Zn/66Zn, and 39K/41K can give an insight on whether Venus accreted slow or fast, i.e. almost to its final mass within the disk lifetime.

The Venus Emissivity Mapper is the first flight instrument designed to focus on mapping the surface of Venus using atmospheric windows around 1 micron. After several years of development, VEM has a mature design with an existing laboratory prototype verifying an achievable instrument SNR of well above 1000, as well as predicted error in retrieval of relative emissivity of better than 1%, assuming the availability of an improved Venus topography. It will provide a global map of rock type, iron contents and redox state of the surface by observing the surface with six narrow band filters, ranging from 0.86 to 1.18 micron. Three additional windows allow corrections for cloud composition and variability, two measure water abundance, and three compensate for stray light. Continuous observation of Venus' thermal emission will also place tighter constraints on current day volcanic activity. Eight of the channels provide measurements of atmospheric water vapor abundance as well as cloud microphysics and dynamics and permit accurate correction of atmospheric interference on the surface data. Combining VEM with a high-resolution radar mapper, such as on the ESA EnVision or NASA VERITAS mission proposals, will provide key insights into the divergent evolution of Venus and Earth.

International audience; Recent observations of sulfur containing species (SO2, SO, OCS, and H2SO4) in Venus’ mesosphere have generated controversy and great interest in the scientific community. These observations revealed unexpected spatial patterns and spatial/temporal variability that have not been satisfactorily explained by models. Sulfur oxide chemistry on Venus is closely linked to the global-scale cloud and haze layers, which are composed primarily of concentrated sulfuric acid. Sulfur oxide observations provide therefore important insight into the on-going chemical evolution of Venus’ atmosphere, atmospheric dynamics, and possible volcanism.This paper is the first of a series of two investigating the SO2 and SO variability in the Venus atmosphere. This first part of the study will focus on the vertical distribution of SO2, considering mostly observations performed by instruments and techniques providing accurate vertical information. This comprises instruments in space (SPICAV/SOIR suite on board Venus Express) and Earth-based instruments (JCMT). The most noticeable feature of the vertical profile of the SO2 abundance in the Venus atmosphere is the presence of an inversion layer located at about 70–75 km, with VMRs increasing above. The observations presented in this compilation indicate that at least one other significant sulfur reservoir (in addition to SO2 and SO) must be present throughout the 70–100 km altitude region to explain the inversion in the SO2 vertical profile. No photochemical model has an explanation for this behaviour. GCM modelling indicates that dynamics may play an important role in generating an inflection point at 75 km altitude but does not provide a definitive explanation of the source of the inflection at all local times or latitudesThe current study has been carried out within the frame of the International Space Science Institute (ISSI) International Team entitled ‘SO2 variability in the Venus atmosphere’.

High-resolution ( R ~ 43 , 000 ) spectroscopic observations of both day and night sides of Venus were acquired using CSHELL at IRTF between 2202 and 2207 cm − 1 (4.53– 4.54 μ m ) during the latest maximal eastern and western elongations of Venus in two four-nights observing runs in August 2012 and November 2013. Their purpose was to investigate the effect of the recent (from 2007 onwards) decrease of sulfur dioxide (SO2) at the cloud top level on the spatial distribution of carbon monoxide (CO), since both species are involved in the mesospheric photochemical cycles. Observations of neighboring CO2 lines are fully consistent with the previously determined aerosol scale height in the 68–74 km range. We could therefore determine CO mixing ratio on both day and night sides of Venus, taking into account both scattered solar and thermal components, as well as the overlying CO dayglow on the day side. CO spatial distribution is mostly unchanged compared to previous measurements, ranging from 25 ppmv to 45 ppmv at 70 km. The scattered solar component reveals an increase in CO with increasing altitude with a scale height of ( 5 ± 0.5 ) km between 70 and 76 km. Horizontal variability is found to be weak, with a possible increase towards higher latitudes on the day side of about 10 ppmv. Yet the accuracy of our absolute values of CO mixing ratio is limited by several assumptions, and we cannot rule out that some of the variability we measure for CO could alternatively be explained by other changes occurring in the Venusian atmosphere, e.g. changes in both dT/dz and aerosol scale height.

International audience; The thermal structure of Venus upper atmosphere (90–140 km) was investigated using stellar occultation measurements acquired by the SPICAV experiment on board Venus Express. The SPICAV ultraviolet channel provides CO2 local density and temperature vertical profiles with a vertical resolution of View the MathML source of both the southern and the northern hemispheres on the nightside (18:00-06:00 hr local time). A permanent layer of warm air is observed at the mesopause in the altitude range 90–100 km. Temperature then decreases with increasing altitude reaching a minimum value around 125 km. Spatial and temporal changes in the thermal structure have been analyzed. Local time variations dominate the structure of Venus atmosphere at these altitudes: temperatures show an increase of View the MathML source on the morning side compared to the evening side. The homopause altitude was also determined; it varies between 119 and 138 km of altitude, increasing from the evening side to the morning side. SPICAV temperature profiles were compared to several literature results from ground-based observations, previous spacecraft missions and the Venus Express mission.

International audience; This paper deals with the composition and chemical processes occurring in the neutral atmosphere of Venus. Since the last synthesis, observers as well as modellers have emphasised the spatial and temporal variability of minor species, going beyond a static and uniform picture that may have prevailed in the past. The outline of this paper acknowledges this situation and follows closely the different dimensions along which variability in composition can be observed: vertical, latitudinal, longitudinal, temporal. The strong differences between the atmosphere below and above the cloud layers also dictate the structure of this paper. Observational constraints, obtained from both Earth and Venus Express, as well as 1D, 2D and 3D models results obtained since 1997 are also extensively referred and commented by the authors. An non-exhaustive list of topics included follows: modelled and observed latitudinal and vertical profiles of CO and OCS below the clouds of Venus; vertical profiles of CO and SO2 above the clouds as observed by solar occultation and modelled; temporal and spatial variability of sulphur oxides above the clouds. As a conclusion, open questions and topics of interest for further studies are discussed.

International audience; The Venus Emissivity Mapper (VEM) is the first flight instrument specially designed with a sole focus on mapping the surface of Venus using the narrow atmospheric windows around 1μm. VEM will provide a global map of surface composition as well as redox state of the surface, providing a comprehensive picture of surface-atmosphere interaction on Venus. In addition, continuous observation of the thermal emission of the Venus will provide tight constraints on current day volcanic activity. These capabilities are complemented by measurements of atmospheric water vapor abundance as well as cloud microphysics and dynamic. Atmospheric data will allow for the accurate correction of atmospheric interference on the surface measurements and represent highly valuable science on their own. A mission combining VEM with a high-resolution radar mapper such as the NASA VOX or the ESA EnVision mission proposals in a low circular orbit will provide key insights in the divergent evolution of Venus.

International audience; Even though a thick atmosphere stands between Venus's cloud top and its surface, recent observations now establish the impact of Venus's topography on its upper atmospheric dynamics. Understanding how this is possible will lead to substantial progress in atmospheric computer models.

International audience; In this paper we present the first night side distribution of SO2 content in Venus’ upper mesosphere (altitudes from 85 to 105 km). The dataset is based on the SPICAV UV stellar occultation experiment which took place onboard ESA's Venus Express (VEX) orbiter in 2006-2014. The UV channel of SPICAV spectrometer detected absorption bands of SO2 and CO2 in the spectral range 180-300 nm with a resolution of 1-2 nm while stellar light was occulted by the mesosphere. Altitude profiles of sulfur dioxide's volume mixing ratio (VMR) could be retrieved in the upper part of the mesosphere covering the whole night side on Venus. In parallel, we have reprocessed the terminator UV solar occultations dataset (Belyaev et al. (2012). Icarus 217, 740-751) in the same altitude range and extended its statistics until 2014. On average the SO2 VMR increases with altitude from 10-30 ppb at 85 km to 100-300 ppb at 100 km in both regimes of occultation. The midnight SO2 abundance appears to be 3-4 times higher than in the terminator region: 150-200 ppbv versus 50 pppv at altitude around 95 km. These new results were compared with the distribution of oxygen atoms, which are tracers of the global subsolar-antisolar (SS-AS) circulation at ∼100 km (the data provided by Soret et al. (2012). Icarus, 217, 849–855). The night time behavior looks similar for SO2 molecules and O atoms with a correlation coefficient Rcorr = 0.73. Moreover, the retrieved SO2 enrichment above 85 km appears to correlate with the density of H2SO4 droplets (Luginin et al., 2016; Icarus 277, 154–170).

International audience; The vertical distribution of sulfur species in the Venus atmosphere has been investigated and discussed in Part I of this series of papers dealing with the variability of SO2 on Venus. In this second part, we focus our attention on the spatial (horizontal) and temporal variability exhibited by SO2. Appropriate data sets – SPICAV/UV nadir observations from Venus Express, ground-based ALMA and TEXES, as well as UV observation on the Hubble Space Telescope – have been considered for this analysis. High variability both on short-term and short-scale are observed. The long-term trend observed by these instruments shows a succession of rapid increases followed by slow decreases in the SO2 abundance at the cloud top level, implying that the transport of air from lower altitudes plays an important role. The origins of the larger amplitude short-scale, short-term variability observed at the cloud tops are not yet known but are likely also connected to variations in vertical transport of SO2 and possibly to variations in the abundance and production and loss of H2O, H2SO4, and Sx.

The lower atmosphere of Venus below the clouds is a transitional region between the relatively calm lowermost scale height and the super-rotating atmosphere in the cloud region and above. Any observational constraint is then welcome to help in the development of general circulation models of Venus, a difficult task considering the thickness of its atmosphere. Starting from a state-of-the-art 3D Venus GCM [Lebonnois et al., 2010], we have included passive tracers in order to investigate the latitudinal variability of two minor gaseous species, carbonyl sulfide (OCS) and carbon monoxide (CO), whose vertical profiles and mixing ratios are known to vary with latitude between 30 and 40 km [Marcq et al., 2008]. The relaxation to chemical equilibrium is crudely parametrized through a vertically uniform timescale τ. A satisfactory agreement with available observations is obtained with 108 s ≲ τCO ≲ 5 * 108 s and 107 s ≲ τOCS ≲ 10 s. These results, in addition to validating the general circulation below the clouds, are also helpful in characterizing the chemical kinetics of Venus' atmosphere. This complements the much more sophisticated chemical models which focus more on thermodynamical equilibrium [Yung et al., 2009; Krasnopolsky, 2007].

[1] The thermal evolution of magma oceans produced by collision with giant impactors late in accretion is expected to depend on the composition and structure of the atmosphere through the greenhouse effect of CO2 and H2O released from the magma during its crystallization. In order to constrain the various cooling timescales of the system, we developed a 1-D parameterized convection model of a magma ocean coupled with a 1-D radiative-convective model of the atmosphere. We conducted a parametric study and described the influences of the initial volatile inventories, the initial depth of the magma ocean, and the Sun-planet distance. Our results suggest that a steam atmosphere delays the end of the magma ocean phase by typically 1 Myr. Water vapor condenses to an ocean after 0.1, 1.5, and 10 Myr for, respectively, Mars, Earth, and Venus. This time would be virtually infinite for an Earth-sized planet located at less than 0.66 AU from the Sun. Using a more accurate calculation of opacities, we show that Venus is much closer to this threshold distance than in previous models. So there are conditions such as no water ocean is formed on Venus. Moreover, for Mars and Earth, water ocean formation timescales are shorter than typical time gaps between major impacts. This implies that successive water oceans may have developed during accretion, making easier the loss of their atmospheres by impact erosion. On the other hand, Venus could have remained in the magma ocean stage for most of its accretion.

International audience; A pulse of sulphur dioxide in Venus's upper atmosphere was observed by the Pioneer Venus spacecraft in the 1970s and 1980s and attributed to volcanism. Recent sulphur dioxide measurements from Venus Express indicate decadal-scale fluctuations in sulphur dioxide above Venus's cloud tops in an atmosphere that is more dynamic than expected.

International audience; SPICAV VIS-IR spectrometer on-board the Venus Express mission measured the H2O abundance above Venus’ clouds in the 1.38 µm band, and provided an estimation of the cloud top altitude based on CO2 bands in the range of 1.4-1.6 μm. The H2O content and the cloud top altitude have been retrieved for the complete Venus Express dataset from 2006 to 2014 taking into account multiple scattering in the cloudy atmosphere. The cloud top altitude, corresponding to unit nadir aerosol optical depth at 1.48 μm, varies from 68 to 73 km at latitudes from 40ºS to 40ºN with an average of 70.2±0.8 km assuming the aerosol scale height of 4 km. In high northern latitudes, the cloud top decreases to 62-68 km. The altitude of formation of water lines ranges from 59 to 66 km. The H2O mixing ratio at low latitudes (20ºS-20ºN) is equal to 6.1±1.2 ppm with variations from 4 to 11 ppm and the effective altitude of 61.9±0.5 km. Between 30º and 50º of latitude in both hemispheres, a local minimum was observed with a value of 5.4±1 ppm corresponding to the effective altitude of 62.1±0.6 km and variations from 3 to 8 ppm. At high latitudes in both hemispheres, the water content varies from 4 to 12 ppm with an average of 7.2±1.4 ppm which corresponds to 60.6±0.5 km. Observed variations of water vapor in 2-3 times on the short timescale appreciably exceed individual measurement errors and could be explained as a real variation of the mixing ratio or/and possible variations of the cloud opacity within the clouds. The maximum of water at lower latitudes supports a possible convection and injection of water from lower atmospheric layers. The vertical gradient of water vapor inside the clouds explains well the increase of water near the poles correlating with the decrease of the cloud top altitude and the H2O effective altitude. On the contrary, the depletion of water in middle latitudes does not correlate with the H2O effective altitude and cannot be completely explained by the vertical gradient of water vapor within the clouds. Retrieved H2O mixing ratio is higher than those obtained in 2.56 μm from VIRTIS-H data [Cottini et al., 2015] at altitudes of 68-70 km which is well consistent with the lower altitudes of water mixing ratio from the 1.38 µm band. Observations for different solar and emission angles allowed to constrain also the average vertical distribution of H2O mixing ratio in the clouds at altitudes of 59-66 km with 2 ppm at 66 km and 7-7.5 ppm at 59-61 km. The water vapor latitudinal-longitudinal distribution does not show any direct correlation with the cloud tops. Yet a strong asymmetry of H2O longitudinal distribution has been observed with a maximum of 7-7.5 ppm from -120º to 30º of longitude and shifted to the southern hemisphere (20ºS-10ºN). To the east, the minimum is observed with values not in excess of 6 ppm and over a wide range of longitudes from 30º to 160º. Bertaux et al. (2015) announced a correlation between the zonal wind pattern in the equatorial region and underlying topography of Aphrodite Terra as the result of stationary gravity waves produced at the ground level near the mountains. The water minimum corresponds to the Aphrodite Terra highlands and can be also associated with the influence of Venus topography. No prominent long-term on the time scale of 8.5 years nor local time variations of water vapor and the cloud top altitude were detected.

International audience; To date, ozone has only been identified in the atmospheres of Earth and Mars. This study reports the first detection of ozone in the atmosphere of Venus by the SPICAV ultraviolet instrument onboard the Venus Express spacecraft. Venusian ozone is characterized by a vertically confined and horizontally variable layer residing in the thermosphere at a mean altitude of 100 km, with local concentrations of the order of 107-108 molecules.cm-3. The observed ozone concentrations are consistent with values expected for a chlorine-catalyzed destruction scheme, indicating that the key chemical reactions operating in Earth's upper stratosphere may also operate on Venus.

Hubble Space Telescope Imaging Spectrograph (HST/STIS) UV observations of Venus' upper cloud tops were obtained between 20N and 40S latitude on December 28, 2010; January 22, 2011 and January 27, 2011 in coordination with the Venus Express (VEx) mission. The high spectral (0.27nm) and spatial (40-60km/pixel) resolution HST/STIS data provide the first direct and simultaneous record of the latitude and local time distribution of Venus' 70-80km SO and SO2 (SOx) gas density on Venus' morning quadrant. These data were obtained simultaneously with (a) VEx/SOIR occultation and/or ground-based James Clerk Maxwell Telescope sub-mm observations that record respectively, Venus' near-terminator SO2 and dayside SOx vertical profiles between ~75 and 100km; and (b) 0.36μm VEx/VMC images of Venus' cloud-tops. Updating the (Marcq, E. et al. [2011]. Icarus 211, 58-69) radiative transfer model SO2 gas column densities of ~2-10μm-atm and ~0.4-1.8μm-atm are retrieved from the December 2010 and January 2011 HST observations, respectively on Venus' dayside (i.e., at solar zenith angles (SZA)x gas densities. On December 28, 2010 SO2 VMR values ~280-290ppb are retrieved between 74 and 81km from the HST and SOIR data obtained near Venus' morning terminator (at SZAs equal to 70° and 90°, respectively); these values are 10× higher than the HST-retrieved January 2011 near terminator values. Thus, the cloud top SO2 gas abundance declined at all local times between the three HST observing dates. On all dates the average dayside SO2/SO ratio inferred from HST between 70 and 80km is higher than that inferred from the sub-mm the JCMT data above 84km confirming that SOx photolysis is more efficient at higher altitudes. The direct correlation of the SOx gases provides the first clear evidence that SOx photolysis is not the only source for Venus' 70-80km sulfur reservoir. The cloud top SO2 gas density is dependent in part on the vertical transport of the gas from the lower atmosphere; and the 0.24μm cloud top brightness levels are linked to the density of the sub-micron haze. Thus, the new results may suggest a correlation between Venus' cloud-top sub-micron haze density and the vertical transport rate. These new results must be considered in models designed to simulate and explore the relationship between Venus' sulfur chemistry cycle, H2SO4 cloud formation rate and climate evolution. Additionally, we present the first photochemical model that uniquely tracks the transition of the SO2 atmosphere from steady to non-steady state with increasing SZA, as function of altitude within Venus' mesosphere, showing the photochemical and dynamical basis for the factor of ~2 enhancements in the SOx gas densities observed by HST near the terminator above that observed at smaller SZA. These results must also be considered when modeling the long-term evolution of Venus' atmospheric chemistry and dynamics.

On the basis of geological evidence, it is often stated that the early martian climate was warm enough for liquid water to flow on the surface thanks to the greenhouse effect of a thick atmosphere. We present 3D global climate simulations of the early martian climate performed assuming a faint young sun and a CO2 atmosphere with pressure between 0.1 and 7 bars. The model includes a detailed radiative transfer model using revised CO2 gas collision induced absorption properties, and a parameterisation of the CO2 ice cloud microphysical and radiative properties. A wide range of possible climates is explored by using various values of obliquities, orbital parameters, cloud microphysic parameters, atmospheric dust loading, and surface properties. Unlike on present day Mars, for pressures higher than a fraction of a bar, surface temperatures vary with altitude because of the adiabatic cooling and warming of the atmosphere when it moves vertically. In most simulations, CO2 ice clouds cover a major part of the planet but greenhouse effect does not exceed +15 K. We find that a CO2 atmosphere could not have raised the annual mean temperature above 0{\deg}C anywhere on the planet. The collapse of the atmosphere into permanent CO2 ice caps is predicted for pressures higher than 3 bar, or conversely at pressure lower than one bar if the obliquity is low enough. Summertime diurnal mean surface temperatures above 0{\deg}C (a condition which could have allowed rivers to form) are predicted for obliquity larger than 40{\deg} at high latitudes but not in locations where most valley networks are observed. In the absence of other warming mechanisms, our climate model results are thus consistent with a cold early Mars scenario in which non climatic mechanisms must occur to explain the evidence for liquid water. In a companion paper by Wordsworth et al., we simulate the hydrological cycle on such a planet., Comment: Icarus, In press. 23 pages, 18 figures

International audience; New measurements of sulfur dioxide (SO2) and monoxide (SO) in the atmosphere of Venus by SPICAV / SOIR instrument onboard Venus Express orbiter provide ample statistics to study the behavior of these gases above Venus' clouds. The instrument (a set of 3 spectrometers) is capable to sound atmospheric structure above the clouds in several observation modes (nadir, solar and stellar occultations) either in the UV or in the near IR spectral ranges. We present the results from solar occultations in the absorption ranges of SO2 (190-230 nm, and at 4 μm) and SO (190-230 nm). The dioxide was detected by the SOIR spectrometer at the altitudes of 65-80 km in the IR and by the SPICAV spectrometer at 85-105 km in the UV. The monoxide's absorption was measured only by SPICAV at 85-105 km. We considered 39 sessions of solar occultation, where boresights of both spectrometers are oriented identically, to provide full vertical profiling of SO2 of the Venus' mesosphere (65-105 km). Here we report the first firm detection and measurements of two SO2 layers. In the lower layer SO2 mixing ratio is within 0.02-0.5 ppmv. The upper layer, also conceivable from microwave measurements by Sandor et al. (2010) is characterized by SO2 increasing with the altitude from 0.05 to 2 ppmv, and the [SO2]/[SO] ratio varying from 1 to 5. The presence of the high-altitude SOx species could be explained by H2SO4 photodissociation under certain temperature conditions in Venus mesosphere. At 90-100 km the content of the sulfur dioxide correlates with temperature increasing from 0.1 ppmv at 165-170 K to 0.5-1 ppmv at 190-192 K. It supports the hypothesis of SO2production by the evaporation of H2SO4 from droplets and its subsequent photolysis at around 100 km.

[1] In order to understand the early history of telluric interiors and atmospheres during the ocean magma stage, a coupled interior-atmosphere-escape model is being developed. This paper describes the atmospheric part and its first preliminary results. A unidimensional, radiative-convective, H2O-CO2 atmosphere is modeled following a vertical T(z) profile similar to Kasting (1988) and Abe and Matsui (1988). Opacities in the thermal IR are then computed using a k-correlated code (KSPECTRUM), tabulated continuum opacities for H2O-H2O and CO2-CO2 absorption, and water or sulphuric acid clouds in the moist convective zone (whenever present). The first results show the existence of two regimes depending on the relative value of the surface temperature Ts compared to a threshold temperature Tc depending on the total gaseous inventory. For Ts Tc, the blanketing is not efficient enough to prevent large radiative heat loss to space through a hot, cloudless atmosphere. Our current calculations may underestimate the thermal flux in the case of hot surfaces with little gaseous content in the atmosphere.

International audience; The chemical regimes in the atmosphere of Venus vary from photochemistry in the middle atmosphere to thermal equilibrium chemistry in the lower atmosphere and the surface. Many chemical cycles have been proposed, but few details about these cycles are fully verified by comparison between observations and modeling. Recent high-quality data of carbonyl sulfide (OCS) and CO from ground-based and Venus Express observations provide a unique opportunity to test our understanding of chemistry and transport in the lower atmosphere of Venus. The spatial distributions of OCS and CO in the atmosphere reflect a sensitive balance between chemistry and transport. On the basis of our updated photochemical model and winds from Lee et al.'s (2007) general circulation model, we study the chemistry and transport in a simplified two-dimensional chemistry-transport model. OCS is produced by heterogeneous reactions on the surface; the middle atmosphere is a net sink for OCS. The combination of data and modeling provides strong evidence for the loss of OCS by conversion to CO. The detailed chemical mechanism is currently unknown, although a number of speculations have been proposed. The sensitivity of the distributions of OCS and CO to model parameters is reported.

International audience; The high-resolution channel (R $\simeq$ 2000) of the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) instrument (VIRTIS-H) aboard Venus Express has provided numerous spectra of the nightside infrared thermal emission in the 2.3-μm window. Mixing ratios of various minor species in the 30-40 km range could therefore be inferred using this spectral window at higher latitudes accessible to the spacecraft but which cannot be observed from Earth. The previously known enhancement in carbon monoxide (CO) toward high latitudes is confirmed and extended up to 60° with a mixing ratio varying from 24 +/- 3 to 31 +/- 2 ppmv at 36 km. Measurements of carbonyl sulfide (OCS) also agree with the previously suspected latitudinal variations that are anticorrelated with those of CO, ranging between 2.5 +/- 1 and 4 +/- 1 ppmv at 33 km. New constraints were also derived on the mean abundance of water vapor (H2O, 31 +/- 2 ppmv) and sulfur dioxide (SO2, 130 +/- 50 ppmv) in the probed altitude range. CO and OCS variations are interpreted as caused by large-scale vertical motions, an explanation under current testing by various chemical and dynamical modeling. In such a case, these variations may help constrain the chemical time scale of those species in the lower troposphere.

We present an investigation of the lower atmosphere in the 25–40 km altitude range from data of Venus’ night side in the 2.3- μ m region. We used observations recorded at the NASA/IRTF in August 2004 with the SpeX spectro-imager. The previous conclusions of Marcq et al. [2005, Latitudinal variations of CO and OCS in the lower atmosphere of Venus from near-infrared nightside spectro-imaging, Icarus 179, 375–386] about CO and OCS abundance latitudinal variations are confirmed with a better accounting for cloud opacity variations; in particular, an enhancement of 12 ± 4 % in CO at 36 km is found at 40 ∘ S with respect to the equator. There is also a depletion of OCS southward of 20 ∘ S, that may be correlated with the CO increase. Information on the vertical gradients of the CO and OCS profiles was derived, yielding the following mixing ratios in the probed altitude range: CO ( 30 km ) = 22.5 ± 3.5 ppm , CO ( 36 km ) = 24 ± 2 ppm ; OCS ( 30 km ) = 5 – 20 ppm , OCS ( 36 km ) = 0.55 ± 0.15 ppm . The study was also extended to H 2 O and no latitudinal variations are found beyond our error bars ( 26 ± 4 ppm at 35 km ).

International audience; Spectro-imaging of Venus' nightside in the 2.3-μm window provides a powerful means of probing the lower atmosphere in the 25–40 km altitude range. We present observations recorded at the NASA/IRTF in February 2003 and August 2004, using the SpeX spectro-imager in the 2.1–2.5-μm region. Abundances of CO and OCS have been derived as a function of latitude for different longitudes. The CO abundance increases by about 15% between the equatorial region and higher latitudes (±40°). No longitudinal or temporal variations are observed. The OCS abundance shows the opposite variation in observational sets with sufficient S/N. These variations and anticorrelation are consistent with upwelling motions in the equatorial region and downwelling at higher latitudes.

Earth has had oceans for nearly four billion years and Mars had lakes and rivers 3.5-3.8 billion years ago. However, it is still unknown whether water has ever condensed on the surface of Venus because the planet - now completely dry - has undergone global resurfacing events that obscure most of its history. The conditions required for water to have initially condensed on the surface of Solar System terrestrial planets are highly uncertain, as they have so far only been studied with one-dimensional numerical climate models that cannot account for the effects of atmospheric circulation and clouds, which are key climate stabilizers. Here we show using three-dimensional global climate model simulations of early Venus and Earth that water clouds - which preferentially form on the nightside, owing to the strong subsolar water vapour absorption - have a strong net warming effect that inhibits surface water condensation even at modest insolations (down to 325 W/m2, that is, 0.95 times the Earth solar constant). This shows that water never condensed and that, consequently, oceans never formed on the surface of Venus. Furthermore, this shows that the formation of Earth's oceans required much lower insolation than today, which was made possible by the faint young Sun. This also implies the existence of another stability state for present-day Earth: the 'Steam Earth', with all the water from the oceans evaporated into the atmosphere., Comment: Published in Nature (13 October 2021)

Based on experience gained from using the VIRTIS instrument on Venus Express to observe the surface of Venus and the new high temperature laboratory experiments, we have developed the multispectral Venus Emissivity Mapper (VEM) to study the surface of Venus. VEM imposes minimal requirements on the spacecraft and mission design and can therefore be added to any future Venus mission. Ideally, the VEM instrument will be combined with a high-resolution radar mapper to provide accurate topographic information, as it will be the case for the NASA Discovery VERITAS mission or the ESA EnVision M5 proposal.