1. High and ultra-stable energy storage from all-carbon sodium-ion capacitor with 3D framework carbon as cathode and carbon nanosheet as anode
- Author
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Wenlong Shao, Cheng Liu, Xigao Jian, Siyang Liu, Ce Song, Guipeng Yu, Shengming Li, Fangyuan Hu, and Tianpeng Zhang
- Subjects
Materials science ,Heteroatom ,Energy Engineering and Power Technology ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Capacitance ,Cathode ,Energy storage ,0104 chemical sciences ,Anode ,law.invention ,Capacitor ,Fuel Technology ,chemistry ,Chemical engineering ,law ,Electrochemistry ,0210 nano-technology ,Carbon ,Energy (miscellaneous) ,Nanosheet - Abstract
Sodium-ion capacitors (SICs) are extremely promising due to the combined merits of high energy-power characteristics and considerable price advantage. However, it is still difficult to achieve high energy-power outputs and cycle stability in a typical configuration of the metal-based battery-type anode and activated carbon capacitor-type cathode due to the kinetic mismatching. In this work, a carbon nanosheet (PSCS-600) with large interlayer spacing of 0.41 nm derived from the bio-waste pine cone shell was prepared. Besides, the covalent triazine framework derived carbon (OPDN-CTF-A) was obtained through ionothermal synthesis strategy, exhibiting beneficial hierarchical pores (0.5–6 nm) and high heteroatoms (5.6 at% N, 6.6 at% O). On this basis, the all-carbon SICs were fabricated by the integration of PSCS-600 anode and OPDN-CTF-A cathode. The device delivered high energy density 111 Wh kg−1, high power output of 14,200 W kg−1 and ultra-stable cycling life (∼90.7% capacitance retention after 10,000 cycles). This work provides new ideas in fabricating carbon-carbon architectural SICs with high energy storage for practical application.
- Published
- 2021
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