Search

We compare the contact characteristics for Mo, Pd, and Ti on n-InGaAs layer with a range of active donor concentration from $1.6 \times 10^{18}$ cm−3 to $4.8 \times 10^{19}$ cm−3. The Fermi level pinning of 0.18 eV lower than the bottom of n-InGaAs conduction band is experimentally manifested. It is also revealed that the contact resistivity ( $\rho _{\text {c}}$ ) of Mo/n-InGaAs contact clearly outperforms after annealing. However, for the first time, we demonstrate that the Mo/Pd (2nm)/n-InGaAs contact can achieve a $\rho _{\text {c}}~35$ % and 20% lower than a single Mo/n-InGaAs contact after annealing at 400 °C and 450 °C for 1min, respectively.

Herein, the carrier lifetime in approximately 5x10^16 cm^(-3) n-doped In(x)Ga(1-x)As layers is studied by diode current–voltage analysis and by time-resolved photoluminescence. Two sets of hetero-epitaxial layers are grown on semi-insulating InP or GaAs substrates. The first set corresponds with a constant In content p + n stack, while the second set has a fixed x = 0.53 for the n-layer, while containing various extended defect densities by using a strain relaxed buffer with different x. This results in threading dislocation densities (TDDs) between approximately 10^5 cm^(-2) and a few 10^9 cm^(-2). It is shown that the overall trend of the recombination lifetime versus TDD can be described by a first-order model considering a finite recombination lifetime value inside a dislocation core of 1 nm. For the generation lifetime, a strong electric-field enhancement factor is found. Also, the residual strain in the n-layer has an impact. Overall, the safe limit for TDD depends on the type of application and on the operation conditions (reverse diode bias).

The increasing scientific and industry interest in 2D MX

In this paper we review the details and results of the replacement fin process technique used to successfully demonstrate InGaAs based channel devices from FinFets to ultra scaled nanowires on 300 mm Si substrates. For FinFet devices a Mg p-type doping solution was developed to counteract the unintentional n-type doping of the InP buffer layer which resulted in high source-drain leakage. However, the performance of these devices is found to be limited by the Mg doping as the mobility is degraded. By switching to a GAA architecture the problem of source-leakage through the InP buffer is effectively eliminated and best devices with L G = 60 nm have a peak transconductance of 1030 μS/μm with a SS SAT of 125 mV/dec are achieved. A comparison of gate first to gate last processing highlights the importance of using a low thermal budget process to maintain the integrity of the InGaAs/high- k interface. Nanowires with a diameter of 6 nm were demonstrated to show quantization induced immunity to D it resulting in a SS SAT as low as 66 mV/dec for 85 nm L G devices.

We study in this paper the epitaxial growth and electrical characterization of an n+In 0.5 Ga 0.5 As/p+GaAs 0.5 Sb 0.5 Esaki diode lattice matched to (001)-oriented InP substrate. First, the effects of molecular beam epitaxy growth temperature and group-V growth rates on the GaAs x Sb 1− x composition are characterized by means of X-ray diffraction (XRD). It is found that GaAs x Sb 1− x lattice constant is mainly determined by the Sb 4 incorporation rather than the As 4 one. After optimization, high quality In 0.54 Ga 0.46 As(Si)/GaAs 0.52 Sb 0.48 (Be) heterostructure is confirmed by XRD, Transmission electron microscope (TEM) and Secondary Ion Mass Spectroscopy (SIMS) profiles meeting requirements for sub-60 mV/dec operating devices. Esaki tunnel diodes are then fabricated to be used as a prediction of Band-To-Band Tunneling (BTBT) for Tunnel Field-Effect transistors (TFETs). The results are compared to previously reported n+/p+In 0.5 Ga 0.5 As homojunction diodes, showing a ×60 factor improvement of BTBT current density for the same electric field with an excellent average Peak-to-Valley Current Ratio (PVCR) of 14.

New materials and device architectures will be needed to extend CMOS scaling.High mobility materials in the channel can boost the performance at scaled supply voltage.Ultimate reduction of power dissipation will require new concepts like Tunnel FET.Vertical devices and 3D stacking allow to further downscale the transistor dimensions. In this work, we will give an overview of the innovations in materials and new device concepts that will be needed to continue Moore's law to the sub-10nm technology nodes. To meet the power and performance requirements high mobility materials in combination with new device concepts like tunnel FETs and gate-all-around devices will need to be introduced. As the density is further increased and it becomes increasingly difficult to put contacts, spacers and gate in the available gate pitch, disruptive integration schemes such as vertical transistors and monolithic 3D integration might lead the way to the ultimate scaling of CMOS.

The aim of this review paper is to describe the impact of so-called border traps (BTs) in high- k gate oxides on the operation and reliability of high-mobility channel transistors. First, a brief summary of the physics of BTs will be given, describing the charge trapping and release in terms of the elastic tunneling model. It will be also pointed out how information on the BT properties can be extracted from popular measurement techniques such as low-frequency (1/f) noise and variable-frequency charge pumping. In the next two parts, the impact of BTs on metal-oxide-semiconductor structures fabricated on Ge or III-V channel materials is outlined, with particular emphasis on the development of novel or adapted measurement techniques such as AC transconductance dispersion or trap spectroscopy by charge injection and sensing. Finally, the effect of BTs on the operation and reliability of high-mobility channel MOSFETs is discussed. It is also shown that the density of BTs is closely linked to the quality or defectivity of the high- k gate stack, indicating room for improvement by optimization of processing or by implementation of a suitable bulk-oxide defect passivation step.

The semiconductor ICT industry continues its neverending pursuit of new approaches for fabricating integrated circuits to reduce device cost and improve device performance. For future device generations, many different approaches are considered, for which the efficient engineering of new materials and architectures are the main challenge to improve device performance. InP is one of these new materials, which is considered to be used as virtual substrate for III-V based nMOS devices.

In this letter, we present the first InGaAs gate-all-around (GAA) nanowire devices fabricated on 300mm Si substrates. For an \(L_{\mathrm {\mathbf {G}}}\) of 60 nm an extrinsic \(g_{\mathrm {\mathbf {m}}}\) of \(1030~\mu \) S \(/\mu \) m at \(V_{\mathrm {\mathbf {ds}}} = 0.5\) V is achieved which is a \(1.75\times \) increase compared with the replacement fin FinFet process. This improvement is attributed to the elimination of Mg counterdoping in the GAA flow. Ultrascaled nanowires with diameters of 6 nm were demonstrated to show immunity to \(D_{\mathrm {{it}}}\) resulting in an SS \(_{\mathrm {{SAT}}}\) of 66 mV/decade and negligible drain-induced barrier lowering for 85-nm \(L_{\mathrm {{G}}}\) devices.

We introduce an ac transconductance dispersion method (ACGD) to profile the oxide traps in an MOSFET without needing a body contact. The method extracts the spatial distribution of oxide traps from the frequency dependence of transconductance, which is attributed to charge trapping as modulated by an ac gate voltage. The results from this method have been verified by the use of the multifrequency charge pumping (MFCP) technique. In fact, this method complements the MFCP technique in terms of the trap depth that each method is capable of probing. We will demonstrate the method with InP passivated InGaAs substrates, along with electrically stressed Si N-MOSFETs.

© 2015 AIP Publishing LLC. Metrology for structural and electrical analyses at device level has been identified as one of the major challenges to be resolved for the sub-14 nm technology nodes. In these advanced nodes, new high mobility semiconductors, such as III-V compounds, are grown in narrow trenches on a Si substrate. Probing the nature of the defects, the defect density, and the role of processing steps on the surface of such structures are prime metrology requirements. In order to enable defect analysis on a (III-V) surface, a proper sample preparation for oxide removal is of primary importance. In this work, the effectiveness of different chemical cleanings and thermal annealing procedures is investigated on both blanket InP and oxide embedded InP trenches by means of scanning probe microscopy techniques. It is found that the most effective approach is a combination of an HCl-based chemical cleaning combined with a low-temperature thermal annealing leading to an oxide free surface with atomically flat areas. Scanning tunneling microscopy (STM) has been the preferred method for such investigations on blanket films due to its intrinsic sub-nm spatial resolution. However, its application on oxide embedded structures is non-trivial. To perform STM on the trenches of interest (generally

Extended abstract of a paper presented at Microscopy and Microanalysis 2009 in Richmond, Virginia, USA, July 26 – July 30, 2009

We use an improved AC conductance method and a modified Gray-Brown method to study fast interface traps and slow border traps in Ge-based MOS capacitors. The combined methods provide the corrected Fermi energy level (E) versus gate voltage (Vg) relationship, even in samples with high densities of traps that cause significant C-V distortion, the energy distribution of interface traps, their capture cross sections (σ), as well as slow border traps. A wide range of σ’s in p-type Ge is found, indicating that there is more than one type of interface trap near the Ge valence band edge. In contrast, a constant σ near the Ge conduction band edge is observed in n-type Ge. XPS results indicate that Ge suboxides near the interface are accountable for the detected slow border traps.

Tuning the desorption temperature of an As cap layer allows to achieve In0.53Ga0.47As(001) surfaces with (2 x 4) and (4 x 2) reconstructions which exhibit different chemical reactivity upon exposure in atmospheric pressure. Trimethyl-Al based atomic layer deposition of Al2O3 films on the two exposed surfaces causes a non-equivalent interface composition. This behavior is associated with a worse electrical quality of the interface with the exposed (4 x 2) In0.53Ga0.47As reconstruction. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3659688] We acknowledge grant from ARAMIS Project and M. Alia (MDM) for metal gate deposition

In this letter, we propose an atmospheric pressure-chemical vapor deposition technique to grow metastable GeSn epitaxial layers on Ge. We report the growth of defect free fully strained undoped and in-situ B doped GeSn layers on Ge substrates with Sit contents up to 8%. Those metastable layers stay fully strained after 30 min anneal in N-2 at 500 degrees C.; Ge-Sn interdiffusion is seen at 500 degrees C but not at lower temperature. B is 100% active in the in-situ GeSn:B layers up to a concentration of 1.7 x 10(19) cm(-3). GeSn:B provides slightly lower Hall hole mobility values than in pure p-type Ge especially for low B concentrations. (C) 2011 American Institute of Physics [doi.10.1063/1.3645620]

The efficiency of the ammonium sulfide vapor (ASV) treatment, as opposed to the wet treatment in the liquid ammonium sulfide solution, on the performance improvement of the In0.53Ga0.47As surface-channel as well as InP-capped buried-channel metal-oxide-semiconductor field-effect-transistors (MOSFET) was demonstrated for the first time. MOSFETs were fabricated with either HCl or ASV surface treatments prior to the gate oxide deposition. ASV treatment was found to be very efficient in boosting the drive current of the transistors compared to that of the HCl treatment. It was also found that the ASV treatment leads to a lower border trap density and slightly higher oxide/semiconductor interface defect density compared to that of the HCl treatment. X-ray photoelectron spectroscopy (XPS) studies of In0.53Ga0.47As native oxide regrowth after both surface treatments identified indium sub-oxides as a possible cause of the performance degradation of the HCl treated devices. Based on this work, ASV treatment could be an efficient solution to the passivation of III-V surfaces. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3638492] The authors acknowledge the European Commission for financial support in the DualLogic project no. 214579. Further, we thank the IMEC core partners within the IMEC’s Industrial Affiliation Program on Logic/Ge-III/V.

Experiments on internal photoemission of electrons from Si and TiNx into thin Al2O3 layers suggest that crystallization of amorphous Al2O3 to the cubic γ-Al2O3 is accompanied by only a ≈ 0.5 eV upshift of the conduction band bottom edge. As it is known that in transforming from the amorphous to the γ-phase, the bandgap of Al2O3 increases from 6.2 eV to 8.7 eV, more than 80% of this gap widening must occur at the VB side of the gap. The latter suggests that interaction between electron states of O anions plays the dominant role in the oxide gap widening.