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[Display omitted] • The first efficient ligand free iron-catalyzed hydroaminocarbonylation of alkynes to produce succinimides with NH 4 HCO 3 as the ammonia source. • With NH 4 HCO 3 as easy-to-handle ammonia source, a variety of internal and terminal alkynes were well tolerated in this catalytic system. • Preliminary mechanistic studies reveal the activation model involving interactions of NH 4 HCO 3 with both iron catalyst and alkyne substrates. Succinimide derivatives are valuable compounds in synthesis of natural products and pharmaceuticals. A catalytic hydroaminocarbonylation reaction was developed for the synthesis of succinimides from alkynes, CO and NH 4 HCO 3. The novel transformation proceeds in the presence of Fe 3 (CO) 12 without the need for expensive ligands or additives. Various substituted alkynes are selectively transformed into corresponding succinimides in good yields. Preliminary mechanistic studies suggest that NH 4 HCO 3 plays an important role in the formation and stabilization of iron catalyst. [ABSTRACT FROM AUTHOR]

Catalytic carbonylations of alkynes represent straightforward and atom-economic synthesis of α,β-unsaturated carbonyl compounds. One of the issues associated with the currently known catalytic systems is insufficient efficiency. In this context, Pd/ligand-catalyzed regioselective and efficient alkoxycarbonylation of terminal alkynes is desirable for the synthesis of α,β-unsaturated esters. Herein, we present the use of a newly designed bifunctional ligand for efficient Pd-catalyzed alkoxycarbonylation of alkynes. Both aliphatic and aromatic alkynes were smoothly transformed to the branched desired products with high selectivity (28 examples, 45–96% yields, 95.0–99.9% selectivity). [ABSTRACT FROM AUTHOR]