1. Hetero-Nanonet Rechargeable Paper Batteries: Toward Ultrahigh Energy Density and Origami Foldability.
- Author
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Cho, Sung‐Ju, Choi, Keun‐Ho, Yoo, Jong‐Tae, Kim, Jeong‐Hun, Lee, Yong‐Hyeok, Chun, Sang‐Jin, Park, Sang‐Bum, Choi, Don‐Ha, Wu, Qinglin, Lee, Sun‐Young, and Lee, Sang‐Young
- Subjects
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STORAGE batteries , *PROPERTIES of matter , *ION transport (Biology) , *ACTIVE biological transport , *DYNAMICS - Abstract
Forthcoming smart energy era is in strong pursuit of full-fledged rechargeable power sources with reliable electrochemical performances and shape versatility. Here, as a naturally abundant/environmentally friendly cellulose-mediated cell architecture strategy to address this challenging issue, a new class of hetero-nanonet (HN) paper batteries based on 1D building blocks of cellulose nanofibrils (CNFs)/multiwall carbon nanotubes (MWNTs) is demonstrated. The HN paper batteries consist of CNF/MWNT-intermingled heteronets embracing electrode active powders (CM electrodes) and microporous CNF separator membranes. The CNF/MWNT heteronet-mediated material/structural uniqueness enables the construction of 3D bicontinuous electron/ion transport pathways in the CM electrodes, thus facilitating electrochemical reaction kinetics. Furthermore, the metallic current collectors-free, CNF/MWNT heteronet architecture allows multiple stacking of CM electrodes in series, eventually leading to user-tailored, ultrathick (i.e., high-mass loading) electrodes far beyond those accessible with conventional battery technologies. Notably, the HN battery (multistacked LiNi0.5Mn1.5O4 (cathode)/multistacked graphite (anode)) provides exceptionally high-energy density (=226 Wh kg−1 per cell at 400 W kg−1 per cell), which surpasses the target value (=200 Wh kg−1 at 400 W kg−1) of long-range (=300 miles) electric vehicle batteries. In addition, the heteronet-enabled mechanical compliance of CM electrodes, in combination with readily deformable CNF separators, allows the fabrication of paper crane batteries via origami folding technique. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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