1. Polymeric Semiconductors with a Pre-Specified Alternation of Conjugated Bonds and Metal Clusters
- Author
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Alexei R. Khokhlov, Alek R. Tameev, A. V. Vannikov, Boris L. Tsetlin, Alexandr V. Vlasov, and V. N. Golubev
- Subjects
Conductive polymer ,Polymers and Plastics ,Chemistry ,business.industry ,Organic Chemistry ,Alternation (geometry) ,Chemical modification ,Conjugated system ,Crystallography ,Semiconductor ,Electrical resistivity and conductivity ,Polyamide ,Polymer chemistry ,Materials Chemistry ,business ,Metal clusters - Abstract
In this work the first samples of polymeric semi-conductors of a new structure are produced. Their electric conductivity is of the order ∼10 -2 Ohm -1 . cm -1 and it increases with temperature. Their synthesis includes a stage of radiation grafting of a matrix-type on stretched polyamide films. Conducting molecular circuits in such materials include fragments with conjugated bonds and metal clusters. The alternation of these fragments is determined by the polyamide matrix.
- Published
- 2004
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